• Bulletin of the Korean Chemical Society
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• v.27 no.12
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• pp.2040-2044
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• 2006

Dielectric studies of methyl acrylate with 1-propanol, 1-butanol, 1-heptanol and 1-octanol binary mixtures have been carried out over the frequency range from 10 MHz to 10 GHz at temperatures of 283, 293, 303 and 313 K using Time Domain Reflectometry (TDR) for various concentrations. The Kirkwood correlation factor and excess inverse relaxation time were determined and discussed to yield information on the molecular structure and dynamics of the mixture. The values of the static dielectric constant, relaxation time and the Kirkwood correlation factor decrease with increased concentration of methyl acrylate in alcohol. The Bruggman plot shows a non-linearity of the curves for all the systems studied indicates the heterointeraction which may be due to hydrogen bonding of the OH group of alcohol with C=O of the methyl acrylate. The excess inverse relaxation time values are negative for all the systems at all the temperatures indicates that the solute-solvent interaction hinders the rotation of the dipoles of the system.

• Computers and Concrete
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• v.33 no.5
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• pp.621-630
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• 2024

This study presents novel electromagnetic wave-based methods for evaluating the integrity of cement-based structures using time domain reflectometry (TDR). Two cement-based plates with embedded rebars are prepared under sound and defective conditions. TDR tests are carried out using transmission lines with various numbers of artificial joints, and electromagnetic waves are measured to assess the integrity of the plates. The experimental results show that the travel time of electromagnetic waves is consistently longer in sound plates than in defective ones, and an increase in the reflection coefficients is observed in the defect zone of the defective plates. Electromagnetic wave velocities are higher in the defective plates, especially when connectors are present in the transmission line. A novel approach based on the area of the reflection coefficient provides larger areas in the defective plates, and the attenuation effect of the electromagnetic waves induces a difference in the areas of the reflection coefficient between the two defect conditions. An alternative method using the centroid of the defect zone slightly overestimates the location of the defect zone. The length of the defect zone is estimated using the defect ratio and wave velocities of cement, air, and plate. The length of the defect zone can also be calculated using the travel times within the plate, total measured length of the plate, and wave velocities in the cement and air. Therefore, the electromagnetic wave-based methods proposed in this study may be useful for estimating the location and length of defect zones by considering attenuation effects.

• Journal of Korea Soil Environment Society
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• v.4 no.1
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• pp.109-118
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• 1999

Recently, transport parameters of conservative solutes such as KCl in a porous medium have been successfully determined using time domain reflectometry (TDR) . This study was initiated to Investigate the applicability of TDR technique to monitoring the fate of a heavy metal ion in a sandy soil and the distribution of its concentration along travel distance with time. A column test was conducted in a laboratory that consists of monitoring both resident and flux concentrations of $ZnCl_2$in a sandy soil under a breakthrough condition. A tracer of $ZnCl_2$(10 g/L) was injected onto the top surface of the sample as pulse type as soon as a steady-state condition was achieved. Time-series measurements of resistance and electrical conductivity were performed at 10 cm and 20 cm of distances from the inlet boundary by horizontal-positioning of parallel TDR metallic rods and using an EC-meter for the effluent exiting the bottom boundary respectively. In addition. Zn ions of the effluent were analyzed by ICP-AES. Since the mode and position of concentration detected by TDR and effluent were different, comparison between ICP analysis and TDR-detected concentration was made by predicting flux concentration using CDE model accommodating a decay constant with the transport parameters obtained from the resident concentrations. The experimental results showed that the resident concentration resulted in earlier and higher peak than the flux concentration obtained by EC-meter, implying the homogeneity of the packed sandy soil. A close agreement was found between the predicted from the transport parameters obtained by TDR and the measured $ZnCl_2$concentration. This indicates that TDR technique can also be applied to monitoring heavy metal concentrations in the soil once that a decay constant is obtained for a given soil.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.11a
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• pp.201-205
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• 1998

Leakage of hydrocarbon compound from underground storage tank has been a significant issue to the hazard of environmental contaminants. It is therefore necessary to develop the measurement technique of hydrocarbon compound concentration. In this study, the possibility of TDR application to measure concentration of hydrocarbon compound, especially diesel, in a sandy soil was investigated. Experiments were conducted in two different conditions. The first one was to measure the resistances of the soil columns packed according to the various ratios of tab water and diesel content in the total voids. The other was to measure the resistance of the soil under the flow condition where diesel oil was allowed to infiltrate into the KCl-saturated soil column. The experimental results showed that there exists a significant relationship between oil% and TDR-measured resistance. This suggests that TDR can be an effective device to measure the concentration of hydrocarbon compound in a soil.

• Journal of the Korean Chemical Society
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• v.56 no.1
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• pp.20-27
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• 2012

Complex permittivity spectra of Allyl Chloride (AC), 2-Butanone (2-BU) and their binary mixtures over the entire range of concentration were obtained using the Time Domain Reflectometry (TDR) technique in microwave frequency range at various temperatures. Static dielectric constant and relaxation time are obtained from complex permittivity spectra. Density ($\rho$) and refractive index ($n_D$) are also measured. These parameters are used to determine excess dielectric constant, excess inverse relaxation time, excess molar volume, excess molar refraction, polarity, Bruggeman factor and thermodynamic parameters viz. enthalpy of activation and entropy of activation. The values of static dielectric constant and relaxation time increases while density and refractive index decreases with the percentage of 2-Butanone in Allyl Chloride increases. Excess parameters were fitted to a Redlich-Kister equation.

• Journal of the Korean GEO-environmental Society
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• v.4 no.2
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• pp.15-25
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• 2003

Time Domain Refletometry, or TDR, is a remote sensing electrical measurement technique that has been used for many years to determine the spatial location and nature of various objects, especially in the United States of America and Australia at mining industry. Since early on 1990, the TDR techniques have been applied to the geotechnical engineering such as : deformation measurement of rock slope and landslide, monitoring of ground water content and ground water level change, investigation of ground contamination and its movement. The first application of this technique, in 1996, to the domestic area is to determine the possibility of ground settlement caused by subsidence from abandoned underground mines at the Tongri and Gosari in Gangwon-d. In this paper, through the results of analysed deformation data between conventional measurements and the TDR, it was concluded that the TDR technique is a useful instrumentation method for the prediction of ground deformation.

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.17-22
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• 2009

계절에 따른 토양공극의 수리학적 변화를 파악하기 위해서 설마천 유역의 범륜사 독립사면과 광릉 원두부 소유역의 독립사면을 대상으로 장력침투실험을 실시하였다. 토양수분 확보에 신뢰를 받기위해서 TDR(Time Domain Reflectometry)및 현장에서 토양의 불포화 투수계수 측정이 가능한 장력침투계(Tension infiltrometer)를 이용하였다. 계절에 따른 자료수집을 위해서 2008년 3월 20일 부터 약 6주간격으로 10월 29일까지 5회에서 6회 토양수분 자료 및 토양장력침투 자료를 획득하였다. 획득한 자료를 이용하여 포화 및 불포화 수리전도도, 대공극 유효흐름분율(macropore flow), 대공극 유효부피분율을(effective macroporosity) 나타내었다. 분기별로 자료분석 결과 계절별 특성이 나타남을 알 수 있다. 수리전도도는 3월, 5월, 10월은 유사한 반면 6월과 7월 그리고 9월은 상대적으로 높았다. 이는 여름철에 공극 발달이 활발하다는 것을 의미한다. 선행토양수분은 수리전도도에 영향을 미치는 것으로 나타났다. 대공극의 발달은 삼림과 같은 복잡 경관에서는 강우사상에 따른 토양수분의 공간 분포 및 이송, 유출과정이 물순환에 영향을 미친다. 지형분석을 통한 공극의 흐름특성과 토양수분 유의성에 대하여 논의하였고, 대공극 변화에 밀접한 관계가 있는 식생과 그밖에 계절적으로 발달을 일으키는 요인을 모색 하였다. 본 연구는 계절에 따라 변하는 수리전도도를 기초로 하여 불포화대에서 토양공극의 수리학적 변화와 시공간적으로 침투흐름에 얼마나 영향을 주는가를 보여준다.

• Proceedings of the Korea Water Resources Association Conference
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• 2004.05b
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• pp.209-214
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• 2004

Time Domain Reflectometry with multiplex system has been installed to configure the spatial and temporal characteristics of soil moisture in a mountainous hillslope. An intensive surveying was performed to build a refined digital elevation model and flow determination algorithms with inverse surveying have been applied to establish an efficient soil monitoring system. Steady state wetness index, quasi-dynamic wetness index and fully dynamic wetness index have been calculated. Continuous monitoring of soil moisture data were analyized with wetness indices. Limitations and hydrological interpretations of this approach have beer discussed.

• Journal of the Korea institute for structural maintenance and inspection
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• v.13 no.5 s.57
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• pp.93-100
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• 2009

This study presents reasonable relationships to estimate the deformation based on beam mechanism analysis and TDR(Time Domain Reflectometry) data. To declar the length points of co-axial cable installed in civil structure, Nano material ($BaTiO_3$ powders and silver mixture) is used on co-axial cables. From the laboratory test, nano material could make the correct information about attached cable points on beam, and TDR sensor system and Fourier series (data filter) found out the deformation of beam. Therefore it is concluded that the correct deformed information of beam were acquired by Nano-TDR and Fourier filter, they are much more effective to apply at health monitoring system in civil structure compared to conventional TDR or Fiber Optic Sensor (FOS) systems.

• Journal of the Korean Geosynthetics Society
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• v.13 no.3
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• pp.1-10
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• 2014

Several types of methods such as resistivity survey, ground penetration radar, etc are used for detection of levee leakage and according to the river design guidelines detection of levee leakage is performed by measuring the hydraulic conductivity of levee soil. But, the former can not verify the leakage point and degree of saturation, the latter is an after treatment method. Movable sensor, which is a high-tech TDR system developed since 2000, can obtain directly the dielectric constant profile covering the whole depth of levee. In this study, laboratory and field model experiments were carried out using movable TDR sensor in order to evaluate the applicability as detection system of levee leakage, As the result, movable TDR system has proven to be 3 times more sensitive to water contents than dry unit weight, and the results conclude that the dielectric constant, water contents and density of the ground proved to have a correlation among them, and the dielectric constant is expected to be a basic data on detection of levee leakage.