• Journal of Korean Society on Water Environment
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• v.32 no.1
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• pp.98-107
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• 2016

This study examined the effects of environmental conditions and the presence of refractory organic matter on oxidation rates of total organic carbon (TOC) measurements based on high temperature combustion and ultraviolet-sulfate methods. Spectroscopic indices for prediction of oxidation rates were also explored using the UV spectra and fluorescence excitation-emission matrix (EEM) of humic acids. Furthermore, optimum TOC instrument conditions were suggested by comparing oxidation rates of a standard TOC material under various conditions. Environmental conditions included salts, reduced ions, and suspended solids. Salts had the greatest influence on oxidation rates in the UV-sulfate method. However, no effect was detected in the high temperature combustion method. The UV-sulfate method showed lower humic substance oxidation rates, refractory natural organic matter, compared to the other methods. TOC oxidation rates for the UV-sulfate method were negatively correlated with higher specific-UV absorbance, humification index, and humic-like EEM peak intensities, suggesting that these spectroscopic indices could be used to predict TOC oxidation rates. TOC signals from instruments using the UV-sulfate method increased with increasing chamber temperature and increasing UV exposure durations. Signals were more sensitive to the former condition, suggesting that chamber temperature is important for improving the TOC oxidation rates of refractory organic matter.

• Journal of Korean Society on Water Environment
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• v.24 no.6
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• pp.741-749
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• 2008

Many small-scale ponds that serve as ecological habitat, recreation and irrigation are faced to eutrophication problem, which causes aesthetic nuisance and ultimately loss of their functions. Thus accurate evaluation of the trophic state of these ponds is essential to provide rational information to the stakeholders so that they can develop effective management actions. In this study, the trophic state of a small pond (Wonheung) that experiencing water quality degradation due to vicinity land development was assessed using various Trophic State Indexes (TSIs) and statistical analysis including Principal Components Analysis (PCA) based on the field monitoring data obtained from May to December, 2007. The results showed that the pond is under eutrophic state with average total nitrogen (T-N) and total phosphorus (T-P) concentrations of $708.1{\mu}g/L$ and $59.3{\mu}g/L$, respectively. The factor loading plot obtained from PCA showed distinct two influencing factors, PC 1 and PC 2. PC 1 was grouped by T-P, Chlorophyll a (Chl-a), suspended solids (SS), TN/TP ratio, and transparency that all strongly related to the eutrophication state, while PC 2 by temperature, conductivity, dissolved oxygen (DO) and turbidity that explains the seasonal water quality variations. The limiting factor was identified as light rather than phosphorus by both T-N/T-P ratio and TSI indexes analysis. The results and methodology adopted in this study can be used for water quality assessment for other small ponds and lakes.

• Journal of the Korean Institute of Landscape Architecture
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• v.33 no.6 s.113
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• pp.51-77
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• 2006

Pond management is a critical part of overall golf course management, both during growth and maintenance modes of turf care. This study investigated 48 ponds in nine 18- or 27-hole golf courses to analyze the environmental characteristics of ponds. The research process had three phases: (1) inventory and analysis of grading plans and drainage plans, (2) field verification and interviews with greenskeepers, and (3) analyses of water quality and statistics. All data were collected from May to August in 2004. The results of this study can be summarized as follows: 1. It is desirable to site a golf course in a small watershed with high watershed eccentricity to control storm water runoff efficiently and to minimize soil erosion during construction. 2. The siting and size of a pond should be determined through a land-use analysis of the watershed for the purpose of ecological management. The bigger the forest-to-golf course ratio, the better the water quality will be. 3. The size and capacity of each individual ponds varied and there were many somewhat longish rather than round ponds. 4. There were many differences among golf courses in naturalness of the ponds, and the correlation between naturalness and area of aquatic plants was very high. 5. Analyses of pond water quality indicated that the degrees of Dissolved Oxygen, Chemical Oxygen Demanded and Suspended Solids were relatively low values but Total Phosphorus and Total Nitrogen were too high. Therefore a systematic approach is needed to solve e problem. Pesticide residues were not detected in all ponds. 6. Water depth and area of hydrophyte should be considered when designing an ecological pond. 7. All ponds used storm water as a main source of water supply and added underground water. Aquatic plants and physical methods such as water aeration and spray fountains were the main choices for maintaining a healthy aquatic environment.

• Analytical Science and Technology
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• v.8 no.4
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• pp.759-770
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• 1995

By extensive studies with the quantitative status of the mineral constituents of thousands of water samples, it was found that almost in all natural waters irrespective of the surface or sub-surface sources, minimum 99.5% of the total amount of the cationic constituents are generally the contributions of 3 commonly present parameters viz. Ca, Mg and Na and that of the anionic species are same and contributed by $HCO_3$, Cl and $SO_4$ only. In the field of water works, all these major mineral substances are conventionally measured as their individual ions. But till now, no reliable and generalised methods or rules have been developed for the determination of the exact kinds of the individual salt components and their amounts from these ionic constituents normally present in water. As salt content, only the TDS (Total Dissolved Solids) parameter is frequently measured by evaporation of the water sample. But TDS can tell nothing about the kinds and amounts of the individual salts present in it. Considering the analytical importance of the estimation of the mineral substances as their individual salts, some generalised mathematical models have been developed by this research which are based on the 'hypothetical order of chemical combinations' as may occur among the ionic constituents. With the help of these models, one can easily assume the most probable salts with approximate quantities derived from the ionic constituents. In addition, approximate amount of Na content can also be estimated mathematically with simultaneous verification of the correctness of the water analysis results. The models are stated in this paper with practical illustrations and descriptions of the method of applications.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.1-10
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• 2012

Throughout much of the world, many ecological problems have arisen in watersheds where a significant portion of stream flows are diverted to support agriculture production. Within endorheic watersheds (watersheds whose terminus is a terminal lake) these problems are magnified due to the cumulative effect that reduced stream flows have on the condition of the lake at the stream's terminus. Within an endorheic watershed, any diversion of stream flows will cause an imbalance in the terminal lake's water balance, causing the lake to transition to a new equilibrium level that has a smaller volume and surface area. However, the total mass of Total Dissolved Solids within the lake will continue to grow; resulting in a significant increase in the lake's TDS concentration over time. The ecological consequences of increased TDS concentrations can be as limited as the intermittent disruption of productive fisheries, or as drastic as a complete collapse of a lake's ecosystem. A watershed where increasing TDS concentrations have reached critical levels is the Walker Lake watershed, located on the eastern slope of the central Sierra Nevada range in Nevada, USA. The watershed has an area of 10,400 sq. km, with average annual headwater flows and stream flow diversions of 376 million $m^3/yr$ and 370 million $m^3/yr$, respectively. These diversions have resulted in the volume of Walker Lake decreasing from 11.1 billion m3 in 1882 to less than 2.0 billion $m^3$ at the present time. The resulting rise in TDS concentration has been from 2,560 mg/l in 1882 to nearly 15,000 mg/l at the current time. Changes in water management practices over the last century, as well as climate change, have contributed to this problem in varying degrees. These changes include the construction of reservoirs in the 1920s, the pumpage of shallow groundwater for irrigation in the 1960s and the implementation of high efficiency agricultural practices in the 1980s. This paper will examine the impacts that each of these actions, along with changes in the region's climate, has had on stream flow in the Walker River, and ultimately the TDS concentration in Walker Lake.

• Membrane and Water Treatment
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• v.10 no.1
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• pp.1-11
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• 2019

The Intergovernmental Panel on Climate Change (IPCC) Fifth Assessment Report (AR5) predicted that recent extreme hydrological events would affect water quality and aggravate various forms of water pollution. To analyze changes in water quality due to future climate change, input data (precipitation, average temperature, relative humidity, average wind speed and sunlight) were established using the Representative Concentration Pathways (RCP) 8.5 climate change scenario suggested by the AR5 and calculated the future runoff for each target period (Reference:1989-2015; I: 2016-2040; II: 2041-2070; and III: 2071-2099) using the semi-distributed land use-based runoff processes (SLURP) model. Meteorological factors that affect water quality (precipitation, temperature and runoff) were inputted into the multiple linear regression analysis (MLRA) and artificial neural network (ANN) models to analyze water quality data, dissolved oxygen (DO), biological oxygen demand (BOD), chemical oxygen demand (COD), suspended solids (SS), total nitrogen (T-N) and total phosphorus (T-P). Future water quality prediction of the Anseongcheon River basin shows that DO at Gongdo station in the river will drop by 35% in autumn by the end of the $21^{st}$ century and that BOD, COD and SS will increase by 36%, 20% and 42%, respectively. Analysis revealed that the oxygen demand at Dongyeongyo station will decrease by 17% in summer and BOD, COD and SS will increase by 30%, 12% and 17%, respectively. This study suggests that there is a need to continuously monitor the water quality of the Anseongcheon River basin for long-term management. A more reliable prediction of future water quality will be achieved if various social scenarios and climate data are taken into consideration.

• Korean Journal of Ecology and Environment
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• v.44 no.4
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• pp.373-384
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• 2011

The objective of this was to determine how the seasonal intensive rainfall influenced the water quality, and to analyze the long-term temporal trend of water chemistry and spatial heterogeneity in the upstream watershed of Southern Han River using water quality dataset from 1997 to 2007. The largest seasonal variability in most parameters occurred during the two month July and August and there were closely associated with a large spate of summer monsoon rain. Total phosphorus (TP), chemical oxygen demand (COD), and suspended solids (SS) were greater during summer than any other seasons, and had a direct correlation with precipitation (r>0.4, p<0.01, n-120). In addition, dissolved oxygen (DO) had and inverse function with precipitation (r=-0.542, p<0.01). Overall, the data of total phosphorus (TP) and suspended solids (SS) showed that water quality was worst in Site I1, compared to the others. This was due to continuous effluents from the highlands' fields and cattle farms within the upstream area of Doam lake (Song stream). Based on the overall dataset, an efficient water quality management is required in the highlands and farms areas for better water quality with precipitation (r.0.4, p<0.01, n=120).

• Journal of the Korean Society for Marine Environment & Energy
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• v.14 no.1
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• pp.40-50
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• 2011

We study the characteristic and total flux of non-point pollutants such as total suspended solids (TSS), chemical oxygen demand (COD), dissolved nutrients, total phosphorus (TP) and total nitrogen (TN) in the storm water runoff from urban streams and sewer outlets of Banweol Industrial Complex around Shihwa Lake. The concentrations of non-point pollutants were generally increased with increasing of the duration and intensity of rainfall. Mean TSS concentration of Ansan stream was higher than that of sewer outlets but mean concentrations of COD, TP and TN were approximately 2~5 times higher of sewer outlet than of urban stream. TSS showed statistically positive relationships with COD and TP but it had negative correlation with dissolved nutrients. There was a significant correlation between total flux of non-point pollutants in the storm water runoff and total basin area of each sewer outlet, showing that the highest runoff flux was observed at 3rd sewer outlet which represents the largest basin area from Banweol industrial complex. Total runoff fluxes for TSS, COD, TP and TN in this study were 187,536 kg, 17,118 kg, 922 kg, 13,519 kg, respectively. Given the basin area of sewer outlet in Banweol industrial complex which corresponds only 3% from total catchment area around Shihwa Lake, enormous amount of non-point pollutants will be entered into Shihwa Lake without any treatment. It is necessary to manage and reduce of various non-point sources and pollutants because the runoff of nonpoint pollutants during storm events should be deteriorating the water quality of Shihwa Lake. Our results provides useful informations on the development of best managements practices (BMPs) for effective implementation of total pollution loads management system of Shihwa Lake.

• Korean Journal of Ecology and Environment
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• v.43 no.3
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• pp.437-450
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• 2010

Ecological influences of indigenous freshwater bivalve Unio douglasiae on the water quality and epilithic diatom community was examined with artificial stream (AST), which constructed in a laboratory daily receiving the eutrophic lake water. For the colonization of new periphyton community, forty commercial slide glasses were deposited as a substrate into the lowest part of each AST. Prior to 1 week, the AST was operated to induce the freely-colonization of the algal community in the absence of mussels. After the mussels was introduced at 435 indiv. $m^{-2}$ between step 1 and step 5, the passed water and substrates were daily collected to analysis the change of water quality and lotic and lentic algae abundance for 10 days. Compared to the control, turbidity (60.0% of control), suspended solids (62.5%), and chlorophyll-$\alpha$ (72.2%) in mussel-passed waters were decreased significantly, while a strong increase of ammonia (up to 800% of control) was companied with the decrease of dissolved oxygen (19.5% of control) and total phosphorus (23.9%), respectively. On average, the concentrations of suspended solids (67.0% of control) and chlorophyll-$\alpha$ (89.4%) in mussel-treated substrates were remarkably increased, however algal abundance in its water simultaneously decreased. These results indicate that incidentally or purposely mussel introductions can decrease organic matter of the stream and increase transparency of stream water, however, mussel-mediated nutrient and pseudofeces release may stimulate the adverse growth of periphyton or phytoplankton community in the lower stream or reservoir.

• Journal of The Korean Society of Agricultural Engineers
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• v.47 no.5
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• pp.3-13
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• 2005

The present study examined the 3 dimensional space distribution characteristics of sea water intrusion using data available from previous observations. For this study, we used 3D FEMWATER, which is a 3 dimensional finite element model. The target area was around Daechang-ri, Gimje-si, Jeollabuk-do. The area is relatively easy to formulate a conceptual model and has observation wells in operation for surveying sea water intrusion. Considering the uncertainty of numerical simulation, we analyzed sensitivity to hydraulic conductivity, which has a relatively higher effect. According to the result of the analysis, the variation of TDS concentration had an error range of $-1,336{\~}+107 mg/{\iota}$. Taking note that the survey data from observation wells were collected when the boundary between fresh water and sea water in the aquifer was in equilibrium, we set the range of time for numerical simulation and estimated the spatial distribution of TDS concentration as the range of sea water intrusion. According to the result of estimation, the spatial distribution of TDS concentration calculated when 1,440 days were simulated was taken as the range of sea water intrusion. Using the result of calculation, we can draw not only vertical views for a certain section but also horizontal views of different depth. These views will be greatly helpful in understanding the spatial distribution of the range of sea water intrusion. In addition, the result of this study can be used rationally in proposing an optimal quantity of water pumping through investigating the moving route of sea water intrusion over time in order to prevent excessive water pumping and to maintain an optimal number of water pumping wells per interval.