• 한국대기환경학회지
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• 제2권2호
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• pp.60-65
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• 1986

Atmospheric particulates were collected at a site near the front gate of the Yonsei University using nine stages Andersen air sampler and the distribution of seasonal particle size was investigated. Rubber, Pb and Zn contents of the collected particulates in each stage were determined. Particle size distribution of atmospheric particulate, which was made by concentration distribution curve method, was usually divided into two groups, course (particles larger than 1 - 2 $\mu m in diameter$) and fine (particles smaller than 1 - 2 \mu m in diameter$) groups, regardless of sampling period. More than 80 percent of the total rubber contents in atmospheric particulates were larger than $5 \mu m$ in diameter, meaning that most of rubber particles were originated from tire tread. After benzene extraction for 4 hrs, the extracts were analyzed by Curie-point pyrolysis gas chromatography for rubber content. Pb and Zn contents were determined by atomic absorption spectroscopy. The annual average concentration of rubber particles was $4.2 \mu g/m^3$, which corresponded to 2.2% of the annual average total suspended particulates. Average concentration of styrene brtadiene rubber was about five times that of natural rubber. Annual average concentrations of Pb and Zn were $1.2 \mu g/m^3 and 0.4 \mu g/m^3$ respectively, which corresponded to about 0.7% and 0.2% of the annual average total suspended particulates.

• 한국산업보건학회지
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• 제11권2호
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• pp.145-152
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• 2001

This study was performed to evaluate the coke oven emissions (COE) and polynuclear aromatic hydrocarbon levels in coke manu-facturing industry, secondary lead smelting industry and glass bottle manufacturing industry. 1. There were no significant difference between the means of personal samples and area samples by the types of industry(p>0.05). The levels of airborne total particulates of the secondary lead smelting industry was the highest($2.30mg/m^3$), and those of the coke manu-facturing industry and glass bottle manu facturing industry were $1.95mg/m^3$ and $1.37mg/m^3$. The concentration of COE was the highest in the glass bottle manufacturing industry($0.79mg/m^3$), and in order of $0.19mg/m^3$ in the coke manufacturing industry and $0.06mg/m^3$ in the secondary lead smelting industry. COE/total particulates(%) was highest in the glass bottle manufacturing industry(58.1%) and in order of 10.3% in the coke manufacturing industry and 3.1% in secondary lead smelting industry. There were significant differences in the total particle concentration and COE by the types of industry(p<0.05). 2. The levels of airborne total particulates was the highest at the smelting process of secondary lead smelting industry($2.30{\pm}0.72mg/m^3$), and the lowest at the smelting process of glass bottle manufacturing industry ($0.99{\pm}1.22mg/m^3$) Concentration of COE was the highest at the casting process of glass bottle manufacturing industry ($1.09{\pm}1.15mg/m^3$), the lowest at the smelting process of secondary lead smelting industry ($0.06{\pm}0.03mg/m^3$). The COE/total particulates(%) was the highest at the casting process of glass bottle manufacturing industry($65.9{\pm}20.5%$), and the lowest at the smelting process of secondary lead smelting indusry($3.1{\pm}2.7%$). 3. There were positive correlations between level of The airborne total particulates and concentration of COE in coke manufacturing industry and glass bottle manufacturing industry (p<0.05), but negative correlation in secondary lead smelting industry. 4. The numbers of case and rates that over the Threshold Limit Values(TLVs) were 24 (77.4%)cases in glass bottle manufacture, 14(23.7%) cases in the coke manufacturing industry and no one case in secondary lead smelting industry. Total numbers of case and rates that over TLVs were 38( 35.5%) cases. 5. The limit of detection(LOD) for PAH was $10{\mu}g/ml$ in standard sample. All PAH levels of the cokes manufacturing industry and the secondary lead smelting industry and the glass bottle manufacturing industry were trace or not to detect.

• 한국환경성돌연변이발암원학회지
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• 제15권2호
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• pp.131-139
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• 1995

Air suspedned particulates are the most serious factor among air pollutants in Seoul and their extracts have been revealed to be pulmonary carcinogenes. Air particulates were collected at a site representative of the high traffic area of Seoul from December 1993 to May 1994. Polycyclic aromatic hydrocarbons (PAHs) and nitroarenes in organic extracts of air particulates were determined by gas chromatography and mutagenicity of particle extracts was evaluated by the pre-incubation procedure with Salmonella typhirnurium TA98 and TA 98NR. The average concentration of total suspended particulates and inhalable (less than 10 $\mu$m) particulates were 169.63 $\mu g/m^3$, 141.92 $\mu g/m^3$, respectively. The relative contribution of organic matters was highest in neutral fraction and was lowest in basic fraction. Among identified 20 PAHs, the level of PAHs with 4-benzen ring i.e., pyrene, benzo(a)anthracene and chrysene were much higher than the PAHs with higher ring numbers. The mutagenicity of air particulates was much higher in the presence of rat liver microsomai fraction (S9 mixture) than that observed in its absence, which indicates that air particulates contained both direct and indirect mutagens. Nitroarenes in this study were not almost detected but mutagenicity of their fraction was higher. These results are represent to research for the identification of nitroarenes in the forward study.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2003년도 International Symposium on Clean Environment
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• pp.19-26
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• 2003

The dispersion of recycled particulates in the complex coastal terrain containing Kangnung city, Korea was investigated using a three-dimensional non-hydrostatic numerical model and lagrangian particle model (or random walk model). The results show that particulates at the surface of the city that float to the top of thermal internal boundary layer (TIBL) are then transported along the eastern slope of the mountains with the passage of sea breeze and nearly reach the top of the mountains. Those particulates then disperse eastward at this upper level over the coastal sea and finally spread out over the open sea. Total suspended particulate (TSP) concentration near the surface of Kangnung city is very low. At night, synoptic scale westerly winds intensify due to the combined effect of the synoptic scale wind and land breeze descending the eastern slope of the mountains toward the coast and further seaward. This increase in speed causes development of internal gravity waves and a hydraulic jump up to a height of about 1km above the surface over the city. Particulate matter near the top of the mountains also descends the eastern slope of the mountains during the day, reaching the central city area and merges near the surface inside the nocturnal surface inversion layer (NSIL) with a maximum ground level concentration of TSP occurring at 0300 LST. Some particulates were dispersed following the propagation area of internal gravity waves and others in the NSIL are transported eastward to the coastal sea surface, aided by the land breeze. The following morning, particulates dispersed over the coastal sea from the previous night, tend to return to the coastal city of Kangnung with the sea breeze, developing a recycling process and combine with emitted surface particulates during the morning. These processes result in much higher TSP concentration. In the late morning, those particulates float to the top of the TIBL by the intrusion of the sea breeze and the ground level TSP concentration in the city subsequently decreases.

• 한국대기환경학회지
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• 제8권4호
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• pp.247-256
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• 1992

Airborne suspended particulates were collected at Shinchon by a high volume cascade impactor from Sep. 1990 to Aug. 1991. Organic matter was extracted from particulates and fractionated by liquid-liquid extraction and thin layer chromatography. Substances in the PAHs and nitroarenes'subfraction of neutral fraction were determined by capillary gas chromatography. Based on unit risk estimates by multi-stage model of benzo[a]pyrene and the results of exposure estimates, cancer risk was assessed. The annual average concentration of total suspended particulates was 201.77g/$m^3$. The percentage of fine particulates was 57.40. The concentration of total suspended particulates showed seasonal variations and was high in winter and spring. The average concentration of extractable organic matter was 8.12g/$m^3$. In all, 21 PAHs were identified and quantified. The annual concentration of fluoranthene was 2.38ng/$m^3$, and that was the highest value of all PAHs. A carcinogenic compound, benzo[a]pyrene, was at a concentration of 1.84ng/$m^3$. All the 10 nitroarenes were also identified and quantified. The major nitroarene in the Shinchon area was 2,7-dinitrofluorene. The annual concentration of 1-nitropyrene was 1.56ng/$m^3$. Concentrations of PAHs and nitroarenes were high in winter and low in summer. The life time excess risk estimates of benzo[a]pyrene was calculated as 0.96 persons/a million population in this experiment. In the rank of relative potenties, carcinogenic effects of the other PAHs were calculated as 0.004-0.108 persons/a million population.

• Journal of Preventive Medicine and Public Health
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• 제12권1호
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• pp.49-55
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• 1979

In order to investigate air pollution by heavy metals in Seoul city, the suspended particulates in the atmosphere were sampled with high volume air sampler in industrial area(Ku Ro Dong), commerical(Kwang Hwa Moon) and residential(Shin Chon Dong) from January to November, 1977. The sampled suspended particulates were digested and extracted from suspended particulates with the acidic solution by reflux-extraction technique, and were measured by atomic absorption spectrophotometry. And mercury was measured by mercury analyzer applying the reducing sublimation technique. Among heavy metals analyzed, the iron was identified at the highest level in the suspended particulates and the chromium was the least. Through the surveyed area, the concentration of heavy metals of the industrial area was comparatively high among others and the commercial was the second. It was detected that lead was the most concentrated in the suspended particulate of the commercial area, that might be caused of the traffic emissions. The seasonal variations were analyzed and the correlations among heavy metals and total suspended particulate were also calculated. Especially, the iron was highly correlated with total suspended particulate in all the surveyed areas.

• Asian Journal of Atmospheric Environment
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• 제1권1호
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• pp.19-27
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• 2007

Hazardous polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) are mainly originated from imperfect combustion of fossil fuels such as petroleum and coal. The consumptions of not only petroleum but also coal have been increasing in the East Asian countries. This review describes the result of international collaboration research concerning characteristics and major contributors of atmospheric PAHs and NPAHs in cities in Japan, Korea, China and Russia. We collected airborne particulates in ten cities in the above countries and six PAHs and eleven NPAHs were determined by HPLC methods using fluorescence and chemiluminescence detections. The total PAH concentrations were much higher in Chinese cities (Fushun, Tieling, Shenyang and Beijing) than those in other cities (Vladivostok, Busan, Kanazawa, Kitakyushu, Sapporo and Tokyo). The total NPAH concentrations were also higher in Chinese cities than those in the other cities. The [NPAH]/[corresponding PAH] ratios are much larger in diesel-engine exhaust particulates than those in coal-burning particulates. The [1-nitropyrene]/[pyrene] ratio of airborne particulates was much smaller in the four Chinese cities, suggesting that coal combustion systems such as coal heaters were the main contributors. On the other hand, the ratios were larger in Korean and Japanese cities, suggesting the large contribution of diesel-engine vehicles.

• 한국환경과학회지
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• 제2권3호
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• pp.217-225
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• 1993

This study was performed at Sa-Sang Industrial area in Pusan City. To measure the total suspended particulates(T.S.P) and $SO_3$ following places was selected industrial area, down town, residentail area. T.S.P was collected on glass filters by High-Volume Air Sampler, $SO_3$ was measured by PbO2 Candle method. The collected T.S.P was analyzed for various anlon(for example, $NO_3$, $SO_4$, $PO_4$, F, Cl) by ion Chromatography, and Pb by Inductively Coupled Plasma.

• 한국환경과학회지
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• 제2권3호
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• pp.201-206
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• 1993

The concentration of Total Suspended Particulates(T.S.P), size distribution of suspended particulates, and soluble anions of T.S.P in atmosphere of industrial region in Busan were investigated. T.S.P was measured by High-Volume Air Sampler and particle size distribution was measured by Anderson Air Sampler. We analyzed the chemical component of the T.S.P by ion Chromatography and measure4 the shape and size of T.S.P by Scanning Electron Micrography The small size of T.S.P mainly exist in industrial region, but the large size of T.S.P mainly exist in residentail area.

• Journal of Korean Society for Atmospheric Environment
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• 제10권E호
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• pp.325-331
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• 1994

Organic extracts of diesel- exhaust particulates were analyzed for mutagenicity using Ames Salmonella typhimurium assay system. An experimental diesel microbus used was drived on the chassis dynamometer according to CVS-75 mode. The samples were taken from the mixed gases in a dilution tunnel. With a high-volume air sampler equipped with double filter holders, particulate matters were collected on a teflon-coated glass fiber filter placed behind a activated carbon filter. After ultrasonic extraction with benzene- ethanol and evaporation to dryness, the residue was dissolved in dimethylsulfoxide. Each sample was tested toward 2 strains, TA100 and TA98 by the pre-incubation method in the absence and presence of S-9mix. Average concentration of diesel- exhaust particulates was about 116.6mg/m$^3$, and 44.1~62.2 ％ to the total weight of particulates, consisted of organic matters. The mutagenicities of diesel- exhaust particulate organic matters were 4,512 and 2,205 revertants/m$^3$ toward TA100 without and with S-9mix, respectively. Those toward TA98 were 13,367 and 3,715 revertants/m$^3$, respectively.