• 제목/요약/키워드: Total Cr

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Study of Deposition Flux of Dustfall and Metallic Elements in Western Coastal City, Kunsan, Korea (서해 도시지역 군산의 강하분진 및 금속원소 침착량 연구)

  • 김성천
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.3
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    • pp.291-303
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    • 1999
  • The purpose of this experimental study is to investigate seasonal deposition flux variations of the total dustfall and various inorganic elements in it. Total of 84 dustfall samples were collected from September, 1997 thur August, 1998 at 7 different sites in Kunsan. Each sample was analyzed by an AAS to determine the levels of 5 inorganic elements Zn, Cd, Cr, Fe and Pb. Deposition fluxes, soluble/total fractions for each element were extensively investigated. Estimated depositon fluxes of dustfall and elements in Kunsan were in the range of 37.5~45.1 ton/$ extrm{km}^2$/yr for dustfall, 43.5~81.8kg/$\textrm{km}^2$/yr for Zn, 6.6~11.0kg/$\textrm{km}^2$/yr for Cd, 44.8~110.0kg/$\textrm{km}^2$/yr for Cr, 223~323 kg/$\textrm{km}^2$/yr for Fe, 10.9~22.3 kg/$\textrm{km}^2$/yr for Pb, respectively. Thus, the estimated average total deposition fluxes of dustfall in Kunsan(376.35$\textrm{km}^2$) per day were 43.3 ton and 58.6 kg for Zn, 8.9 kg for Cd, 80.6 kg for Cr, 293.8 kg for Fe and 14.1 kg for Pb, respectively.

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Cr, Ni and Cu removal from Si wafer by remote plasma-excited hydrogen (리모트 수소 플라즈마를 이용한 Si 웨이퍼 위의 Cr, Ni 및 Cu 불순물 제거)

  • 이성욱;이종무
    • Journal of the Korean Vacuum Society
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    • v.10 no.2
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    • pp.267-274
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    • 2001
  • Removal of Cr, Ni and Cu impurities on Si surfaces using remote plasma-excited hydrogen was investigated. Si surfaces were contaminated intentionally by acetone with low purity. To determine the optimum process condition, remote plasma-excited hydrogen cleaning was conducted for various rf-powers and plasma exposure times. After remote plasma-excited hydrogen cleaning, Si surfaces were analyzed by Total X-ray Reflection Fluorescence(TXRF), Surface Photovoltage(SPV) and Atomic Forece Microscope(AFM). The concentrations of Cr, Ni and Cu impurities were reduced and the minority carrier lifetime increased after remote plasma-excited hydrogen. Also RMS roughness decreased by more than 30% after remote plasma-excited hydrogen cleaning. AFM analysis results also show that remote plasma-excited hydrogen cleaning causes no damage to the Si surface. TXRF analysis results show that remote plasma-excited hydrogen cleaning is effective in eliminating metallic impurities from Si surface only if it is performed under an optimum process conditions. The removal mechanism of the Cr, Ni and Cu impurities using remote plasma-excited hydrogen treatments is proposed to be the lift-off during removal of underlying chemical oxides.

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The Population Genetic Structure of the Oyster Crassostera gigas (Bivalvia:Ostreidae) from Gamak Bay in Korea (가막산 참굴의 집단 구조 분석)

  • Cho, Eun-Seob;Jeong, Hee-Dong
    • Journal of Life Science
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    • v.18 no.7
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    • pp.1015-1018
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    • 2008
  • To analyze the population genetic structure of the oyster Crassostrea gigas Thunberg, 34 specimens werecollected from Gamak bay in March, 2007. Total genomic DNA was extracted from each sample and PCR was performed to identify haplotypes of oyster by using HCO2918 and LCO1491 primers. Four kinds of haplotypes (CR1, CR2, CR3, and CR4) were identified. Among these group, CR3 showed the highest relative frequency at 73% than any other of haplotypes. On the basis of hierarchical genetic structure, the population of Gamak showed a higher genetic relationship with Namhae, but the genetic distance between southern and western coasts was negative and no statistical significance was found (p>0.05). Consequently, the oyster from Korea coast is determined to be both homogenous and large.

Selective Removal of Cr (VI) and Cr (III) in Aqueous Solution by Surface Modified Activated Carbon

  • Lee, Jeong-Min;Kim, Min-Il;Lee, Young-Seak
    • Carbon letters
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    • v.9 no.1
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    • pp.23-27
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    • 2008
  • The adsorption and reduction of Cr (VI) to Cr (III) by surface modified activated carbon (AC) in an aqueous solution was studied. The effects of surface modifications on the properties of the carbons were investigated by the analysis of specific surface area, carbon surface pH, acid/base surface values and functional groups. In order to understand the Cr(VI) adsorption and reduction ratio from Cr(VI) to Cr(III), the Cr adsorption capacity of AC was also measured and discussed by using inductively coupled plasma and UV spectrophotometer. The modifications bring about substantial variation in the chemical properties whereas the physical properties such as specific surface area, pore volume and pore size distribution nearly were not changed. Total Cr adsorption efficiency of as-received activated carbon (R-AC) and nitric acid treated activated carbon (N1-AC and N2-AC) were recorded on 98.2, 99.7 and 100%. Cr(III) reduction efficiency of R-AC increased largely from 0.4% to 28.3% compared to N1-AC and N2-AC.

Computed Radiography 환경에서의 REPEAT 유형변화에 대한 고찰

  • An, Mi-Seop;Jang, Gwang-Hyeon;Mun, Hui-Seok;Jeong, Hwan
    • Korean Journal of Digital Imaging in Medicine
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    • v.3 no.1
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    • pp.52-58
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    • 1997
  • Before entering 21st Century, modern medical science is requiring more precise display which is highly estimated in diagnostic value as radial science technology is achieving sharp development. And it is also trying to contribute to improve national health and to offer better service by reducing radial exposure. General projection and Fluoroscopy which are most difficult to be displayed in digital tend to change their way ; from analog to digital with development of Electronic Engineering and Computer Technology, Introducing to CR system in 1994, SMC have displayed General projection and Fluoroscopy 100% in digital using CR system. This study searched differences between repeat rate, repeat type in the exam using Film/Screen and those in the exam using CR system. According to the analysis of repeat types and repeat rate of Film which was reused by using CR system in general projection room and Fluoroscopy room of SMC, we found that total 192,813 films were used and 2,097 films, 1.09% of total were reused. However, actual repeat covers 0.76% to 1,461 sheets with the exception of 636sheets. As above, display process using CR system is 0.76% much lower than general repeat rate 2$\sim$4% of Film/Screen exam. Besides decreased under/over exposure, it is appeared that position failure rate in repeat rate 0.76% covers relatively high 31%. Noticing that repeat caused unskilled devices handing was found many times, sufficient understanding seems to be required to reduce repeat.

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Effect of Hexavalent Chromium on Egg Laying Capacity, Hatchability of Eggs, Thickness of Egg Shell and Post-Hatching Development of Gallus domesticus

  • Asmatullah, Asmatullah;Asma, A.;Latif, A.;Shakoori, A.R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.6
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    • pp.944-950
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    • 1999
  • Hexavalent chromium (CrVI) was fed to one day old chicks of Gallus domesticus in the form of different concentrations (250 and 500 mg/kg feed) of potassium dichromate mixed with the feed, ad libitum, for 32 weeks. After 20 weeks of feeding, the total body weight was higher in the low dose (260 mg/kg (feed) group and lower in the high dose (500 mg/kg feed) group, as compared with the control chicks. After 32 weeks of feeding, however, the total body weight was significantly decreased in both the treated groups. Egg laying was enhanced. Fertility remained unaffected, whereas hatchability was considerably decreased after CrVI-treatment. The egg shell thickness increased significantly (13%). Cr was deposited in a dose dependent manner in the liver and lungs. Some structural derangements in liver were also noted in treated chicks. The results of this study i.e., rapid ageing, excessive Cr deposition, decreased hatchability and hepatotoxicity indicate toxic effects of CrVI.

Half-metallicity and Magnetism at the (001) Surfaces of the Quaternary Heusler Alloys CoFeCrZ (Z = Ga, Ge): A First-principles Study (4원 호이슬러 합금 CoFeCrZ(Z = Ga, Ge)의 (001) 표면에서의 자성과 반쪽금속성: 제일원리 계산 연구)

  • Kim, Dong-Chul;Lee, Jae Il
    • Journal of the Korean Magnetics Society
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    • v.25 no.2
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    • pp.31-38
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    • 2015
  • Recently, a first-principles study led to a prediction that quaternary Heusler compounds, CoFeCrZ (Z = Ga, Ge) are excellent half-metallic ferromagnets. In this study, we investigate the electronic and the magnetic properties at the (001) surfaces of CoFeCrGa and CoFeCrGe by means of the full-potential linearized augmented plane wave (FLAPW) method within generalized gradient approximation. We considered two types of surface termination: CoFe-terminated and CrZ-terminated surfaces, Z being either Ga or Ge. From the calculated total magnetic moments and the local density of states, we found that half-metallicity is not preserved for all the surfaces. But the calculated atomic density of states showed that CrGa-terminated surface of the CoFeCrGa is almost half-metallic. The magnetic moment of the Co, Fe, or Cr atoms at the surface or subsurface layers in each system had very different values.

A Comparison between Bacterial Cr(VI) Resistance and Cr(VI) Reduction among Environmental Isolates (미생물의 크롬내성과 크롬환원의 상호 비교)

  • 오영숙;최성찬
    • Korean Journal of Microbiology
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    • v.33 no.2
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    • pp.125-130
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    • 1997
  • Microbial reduction of hexava1ent(VI) to trivalent(lII) chromium is regarded as one of the mechanisms that confers resistance to bacteria. In order to verify this hypothesis, we compared Cr(VI) resistance with Cr(VI) reduction among 20 phenotypically distinct environmental isolates from Cr-contaminated and uncontaminated soils. With glucose as an electron donor, Cr(VI) reduction by washed cell suspensions ranged from 0.014 to 0.305 mM Cr(VI) reduced $h^1$. Cr(VI) resistance of the isolates were measured by growth inhibitions on a liquid medium containing 2 mM Cr(VI) based on their decrease of $A_{630}1$ as compared to the controls without Cr(VI). The isolates had a broad range of resistance from no inhibition to 93.4% inhibition of their growth. Upon correlation analysis, there was no significant relationship between those two phenomena. At a population level, a comparison of % resistant viable counts among the Cr-contaminated and uncontaminated soils showed 19.1 % and 0.4% of their total viable counts, respectively. The difference of % resistance between two site,. strongly suggested that the Cr(VI) present in the soils influences natural selection for resistant phenotypes. However, it is unlikely that the Cr(VI) resistance is dependent solely on the reduction as judged by the correlation analysis.

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Antioxidant activities and α-Glucosidase Inhibition Effects of Chicories Grown in Hydroponics Added with Cr3+ or Selenium (Cr3+ 또는 Selenium 첨가 배양액으로 재배한 치커리의 항산화활성 및 α-glucosidase저해효과)

  • Choi, Jun-Hyeok;Park, Yun-Hee;Lee, Sung-Gyu;Lee, So-Hee;Yu, Mi-Hee;Lee, Mu-Sang;Park, Sun-Hwa;Lee, In-Seon;Kim, Hyun-Jeong
    • Journal of Food Hygiene and Safety
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    • v.29 no.1
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    • pp.53-59
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    • 2014
  • This study was carried out to investigate the effect on the growth and antioxidant activities of Cichorium intybus L.(CLE), Cichorium intybus L. var. folisum 'treviso' (CLET), Cichorium intybus L. var. folisum 'rosaitaliana' (CLER) in hydroponics added with $Cr^{3+}$ or Selenium (Se) for 4 weeks. Total polyphenol, total flavonoids contents and FRAP values of three species of chicory were grown hydroponically with $Cr^{3+}$ or Se were increased. These extracts were also showed stronger DPPH and ABTS scavenging activity than chicory extracts. In particular, chicories added with $Cr^{3+}$ had higher antioxidant activities than chicories added with Se. CLER and CLE extracts added with $Cr^{3+}$ were also showed ${\alpha}$-glucosidase inhibition activities. These results indicate that chicories were cultivated in culture fluid added with $Cr^{3+}$ or Se could be used as high functional vegetables.

Removal of Cr, Pb and Cd from Reservoir Sediment by Electrokinetic Technique (동전기를 이용한 유수지 오염 퇴적토내 Cd, Pb 및 Cr제거)

  • Shin, Hyun-Moo
    • Journal of Soil and Groundwater Environment
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    • v.14 no.1
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    • pp.68-77
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    • 2009
  • For the reservoir sediment highly contaminated with total Cr, Pb, and Cd, the applicability of electrokinetic remediation method was evaluated. Also, BCR sequential extraction method was adopted to compare the heavy metal speciation in between before and after electrokinetic reaction that is operated under constant current condition for the sediment. After reaction, total Cr and Pb moved toward the direction of anode, while Cd tended to cathode and stayed highest in the midst of sediment specimen. From the BCR sequential extraction analysis, it was known that for total Cr and Pb the residual fraction that showed high fraction before reaction decreased and changed to the oxidation fraction. On the other hand, for Cd the fraction of exchangeable/carbonate that dominated most fractions before reaction changed to the residual and oxidation fractions.