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The Effect of Organic Matter and Lime Treatment on Trichloroethylene Adsorption by Soil (유기물과 석회 처리 수준이 토양의 Trichloroethylene 흡착에 미치는 영향)

  • 이군택;류순호;이민효
    • Journal of Korea Soil Environment Society
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    • v.1 no.1
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    • pp.11-17
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    • 1996
  • Trichloroethylene(TCE) is the organic compound which is used variously at the industrial areas. It contaminates soils and groundwater by leaked storage tank, careless treatment in field and the effluent from waste landfills. This study was carried out to identify adsorptive behavior of TCE by soil. Batch experiments were conducted at different soil-organic matter content and lime treatment to determine Freundlich isothermal adsorption equation constant, k and n, for TCE. Sewage sludge cake was applied to make different soil-organic matter content with the level of Oton/ha(S1), 50ton/ha(S2), 100ton/ha(S3). Lime(calcium hydroxide) was treated with the level of 2ton/ha, 4ton/ha, 6ton/ha, 10ton/ha. Freundlich isothermal adsorption equations obtained from experiment with sewage sludge cake were as follows (on condition that the level of TCE applied to soil ranged from 0.5ng/g soil to 2.5 ng/g soil.) : S1 :x/m = 0.393 $C^2$, S2 : x/m = 0.436 $C^2$, S3 : x/m = 0.636 $C^2$Value of k was increased in higher order of 51, 52, 53 with increased level of sewage sludge cake application. From this results, soil which was applied higher level of sewage sludge cake had a good ability on TCE adsorption. With increased the level of lime application, pH of the soil was increased and the ability of the soil in TCE adsorption was decreased.

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The Estimation of Emission Factor of N2O and CH4 by Measurement from Stacks in the Waste Incinerators and Cement Production Plants

  • Choi, Sang-Min;Im, Jong-Kwon;Hong, Ji-Hyoung;Lee, Sue-Been;Zoh, Kyung-Duk
    • Journal of Environmental Health Sciences
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    • v.33 no.3
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    • pp.217-226
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    • 2007
  • The purpose of this study is to estimate the emission factor of $non-CO_2$ global warming gases such as $N_2O$ and $CH_4$ by measuring concentrations from stacks of waste incinerators and cement production plants. Based on the established monitoring methods, $N_2O$ concentration measured from stacks in incinerator were between 0.62 and $40.60\;ppm_v$ (ave. $11.50\;ppm_v$). The concentration of $N_2O$ was dependent on the incinerator types. However, the concentrations of $CH_4$ gas were between 2.65 and $5.68\;ppm_v$ (ave. $4.22\;ppm_v$), and did not show the dependency on the incinerator types. In the cement production plant, the concentration ranges of $N_2O$ from the stack were from 6.90 to $10.80\;ppm_v$ (ave. $8.60\;ppm_v$), and $CH_4$ were between 1.80 and $2.20\;ppm_v$ (ave. $2.60\;ppm_v$). Using measured concentrations, the emission amounts of $N_2O$ and $CH_4$ from stacks per year were calculated. The results were is 4.2 ton $N_2O/yr$ in the incinerators, and 53.7 ton $N_2O/yr$ in the cement facilities. The big difference is from the flow rate of flue gas in the cement facilities compared to the incinerators. By the same reason, the $CH_4$ emission amounts in cement plant and incinerator was found to be 339 ton $CO_2/yr$ and 34.1 ton $CO_2/yr$, respectively. Finally, the emission factor of $N_2O$ in the incinerators were calculated using the measured concentration and the amount of incinerated wastes, and was $42.5\sim799.1\;g/ton$ in kiln and stoker type, $11.9\sim79.9\;g/ton$ in stoker type, 90.1 ton/g in rotary kiln type, 174.9 g/ton in fluidized bed type, and 63.8 g/ton in grate type, respectively. Also, the emission factors of $CH_4$ were found to 65.2-91.3 g/ton in kiln/stoker type, 73.9-122 g/ton in stoker type, 109.5 g/ton rotary kiln, and 26.1 g/ton in fluidized bed type. This result indicates that the emission factor in incinerators is strongly dependent on the incinerator types, and matched with result of IPCC (International Panel on Climate Change) guideline.

Case Study on the Directions for Establishment of Resource Cycling Agricultural System Focused on Farmer's Organization (생산자조직 내 자원순환형 농업시스템 구축사례와 시사점)

  • Heo, Seung-Wook
    • Korean Journal of Organic Agriculture
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    • v.19 no.4
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    • pp.463-474
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    • 2011
  • The objectives of this study were to establish of resource cycling agricultural system focused on farmer's organization. Case is selected as the farming corporation for the regional agriculture considering the amount of sowing by-products and livestock by-products generated. As a result, generation of fertilizer ingredient depend on feces and urine of Korean native cattle is estimated nitrogen 7.7 ton, phosphoric acid 2.9 ton, and potassium 4.9 ton. On the other hand, generation of fertilizer ingredient demand in cultivated acreage is estimated nitrogen 42.4 ton, phosphoric acid 14.3 ton, and potassium 17.0 ton. Therefore, optimum livestock numbers is estimated 1,867 cattle and it means 1,468 cattle can be raise additionally. In order to complete the resource cycling agricultural system, it should be establish nutrient management system at all of organization level and achieve improvements in regional resource supply. Both economic value of organic fertilizer and the resource cycling system linked market system is considered to develop resource cycling level.

The Investigation Study of Compaction Density by Waste Composition Change in Landfill Site (매립장의 반입쓰레기 성상변화에 따른 다짐밀도 조사연구)

  • Jung, Byung-Gil;Choi, Young-Ik;Kim, Jung-Kwon
    • Journal of Environmental Science International
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    • v.17 no.4
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    • pp.397-403
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    • 2008
  • The purpose of this study is to investigate weighted compaction density according to a leading density in truck, a compaction density of solid waste and composition ratios of solid waste fur calculation of a capacity of the landfill sites. The experiments for calculations of in-place density at landfill site have been conducted in S landfill site at B City. The size of vessel for measuring the compaction density was $1m^3(1m{\times}1m{\times}1m)$. The experiment tests have been carried out methods (1 time for bulldozer and 4 times for compactor) that do contain all of specification at the landfill site. Average of the loading density at the landfill site was $0.264\;ton/m^3$ ($0.113{\sim}0.487\;ton/m^3$). When the loading density for each compositions was compared, the composition of the highest average loading density ($0.474\;ton/m^3$) was miscellaneous wastes. The composition of the lowest average loading density ($0.120 ton/m^3$) was general solid waste. The reported results indicated that the compaction density at the landfill site was $0.538\;ton/m^3$, which was calculated with weighted incoming ratios of compositions. The ranges of the density for each composition were from $0.021\;ton/m^3$ to $0.221\;ton/m^3$. When the compaction density for each composition was compared, the composition with the highest average compaction density ($0.221\;ton/m^3$) was miscellaneous wastes. The composition with the lowest average compaction density ($0.021\;ton/m^3$) was general solid wastes.

Estimation of Water Footprint for Livestock Products in Korea (한국의 축산물 물발자국 산정)

  • Lee, Sang-Hyun;Choi, Jin-Yong;Yoo, Seung-Hwan;Kim, Young Deuk;Shin, Ankook
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.2
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    • pp.85-92
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    • 2015
  • Since the consumption of the livestock products increased for the past 10 years in Korea, the water use for live animals has become more important in terms of water savings. Therefore, the index connecting water use and livestock products consumption should be required for sustainable water management, and water footprint concept could be suggested as the index. The aim of this study is to estimate the water footprint for livestock products; beef cattle, swine, and broiler chicken. The water footprint for livestock products is divided into direct and indirect water. The direct water includes the drinking and servicing water, and the indirect water includes the water for the cultivation of feed crops. The water footprint of beef cattle was calculated to $17,023.1m^3/ton$, and direct water was $91.2m^3/ton$, and indirect water was $16,931.9m^3/ton$. The water footprint of swine was calculated to $4,235.8m^3/ton$, and direct water was $129.7m^3/ton$, and indirect water was $4,106.0m^3/ton$. The water footprint of broiler chicken was calculated to $2,427.7m^3/ton$, and direct water was $7.6m^3/ton$, and indirect water was $2,420.1m^3/ton$. Also, we compared the water footprint to water demand of water vision 2020 which is the main report for national water management. The water vision 2020 reported only direct water for live animal, but the water footprint includes the direct and indirect water. Therefore, the water footprint could be applied to various fields relating water and food.

Effects of Cattle Manure Application on the Soil Properties , Yield Performance and Quality of Silage Corn Cultivated on Paddy land (전전환 논에서 우분시용이 토양화학성 및 Silage 옥수수의 수량과 품질에 미치는 영향)

  • 진현주;양종성;김정갑;정의수
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.16 no.1
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    • pp.81-86
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    • 1996
  • Silage wm(cv, Gwanganok) was cultivated during 1991-1994 on paddy land as a rotational cropping system of rice, to evaluate the effect of cattle manure application on the soil characteristics, yield performance and quality of com plant. The treatments used in this study were non-fertilizer, NPK standard in chemical fertilizer(N:$P_2O_5$ : $K_2O$= 200 : 150 : 150 kg/ha), cattle manure 20.40, 60 and 80 ton/ha Application of cattle manure improved soil pH, organic matter, available phosphate and exchangeable cations in the soils. During the experiment, soil pH was improved from 4.7 in the chemical fertilizer application(control) to 5.4-5.6 in the application of cattle manure, and available $P_2O_5$ wntent was increased from 72.2 ppm(contro1) to 340.2 ppm(cattle manure 80 ton/ha). Application of cattle manure increased plant growth, plant height and stalk diameter, and silage yields. Dry matter yields were produced 15.88 ton(chemical fertilizer), 20.11 ton(cattle manure 40 ton) and 21.22 ton/ha(cattle manure 80 ton/ha). However, no signicant yield differences were observed between cattle manure 40, 60 and 80 tonlha Productions of total digestible nutrients(TDN) and net energy for lactation(NEL) were also increased under cattle manure application. From the abobe results, the proper application amount of cattle manure was 40 tonha in this experiment.

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The Evaluation of NOx Emission Factor from Large Combustion Facilities in Seoul (서울지역 대형연소시설에서의 질소산화물 배출계수 산정)

  • 조기찬;최종욱;박후경;유병태
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.78-83
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    • 2000
  • The emission factor of nitrogen oxides(NOx) was evaluate to clarify the characteristics of NOx emitted from seven large combustion facilities in seoul area. The emission factors of NOx at A-1 and A-2 facilities of internal combustion engine were 66.957kgNOx/ton and 20.913kgNOx/ton, respectively. The emission factor of A-1 facility was higher than that of A-2 facility even same internal combustion engine, because A-1 facility adopted SCR(selective catalystic reactor) for reduction of NOx emission factor of A-2, A-4, and A-7 power generation boiler facilities were 4.300kgNOx/ton, 2.460kgNOx/ton and 1.796kgNOx/ton, respectively. The capacity of A-2 facility was about two times than that of A-4 and A-7. These emission factors were lower than those at facilities in other areas of korea, because of using low NOx burner of power generation boiler. The emission factors of NOx at A-3 and A-6 incinerator facilities were 0.147kgNOx/ton and 0.221kgNOx/ton which were lower than other facilities, respectively, because these facilities incinerate municipal solid waste of low heating value and uwe SCR for reducing NOx concentration.

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Organic carbon distribution and cycling in the Quercus glauca forest at Gotjawal wetland, Jeju Island, Korea

  • Han, Young-Sub;Lee, Eung-Pill;Park, Jae-Hoon;Lee, Seung-Yeon;Lee, Soo-In;You, Young-Han
    • Journal of Ecology and Environment
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    • v.42 no.2
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    • pp.60-69
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    • 2018
  • Background: This study was conducted from March 2011 to February 2013 in order to evaluate the ecosystem value by examining the organic carbon distribution and cycling in the Quercus glauca forest, evergreen oak community at Seonheul-Gotjawal, Jeju Island. Results: The amount of organic carbon distribution was $124.5ton\;C\;ha^{-1}$ in 2011 and $132.63ton\;C\;ha^{-1}$ in 2012 for aboveground biomass. And it was $31.13ton\;C\;ha^{-1}$ in 2011 and $33.16ton\;C\;ha^{-1}$ in 2012 for belowground biomass. In total, the amount of organic carbon distribution in plants was 155.63 and $165.79ton\;C\;ha^{-1}$ in 2011 and 2012, respectively. In 2011 and 2012 respectively, the amount of organic carbon distribution was 3.61 and $6.39ton\;C\;ha^{-1}$ in the forest floor and it was 78.89 and $100.71ton\;C\;ha^{-1}$ in the soil. As shown, most carbon was distributed in plants. Overall, the amount of organic carbon distribution of the Q. glauca forest was $238.13ton\;C\;ha^{-1}$ in 2011 and $272.89ton\;C\;ha^{-1}$ in 2012. In 2011, the amount of organic carbon fixed in plants through photosynthesis (NPP) was $14.22ton\;C\;ha^{-1}\;year^{-1}$ and the amount of carbon emission of soil respiration was $16.77ton\;C\;ha^{-1}\;year^{-1}$. The net ecosystem production (NEP) absorbed by the Q. glauca forest from the atmosphere was $5ton\;C\;ha^{-1}\;year^{-1}$. Conclusions: The carbon storage value based on such organic carbon distribution was estimated about $23.81mil\;won\;ha^{-1}$ in 2011 and $27.29mil\;won\;ha^{-1}$ in 2012, showing an annual increment of carbon storage value by $3.48mil\;won\;ha^{-1}$. The carbon absorption value based on such NEP was estimated about $500,000won\;ha^{-1}\;year^{-1}$.

The evaluation of Soil Erosion Risk of Urban Area based on Geospatial Information (공간정보를 활용한 도심지 토사유실 위험도 평가)

  • Lee, Geun-Sang
    • Journal of Cadastre & Land InformatiX
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    • v.45 no.2
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    • pp.57-70
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    • 2015
  • Recently, soil erosion have been thickening from heavy rainfall according to climate change. These soil erosion is main reason to cause landslide, the water quality, agricultural counterproductivity and so on. Therefore, it is important to find out the main source area to cause soil erosion using geospatial data including DEM, soil map and land cover those are very sensitive to soil erosion modeling. This study evaluated soil erosion using RUSLE model. Hyoja 4-Dong and Pyonghwa 2-Dong among Wansan-Gu showed high as 10,869 ton/yr and 10,477 ton/yr respectively and Ua 2-Dong of Deokjin-Gu showed high as 17,603 ton/yr in soil erosion. And Hyoja 1-Dong and Pyonghwa 1-Dong among Wansan-Gu showed high as $1,485.7ton/km^2$ and $1,297.0ton/km^2$ respectively and Inhu 3-Dong of Deokjin-Gu showed high as $2,557.7ton/km^2$ in unit soil erosion that was applied to the evaluation of soil erosion potential. It is anticipated that achievement of this study can apply to forecast and prepare the risk of soil erosion and debris flow in urban area.

Development of Microbubble Flotation Technique for the Production of High Grade Coal (Microbubble Flotation에 의한 고품위(高品位) 석탄생산(石炭生産) 기술(技術) 개발(開發))

  • Han, Oh-Hyung;Park, Sin-Woong;Kim, Byoung-Gon
    • Resources Recycling
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    • v.21 no.4
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    • pp.44-52
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    • 2012
  • The purpose of this study is to confirm the possibility of obtaining high grade coal from fixed carbon 20.68% coal. Also, the mineralogical, physical/chemical and liberation characteristics was found with the aim of decrease in ash amount, during the pre-processing of clean coal technology. In this study, batch flotation and microbubble column flotation that was appropriate for the processing of fine particles was used with the variation in kinds and quantity of frother, collector and depressant. Also grinding time, air flow rate and feeding rates were examined. As a result of batch flotation, using pulp density 20%, collector DMU-101+dodecyl amine(100 mL/ton), frother pine oil (200 mL/ton), depressant sodium silicate(1 kg/ton), obtained the result of ash rejection 81.55% and combustible recovery 70.23%. In result of microbubble column flotation, the result was ash rejection 83.85% and combustible recovery 70.42% under the condition of pulp density 5%, grinding time 5 min. collector DMU-101+DDA(100 mL/ton), frother AF65(5.4 L/ton), depressant SMP(3.5 kg/ton), wash water(360 mL/min.) and air flow rate(1,197 mL/min.).