• Korean Journal of Optics and Photonics
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• v.3 no.3
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• pp.183-190
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• 1992

Luminescence properties of asymmetric double quantum well structure composed of $Al_x/Ga_{1-x}$ /As AIAs/GaAs have been studied by steady state and time-resolved photoluminescence and phtoluminescence excitation spectroscopy at low temperature. Two quantum well samples with different barrier thickness (15$\AA$ and 150$\AA$) were prepared to investigate the dependence of tunneling characteristics on barrier thickness. The abscence of excitonic recombination peak from $Al_x/Ga_{1-x}$As well for the 15$\AA$ barrier sample indicates a very fast electron tunneling to GaAs well. Meanwhile, T-X transition between well and barrier is supposed to be a major route for the fast decay of luminescence from $Al_x/Ga_{1-x}$As well in the 150$\AA$ barrier sample. Time-resolved photduminescence from GaAs well of 15$\AA$ sample shows the exsitence of the rise with 100 ps which is attributed to the hole tunneling.

• Journal of Radiation Protection and Research
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• v.42 no.1
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• pp.69-76
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• 2017

Background: Time-resolved optically stimulated luminescence (TR-OSL) is a very useful method for calculating the lifetimes of crystalline quartz and feldspar. Materials and Methods: A compact TR-OSL system was developed, comprising a heater assembly manufactured using Kanthal wire, 2 powerful blue light-emitting diodes (LED, LXHL-PB02) for optical stimulation equipped with VIS liquid light guides, and a photomultiplier tube combined with an optical filter for luminescence detection. A pulse generated from the data acquisition board (NI PCI 6250) was used to initiate on/off signals in LED and TR-OSL measurements. Results and Discussion: The TR-OSL and background signals measured using this TR-OSL system using quartz samples were very similar to those reported in a previous study. Additionally, the lifetimes of the build-up and TR-OSL signals were calculated as $27.4{\pm}2.2{\mu}s$ and $30.3{\pm}0.6{\mu}s$, respectively, in good agreement with the findings of a previous study. Conclusion: It was concluded that the developed TR-OSL system was very reliable for TR-OSL signal measurements and lifetime calculations.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.4
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• pp.497-508
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• 2020

In the geochemical field, the chemical speciation of hexavalent uranium (U(VI)) has been widely investigated by performing measurements to determine its luminescence properties, namely the excitation, emission, and lifetime. Of these properties, the excitation has been relatively overlooked in most time-resolved laser fluorescence spectroscopy (TRLFS) studies. In this study, TRLFS and continuous-wave excitation-emission matrix spectroscopy are adopted to characterize the excitation properties of U(VI) surface species that interact with amorphous silica. The luminescence spectra of U(VI) measured from a silica suspension and silica sediment showed very similar spectral shapes with similar lifetime values. In contrast, the excitation spectra of U(VI) measured from these samples were significantly different. The results show that distinctive excitation maxima appeared at approximately 220 and 280 nm for the silica suspension and silica sediment, respectively.

• Applied Science and Convergence Technology
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• v.27 no.3
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• pp.56-60
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• 2018

The optical properties of the digital-alloy $(In_{0.53}Ga_{0.47}As)_{1-z}/(In_{0.52}Al_{0.48}As)_z$ grown by molecular beam epitaxy as a function of composition z (z = 0.4, 0.6, and 0.8) have been studied using temperature-dependent photoluminescence (PL) and time-resolved PL (TRPL) spectroscopy. As the composition z increases from 0.4 to 0.8, the PL peak energy of the digital-alloy $In(Ga_{1-z}Al_z)As$ is blueshifted, which is explained by the enhanced quantization energy due to the reduced well width. The decrease in the PL intensity and the broaden FWHM with increasing z are interpreted as being due to the increased Al contents in the digital-alloy $In(Ga_{1-z}Al_z)As$ because of the intermixing of Ga and Al in interface of InGaAs well and InAlAs barrier. The PL decay time at 10 K decreases with increasing z, which can be explained by the easier carrier escape from InGaAs wells due to the enhanced quantized energies because of the decreased InGaAs well width as z increases. The emission energy and luminescence properties of the digitalalloy $(InGaAs)_{1-z}/(InAlAs)_z$ can be controlled by adjusting composition z.

• Analytical Science and Technology
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• v.31 no.1
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• pp.7-13
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• 2018

In this study, we measured the time-resolved optically stimulated luminescence (TR-OSL) of Paleolithic paleosol quartz and evaluated its lifetime. Considering the lifetime dependence on the preheating applied after irradiation, the radiation exposure, and the optical pulse stimulation, we found that the optimum measurement condition for determining the lifetime of paleosol quartz was the optical pulse stimulation at a dwelling time of $250{\mu}s$, pulse width of $10{\mu}s$, and sweep number of 100,000, without preheating after 100 Gy of irradiation. Based on the dependence of the lifetime on the reading temperature, the thermal quenching activation energy ${\Delta}E$ and thermal assistance activation energy $E_a$ were evaluated as $0.60{\pm}0.14eV$ and $0.053{\pm}0.029eV$, respectively. These values were in good agreement with those reported in the literature. Therefore, we concluded that the resulting kinetic parameters for paleosol quartz are quite reliable.

• Korean Journal of Optics and Photonics
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• v.5 no.1
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• pp.90-99
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• 1994

Picosecond time-correlated single photon counting system and time-resolved luminescence spectrometer were constructed, employing a mode-locked picosecond laser, fast electronics, and microchannel plate tube. It has been shown that the instrument response function critically depends on laser pulse shape, timing jitter and walk of the electronics, and characteristics of detector and amplifier. Correcting time dispersion in the optical system, the best instrument response function obtained appears to be 25 ps, which made it possible to measure the luminescence lifetime with less than 10 ps resolution in the picosecond to microsecond range. range.

• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2409-2413
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• 2007

Time resolved phosphorescence of Dibromobenzophenone (DBBP) choleic acid crystal was observed at 4.2 K as functions of excitation energy and delay time. The experimental results reveal that the energy transfer efficiency is dependent on the excitation energy, i.e. the density of acceptors sites. As the excitation energy or delay time increases, the resonance phosphorescence does not broaden and shift gradually, rather a broad luminescence band develops about 290 cm?1 to lower energy of the resonance phosphorescence. The observation implies that energy transfer from high to low energy sites in this system is controlled by emission of phonons or vibrons. The data of time resolved experiments were analyzed in terms of a mechanism involving direct donor-acceptor excitation transport by exchange coupling. It was concluded that an isotropic twodimensional exchange interaction topology is consistent with energy transfer in this system.

• Rapid Communication in Photoscience
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• v.4 no.3
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• pp.54-58
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• 2015

Under the condition of femtosecond impulsive nonlinear optical irradiation, the bright and narrowed blue emission of silicon nanocrystal was observed. This synthetic method produced very small (~ 4 nm) oxide-capped silicon nanocrystal having probably ultra small emitting core (~ 1 nm) inferred from luminescence. By controlling the stirring condition, very high efficiencies of luminescence ( 4 fold higher) were obtained compared with the other conventional femtosecond laser fragmentation methods, which was attributed to the differences in hydration shell structure during the femtosecond laser induced irreversible phase transition reaction. When we properly adjusted the irradiation times of the white light continuum and stirring condition, very homogeneous luminescent silicon nanocrystal bands having relatively sharp lineshape were obtained, which can be attributable to the luminescent core site isolated and free from the surface defects.

• Proceedings of the Korean Vacuum Society Conference
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• 2009.02a
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• pp.114.2-114.2
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• 2009

• Proceedings of the Korean Biophysical Society Conference
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• 1997.07a
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• pp.44-44
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• 1997

Ca$^{2＋}$ is one of the most common metal ions associated with proteins, playing more or less well-defined functional roles in biological activities. In protease, the presence of $Ca^{2＋}$ slows down autolysis and enhances thermal stability. Subtilisin, one of the best studied proteases, is known to have two $Ca^{2＋}$ -binding sites.(omitted)