• Economic and Environmental Geology
• /
• v.38 no.4 s.173
• /
• pp.451-462
• /
• 2005

In order to examine the extent of environmental contamination at abandoned Samsanjeil Cu mines in Kosung-kun, Kyeongsangnam-do, we have investigated the contaminations and mobility of toxic trace elements from mine wastes including about 280,000 tonnages of tailings by chemical experiments (total extraction, partial extraction by 0.1N HCI and sequential extraction procedure). Total concentrations of trace elements showed that Cu, As, Co, Zn, Pb, and Cd concentrations in tailings were 14.0, 3.6, 3.1, 2.1, 2.1 and 1.6 times greater than those in background soil, respectively. From the proportion of metals bound to the exchangeable and carbonate fractions, the comparative mobility of metals decrease in order of $Zn(29.0\%)>Cu(12.3\%)Pb(9.6\%)>Cd(3.0\%)>As=Co(0.0\%)$. Based on the concentrations, chemical speciations of tailings, waste rock and nearby soil, it was revealed that Cu and Zn were the most possible elements to contaminate the surrounding environment in Samsanjeil mine area. In addition, the tailings had total trace metal concentrations below Dutch guideline values except Cu, and they might not affect adverse impact on environment.

• Journal of Animal Science and Technology
• /
• v.65 no.1
• /
• pp.132-148
• /
• 2023

Ruminants are the main contributors to methane (CH₄), a greenhouse gas emitted by livestock, which leads to global warming. In addition, animals experience heat stress (HS) when exposed to high ambient temperatures. Organic trace minerals are commonly used to prevent the adverse effects of HS in ruminants; however, little is known about the role of these minerals in reducing enteric methane emissions. Hence, this study aimed to investigate the influence of dietary organic trace minerals on rumen fermentation characteristics, enteric methane emissions, and the composition of rumen bacteria and methanogens in heat-stressed dairy steers. Holstein (n=3) and Jersey (n=3) steers were kept separately within a 3×3 Latin square design, and the animals were exposed to HS conditions (Temperature-Humidity Index [THI], 82.79 ± 1.10). For each experiment, the treatments included a Control (Con) consisting of only basal total mixed rations (TMR), National Research Council (NRC) recommended mineral supplementation group (NM; TMR + [Se 0.1 ppm + Zn 30 ppm + Cu 10 ppm]/kg dry matter), and higher concentration of mineral supplementation group (HM; basal TMR + [Se 3.5 ppm + Zn 350 ppm + Cu 28 ppm]/kg dry matter). Higher concentrations of trace mineral supplementation had no influence on methane emissions and rumen bacterial and methanogen communities regardless of breed (p > 0.05). Holstein steers had higher ruminal pH and lower total volatile fatty acid (VFA) concentrations than Jersey steers (p < 0.05). Methane production (g/d) and yield (g/kg dry matter intake) were higher in Jersey steers than in Holstein steers (p < 0.05). The relative abundances of Methanosarcina and Methanobrevibacter olleyae were significantly higher in Holstein steers than in Jersey steers (p < 0.05). Overall, dietary organic trace minerals have no influence on enteric methane emissions in heat-stressed dairy steers; however, breed can influence it through selective alteration of the rumen methanogen community.

• Asian-Australasian Journal of Animal Sciences
• /
• v.23 no.1
• /
• pp.90-97
• /
• 2010

An experiment was conducted to evaluate the effects of low concentrations of organic and inorganic dietary trace minerals on broiler performance and trace mineral digestibility along the small intestine of 35-day-old broiler chickens reared under floor-pen conditions. Eight hundred male, day-old Cobb broiler chickens were randomly allocated to 4 dietary treatments (25 birds per pen with 8 replicates per treatment). Broilers fed diets supplemented with 4, 20, 40 and 30 mg/kg, respectively, of Cu, Fe, Mn and Zn from organic chelates and inorganic salts achieved the same body weight gain as those supplemented at the NRC levels (8 mg Cu, 40 mg Fe, 60 mg Mn and 40 mg Zn/kg, respectively) from inorganic salts. However, birds fed a control diet without any supplementation at dietary levels of 7.4-8.8, 60.1-69.2, 14.6-15.4 and 19.1-20.6 mg/kg of Cu, Fe, Mn and Zn, respectively, had decreased feed intake and growth rate. There was no significant difference in the digestibility of Cu in all regions of the small intestine. Throughout the small intestine the apparent absorption of Mn from both organic and inorganic sources was small, whereas the digestibility of Zn seemed to be more complex, exhibiting differences in the apparent absorption due to both mineral source and intestinal site. Therefore, the digestibility of organic Zn was improved (p<0.01) in the ileum compared to inorganic Zn. The digestibility of Zn in the duodenum was smaller (p<0.05) than that in the ileum.

• Ocean and Polar Research
• /
• v.41 no.3
• /
• pp.169-181
• /
• 2019

The purpose of this study is to develop geochemical tracers to identify a specific source desert of mineral dust in China using the published data. In addition, we tested the applicability of these tracers to wet-deposits and soil samples collected in Jeju, Korea. Because of similarity in trace elemental compositions of mineral dust from the major arid regions in China, such as Taklimakan, West Ordos (Badain Jaran), East Ordos (Mu Us and Hobq), East Northern China (Horqin), West Northern China (Gurbantunggut), and Chinese Loess Plateau, there has been limited to the use of geochemical data for source identification. Here we propose the four (4) plots using combination of seven (7) geochemical variables as a source indicator to distinguish one from other source regions in China: $\frac{Y}{Tb_N}$ vs. $\frac{Th}{{\Sigma}REE_N}$, $\(\frac{La}{Gd}\)_N$ vs. $\frac{Y}{{\Sigma}REE_N}$, $\frac{Th}{Tb_N}$ vs. $\frac{Y}{Nd_N}$, and $\frac{Th}{Tb_N}$ vs. $\(\frac{Ce}{Ce}\)_N^*$, where $_N$ and $\(\frac{Ce}{Ce}\)_N^*$ stand for values normalized to Post-Archean Average Shale composition and Ce anomaly, respectively. Mineral dusts from aforementioned six major deserts are distinguished one from the others by the combined use of these variables. Jeju rock and soil samples form a separate domain from Chinese mineral dusts in all four plots. In contrast, most of Jeju dust samples were comparable with the West Ordos desert (Badain Jaran) domain, indicative of strong influence of Badain Jaran dust in Jeju in spring season when the mineral dust was collected. A weak positive Ce anomaly in Jeju samples implies minimal local contribution. Our study suggests that the combination of $\frac{Y}{Tb_N}$ vs. $\frac{Th}{{\Sigma}REE_N}$, $\(\frac{La}{Gd}\)_N$ vs. $\frac{Y}{{\Sigma}REE_N}$, $\frac{Th}{Tb_N}$ vs. $\frac{Y}{Nd_N}$, and $\frac{Th}{Tb_N}$ vs. $\(\frac{Ce}{Ce}\)_N^*$ can be used to identify a specific source region of mineral dust in China as well as Jeju mineral particles.

• Journal of Applied Biological Chemistry
• /
• v.49 no.4
• /
• pp.154-156
• /
• 2006

Trace metals in honey have an influence on the taste of honey along with pollens. Western bee honeys, which are mostly collected from acacia, have less than 0.1% of ash. Savor of Korean native-bee honey is thought to be due to the difference of the contents of trace metals. Korean native-bee honeys collected from Jirisan District, which is the greatest producing area of native-bee honey in Korea, showed high contents of ash. Korean native-bee honeys from the districts other than Jirisan District also showed similar results($0.44{\sim}0.83%$ of ash) to those from Jirisan District. Potassium was found to be the principal factor of high content of ash with over 85% of trace metals in ash.

• Economic and Environmental Geology
• /
• v.41 no.4
• /
• pp.405-425
• /
• 2008

In order to investigate the amounts of trace elements flowing into reservoir, and to elucidate the relationship between trace element mobility and fraction size, the stream water and sediment samples were collected from thirty-two sites of the 3rd or 4th order stream within watershed surrounding the Juam reservoir. Chemical analyses of trace elements (As, Cd, Cr, Cu, Ni, Pb and Zn) for all samples were completed, and additionally cationi and anion for stream water samples. Considering the distribution of rocks and contamination sources in watershed, the eight stream sediments were selected from typical sites representing study areas, and we determined the concentrations of trace elements according to size fractions ($2\;mm{\sim}200\;{\mu}m$, $200{\sim}100\;{\mu}m$, $100{\sim}50\;{\mu}m$, $50{\sim}20\;{\mu}m$ and < $20\;{\mu}m$). The correlation relationships between concentrations and size fractions of stream sediments were important to identify the hydro-geochemical behavior of trace elements that flow into Juam reservoir. Stream waters showed four water types (Ca-Mg-$HCO_3$, Ca-Na-$HCO_3$-Cl, Ca-Na-$HCO_3-SO_4$, Ca-Na-$HCO_3$) depending on pollution sources such as coal mine, metal mine, farm-land and dwellings. Concentrations of trace elements increased clearly with the decrease in size fractions of stream sediments. Concentrations of Cu, Pb and Zn increased dramatically in silt size (< $20\;{\mu}m$) fraction, while As had high concentrations in sand size ($2\;mm{\sim}100\;{\mu}m$) fraction in downstream sediments of metal mines. These indicate that Cu, Zn, and Pb moved into Juam reservoir easily in the adsorbed form on silt size grain in sediments, and As was transported as As-bearing mineral facies, resulting in its less chance to reach into Juam reservoir.

• Korean Journal of Mineralogy and Petrology
• /
• v.37 no.3
• /
• pp.139-153
• /
• 2024

Recently, resources-rich advanced countries are putting more effort into mineral resource exploration as mineral resource depletion worsens along with deepening resource nationalism regarding mineral resources. Therefore, one of the methods used to explore mineral resources is to explore through the chemical composition of mineral. Pyrite, which is formed throughout the mineralization process and regardless of the mineral commodity type, is widely used as major geochemical indicator in mineral deposit exploration using content and list of trace elements in the pyrite. In this paper, the author aims to report on indicator elements that can be used when exploring lead-zinc orebody by studying the occurrence and chemical composition of pyrites from wallrock, wallrock alteration and lead-zinc orebody in the Janggun lead-zinc deposit. This deposit is hydrothermal replacement deposit formed by reaction of lead and zinc-bearing hydrothermal fluid and Paleozoic Janggum limestone formation. The wallrock alteration that is remarkably recognized with Pb-Zn mineralization at this hydrothermal replacement orebody consists of mainly rhodochrositization with minor of dolomitization, pyritization, sericitization and chloritization. Pyrite, which is occurred from wallrock, wallrock alteration, and lead-zinc orebody, is classified into three types (Py I type, Py II type, and Py III type) based on the texture, occurrence and paragenetic relationship. Pyrite on the basis of paragenetic sequence are as followed : Py I type (wallrock and wallrock alteration) → Py II type (wallrock alteration and Pb-Zn orebody) → Py III type (wallrock alteration and Pb-Zn orebody). Trace elements with a large content change in pyrite by all types are Mn, As, Ag, Sb and Pb elements, but trace elements with a small content change in pyrite are Zn, Cu, Cd, Se, Te, Co, Ni, Au, In and Sn elements. The substitution of these elements in all pyrite types is as followed: Fe²⁺↔Co²⁺ substitution (Py I type), 3Fe²⁺↔Ag¹⁺+(Mn²⁺+Ni²⁺+As²⁺)+(As3++Sb3+) substitution (Py II type) and 3Fe²⁺↔Ag¹⁺+(Mn²⁺+As²⁺+Pb²⁺)+(Mn³⁺+As³⁺+Sb³⁺), S^1-↔(As^1-+Sb^1-) substitution (Py III type). This means that Mn, As, Sb, Ag and Pb elements were enriched during evolution of hydrothermal fluid. Therefore, based on the above research results, pyrite is a useful mineral for exploration of lead-zinc orebody. And when exploring lead-zinc orebody with similar geological conditions, lead-zinc orebody is explored through the enrichment of as indicator elements.

• Nuclear Engineering and Technology
• /
• v.38 no.5
• /
• pp.423-426
• /
• 2006

A developed neutron activation analysis(NAA) and gamma-spectrometry were applied to improve the analytical sensitivity and precision of impurities in electronic-circuit raw materials. It is well known that soft errors in high precision electronic circuits can be induced by alpha particles emitted from naturally occurring radioactive impurities such as U and Th. As electronic circuits have recently become smaller in dimension and higher in density, these alpha-particle emitting radioactive impurities must be strictly controlled. Therefore, new NAA methods have been established using a HTS(Hydraulic Transfer System) irradiation facility and a background reduction method. For eliminating or stabilizing fluctuated background caused by Rn-222 and its progeny nuclides in air, a nitrogen purging system is used. Using the developed NAA and gamma-spectrometry, ultra trace amounts of U(0.1ng/g) and Th(0.01ng/g) in an alumina ball and high purity silica used for an epoxy molding compound (EMC) could be determined.

• Preventive Nutrition and Food Science
• /
• v.17 no.4
• /
• pp.299-305
• /
• 2012

Yam has been recognized having the beneficial effects for the prevention of various diseases, such as cancer, immunity, infection and obesity etc. There is increasing consideration to supplement the antioxidant nutrients to make up the lack of the antioxidant nutrient intakes. No study has been reported for the analysis of antioxidant mineral contents and comparison to dietary recommended intake for the sense of health promotion. In our study, we analyzed the contents of antioxidant trace elements (Zn, Mn, Fe, Cu and Se) and Cr contents in cultivated Korean yam powders for evaluation of nutrient intake aspects. We collected the commercial yam powders from six different cultivated areas in the South Korea and measured antioxidant minerals (Zn, Mn, Fe, Cu and Se) and Cr contents using trace element-free plasma spectrometer (ICP) or atomic absorption spectrometer (AAS) after dry-ashing and then wet-acid digestion. The accuracy of mineral analysis method was confirmed by the mineral analysis of standard reference material. Each analyzed element contents in yam were compared to dietary reference intakes of Koreans (KDRIs). The average levels of trace elements (Zn, Mn, Fe, Cu, Se and Cr) in yam powders were 18.3, 11.9, 36.0, 3.7, 1.9 and 1.27 ${\mu}g/g$ yam powder, respectively. The intakes of Zn, Fe, Cu and Se of which KDRIs is determined, are accounted as being up to 23.8%, 55.6%, 32.5% and 236% recommended intake (RI) of KDRIs, if daily yam supplementation (50 g) of commercial instruction would be considered. The intake of Mn is about 25% adequate intake (AI) of KDRIs with the daily supplementation of yam powder. Most of mineral intakes from daily yam supplementation were with the range of non-detectable to <10% upper limit (UL) level, which is very much safe. The study results show that daily supplementation of Korean yam power is beneficial to provide the supplemental nutrient intake and also is safe, if the suggested dosage would be considered.

• Asian-Australasian Journal of Animal Sciences
• /
• v.20 no.6
• /
• pp.976-982
• /
• 2007

This study investigated whether supplemental Cu, Fe, Zn, and Mn are needed in a practical diet for pullets. Four hundred and twenty females of an egg-laying strain (1-d-old, Lohmann Brown Layer) were randomly distributed into 4 groups, consisting of 7 replicates of 15 birds each. During the 18-week experimental period, chicks were given three basal diets in sequence, each with single or multiple Mn, Zn and Cu supplementation to improve the mineral balance gradually. In the Control, no Mn, Zn, and Cu were added; in the single Mn supplemented group (sMn) Mn was added to 120, 60, and 60 mg/kg for 1-6, 7-12, and 13-18 weeks of age, respectively; in the multiple Mn and Zn supplemented group (mMnZn), Mn was added to 180, 90, and 90 mg/kg and Zn was added to 120, 105, and 105 mg/kg for 1-6, 7-12, and 13-18 weeks of age, respectively; in the multiple Mn, Zn, Cu supplemented group (mMnZnCu), Mn, Zn, and Cu were added to the same multiple of basal Fe concentration relative to NRC (1994) recommendations. Energy and protein metabolizability were determined by subtracting energy/protein intake by energy/protein excretion (from both feces and urine) and dividing by energy/protein intake. There were no statistically significant differences between groups in terms of feed intake, final body weight or tibia length throughout the experiment. Optimal growth performance was observed in the Control, while adding trace minerals to basal diets tended to result in decreased productive performance. Protein metabolizability was increased by mMnZn and mMnZnCu treatments, but energy metabolizability was not affected. Concentrations of Mn, Zn, Cu in excreta varied greatly related to dietary content, and the retentions of Cu, Fe, Zn and Mn were all increased due to the improvement of mineral balance. Based on these results, it is suggested that the concentrations of Cu, Fe, Zn and Mn in typical basal diets used in this study were adequate for normal growth for pullets from 1 to 18 weeks of age.