• Title/Summary/Keyword: Trace $H_2O$ and $O_2$

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Development of Economical Fertilizer-Based Media for Mass Culturing of Nannochloropsis oceanica

  • Bae, Jean-Hee;Hur, Sung-Bum
    • Fisheries and Aquatic Sciences
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    • v.14 no.4
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    • pp.317-322
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    • 2011
  • This study was conducted to develop economical agricultural fertilizer media for the mass culturing of Nannochloropsis oceanica. Specific growth rates of N. oceanica cultured with differing concentrations of commercial compounds, urea fertilizers, and trace elements (Zn, Cu, Co, Mo) were compared with the growth rate in f/2 medium. Among the various added trace elements, $CuSO_4{\cdot}5H_2O$ was most effective for high growth of N. oceanica. The main nitrogen source in the agricultural fertilizers was ammonium, which was unsuitable for the growth of N. oceanica. Thus, the fertilizer at a lower concentration infused with $NaNO_3$ as a nitrogen source was more effective than fertilizer at higher concentrations. In this study, the growth of N. oceanica cultured with an agricultural fertilizer medium composed of compound fertilizer (41.7 mg/L), urea fertilizer (34.4 mg/L), $NaNO_3$ (150 mg/L), and $CuSO_4{\cdot}5H_2O$ (0.0588 mg/L) was similar to that of N. oceanica cultured in f/2 medium.

A Study on Enhancements of Aerosol, Ozone, and Its Precursors over Korea during Asian Dust Events Related to Regional Climate Condition

  • Moon, Yun-Seob;Shin, Hye-Jung;Kim, Yoo-Keun;Oh, Sung-Nam;Park, Byoung-Cheol;Chung, Hyo-Sang;Jeong, Ju-Hee;Kim, Seong-Kyoun;Kim, Jeong-Sik
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.255-258
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    • 2002
  • The vertical exchange of trace gases and aerosols in upper regions of the atmosphere is primarily controlled by the atmospheric conditions. The study of the vertical and temporal variation of the upward transport of $H_2O$ and the downward transport of $O_3$, NO$_2$, CO and other long-lived trace species will enable a better understanding of these transport mechanisms. (omitted)

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Synthesis and Characterization of Delafossite $CuLaO_2$ for Thermoelectric Application

  • Takahashi, Yuhsuke;Matsushita, Hiroaki;Katsui, Akinori
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1114-1115
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    • 2006
  • The preparation of single-phase $CuLaO_2$ with delafossite-type structure by means of the solid-state reaction method was investigated using X-ray diffraction. The results showed that notwhistanding the fact that there was a trace of metallic copper, nearly single-phase $CuLaO_2$ was obtained by using $La(OH)_3$ as a lanthanum source and by firing the mixed powder with nonstoichiometric composition ratio of $La(OH)_3:Cu_2O=1:1.425$ in a vacuum at 1273 K for 10 h. The measurement of electrical conductivity and Seebeck coefficient showed that $CuLaO_2$ thus obtained was a p-type semiconductor and had a Seebeck coefficient of approximately $70{\mu}V/K$.

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Turn-On Type Fluorogenic and Chromogenic Probe for the Detection of Trace Amount of Nitrite Ion in Water

  • Saleem, Muhammad;Abdullah, Razack;Hong, In Seok;Lee, Ki-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.389-393
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    • 2013
  • A rhodamine B-based fluorescent probe for nitrite ion ($NO{_2}^-$) has been designed, synthesized, characterized and its properties for recognition of $NO{_2}^-$ were studied. Nearly non fluorescent probe upon reaction with nitrite ion significantly triggered the fluorescence. Fluorescence response is based on ring opening of the spirolactam of rhodamine B phenyl hydrazide showing maximum absorbance at 552 nm and maximum emission at 584 nm. Probe 3 exhibited high sensitivity and extreme selectivity for nitrite ion over other common ions and oxidants ($Cl^-$, $ClO^-$, $ClO{_2}^-$, $ClO{_3}^-$, $ClO{_4}^-$, $SO{_4}^{2-}$, $SiO{_3}^{2-}$, $NO{_3}^{2-}$, $CO{_3}^{2-}$) examined in methanol water (1:1, v/v) at pH 7.0. The probe might be a new efficient tool for detection of nitrite ion in natural water and biological system.

HPLC Analysis of Phytosphingosine and Its Metabolites in Mammalian Cells with TCPO-$H_2O$$_2$ Chemiluminescence Reaction

  • Jin, You-Xun;Choi, Chang-Hwan;Yoo, Hwan-Soo;Lee, Yong-Moon
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.216.2-216.2
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    • 2003
  • Sphingolipids has been known to induce apoptosis, cell proliferation, differentiation and migration in a variety of cell types. Recently, its phosphate form was suggested that they may act both as an agonist ligand to SlPRs and a second messenger in intracellular action. Phytosphingosine(PHS) is not easily detected due to trace component of cellular lipids in mammalian and human tissues while this is a major sphingolipid in yeast and plants. We therefore developed highly sensitive and reproducible analytical method for PHS and its phosphate by oxalic acid bis(2,4,6-tri-chlorophenyl) ester(TCPO)-hydrogen peroxide(H$_2$O$_2$) chemiluminescence. (omitted)

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Synthesis of Multifunctional AN-co-(MMA/IA) Fibrous ion-exchanger by Hydrolysis and Adsorption Properties for Trace Transition Elements (가수분해에 의한 AN-co-(MMA(IA) 다관능성 섬유이온교환체의 합성 및 미랑 전이금속 흡착특성)

  • 황택성;이선아;황계순
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.765-773
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    • 2001
  • In In order to remove harmful trace elements such as $Co^{2+}$, $Ni^{2+}$ , $Cr_2O_7\;^{2-}$ from water, we synthesized AN-co-(MMA/IA) according to various mole ratio of monomers and spun by wet-spinning. And multi-functional PAN ion exchangers were prepared by hydrolysis. We observed structure, degree of functionalization, ion exchange capacity, distribution coefficient and mechanical properties for ion exchanger. Anion exchange capacity decreased in 4.5 ~ 4.2 meq/g with increasing of IA content and cation exchange capacity increased in 1.8 ~ 2.2 meq/g. Tensile strength of the ion exchanger increased up to 0.008 mol% IA content and appeared maximum value by 216$kg/cm^2$Distribution coefficient for AN-co-(MMA/IA) ion exchanger appeared maximum value for Co(II), Ni(II) in pH 5-6 range and for Cr(III) in pH 3-4 range. And the adsorption capacity was in the order of Cr(III) > Co(II) > Ni(II) for multicomponent in continuous process.

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Low Temperature Sintering and Microwave Dielectric Properties of Ba5Nb4O15 Ceramics (Ba5Nb4O15 세라믹스의 저온소결 및 마이크로파 유전특성)

  • Kim, Jong-Dae;Kim, Eung-Soo
    • Journal of the Korean Ceramic Society
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    • v.41 no.10 s.269
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    • pp.783-787
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    • 2004
  • Microwave dielectric properties and the microstructure of $Ba_5Nb_4O_{15}$ ceramics with $PbO-B_2O_3-SiO_2$ glass frit were investigated to reduce the sintering temperature of $Ba_5Nb_4O_{15}$ ceramics as a function of the amount of glass frit from $0.5wt\%$ to $10wt\%$ and the sintering condition. The sintered density and the microwave dielectric properties of $Ba_5Nb_4O_{15}$ ceramics were remarkably changed with the amount of glass fit which existed as a liquid phase and assisted the densification. $Ba_5Nb_4O_{15}$ with $3wt\%$ $PbO-B_2O_3-SiO_2$ glass frit sintered at $900^{\circ}C$ for 2 h showed dielectric constant (K) of 41.4, a quality factor (Q $\times$f) of 13,485 GHz, and a Temperature Coefficient of resonant Frequency (TCF) of 9 ppm/$^{\circ}C$. Due to no trace of physical and chemical reaction between this composition and Ag electrode cofired at $900^{\circ}C$ for 2 h, this ceramics can be a good candidate for the multilayer dielectric filter.

Comparing the Dyeing Properties of Synthetic Mordants and Hwangsu Spring

  • Ahn, In-Yong;Suh, Hwa-Jin;Song, Eun-Young;Lee, Kyung-Ok;Kim, Jung-Su;Park, Young-Mi;Kwon, Oh-Oun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.121-121
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    • 2012
  • To evaluate the Hwangsu spring as natural mordants effect on dyeing. The natural mordant effect of Hwangsu spring was analyzed by pH, temperature, trace elements and organic matter. Hwangsu spring having pH 2.42 and $14.4^{\circ}C$ was harvested at the end of September, 2011, in Yeongcheon(Gyeongbuk Province, Korea) and left on a $0^{\circ}C$ and $25^{\circ}C$ before use. The Result of ICP analysis, it contain bned Fe(414.9 ppm), Al(88.9 ppm), Mn(4.9 ppm). Dyeing and post-mordant procedure; Fabrics(cotton, silk, rayon) were dyed with natural colorants(Sopbora Japonica L., Caesalpinia sappan L., Allium cepa L.) for 20 min at $80^{\circ}C$. Hwangsu spring, aluminium sulfate $14-18H_2O(Al_2(SO_4)_3{\cdot}14-18H_2O)$, iron sulfate peptahydrate($FeSO_4{\cdot}7H_2O$), copper sulfate pentahydrate($CuSO_4{\cdot}5H_2O$) were used by post mordants. But in the case of Caesalpinia sappan L. was dyed after pre-mordanting with Al(II). The fabrics were dyed with each mordant solutions at $25^{\circ}C$ for 10min. The colorless also was measured by color-differnce meter. Comparison with a synthetic mordants, the K/S values of cotton fabrics dyed with Hwangsu sping were increased.

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Electrical discharge machining of $TiC/Al_2O_3$ Ceramic Composite (탄화티탄/알루미나 세라믹 복합체의 방전가공)

  • Wang, D.H.;Woo, J.Y.;Ahn, Y.C.
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.9
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    • pp.80-89
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    • 1997
  • Die sinking electrical discharge machining(EDM) was conducted for ceramic composite of 33 weight percent TiC based on AI$_{2}$O$_{3}$ ceramic matrix according to the change of current and duty factor(DF). Material removal rate(MRR) was increased as the current and the duty factor increased, but better surface mor-pholoty was obtained in the region of lower current and duty factor. From the scanning electron microscopy(SEM) photographs and the energy dispersive X-ray spectroscopy(EDX) of the EDMed surface, EDM trace formed by one discharge spark was analyzed. Although the bending strength after EDM was highly decreased, reliability obtained by weibull analysis was increased twice. The bending strength was recovered or more by barrel polishing after EDM. From the FEM analysis of temperature for one spark, the possible melting region of AI$_{2}$O$_{3}$and TiC was obtained.

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Element Dispersion and Wallrock Alteration of TA26 Seamount, Tonga Arc (통가열도 TA26 해저산의 모암변질과 원소분산)

  • Yoo, Bong-Chul;Choi, Hun-Soo;Koh, Sang-Mo
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.359-372
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    • 2011
  • TA26 seamount, which is located at south part of Tonga arc, occurs widely hydrothermal plume and is area that sampled hostrock, hydrothermal ore and hydrothermal alteration rock for this study. Hostrocks are basalt and basaltic andesite. Altered rocks by hydrothermal solution consists of plagioclase, pyroxene, pyrite, ilmenite, amorphous silica, barite, smectite, iron sulfates, Fe-Si sulfates and Fe silicates. Gains and losses of major, trace and rare earth elements during wallrock alteration suggest that $K_2O$(+0.04~+0.45 g), $SiO_2$(-6.52~+10.56 g), $H_2O$(-0.03~+6.04 g), $SO_4$(-0.46~+17.54 g), S(-0.46~+13.45 g), total S(-0.51~+16.93 g), Ba(-7.60~+185078.62 g), Sr(-36.18~+3033.08 g), Ag(+54.83 g), Au(+1467.49 g), As(-5.80~+1030.80 g), Cd(+249.78 g), Cu(-100.57~+1357.85 g), Pb(+4.91~+532.65 g), Sb(-0.32~+66.59 g), V(-113.58~+102.94 g) and Zn(-49.56~+14989.92 g) elements are enriched from hydrothermal solution. Therefore, gained(enriched) elements(($K_2O$, $H_2O$, $SO_4$, S, total S, Ba, Sr, Ag, Au, As, Cd, Cu, Pb, Sb, V, Zn) represent a potentially tools for exploration of sea-floor hydrothermal deposits from the Tonga arc.