• Title/Summary/Keyword: Toxic Gas

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Effect of STEL-toluene on Metabolism of Benzene in Rats (단시간 허용농도의 toluene이 benzene대사에 미치는 영향)

  • Roh, Jae-Hoon;Shin, Dong-Chun;Park, Jung-Gyun;Moon, Young-Hahn;Chung, Ho-Keun
    • Journal of Preventive Medicine and Public Health
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    • v.21 no.1 s.23
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    • pp.152-162
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    • 1988
  • Benzene and toluene, which are widely used aromatic hydrocarbons in workplace, are recently proved to cause health hazards due to their toxic effects. This study investigated the influence of toluene on the urinary excretion of benzene metabolite by administering short term exposure limit(STEL) of these compounds(i.e., 13.8mg/kg of benzene and 108.8 mg/kg of toluene) intraperitoneally into Sprague-Dawley rats. After administration, urinary phenol concentration of rat was measured by gas chromatography for every three hours. Data were analyzed by non-parametric statistical methods using Kruskal-Wallis multi-sample test and Mann-Whitney U test. The following results were obtained : 1. Administration of STEL-benzene increased urinary phenol concentration in lats. 2. Urinary phenol concentration was increased logarithmically according to the dosage of benzene. 3. Excretion of phenol in urine was decreased when benzene and toluene were administered simultaneously compared with administering benzene alone. In summary, these results reveal that administration of STEL of toluene has antagonistic effect of urinary excretion of benzene metabolite in rats.

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A Study on the Treatment of Phenol Wastewater in an Anaerobic Fluidized-Bed Reactor (혐기성 유동층 반응기에서 페놀 폐수 처리에 관한 연구)

  • 박동일;안재동;신승훈;장인용
    • Journal of Environmental Health Sciences
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    • v.22 no.2
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    • pp.96-103
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    • 1996
  • The objectives of this study were to examine the biodegradation of phenol using the anaerobic fluidized bed reactor(AFBR). Mixed microorganisms were selected from the anaerobic digestion tank, and could be adapted to high concentration of phenol by increasing the phenol concentration 600-3600 mg/l step by step. The results were summarized as follows: 1. The average removal efficiency of phenol was 90%, decreased by increasing concentration of phenol, and then a shock range was 1200~2400 ppm. 2. The production rate of biogas in overall limits was proportional to the concentration of influent phenol. 3. At steady state, compositions of gases were $CH_4$ 55~60%, $C0_2$ 34~43%, respectively. These were similar to that of the theoretical estimates. 4. The production rates of biogas and methane per the molarity of phenol removed were linearly increased, 56.45 l gas/mol-phenol and 29.20 l $CH_4/mol$-phenol. Using this biogas, the recoverable energy was 269.1 kcal/mol phenol. It was 120.2 kcal/g-COD, transforming into the chemical oxygen demand. 5. The bulk of microorganisms existed in suspended section of fluidized bed with type of biofilm and its concentration was 340 mg/g-media. In conclusion, the anaerobic treatment of pure phenol was possible and its removal efficiency, introducing the AFBR, was successful. Also toxic organic compound such as phenol was biodegradable and was recoverable as resource of energy.

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An Experiment Study for Flame Spread Prevention System of Snadwich Panels (샌드위치 패널의 화재확대 방지시스템 개발을 위한 실험적 연구)

  • Shin, Hyun-Joon;In, Ki-Ho;Yoo, Yong-Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.6
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    • pp.307-312
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    • 2015
  • The sandwich panel is commonly used domestically because it's less costly and easier to handle. But fires have frequently occurred in buildings employing sandwich panels, such as the fires in Eecheon cold storage and in Gwangju Pyungdong industrial zone. Sandwich panels with steel plates on their surface prevent fire water from penetrating to the fire source, which makes it difficult to extinguish a fire in a timely manner. Toxic gas generated from some insulation material leads to serious loss of life and property. This study is intended to develop an extinguishing system for sandwich panels, thereby reducing the fire risk. Fire water and volume were determined in the wake of the study on the structure of a sandwich panel extinguishing system, and improvement and testing of the fire characteristics of the sandwich panel. Based on such study and test, a fire model test was conducted. Consequently, the sandwich panel with extinguishing system was proven to have a reduced fire risk, compared to traditional or fire retardant panels.

N-nitroso-N-methylurea and N-nitroso-N-ethylurea Decrease in Nitric Oxide Production in Human Malignant Keratinocytes

  • Moon, Ki-Young
    • Biomedical Science Letters
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    • v.24 no.1
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    • pp.50-54
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    • 2018
  • N-nitroso-N-methylurea (NMU) and N-nitroso-N-ethylurea (NEU), direct alkylating chemical mutagens and carcinogens, are shown to be the upregulators of cellular $NF-{\kappa}B$, regulating various genes that mediate tumorigenesis and carcinogenesis. Nitric oxide (NO), a toxic reactive radical gas, has been known to induce programmed cell death or apoptosis in various cells. Therefore, the assessment of NO production was examined to elucidate the possible contribution of NO release to the chemical carcinogenic potency of NMU and NEU in human skin cells. NMU and NEU did not alter the NO production, but they caused a significant downregulation of the NO generation on lipopolysaccharide (LPS)-induced NO production at concentrations ranging from $2{\sim}5{\mu}M$. The degree of downregulation of NO by NMU and NEU decreased up to 15% and 20%, respectively, compared to the control. These results demonstrate that the LPS-inducible keratinocytes NO synthase is involved in modulating carcinogenic potency by NMU and NEU, and the regulation of the cellular $NF-{\kappa}B$ activity by NMU and NEU is negatively correlated with the level of LPS-induced NO production in human skin cells. The findings of this study suggest the hypothesis that NMU and NEU-induced carcinogenesis may be associated with the downregulation of NO production, and the inducible NO may play an important role in NMU and NEU-induced carcinogenicity in human epidermal keratinocytes.

A Study on Distillation Property of Automotive Gasoline and Diesel Fuel (자동차용 가솔린과 디젤 연료의 증류특성에 관한 연구)

  • Youm, Kwang-Wook;Kim, Sang-Jin
    • Journal of Power System Engineering
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    • v.18 no.5
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    • pp.11-15
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    • 2014
  • Currently, there are active researches being conducted on a new combustion technology that can reduce emission quantity while enhancing vehicle performance as well as Improving fuel quality. In a gasoline engine that uses petroleum, high volatility makes it easy to jump spark ignition and prevent knocking phenomenon that occurs inside an engine. In a diesel engine that uses diesel fuel, high volatility reduces combustion residues and toxic gas and is therefore good for protecting the environment. Therefore, for fuel used in a vehicle, volatility is an important factor that influences not only engine performance but also environmental protection. This research conducted a distillation experiment using gasoline and diesel fuel for vehicles produced by domestic oil companies. The test was conducted in accordance with the method of distillation experiment described in KS M ISO3405. In addition, it used the result of analysis from the experiment to examine visual distillation characteristics of each fuel and developed a formula based on distillation temperature.

A Study of Local Ventilation Design on PC Programm (국소환기 설계의 전산화에 관한 연구)

  • Yoon, Myong Cho
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.3 no.2
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    • pp.213-226
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    • 1993
  • The purpose of this study is to computerize the design of single source for a duct work system which is essential for the improvement of working places. There are different types of hood, such as general hood, push pull hood and canopy hood. And out of these three types, general hood and canopy hood were used as subjects of this study. The software used here was Quattro Pro 123 programm, and the hardware was IBM PS/SX(type 5510-SK4 S/N 83-05164). And the results are tabulated in

    and
    . All of the hazardous factors of working places, except for physical factors, such as noise, vibration, illumination and etc, are control measurement related. In order words, workiong places that have problems with toxic gas, mist, fume, dust, odors, biological factors or wetness can be improved by means of the local ventilation design. However, the reqires very complicate processes, and in the case of canopy hood, particularly, one runs into difficulties due to frequent discrepancies generated from calculations through many processes. Recently, progress of the computer hardware technics has been dazzling, and also the software is development rapidly. As proven in the results of this study, it is good that designs for industrial ventilation systems are readily available for easy use. It is hopeful that young scholars will develop easier and quicker methods for local ventilation designs in the future.

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  • Standardization of the Performance Test Procedure for Smoke Control System (제연설비 성능시험방법의 표준화)

    • Kwark, Ji-Hyun
      • Fire Science and Engineering
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      • v.20 no.3 s.63
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      • pp.21-28
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      • 2006
    • Since hot toxic gas included in the fire is the most principal reason of the death and has the fluid mechanical characteristics unlike air, smoke control method appropriate for the figure and structure of a fire room is needed and each unit of the smoke control system requests high performance according to this characteristics, for which performance test procedures and evaluation criteria must be established. Domestic criteria involved with the smoke control consist of the pre-investigation by documents and the part inspection, which has lots of problems because they are far from the performance based evaluation method compared with the references of developed countries. Consequently, domestic and international references were compared and analyzed, problems being emerged and standardization scheme of the test procedure was presented.

    How Visual-Field Obstruction from Fire Smoke Influences a Resident's Necessary Time to Reach Fire Escape and Evacuation Route in a High-rise Apartment Housing (연기발생으로 인한 시야장애가 초고층 공동주택 거주자의 피난계단실 진입시간과 피난경로에 미치는 영향)

    • Seo, Sang-Mok;Choi, Jun-Ho;Hong, Won-Hwa
      • Journal of the Korean housing association
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      • v.19 no.5
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      • pp.103-110
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      • 2008
    • The purpose of this study is to know how visual-field obstruction from fire smoke influences a resident's necessary time to reach fire escape and evacuation movement in a high-rise apartment housing. Generally, fire smoke not only gives visual-field obstruction and breath troubles to residents but interrupts their evacuation behavior. If a fire smoke layer is formed in the core department when evacuee enters at the evacuation staircase until, residents will be made to undergo a range of vision obstacle. In order to set a situation like that, participants wore eye bandage which had been made especially before the experiment. Also as a comparative standard, through no.1442 Japanese construction ministry notices about the building evacuation safety verification method, this study calculated smoke layer's dissent time and evacuation time. Then to compare with the former, the participants without an eye bandage joined a experiment once again. This study has understood how fire smoke effects on one's evacuation delay by analyzing residents' evacuation time to reach the staircase and movement route, however, in this study a toxic gas is not considered because it might threaten participants not to breathe.

    An Experimental Study on Smoke Movement by the External Wind in Road Tunnel Fires (도로터널 화재 시 외부 바람에 의한 연기거동 특성에 관한 실험적 연구)

    • Lee, Sung-Ryong
      • Tunnel and Underground Space
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      • v.24 no.4
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      • pp.308-315
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      • 2014
    • In this study, reduced scale experiments were carried out to evaluate the effect of external wind in a road tunnel fire. Experiments were conducted in a $1.1m{\times}0.5m{\times}50.4m$ tunnel. 4.5 litter gasoline was used as a fuel. Temperature, oxygen and carbon monoxide concentration were measured. Smoke reaching time to the tunnel exit was affected by the external wind. When a fire was fully developed, wind effect is reduced compared with the early stage of a fire. CO concentration was reached at more than 1,500 ppm.

    Bioinspired superhydrophobic steel surfaces

    • Heo, Eun-Gyu;O, Gyu-Hwan;Lee, Gwang-Ryeol;Mun, Myeong-Un
      • Proceedings of the Korean Vacuum Society Conference
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      • 2011.02a
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      • pp.509-509
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      • 2011
    • Superhydrophobic surfaces on alloyed steels were fabricated with a non-conventional method of plasma etching and subsequent water immersion procedure. High aspect ratio nanopatterns of nanoflake or nano-needle were created on the steels with various Cr content in its composition. With CF4 plasma treatment in radio-frequence chemical vapor deposition (r.-f. CVD) method, steel surfaces were etched and fluorinated by CF4 plasma, which induced the nanopattern evolution through the water immersion process. It was found that fluorine ion played a role as a catalyst to form nanopatterns in water elucidated with XPS and TEM analysis. The hierarchical patterns in micro- and nano scale leads to superhydrophobic properties on the surfaces by deposition of a hydrophobic coating with a-C:H:Si:O film deposited with a gas precursor of hexamethlydisiloxane (HMDSO) with its lower surface energy of 24.2 mN/m, similar to that of curticular wax covering lotus surfaces. Since this method is based on plasma dry etching & coating, precise patterning of surface texturing would be potential on steel or metal surfaces. Patterned hydrophobic steel surfaces were demonstrated by mimicking the Robinia pseudoacacia or acacia leaf, on which water was collected from the humid air using a patterned hydrophobicity on the steels. It is expected that this facile, non-toxic and fast technique would accelerate the large-scale production of superhydrophobic engineering materials with industrial applications.

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