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The Formation Characteristics of THMs and HAAs in Chlorination of Raw Water of Different Organic Matter Characteristics (상수원수의 유기물 특성에 따른 염소처리시 THMs 및 HAAs의 생성특성)

  • Oh, Sun-Mi;Kim, Seung-Hyun;Lee, Min-Gyu;Xu, Mei-Lan;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.15 no.8
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    • pp.785-797
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    • 2006
  • The formation characteristics of trihalomethanes (THMs) and haloacetic acids (HAAs) were investigated in chlorination of raw water of different organic mallet characteristics. The samples used in this study were hydrophobic (N-HPO) and hydrophilic fraction (N-HPI) (which were concentrated and separated from Nakdong river water), and humic acid (HA) (which is known as a strong hydrophobic acid) as a reference organic matter, the specific UV absorbance (SUVA) of which was 2.19, 1.15 and 7.92, respectively. With increasing chlorine contact time, THMFP and HAAFP (the formation potential of THMs and HAAs) increased, but their increase was different depending on the organic mallet characteristics (i.e., for N-HPI, THMFP was higher than HAAFP, but the inverse result was obtained for N-HPO and HA and the ratio between them was greater for HA), and the mainly formed chemical species were CHCI$_3$ in case of THMs and dichloroacetic acid (DCAA) and trichloroacetic acid (TCAA) in case of HAAs for N-HPO and HA (and the ratios of CHCI$_3$ to total THMs and DCAA and TCAA to total HAAs for HA were higher than those for N-HPO), but for N-HPI, the ratio of brominated THMs was a little higher than that of CHCI$_3$ and the ratio of DCAA and TCAA to total HAAs was lower than that of N-HPO, although they are main chemical species in case of HAAs. Comparing THMFP and HAAFP with the increase in bromide concentration added with those in not adding it, the former increased greatly and its increase was higher for the organic mallet with stronger hydrophobicity, but the latter was lower for N-HPO and N-HPI and was similar for HA. The main chemical species with increasing bromide concentration were CHBt$_3$ in case of THMs regardless of organic matter characteristics, and dibromoacetic acid (DBAA) for N-HPO and N-HPI, DBAA and tribromoacetic acid (TBAA) for HA in case of HAAs. With increasing reaction temperature and pH, THMFP and HAAFP increased for the former, but for the latter, THMFP increased and HAAFP decreased, although the rate of increase or decrease was different with organic mallet characteristics.

Effect of n-6/n-3 fatty acid ratio on hepatic glycerolipid partitioning in second generation rats (n-6/n-3 지방산 비율이 차세대 랫드의 지질대사 분할에 미치는 영향)

  • Park, Byung-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.839-850
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    • 2017
  • The objective of this study was to investigate the effect of diets with different omega-6 (n-6) and omega-3 (n-3) fatty acid ratios (0, 1.2: 1, 8: 1, 19: 1) on mechanisms of partitioning of in vivo hepatic glycerolipid metabolism in next generation rats. Biomonitoring techniques were used in rats (jugular vein cannula were attached). The range of $^{14}CO_2$ exhaled by glycerolipid metabolism was 7.05-20.17% in the group having diet with n-6/n-3 ratio less than 8:1. It was the lowest in the control group. Total glycerolipid was the highest in the control group. For groups with different n-6/n-3 ratio, it had the following order: 19:1>8:1>1.2:1. Secreted triglyceride was decreased by 36.35%, 20.93%, and 13.72% in 1.2:1,8:1, and 19:1 groups, respectively, compared to that in the control group. The ratio of phospholipid to total glycerolipid was 1.38, 1.29, and 1.17 times higher in 1.2:1, 8:1, and 19:1 groups, respectively, compared to that in the control group. The ratio of $^{14}CO_2$ to total glycerolipid was 1.61, 1.52, and 1.29 times higher in 1.2:1, 8:1, and 19:1 groups, respectively, compared to that in the control group.

Nutrient Utilization of Broiler Litter and Bakery By-product Ration in Sheep (육계분-제과부산물 발효 완전혼합사료(TMR)의 면양 체내에서의 영양소 이용성 평가)

  • Kwak, W.S.;Yoon, J.S.;Jung, K.K.
    • Journal of Animal Science and Technology
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    • v.45 no.4
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    • pp.607-616
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    • 2003
  • This study was conducted to determine the effect of feeding a total mixed ration(TMR) of broiler litter(BL) and bakery by-product(BB) with additional BL or rice straw incorporated at 10% of dietary DM as a roughage source on behavior pattern, nutrient intake, digestibility, digestible nutrient intake, ruminal and blood parameters, and N balance of sheep. All the treatment diets were formulated to be isoenergetic[total digestible nutrients(TDN) 66.9%]. Compared with the conventional formulated feed - rice straw feeding system(control), feeding TMR with BL(T1) or rice straw(T2) at 10% of dietary DM resulted in reduced eating, ruminating and total chewing time(P<0.05), similar DM intake, low(P<0.05) digestible DM, OM, fiber and total nutrients intake, low(P<0.05) nutrients digestibilities except EE, similar ruminal characteristics(pH, VFA concentrations and ratios, efficiency of carbohydrate fermentation, NH3-N), and favorable N digestion and retention. There were no differences in the above parameters between T1 and T2 with the exception of increased(P<0.05) eating, ruminating and total chewing time for T2. These results suggested that a TMR of BL and BB with or without rice straw may replace the conventional formulated feed and rice straw in ruminant diets successfully and furthermore feeding the TMR with rice straw made sheep behavior pattern more favorable.

A Study on Formation Pattern of DBPs by Disinfection of Drinking Raw Water II (음용 원수의 염소소독에 의한 소독부산물 생성패턴에 관한 연구 II)

  • Lee, Kang Jin;Hong, Jee Eun;Pyo, Heesoo;Park, Song-Ja;Yoo, Je Kang;Lee, Dae Woon
    • Analytical Science and Technology
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    • v.17 no.1
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    • pp.69-81
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    • 2004
  • The formation pattern of DBPs (disinfection by-products) in raw water treated with hypochlorite, chlorine disinfectant was studied. TOC (total organic carbon), residual chlorine, turbidity and 14 DBPs in raw water from Han-river and Nakdong river during 1 ~ 14 days were determined. Total DBPs in Han river was 101.3 ng/mL (789.6 nM) after 7days and THMs (trihalomethanes) are the dominant portion of 68%. HAAs (haloacetic acids) and chloral hydrate were determined 19% and 10% respectively. In Nakdong river total DBPs was 98.4 ng/mL (678.6 nM) and dominant class was HAAs. (55.8 ng/mL, 57%) THMs(34%) and N-compounds like HANs (haloacetonitriles, 5%) and chloropicrin were increased. It may be explained that high concentration of NH4-N in Nakdong river react with chlorine produced chloramine and this formed different pattern of DBPs. As a result, total DBPs formation pattern depends on raw water and disinfectant and in generally the initial concentration of acidic HAAs was high and THMs was increased gradually.

Morphological Development of Egg and Larvae of Gnathopogon strigatus (Gobioninae) (줄몰개(Gnathopogon strigatus)의 난 발생 및 자치어 형태 발달)

  • Kim, Kyeong-Mu;Jeon, Hyoung-Joo;Song, Ha-Yun
    • Korean Journal of Ichthyology
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    • v.31 no.3
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    • pp.131-140
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    • 2019
  • This study is to observe species identification and early life history of Gnathopogon strigatus and to use it as a basis for taxonomic studies and conservation of species. For the experiments, the mature adults were collected at the Wang-suk Stream located in Namyang-ju city, Gyeong-gi Province and eggs were artificially fertilized by the wet method in the laboratory. The shape of the fertilized egg was globular, adhesive, opaque white in color and had no oil globules. The fertilized egg was 1.66~1.88 mm (average 1.76 mm, n=30) in diameter. The blastular stage occurred at 3 hours 05 minutes after fertilization and the gastrular stage was detected at 8 hours 30 minutes after fertilization. The embryo began to hatch about 54 hrs after fertilization under water temperature of $23{\pm}1^{\circ}C$ and the newly hatched larva (yolksac larva) were 4.1~4.7 mm (mean 4.4 mm, n=20) in total length (TL). The fourth day after hatching, the postlarva were 5.4~5.9 mm (mean 5.6 mm, n=20) in total length, their york sacs were completely absorbed and Start eating Artemia sp. Ten days after hatching, flexion larva were begins Notochord flexion were 7.5~8.6 mm (mean 8.1 mm, n=20) in total length. Sixteenth day after hatching, postflexion larva were complete Notochord flexion were 8.2~9.7 mm (mean 9.1 mm, n=20) in total length. At thirty-eight days after hatching, Juvenile were arrive integer all fin rays and similar to those of adults were 11.3~15.5 mm (mean 13.3 mm, n=20) in total length.

Dietary intake of fat and fatty acids by 1-5-year-old children in Korea: a cross-sectional study based on data from the sixth Korea National Health and Nutrition Examination Survey

  • Baek, YounJoo;Shim, Jae Eun;Song, SuJin
    • Nutrition Research and Practice
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    • v.12 no.4
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    • pp.324-335
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    • 2018
  • BACKGROUND/OBJECTIVES: We examined dietary fat intake and the major food sources by young children in Korea. SUBJECTS/METHODS: A total of 1,041 children aged 1-5 years were identified from the 2013-2015 Korea National Health and Nutrition Examination Survey. Data on total fat and fatty acid intake were obtained by a single 24-h dietary recall. Food sources were identified based on the amounts of total fat and fatty acids consumption according to each food. Fat and fatty acid intakes and their food sources were presented by age group (1-2-y, n = 401; 3-5-y, n = 640). Fat and fatty acid intakes were also evaluated according to socioeconomic characteristics. RESULTS: The mean intake of fat was $27.1{\pm}0.8g$ in the 1-2-y group and $35.5{\pm}0.7g$ in the 3-5-y group, and about 23% of the total energy was obtained from fat in both age groups. The mean intake of saturated fatty acids (SFA) was $10.5{\pm}0.3g$ in the 1-2-y group and $12.7{\pm}0.3g$ in the 3-5-y group, with the 1-2-y group obtaining more energy from SFA than the 3-5-y group (9.2% vs. 8.3%). The mean intake of polyunsaturated fatty acids (PUFA) was $6.3{\pm}0.1g$ in the total subjects, with $0.8{\pm}0.03g$ of n-3 fatty acids and $5.5{\pm}0.1g$ of n-6 fatty acids being consumed. Milk, pork, and eggs were major food sources of total fat, SFA, and monounsaturated fatty acids, and soybean oil was the main contributor to PUFA in both age groups. In the 1-2-y group, children in rural areas had significantly higher intake of PUFA and n-3 fatty acids than did those in urban areas. CONCLUSIONS: Our findings provide current information on dietary fat intake among young Korean children and could be used to establish dietary strategies for improvement of health status.

Comparison of Fatty Acid Composition of Wild and Cultured Sea Cucumber Apostichopus japonicus (자연산과 양식산 해삼(Apostichopus japonicus)의 지방산 조성 비교)

  • Jin, Feng;Md, Anisuzzaman;Jeong, U-Cheol;Choi, Jong-Kuk;Yu, Hak-Sun;Kang, Seung-Wan;Kang, Seok-Joong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.49 no.4
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    • pp.474-485
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    • 2016
  • This study compared the fatty acid composition of wild and cultured specimens of the sea cucumber Apostichopus japonicus. We extracted total lipids from the specimens and determined their fatty acid compositions through capillary gas chromatography, resulting in the identification of 53 fatty acids. We found that wild sea cucumbers were rich in palmitoleic (C16:1n-7) and eicosapentaenoic acid (C20:5n-3), whereas cultured specimens were rich in eicosenoic (C20:1n-9) and arachidonic acid (C20:4n-6). In both types of sea cucumbers, the highest percentage of polyunsaturated fatty acids (PUFA) consisted of polar lipids (PL), followed by total lipids (TL) and neutral lipids (NL). Cultured sea cucumbers contained a higher percentage of total lipids (TL) than wild sea cucumbers did, whereas there was no significant difference between the two groups in the percentages of neutral (NL) and polar lipids (PL).

Tolerance Range Analysis of Fish on Chemical Water Quality in Aquatic Ecosystems

  • Kim, Jeong-Kyu;Han, Jeong-Ho;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.43 no.4
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    • pp.459-470
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    • 2010
  • In this study, we analyzed fish tolerance guilds in mainstems and tributaries of 65 streams and rivers arid their relations to water quality using dataset sampled from April to November, 2009. For the study, water quality parameters including biochemical oxygen demand (BOD), electric conductivity (EC), total nitrogen (TN), total phosphorus (TP), ammonia nitrogen ($NH_3$-N), nitrate nitrogen ($NO_3$-N) and phosphate phosphorus ($PO_4$-P) were analyzed in the laboratory and also tolerance ranges in 3 category fishes of sensitive, intermediate, and tolerant species with high abundance were analyzed. According to fish guild analysis, tolerant species was 58% of the total community and the proportion of omnivore species was 63% of the total, indicating a degradation of habitats and water quality. Water quality was shown typical longitudinal gradients from the headwater to the down-river; TN and TP increased toward the down-rivers except for the big point-source area and ionic contents, based on, electric conductivity showed same pattern. Tolerance guild analysis of 9 major species with high abundance indicated that sensitive groups had narrower tolerance range in the water quality than the groups of intermediate and tolerant species. In contrast, tolerant groups including Zacco platypus, Carassius auratus, and Opsarichthys uncirostris amurensis had wider tolerance ranges than the groups of sensitive and intermediate species. Thus, each group was evidently segregated from the tolerance levels. Principal Component Analysis (PCA) employed for the relations of water quality to fish species in each groups suggests that water quality had highest eigenvalues with fish species in the 1st axis of the PCA and nitrogen (TN, $NH_3$-N, $NO_3$-N) and phosphorus (TP) were key components differentiating three groups of sensitive, intermediate and tolerance guilds.

Dose-Response Effects of n-3 Polyunsaturated Fatty Acids Supplement on the Metabolism of Streptozotocin-Induced Diabetic Rats (n-3 고도불포화 지방상 수준을 달리한 식이가 Streptozotocin으로 유발된 당뇨쥐의 대사에 미치는 영향)

  • Kim, Tae-Suk;Choi, Eun-Jin;Joh, Yong-Gae
    • Journal of the Korean Applied Science and Technology
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    • v.9 no.1
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    • pp.15-23
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    • 1992
  • This study was aimed to observe dose-response effects of squid liver oil enriched in n3 polyunsaturated fatty acids(n-3 PUFA) on the metabolism of streptozotocint(STZ)-induced diabetic rats. In this experiment, 24 STZ-induced diabetic male rats of Sprague Dawley strain were divided into 4 groups and fed for 4 weeks with basal diet(0%). 33%,67% and 100% squid liver oil(SLO) of total fat content, and 6 normal rats were fed with 0% SLO diet at the same time. The results obtained were as follows: 1. Rat group fed with 33% SLO diet showed the least body weight loss and changes in blood glucose, while ones of 100% SLO diet showed the highest level. 2. Serum total protein and ratio of albumin to globulin of all the groups were below the standard level, but did not show significantly different among diet groups. 3. Serum creatinine concentration of all the groups were stayed whthin normal range, but BUN were 3 to 4 times higher than normal rats. BUN concentration of rats fed with 0% and 33% SLO diet was significantly lower than those of others. 4. Total-cholesterol level of serum increased in all the groups except 33% SLO diet, but since HDL-chol, levels and TG concentration went up with an incerase of SLO in the diets, the ratio of HDL-chol. to total-chol, of rats fed with 67% and 100% SLO diet showed higher than those with 0%, and 33% SLO, and TG concentration of rats fed with 67% and 100% SLO diet decreased significantly.

Seasonal Variation of Pollutant load flowing into Yeong-Il bay (영일만 유입오염부하량의 계절 변동에 관한 연구)

  • Yoon, Han-Sam;Lee, In-Cheol;Ryu, Cheong-Ro;Park, Jong-Hwa
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.10a
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    • pp.100-107
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    • 2002
  • This study investigates the seasonal variation and spatial distribution characteristics of pollutant load, as executing the quantity valuation of pollutant load inflowing into Yeong-Il bay from on-land including the Hyeong-san river. Annual total pollutant generating rate from Yeong-Il bay region are 202ton to BOD, 620ton to SS, 42ton to T-N, 16ton to T-P respectively, if expressly point out, pollutant generating rate from the Hyeong-san river is the greatest, which BOD ratio is 78.2%, SS 88.5%, T-N 62.5%, T-P 73.1%. As calculating Tank model with input value of daily precipitation and evaporation of 2001 year in drainage basin of the Hyeong-san river, Estimated result of the annual total river discharge effluencing from this river is $830{\times}106m^3$. As result to estimating annual total effluence rate outflowing at the rivers from each drainage basins, annual total inflow pollutant rate are BOD 10,633ton, SS 19,302ton, T-N 15,369ton, T-P 305ton. The III basin which is population congestion region of the Pohang-city drain away a good many pollutant load than the V basin including the Neang-Chun with wide drainage area. Especially, a great many T-N than T-P inflow into Yeong-Il bay. The accumulation of pollutant load effluenced from on-land will happen on at the inner coast region of Yeong-Il bay, finally we would make a prediction that the water quality will take a bad turn.

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