• Journal of the Korean Chemical Society
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• v.23 no.1
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• pp.20-29
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• 1979

The origin of barriers to internal rotation of hydrogen peroxide and ethane is investigated by using the concept of Bonding and Antibonding Regions. The strong bond formations between the axial and end atoms on the same side make the real charge densities in these molecules less dependent on conformations than those in the hypothetical molecules having no axial atoms. Thus, the existence of the axial atoms should induce the migration of the transition density from the Bonding region to the Antibonding region. Barrier to internal rotation can be understood in terms of this migration of the transition density to such an extent that the change in nuclear-nuclear repulsion energy becomes the dominating part of the total perturbation energy.

• Bulletin of the Korean Chemical Society
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• v.33 no.11
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• pp.3618-3624
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• 2012

Photodissociation dynamics of propiolic acid ($HC{\equiv}C-COOH$) at 212 nm in the gas phase was investigated by measuring rotationally resolved laser-induced fluorescence spectra of OH ($^2{\Pi}$) radicals exclusively produced in the ground electronic state. From the spectra, internal energies of OH and total translational energy of products were determined. The electronic transition at 212 nm responsible for OH dissociation was assigned as the ${\pi}_{C{\equiv}C}{\rightarrow}{\pi}^*{_{C=O}}$ transition by time-dependent density functional theory calculations. Potential energy surfaces of both the ground and electronically excited states were obtained employing quantum chemical calculations. It was suggested that the dissociation of OH from propiolic acid excited at 212 nm should take place along the $S_1/T_1$ potential energy surfaces after internal conversion and/or intersystem crossing from the initially populated $S_2$ state based upon the potential energy calculations and model calculations for energy partitioning of the available energy among products.

• Korean Journal of Materials Research
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• v.29 no.9
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• pp.525-531
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• 2019

The widespread use of automobiles has greatly increased energy demand and exhaust gas pollution. In order to save energy, reduce emissions and protect the environment, making lightweights automobiles is an effective measure. In this paper, carbon fiber composites and automobile B-pillars are briefly introduced, and then the mechanical properties and impact resistance of the DC590 steel B-pillars and carbon fiber composites B-pillars are simulated by the ABAQUS finite element software. The results show that the quality of compound B-pillars is reduced by 50.76 % under the same dimensions, and the mechanical property of unit mass is significantly better than that of metal B-pillars. In the course of a collision, the kinetic energy of the two B-pillars is converted into internal energy, but the total energy remains the same; the converted internal energy of the composite B-pillars is greater, the deformation is smaller and the maximum intrusion and intrusion speed is also smaller, indicating that the anti-collision performance of the composite B-pillars is excellent. In summary, the carbon fiber composites can not only reduce the quality of the B-pillars, but also improve their anti-collision performance.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.2
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• pp.77-87
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• 2018

In this study, the effects of operating conditions on the formation of reversible and irreversible fouling were investigated in the filtration using ceramic membrane for water treatment process. The effect of coagulation pretreatment on fouling formation was also evaluated by comparing the performance of membrane filtration both with and without addition of coagulant. A resistance-in-series-model was applied for the analysis of membrane fouling. Total resistance (RT) and internal fouling resistance (Rf) increased in the membrane filtration process without coagulation as membrane flux and feed water concentrations increased. Internal fouling resistance, which was not recovered by physical cleaning, was more than 70% of the total resistance at the range of the membrane flux more than $5m^3/m^2{\cdot}day$. In the combined process with coagulation, the cake layer resistance (Rc) increased to about 30-80% of total resistance. As the cake layer formed by coagulation floc was easily removed by physical cleaning, the recovery rate by physical cleaning was 54~90%. It was confirmed from the results that the combined process was more efficient to recover the filtration performance by physical cleaning due to higher formation ratio of reversible fouling, resulted in the mitigation of the frequency of chemical cleaning.

• Journal of the Korea Furniture Society
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• v.28 no.3
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• pp.224-232
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• 2017

Building energy saving have been put effort in a long time since buildings consume about 40.6% of total energy use, where heating, cooling and electrical lighting requirement results in energy consumption of building significantly. The window is an important part of building envelope, it usually brings a certain heat load from solar radiation while it allows light passing through, and properly leads to overheating in summer, hence the cooling load increase sand cause of thermal uncomfortable factor. The purpose of this study was to evaluate internal shade performance according to color and materials. There is growing interest in improving the sense of comfort among students who spend most of their time in the classroom. The study examined thermal environment and light environmental performance according to the color and materials of internal blinds to the school classroom. The results of this study were as follows; Among wooden blinds, aluminium blinds, and polyester blinds, the aluminium blinds were most excellent. In addition, among white blinds, light brown blinds, dark brown blinds, the light brown were most excellent.

• Proceedings of the KIEE Conference
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• 1999.07g
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• pp.3141-3143
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• 1999

Fuel cell systems offer high energy efficiencies for transportation application. In addition, they can use alcohols and alternative fuels as the fuel, while producing little or no noxious emissions. Fuel cell-powered energy source should be competitive in performance characteristics and in capital and maintenance costs with internal combustion engine systems. From computer simulation program, battery and fuel cell energy output and total power profile, motor power, battery energy output, fuel cell energy output. It simulates the performance of fuelcell/battery powered energy source operation over any user inputted transit route cycle, and provides performance criteria through user specifications for preliminary design consideration.

• Journal of the Korean Society of Safety
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• v.36 no.3
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• pp.66-73
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• 2021

This report documents the results of an at-power internal events Level 1 Probabilistic Safety Assessment (PSA) for a Korea research reactor (KRR). The aim of the study is to determine the accident sequences, construct an internal level 1 PSA model, and estimate the core damage frequency (CDF). The accident quantification is performed using the AIMS-PSA software version 1.2c along with a fault tree reliability evaluation expert (FTREX) quantification engine. The KRR PSA model is quantified using a cut-off value of 1.0E-15/yr to eliminate the non-effective minimal cut sets (MCSs). The final result indicates a point estimate of 4.55E-06/yr for the overall CDF attributable to internal initiating events in the core damage state for the KRR. Loss of Electric Power (LOEP) is the predominant contributor to the total CDF via a single initiating event (3.68E-6/yr), providing 80.9% of the CDF. The second largest contributor is the beam tube loss of coolant accident (LOCA), which accounts for 9.9% (4.49E-07/yr) of the CDF.

• Journal of the Korean Society of Visualization
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• v.3 no.1
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• pp.3-19
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• 2005

Novel optical techniques are presented for three-dimensional tracking of nanoparticles; Optical Serial Sectioning Microscopy (OSSM) and Ratiometric Total Internal Reflection Fluorescent Microscopy (R-TIRFM). OSSM measures optically diffracted particle images, the so-called Point Spread Function (PSF), and dotermines the defocusing or line-of-sight location of the imaged particle measured from the focal plane. The line-of-sight Brownian motion detection using the OSSM technique is proposed in lieu of the more cumbersome two-dimensional Brownian motion tracking on the imaging plane as a potentially more effective tool to nonintrusively map the temperature fields for nanoparticle suspension fluids. On the other hand, R-TIRFM is presented to experimentally examine the classic theory on the near-wall hindered Brownian diffusive motion. An evanescent wave field from the total internal reflection of a 488-nm bandwidth of an argon-ion laser is used to provide a thin illumination field of an order of a few hundred nanometers from the wall. The experimental results show good agreement with the lateral hindrance theory, but show discrepancies from the normal hindrance theory. It is conjectured that the discrepancies can be attributed to the additional hindering effects, including electrostatic and electro-osmotic interactions between the negatively charged tracer particles and the glass surface.

• Journal of Hydrogen and New Energy
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• v.9 no.1
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• pp.38-45
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• 1998

An energy crisis is expected in near future. Fossil fuel such as oil and natural gas has been used and will be no longer supplied enough to demand in the beginning of coming century. The use of the fuel makes a lot of environmental pollution to threaten human being's health especially in big cities and produces a lot of $CO_2$ to make green house effect of the earth. It is the time to use clean fuel such as hydrogen to prevent the expected energy crisis and the pollution. A new engine such as fuel cell can be used instead of the conventional internal combustion engine with 2 to 3 times higher efficiency of the conventional engine. The fuel cell uses hydrogen and oxygen and produces electric energy and pure water, which is a calm engine without air pollution. In big cities the city buses and the taxies powered by hydrogen fuel cells are suggested to be operated for clean environment. A model of the total energy system for production, transportation and utilization of hydrogen is calculated.

• KIEAE Journal
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• v.15 no.2
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• pp.117-122
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• 2015

Purpose: Generally, 30% of the total energy consumption in office building is used for artificial indoor lightings, and almost 75-85% of electric power in fluorescent and Light-Emitting Diode (LED) lightings can be dissipated as a form of heat into indoor environment. The heat generated by indoor lightings can cause the increase of cooling load in office buildings. Thus, it its important to consider indoor lightings as a heat and light source, simultaneously. Method: In this study, we installed two kinds of indoor lightings including fluorescent and LED lightings and measured surface temperature of both indoor lightings. In addition, we obtained ambient temperature of indoor space and finally calculated total heat dissipated from plenum area and surface of lightings. Result: Total indoor heat gain was 87.17Wh and 201.36Wh in cases of six 40W-LED lightings and 64W-fluorescent lightings, respectively.