• Title/Summary/Keyword: Toxic gas

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DEVELOPMENT ON ENHANCED LEAKED FUEL RECIRCULATION DEVICE OF LPLi ENGINE TO SATISFY SULEV STANDARD

  • Myung, C.L.;Kwak, H.;Park, S.
    • International Journal of Automotive Technology
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    • v.7 no.4
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    • pp.407-413
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    • 2006
  • The liquefied petroleum gas(LPG), mixture of propane and butane, has the potential to reduce toxic hydrocarbon emissions and inhibit ozone formation due to its chemical composition. Conventional mixer systems, however, have problems in meeting the future lower emission standards because of the difficulty in controlling air-fuel ratio precisely according to mileage tar accumulation. Liquid Phase LPG injection(LPLi) system has several advantages in more precise fuel metering and higher engine performance than those of the conventional mixer type. On the other hands, leakage problem of LPLi system at the injector tip is a main obstacle for meeting more stringent future emission regulations because these phenomena might cause excessive amount of THC emission during cold and hot restart phase. The main focus of this paper is the development of a leaked fuel recirculation system, which can eliminate the leaked fuel at the intake system with the activated carbon canister. Leaked fuel level was evaluated by using a fast response THC analyzer and gas chromatography. The result shows that THC concentration during cold and hot restart stage decreases by over 60%, and recirculation system is an effective method to meet the SULEV standard of the LPLi engine.

A Study on Mitigation Methods of Indoor Radon Concentration in Residential Buildings(I) - Test Cell Study (주거용 건축물의 실내 라돈농도 경감방안에 관한 연구(I) -Test Cell Study)

  • Cha, Dong-Won
    • KIEAE Journal
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    • v.1 no.2
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    • pp.21-28
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    • 2001
  • Naturally-ocurring short-lived decay products of radon gas in indoor air are the dominant source of ionizing radiation exposure to the general public. It is written in BEIR VI Report(l999l the radon progeny were identified as the second cause of lung cancer next to cigarette or 10 % to 14 %(15,400 to 21,800 persons p.a.) of all lung cancer deaths in USA. Indoor radon concentrations in houses typically result from radon gaining access to houses mainly from the underlying soil. In the States, they have "Indoor Radon Abatement Act" which was converted from "Toxic Substance Control Act" in 1988 to establish the national long-term goal that indoor air should be as free of radon as the ambient air outside of buildings. To review and study techniques for controlling radon, two test cells were constructed for a series of tests and are under measuring indoor and soil gas (underneath of floor slab)radon concentrations according to EPA's measurement protocol. In this paper, important theoretical studies are previewed and the following paper will explain the test results and confirm the theories reviewed to find out suitable coefficients. On the basis of test analysis, it will be described and evaluated various techniques that can be used to mitigate elevated indoor concentration of radon including the control of radon and its decay products.

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A Study on the $NO_2$ Gas Detection Chracteristics of the Octa(2-ethylhexyloxy) Copper-Phthalocyanine LB Film Depending on the Film Thickness and Temperature (두께와 온도에 따른 Octa(2-ethylhexyloxy) Copper-phthalocyanine LB막의 $NO_2$ 가스 탐지 특성에 관한 연구)

  • Yim, Jun-Seok;Shin, Hyun-Man;Kim, Young-Kwan;Kim, Jung-Soo;Sohn, Byung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.105-109
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    • 1996
  • It is well known that the metallo- phthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as $NO_2$ and also chemically and thermally stable, Therefore, lots of MPcs have been studied for the potential chemical sensor for $NO_2$ gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, ultra-thin films of octa(2-ethylhexyloxy)copper-phthalocyanine were prepared by Langmuir-Blodgett method and characterized by using UV-VIS absortion spectroscopy and ellipsometry. Transfer condition, and characterization of LB films were investigated and preliminary results of current-voltage(I-V) characteristics of these films exposed to $NO_2$ gas as a function of film thickness and temperature were discussed.

Anoxia Techniques to Eradicate Insects for Conservation of Cultural Properties in Museums (박물관에서의 저산소 농도를 이용한 살충 기술)

  • Oh, Joon-Suk
    • Journal of Conservation Science
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    • v.27 no.2
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    • pp.231-241
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    • 2011
  • Anoxia Treatment using inert gas like nitrogen and argon has been used to eradicate insects successfully in museums as alternative of methyl bromide and toxic insecticide. Killing efficacy of insect for anoxia treatment is depend on species of insects, oxygen concentration, temperature, relative humidity and gas. It is possible to kill museum insects which are most tolerant in anoxia environment, within 1 month below 0.03% of oxygen concentration in temperature $15{\sim}25^{\circ}C$ and relative humidity 40~60% of museum environment. And various systems like bag, tent, bubble and chamber depending on size and quantity of objects, are used.

Simultaneous Determination of Alkoxyalcohols in Wet Wipes Using Static Headspace Gas Chromatography and Mass Spectrometry

  • Lee, Soojin;Pyo, Heesoo;Chung, Bong Chul;Kim, Haidong;Lee, Jeongae
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3280-3288
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    • 2014
  • Alkoxyalcohols are used as solvents or preservatives in various consumer products such as wet wipes. The metabolites of alkoxyalcohols are known to be chronically toxic and carcinogenic to animals. Thus, an analytical method is needed to monitor alkoxyalcohols in wet wipes. The aim of this study was to develop a simultaneous analytical method for 14 alkoxyalcohols using headspace gas chromatography coupled with mass spectrometry to analyze the wet wipes. This method was developed by comparing with various headspace extraction parameters. The linear calibration curves were obtained for the method ($r^2$ > 0.995). The limit of detection of alkoxyalcohols ranged from 2 to $200ng\;mL^{-1}$. The precision of the determinative method was less than 18.20% coefficient of variation both intra and inter days. The accuracy of the method ranged from 82.86% to 119.83%. (2-Methoxymethylethoxy)propanol, 2-phenoxyethanol, and 1-phenoxy-2-propanol were mainly detected in wet wipes.

Removal of Toxic Organic Compound using Electro-Fenton Reaction (Electro-Fenton 반응을 이용한 유독성 유기화합물 처리)

  • Park, Sang Won
    • Journal of Environmental Science International
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    • v.13 no.6
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    • pp.551-560
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    • 2004
  • The feasibility and efficiency of the hydrogen peroxide produced by an electrolysis cell reactor was investigated, From regulating voltages for the given reaction time, the concentration of the hydrogen peroxide was gradually increased with increasing voltages. Optimal voltage range was found to be 10~15 V. The concentration of hydrogen peroxide was much higher with oxygen gas than without oxygen gas in the cathodic chamber. But there was a little difference in the generating rate of hydrogen peroxide regardless of the presence of nitrogen gas. Under given conditions, the maximum value of ICE(Instantaneous Current Efficiency) was about 38%, and then current density was 74 $mA/\textrm{cm}^2.$ The specific energy consumption was $0.694[kWh/kg-H_2O_2].$ Since Esp (Specific Energy Consumption)was very little value, It did not demand high energy in this system. Using the hydrogen peroxide gained in the experiment, Fenton's reaction was conducted and the removal of nitrobenzene, 3-chlorophenol and dye wastewater was studied. This results were very similar to the Fenton's reaction by using commercial hydrogen peroxide.

Comparative Analysis of Indoor Mixture Gas Patterns and Reference Single Gas Patterns Obtained from E-Nose for Indoor Air Quality Monitoring

  • Choi, Jang Sik;Yu, Joon Boo;Jeon, Jin Young;Lee, Sang Hun;Kim, Jae Hong;Park, Jang Pyo;Jeong, Yong Won;Byun, Hyung Gi
    • Journal of Sensor Science and Technology
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    • v.27 no.4
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    • pp.227-231
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    • 2018
  • Indoor air pollution has become a serious issue, affecting the health and comfort of building occupants. Volatile organic compounds (VOCs) are among the most common indoor contaminants, and are released from numerous indoor emission sources. Among the VOCs, formaldehyde and toluene are toxic chemicals at low levels and are frequently detected indoors. Exposure to formaldehyde and toluene can irritate sensitive tissue and may increase the risk of cancer. Therefore, monitoring formaldehyde and toluene is critical for the health and comfort of residents. In addition, as human indoor activities can generate VOC gases, analysis of their influence on VOCs is needed. In this study, we compared electronic nose (E-Nose) data for formaldehyde and toluene with E-Nose data for indoor mixture gas with consideration for human indoor activities.

Case Study on Seepage Analysis and Countermeasure Against the Seepage Flow of In-ground LNG Storage Tank (LNG 지하저장탱크의 침투해석 및 용수 대책공법에 대한 사례분석)

  • 신은철;오영인;이상혁
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.65-72
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    • 2001
  • Since Pyoungtaek thermal power plant began using natural gas in 1986, the annual using volume has rapidly increased and reached 12.7 million tons in 1999. When the natural gas is cooled to a temperature of approximately -162$^{\circ}$C at atmospheric pressure, it condenses to a liquid called liquefied natural gas(LNG). LNG has a special characters such as odorless, colorless, non-corrosive, and non-toxic. So, LNG storage tank, tanker ship, transfer pipelines are required the special storage and transportation systems and technology. The presently operating LNG terminals are Pyongtaek and Inchon terminals. A total of 19 above-ground LNG storage tanks(100 thousand ㎘ grade) are currently in operation with a sendout capacity of 4,360tons/hour. To meet the growing domestic demand of LNG supply, the Inchon receiving terminal is expanding(six in-ground tank) and constructing a third LNG terminal at Tongyong. In this paper, case study on seepage analysis and countermeasure against increasing the seepage volume of in-ground LNG storage tank excavation work is reported. The results of an additional seepage analysis are presented to verify the design seepage volume of assumption section and seepage volume after curtain-grouting in the slurry wall.

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Gasification and Pyrolysis Technology for the Treatment of Plastics Waste (플라스틱 폐기물의 건류 및 열분해)

  • Ghim, Young Sung
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.201-206
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    • 1992
  • Annual amount of plastics waste including rubber and leather waste, generated in 1990 was about 2,600,000 tons. Amount of generation of plastics waste has rapidly increased, but fractions of recycling and incineration have gradually decreased. Recently, two-stage incinerator, consisting of gasifier and gas combustor, draws much attention in Korea. Plastics are gasified in the starved air condition in the gasifier and produced gas is fired in the combustor. Combustion of produced gas is much easier than that of solid plastics, and produces a little pollutants. Standardzation of technology and process automation are still needed, but this incineration technology is in the commercial stage. Next topic concerned with this two-stage incineration will be how to treat complex plastics waste including toxic substances generated from automobiles and household appliances. Pyrolysis, realized by indirect heating in inert atmosphere, can provide high-quality products with minimum emissions. Many plastics are easily decomposed into oil in pyrolysis conditions, which can be utilized as chemical feedstocks, or gasoline or kerosene depending on feed materials and operating conditions. This has been demonstrated in several pilot-scale tests performed in Japan, Germany, etc. Easy removal of HCl from PVC is one of the most decisive merits of pyrolysis process. But in general, further efforts should be made for the process to obtain marketability. The future of pyrolysis process depends on public concern about environmental problems and oil prices.

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Plasma Diagnosis of Ne:Xe, Ne:Ar Mixed Gases by Single Langmuir Probe in Inductively Coupled Plasma Light Source System (ICP 광원 시스템의 Ne:Xe, Ne:Ar 혼합가스의 단일탐침법을 이용한 플라즈마 진단)

  • Choi, Yong-Sung;Lee, Woo-Ki;Moon, Jong-Dae;Lee, Kyung-Sup;Lee, Sang-Heon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.05a
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    • pp.91-95
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    • 2006
  • In whole world consciousness of environment maintenance have increased very quickly for the end of the 20th century. To use and disuse toxic substances have been controled at the field of industry. Also the field of lighting source belong to environmental control. And in the future the control will be strong. In radiational mechanism of fluorescence lamp mechanism is the worst environmental problem. In radiational mechanism of fluorescence lamp mercury is the worst environmental problem root. In the mercury free lighting source system the Xe gas lamp is one type. And the Ne:Xe mixing gas lamp improvements firing voltage of Xe gas lamp. Purpose and subject of this study are understand, efficiency, ideal of Ne:Xe plasma which mercury free lamp. Before ICP was designed, basic parameters of plasma, which are electron temperature and electron density, were measured and calculated by Langmuir probe data. Property of electron temperature and electron density were confirmed by changing ratio of Ne:Xe.

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