• Journal of Environmental Science International
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• v.19 no.2
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• pp.229-236
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• 2010

As air pollution has emerged as one of the most pressing urban environmental concerns, many studies have investigated the influence of air pollutants(ex: $O^3$, $NO^2$, $SO^2$, Acid rain, etc.) on roadside trees and urban grove. In Korea, population density started to increase since the industrialization. Since dense population aggravates our living conditions, it's very important for us to preserve and keep a lively and refreshing nature in order to live with green nature in harmony under the current artificial environment-dominating world. In metropolitan cities, the production of pollutants increases in proportion to population growth. The vehicle exhaust gas and air pollutants from cooling and heating systems have been the major causes of acid rain. Furthermore, tire particles which are naturally produced by tire wearing on roads and other toxic substances in exhaust gas have caused a problem in human health directly and indirectly. In fact, a lot of studies have analyzed air pollution, roadside trees and plants in Korea. However, they are mostly limited to covering the influence of air pollution on the growth of plants. No paper has clearly explained why air pollution-resistant or-vulnerable species has shown different reactions yet. Even though a lot of urban roadside trees have died or stopped to grow from time to time, this kind of problem has not been properly examined. This paper is aimed to comparatively analyze physio-ecological characteristic such as photosynthesis, chlorophyll contents, soil volume water figure out their relationship with environmental factors against the expanding roadside trees in Cheong-ju, and provide basic data for management of roadside trees and elaboration of urban environment preservation policies.

• Applied Chemistry for Engineering
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• v.27 no.3
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• pp.265-269
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• 2016

Ammonia gas as a hydrogen source has received great attention since the importance of hydrogen gas as a clean energy source increased. However, ammonia is toxic and corrosive to metal such that the absorbent that can store and transport ammonia became an important issue. As an effort to solve this, a large pored covalent organic framework, COF-10 was proposed as an adsorbent for storage and safe transportation of ammonia. During the ammonia adsorption process, boron in COF-10 structure can act as a Lewis acid site and bind with ammonia. In this study, COF was synthesized and its structure was identified by BET, XRD and FT-IR. The adsorption characteristics of COF were investigated by TPD and adsorption isotherm. The COF-10 showed an excellent adsorption capacity for ammonia (9.79 mmol/g) which could be utilized as an ammonia adsorbent.

• Journal of Korean Society on Water Environment
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• v.22 no.6
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• pp.1123-1129
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• 2006

Pyrene of natural and anthropogenic sources is one of the toxic, mutagenic polycyclic aromatic hydrocarbons (PAHs) listed as priority pollutants. The objectives of this research are to break down pyrene by using ozonation, identify the intermediates and byproducts of pyrene, and test the biodegradability of intermediates and byproducts of pyrene in the aqueous phase. Since pyrene is non-polar, hexane was chosen as a solvent to effectively dissolve pyrene. Pyrene solutions were treated with ozone, as it has high oxidation capacity and electrophilic characteristic. After different ozonation pretreatment times (2, 3, and 10 minutes), intermediates of pyrene in the form of yellowish solid were collected from the hexane solution using a centrifuge. They were identified by gas chromatography/mass spectrometer (GC/MS). $BOD_5$, COD, and E-coli toxicity tests have been performed to assess the ozonation products.

• Proceedings of the KSRS Conference
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• 2008.10a
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• pp.3-5
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• 2008

An increase in oil and gas plants caused by development of process industry have brought into the increase in use of flammable and toxic materials in the complex process under high temperature and pressure. There is always possibility of fire and explosion of dangerous chemicals, which exist as raw materials, intermediates, and finished goods whether used or stored in the industrial plants. Since there is the need of efforts on disaster damage reduction or mitigation process, we have been conducting a research to relate explosion model on the background of real 3D terrain model. By predicting the extent of damage caused by recent disasters, we will be able to improve efficiency of recovery and, sure, to take preventive measure and emergency counterplan in response to unprepared disaster. For disaster damage prediction, it is general to conduct quantitative risk assessment, using engineering model for environmental description of the target area. There are different engineering models, according to type of disaster, to be used for industry disaster such as UVCE (Unconfined Vapour Cloud Explosion), BLEVE (Boiling Liquid Evaporation Vapour Explosion), Fireball and so on, among them, we estimate explosion damage through UVCE model which is used in the event of explosion of high frequency and severe damage. When flammable gas in a tank is released to the air, firing it brings about explosion, then we can assess the effect of explosion. As 3D terrain information data is utilized to predict and estimate the extent of damage for each human and material. 3D terrain data with synthetic environment (SEDRIS) gives us more accurate damage prediction for industrial disaster and this research will show appropriate prediction results.

• Journal of the Korean Institute of Gas
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• v.20 no.2
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• pp.49-57
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• 2016

Aqueous ammonia is widely used in household cleaners, fertilizers and denitrification process. It is usually treated in concentrations from 10 % to 30 %, and release accidents have occurred frequently. In this study, we developed a simplified estimating method and equation to calculate threat zone easily in case of emergency due to release accident of aqueous ammonia. We calculated the consequence distance for toxic endpoints of aqueous ammonia(concentration 10 % ~ 30 %) at different puddle areas($1m^2{\sim}500m^2$) using the ALOHA program. Based on the result, we analyzed the relationship between concentration and puddle area with the threat zone and created the equation.

• Fire Science and Engineering
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• v.28 no.6
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• pp.8-12
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• 2014

Interior finishing materials using noncombustible were regulated by the building codes to prevent the spread of fire and protect occupants. The average deed of stopping time of experimental mouse exposing combustion gas were measured by KS F 2271 gas toxicity test. At that time, The average deed of stopping time under 9 minutes were judged a inconsistence. This experiment method has limit to find out a cause of toxicity effect factor. In this study, particle size analysis were performed for investigate a major factor.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.11
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• pp.1471-1476
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• 2011

The catalytic converter in the front part of an automobile's exhaust system converts toxic exhaust gas into nontoxic gas. The substrate in the central part of the converter has a circular or oval-shaped cross section and fine lattice-shaped walls. In the canning process, the substrate is wrapped in mats and inserted into a can. During this process, mat pressure is induced, which may cause brittle fracturing in the substrate. In this paper, a finite element program for determining the mat pressure distribution was developed to avoid these fractures. The program was created in Microsoft EXCEL, so the input and output procedures are relatively simple. It was assumed that the substrate is rigid, the mat is material nonlinear, and the can is linear elastic. The can is modeled as a beam element to resist both bending and uniform tension/compression. The number of elements is fixed to 35, and the number of iterations, to 20. The solutions are compared to ABAQUS solutions and found to be in good agreement.

• Current Photovoltaic Research
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• v.2 no.3
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• pp.120-123
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• 2014

Thermal doping method using furnace is generally used for solar-cell wafer doping. It takes a lot of time and high cost and use toxic gas. Generally selective emitter doping using laser, but laser is very high equipment and induce the wafer's structure damage. In this study, we apply atmospheric pressure plasma for solar-cell wafer doping. We fabricated that the atmospheric pressure plasma jet injected Ar gas is inputted a low frequency (1 kHz ~ 100 kHz). We used shallow doping wafers existing PSG (Phosphorus Silicate Glass) on the shallow doping CZ P-type wafer (120 ohm/square). SIMS (Secondary Ion Mass Spectroscopy) are used for measuring wafer doping depth and concentration of phosphorus. We check that wafer's surface is not changed after plasma doping and atmospheric pressure doping width is broaden by increase of plasma treatment time and current.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.5
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• pp.293-302
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• 2015

Halonitromethanes (HNMs) are one of the most toxic groups of disinfection by-products. Recently, various studies have been fulfilled. An automated headspace-solid phase microextraction (SPME) gas chromatography/electron capture detector (GC-ECD) technique was developed for routine analysis of 9 HNMs in water samples. The optimization of the method is discussed. The limits of detection (LOD) and limits of quantification (LOQ) range from 90 ng/L to 260 ng/L and from 270 ng/L to 840 ng/L for 9 HNMs, respectively. Matrix effects in tap water and sea water were investigated and it was shown that the method is suitable for the analysis of trace levels of HNMs, in a wide range of waters. The method developed in the present study has the advantage of being rapid, simple and sensitive.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.172-172
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• 2016

The International Maritime Organization(IMO) adopted the International Convention for the Control and Management of Ships' Ballast Water and Sediments in 2004 to prevent the transfer of aquatic organisms via ballast water. Forty ballast water treatment systems were granted final approval. A variety of techniques have been developed for ballast water treatment including UV treatment, indirect or direct electrolysis, ozone treatment, chemical compounds and plasma-arc method. In particular, using plasma and ozone nano-bubble treatments have been attracted in the fields. However, these treatment systems have a problem such as remained toxic substance, demand for high power source, low efficiency, ets. In this paper, we present our strilization results obtained from membrane type electrolytic-reduction treatment system The core of an electrolysis unit is an electrochemical cell, which is filled with pure water and has two electrodes connected with an external power supply. At a certain voltage, which is called critical voltage, between both electrodes, the electrodes start to produce hydrogen gas at the negatively biased electrode and oxygen gas at the positively biased electrode. The amount of gases produced per unit time is directly related to the current that passes through the electrochemical cell. From the results, we could confirm the sterilization effect of bacteria such as S. aureus, E. Coli and demonstrate the mechanism of sterilization phenomena by electrolytic-reduction treatment system.