• Title/Summary/Keyword: Trace Element

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An Criterion to Minimize FE Mesh-Dependency in Concrete Plate under Impact Loading (충격하중을 받는 판형콘크리트 구조물의 요소의존성 최소화 기준식)

  • Kwak, Hyo-Gyoung;Gang, Han-Gul;Park, Lee-Ju
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.27 no.3
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    • pp.147-154
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    • 2014
  • In the context of an increasing need for safety in concrete structures under blast and impact loading condition, the behavior of concrete under high strain rate condition has been an important issue. Since concrete subjected to impact loading associated with high strain rate shows quite different material behavior from that in the static state, several material models are proposed and used to describe the high strain rate behavior under blast and impact loading. In the process of modelling high strain rate conditions with these material models, mesh dependency in the used finite element(FE) is the key problem because simulation results under high strain-rate condition are quite sensitive to applied FE mesh size. This paper introduces an criterion which can minimize the mesh-dependency of simulation results on the basis of the fracture energy concept, and HJC(Holmquist Johnson Cook) model is examined to trace sensitivity to the used FE mesh size. To coincide with the purpose of the perforation simulation with a concrete plate under a projectile(bullet), the residual velocities of projectile after perforation are compared. The analytical results show that the variation of residual velocity with the used FE mesh size is quite reduced and accuracy of simulation results are improved by applying a unique failure strain value determined according to the proposed criterion.

Geochemistry of Granitic Rocks Around the Southern Part of the Yangsan Fault (양산단층 남부일원에 분포하는 화강암질암의 지화학적 연구)

  • Hwang Byoung-Hoon;Yang Kyounghee
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.3 s.45
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    • pp.165-181
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    • 2005
  • The granitic rocks distributed in the southern part of the Yangsan Fault are classified into five distinct rock facies based on the field relation, petrography and geochemical characteristics. These five different rock facies can be grouped into two considering their origins. Group I, which reveals various evidences of magma mixing, includes three rock facies of granodiorite, enclave-rich porphyritic granite, and enclave-poor porphyritic granite. Group H intruding Croup I includes equigranular granite and micrographic granite with no evidence of magma mixing. It is suggested that the distinctively different trace element and isotopic chemistries between group I and II, support evolution from the different parental magma. It is suggested that the three rock facies in group I were generated by different degrees of magma mixing in addition to fractionation of plagioclase. MMEs experienced fractionation of biotite. The two facies in group H seem to have been generated from different parent magma from group I and evolved by fractionation of K-feldspar. The Rb-Sr whole-rock ages of the group I rocks yield $59.2\~58.9Ma$, and those of the group II rocks give 53. $3\~51.7Ma$, regardless of their distribution whether they occur in the eastern or western parts of the Yangsan Fault. Based on Sm-Nd isotope compositions, depleted mantle model ages $(T_2DM)$ of the group I range $0.8\~0.9Ga$, while those of the group II$0.6\~0.7Ga$.

Material Analysis and Coloring Characteristics of Korean Traditional Copper-red Pigment (Jinsa) (동화(진사) 안료의 재료과학적 분석 및 발색특성)

  • Kim, Ji-Young;Cho, Hyun-Kyung;Jun, Byung-Kyu;Cho, Nam-Chul;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.27 no.1
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    • pp.31-40
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    • 2011
  • Copper-red (Dongwha, Jinsa) is Korean traditional inorganic pigment used for red-coloring on the porcelain surface during Goryeo and Joseon Periods. Trace amounts of copper-red porcelains are handed down because of the technical difficulty of making and coloring of the pigment. It is known that copper ore sources were extensively distributed in Korea according to old literatures and some of them are still producing copper ore at this present. Main types of copper-bearing mineral in Korea are chalcopyrite ($CuFeS_2$) and malachite ($Cu_2CO_3(OH)_2$), and they are easily collected from the ground surface. This means Korea had geographical and economic geological advantages for supplying raw material of the pigment. These two minerals showed good red-coloring in color test for porcelain pigment. As a coloring element, copper showed micro size less than $5{\mu}m$ in diameter in glaze matrix. The dispersion of copper particle is the most decisive factor for red chromaticity of copper-red porcelain, as well as copper content of the pigment.

Petrology and Geochemistry of Peridotite Xenoliths from Miocene Alkaline Basalt Near the Mt. Baekdu Area (백두산 지역의 마이오세 알칼리 현무암에 포획된 페리도타이트의 암석학적/지화학적 특성)

  • Kim, Eunju;Park, Geunyeong;Kim, Sunwoong;Kil, Youngwoo;Yang, Kyounghee
    • The Journal of the Petrological Society of Korea
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    • v.26 no.4
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    • pp.311-325
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    • 2017
  • Peridotite xenoliths in middle Miocene alkaline basalt from the Mt. Baekdu area are mainly anhydrous spinel lherzolites, displaying coarse-grained protogranular texture. These xenoliths have late-stage secondary orthopyroxene replacing olivine as the metasomatic mineral and glass formed along the grain boundaries. The studied xenoliths are characterized by the high $Mg{\sharp}[=100{\times}Mg/(Mg+Fe_{total})$ atomic ratio] of olivine, orthopyroxene and clinopyroxene (89~92) and the $Cr{\sharp}[=100{\times}Cr/(Cr+Al)$ atomic ratio] of spinel (10~29). Based on major-element data, the studied xenoliths are similar to those from the abyssal peridotites. Clinopyroxenes of the xenoliths are mostly enriched in incompatible trace elements, exhibiting two types of REE patterns: (1) LREE-depleted with $(La/Yb)_N$ of 0.1~0.2 and $(La/Ce)_N$ of 0.4~0.8. (2) LREE enriched with $(La/Yb)_N$ of 2.2~3.8 and $(La/Ce)_N$ of 1.2~1.6. The calculated equilibrium temperatures and oxygen fugacities resulted in $920{\sim}1050^{\circ}C$ and ${\Delta}fO_2(QFM)=-0.8{\sim}0.2$, respectively. It is suggested that the Mt. Baekdu peridotite xenoliths represent residues left after variable degrees of melt extraction(less than 15 vol%), which was subsequently subjected to different degrees of modal/cryptic metasomatism by silica- and LREE-enriched fluids (or melts).

Petrology of the Cretaceous Volcanic Rocks in the Gyemyeong peak and Janggun peak area, Mt. Geumjeung, Busan (부산 금정산의 계명봉과 장군봉 일대 백악기 화산암류에 관한 암석학적 연구)

  • Kim, Hye-Sook;Kim, Jin-Seop;Moon, Ki-Hoon
    • The Journal of the Petrological Society of Korea
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    • v.18 no.1
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    • pp.1-17
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    • 2009
  • This article carried studies of the petrographical and petrochemical characteristics on the Cretaceous volcanic rocks in the area of Janggun peak and Gyemyeong peak which is located at the northeastern area of Mt. Geumjeong, Busan. The areas are composed of andesitic rock, sedimentary rock, rhyolitic rock, and intrusive hornblende, biotite granites, in ascending order. According to petrochemistry, the major elements show the calc-alkaline rock series ranged medium-K to high-K. With increasing $SiO_2$, $Al_{2}O_{3}$, $Fe_{2}O_{3}$, $TiO_2$ CaO, MgO MnO and $P_{2}O_{5}$ are decreased and $K_{2}O$ and $Na_{2}O$ are increased in the volcanic rocks. The trace element compositions show high LILE/HFSE ratios and negative anomaly of Nb, and REE patterns show enrichments in LREE and (-) anomaly values increase of Eu from the basaltic andesite to andesite facies, therefore the volcanic rocks have typical characteristics of continental margin arc calc-alkaline volcanic rocks, produced in the subduction environment. The volcanic rock show nearly the same patterns in spider and REE diagram. Fractional crystallization of the basaltic magma would have produced the calc-alkaline andesitic magma. And the rhyolitic magma seems to have been evolved from the basaltic andesitic magma with fractional crystallization of plagioclase, pyroxene, hornblende, biotite.

Geochemistry, Isotope Properties and U-Pb Sphene Age of the Jeongeup Foliated Granite, Korea (정읍엽리상화강암의 지구화학 및 동위원소 특성과 U-Pb 스핀 연대)

  • Jeong, Youn-Joong;Cheong, Chang-Sik;Park, Cheon-Young;Shin, In-Hyun
    • Journal of the Korean earth science society
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    • v.29 no.7
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    • pp.539-550
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    • 2008
  • In this paper, we investigate the geochemical and isotope properties of the Jeongeup foliated granite (hereafter, the JFG) in the Jeongeup area, aiming at establishing the movement age of the Honam shear zone by U-Pb sphene geochronology. In the AMF diagram, the JFG corresponds to the calc alkalic rock series, and belongs to the magnesia region in the diagram of silica versus $FeO^{total}/(FeO^{total}+MgO)$. Additionally, in the Rb-Ba-Sr diagram, it is classified as granodiorite and anomalous granite with distinctive negative Eu-anomaly in the REE patterns. According to the silica and trace element contents, the JFG falls on the type VAG+syn-COLG, which implies that this was formed under the circumstance of compressional continental margin or volcanic arc. $^{143}Nd/^{144}Nd$ isotope ratios range from 0.511495 to 0.511783 and $T_{DM}$ are calculated to be about $1.68{\sim}2.36Ga$. U-Pb sphene ages of the JFG are $172.9{\pm}1.7Ma$ and $170.7{\pm}2.8Ma$, based on $^{238}U-^{206}Pb$ and $^{235}U-^{207}Pb$ ages, respectively. Presumably, the dextral ductile shearing in the Jeongeup area has occurred after 173 Ma.

Anti-Ionizing Radiation Effect of Selenium on Osteoporosis Model during Bone Repair Process (골다공증 모델의 뼈 재생기에 있어 셀레늄(Selenium)의 방사선 보호작용)

  • Kim, Hyun;Cho, Sang-Rae;Choe, Changyong;Seong, Hwan-Hoo
    • Journal of Embryo Transfer
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    • v.30 no.3
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    • pp.201-206
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    • 2015
  • Selenium (Se) is an essential trace element for humans and animals, and several findings suggest that dietary Se intake may be necessary for bone health. Accumulating evidence indicates that Se compounds possess anticancer properties. Se is specifically incorporated into proteins in the form of selenocysteine and non-specifically incorporated as selenomethionine in place of methionine. This study evaluated protection by Se in the bone repair process in ovariectomized rats after irradiation. For such purpose, 80 ovariectomized female Sprague-Dawley rats were randomly divided into 4 experimental groups: ovariectomized (Ov), Ov/Se, Ov/irradiated (Irr) and Ov/ Se/Irr. A bone defect was created on the tibia of all animals 40 days after ovariectomy. Two days after surgery, only the Ov/Se and Ov/Se/Irr rats received 0.8 mg Se/kg. Three days after surgery, only the Ov/Irr and Ov/Se/Irr rats received 10 Gy of X-rays on the lower limb region. The animals were euthanized at 7, 15, 22 and 29 days after surgery to assess the repair process, which was evaluated by analysis of trabecular bone number (Masson Trichrome) and birefringence analysis (Picrosirius). It was possible to observe a delay in the bone repair process in the ovariectomized/irradiated group and similarity between the ovariectomized, Ov/ Se and Ov/Se/Irr groups. Our findings suggest that sodium selenite may influence a radioprotective effect in the bone repair of tibia of ovariectomized rats without toxicity.

Direct Conversion of L-Selenomethionine into Methylselenol by Human Cystathionine ${\gamma}$-Lyase (인간 Cystathionine ${\gamma}$-Lyase에 의한 Selenomethionine의 Methylselenol로의 직접분해)

  • Cho, Hyun-Nam;Jhee, Kwang-Hwan
    • Microbiology and Biotechnology Letters
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    • v.42 no.1
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    • pp.11-17
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    • 2014
  • Selenium is an essential trace element for mammals, but it is very toxic. Therefore, the control of selenium concentrations should be precisely and effectively monitored. Selenium is naturally obtained through foods and seleno-L-methionine (LSeMet) is a major form of selenium. It has been reported that L-SeMet is only converted into Se-adenosyl-L-SeMet. However, a recent study suggested that L-SeMet was directly metabolized into methylselenol ($CH_3SeH$) in mouse liver extract by the reaction of cystathionine ${\gamma}$-lyase (CGL). The canonical reaction of CGL was known to catalyze the cleavage of L-cystathionine to L-cysteine, ${\alpha}$-ketobutyrate and $NH_3$. In the present study, we found that L-SeMet could be directly converted to $CH_3SeH$ using purified homogenous human CGL instead of mouse liver cytosol. Authentic $CH_3SeH$ was prepared by reduction of dimethyldiselenide with sodium tetrahydroborate. The gaseous product of the enzymatic reaction with L-SeMet was analyzed by GC/MS spectrometry. The GC/MS data was identical to that of authentic dinitrophenyl selenoether. We also analyzed the kinetic parameters for the formation of $CH_3SeH$ from L-SeMet by human and mouse CGL. These results suggest that human CGL is a critical enzyme which is responsible for L-SeMet metabolism.

Isolation and Identification of Zinc-Enriched Yeast Saccharomyces cerevisiae FF-10 from the Tropical Fruit Rambutan (열대과일 Rambutan으로부터 아연 고함유 효모 Saccharomyces cerevisiae FF-10 분리 및 특성)

  • Cha, Jae-Young;Heo, Jin-Sun;Kim, Jung-Wook;Lee, Seon-Woo;Cho, Young-Su
    • Journal of Life Science
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    • v.18 no.4
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    • pp.447-453
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    • 2008
  • Zinc is an essential trace element in Human Being. Highly zinc containing yeast strain isolated from the tropical fruit, rambutan and the zinc concentration in this yeast strain was 306 ppm (30.6 mg%)per dry matter basis. This strain was found to be a rounded type, normal size, and multi-polar budding. Phylogenetic analysis using the ITS1-5.85 rDNA sequences from isolated strain is most similar to yeast Saccharomyces cerevisiae at the level of nucleotide sequence identity at 99%. This strain was produced alcohol by about 12% using fully colonized koji-rice with Aspergillus oryzae. In conclusion, the isolated strain was found to be closely related to the S. cerevisiae based on its morphological and physiological properties, and alcohol fermentation. The phylogenetic analysis of strain FF-10 using ITS 5.8S rDNA sequence data also supported the closely related to the S. cerevisiae. Accordingly, the isolated yeast was named as S. cerevisiae FF-10. Further studies on the best culture conditions for zinc production from zinc-enriched S. cerevisiae FF-10 are under investigation.

Evaluation of Fluoride Distribution, Fate and Transport Characteristics in Soils (토양 중 불소 분포 및 거동 특성 평가)

  • Lim, Ga-Hee;Lee, Hong-Gil;Kim, Hyoung-Seop;Noh, Hoe-Jung;Ko, Hyoung-Wook;Kim, Ji-In;Jo, Hun-Je;Kim, Hyun-Koo
    • Journal of Soil and Groundwater Environment
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    • v.23 no.6
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    • pp.90-103
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    • 2018
  • Although fluoride is an essential trace element, ingestion of excessive amount of fluoride could have detrimental effect on human health. Generally, the bioavailability of fluoride in soils was low, but it could be harmful to the environment depending on the soil properties. Therefore, it is necessary to understand the concentration distribution, and fate and transport characteristics of fluoride to establish a resonable management strategy for fluoride pollution. This study was conducted to evaluate nationwide fluoride distribution in soils in Korea, as well as its fate and transport characteristics. The average background concentration was 204.5 (15.3~504.8) mg/kg, which is lower than the values of foreign soils. For the three regions of different land use, the average concentration was 229.6 mg/kg in region 1, 195.7 mg/kg in region 2, and 273.4 mg/kg in region 3. The concentration of fluoride was the highest in soils from Youngnam block within tectonic structure derived from metamorphic rocks. The results of sequential extraction to access F bioavailability showed fluoride in soils mainly existed as a residual form, which suggests the bioavailability of fluoride was relatively low. Soil properties such as soil pH, CEC, and clay content were found to affect F bioavailability of soil.