• Macromolecular Research
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• v.11 no.5
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• pp.311-316
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• 2003

The kinetics of photoinitiated polymerization of dimethacrylate macromonomers have been studied to determine the diffusion-controlled reaction parameters using attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). A predicted kinetic rate expression with a diffusion control factor was employed to estimate an effective rate constant and to define the reaction-controlled and diffusion-controlled regimes in the photopolymerization. An effective rate constant, k$_{e}$, can be obtained from the predicted kinetic rate expression. At the earlier stages of polymerization, the average values of kinetic rate constants do not vary during the reaction time. As the reaction conversion, $\alpha$, reaches the critical conversion, $\alpha$$_{c}$, in the predicted kinetic expression, the reaction becomes to be controlled by diffusion due to the restricted mobility of dimethacrylate macromonomers. A drop in value of effective rate constant causes a drastic decrease of reaction rate at the later stages of polymerization. By determining the effective rate constants, the reaction-controlled and diffusion-controlled regimes were properly defined even in the photopolymerization reaction system.m.m.

• Magazine of the Korean Society of Agricultural Engineers
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• v.15 no.4
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• pp.3153-3159
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• 1973

Although standard method of test for liquid limit procedure is issued under the fixed designation KSF-2303 in 1968, for both of general method and on point method, the latter of which is not still favorably used among laboratory engineers with its defficiency of adquate informations. This study intended as to furnish proper information to the laboratory engineers for the use of one point liquid limit test with full advantages of time-saving and labor-saving. further more, the following conversion formula to the one point method VS. general method is presented by the results of analytical study on 1017 Soil sampls existing liquid limit test data The formula is; $$W_L = W(\frac{N}{25})^{0.118}$$ The conversion factor (table-4) is also attached for the convenience of the users.

• Proceedings of the KIEE Conference
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• 2000.07b
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• pp.1348-1350
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• 2000

Zero-voltage and zero-current switched single-stage approach with high power factor is presented to reduce the switching losses and to achieve sinusoidal, unity power factor input currents. This single-stage approach, which combines a boost converter used as PFC with a half-bridge converter used as do to do conversion into one power stage, has a simple structure and low cost. At the same time, since the switches of the proposed converter are designed to be turned on at zero-voltage and off at zero-current, the switching losses could be reduced considerably. Detailed analysis and experimental results are presented on the proposed converter, which is operated at constant switching frequency and in discontinuous conduction mode.

• Restorative Dentistry and Endodontics
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• v.20 no.1
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• pp.33-54
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• 1995

The degree of conversion of composite resin was known to have influence on the mechanical properties of composite materials such as hardness, strength, wear resisitance, dimensional and color stability. Also unreacted monomer was reported to be harmful to the pulp. So the degree of conversion was a very important factor in the success of composite resin restorations. In recent, the dual cure resin cement was developed with the advocations that it could increase the curing rates in the sites where the curing ligt could not reach. Moreover many manufactors added some adhesive components in the resin cement. This study was undertaken to observe the effects of curing depth and light curing times on the degree of conversion of dual cure resin cements. CR INLAY CEMENT, DUAL CEMENT and OPTEC BOND, by the Fourier transform Infrared analysis, changing the curing depth 1mm, 2mm and 3mm, and varying the light curing time 20 seconds, 40 seconds and 80 seconds at each depth. The cytotoxicity of dual cure resin cements was tested by the in vitro MTT method using L929 cell. The results was evaluated and compared statistically. The results were obtained as follows : 1. The dual cure resin cements reavealed various degree of conversion, CR INLAY CEMENT and DUAL CEMENT had a tendency to be more reactive to the light cure and OPTEC BOND was a more chemical one. 2. CR INLAY CEMENT and DUAL CEMENT showed the lowest degree of conversion in 2 mm depth, and in 3mm depth the degree of conversion increased, which were due to the chemical cure of dual cures, but OPTEC BOND showed decreasing degree of conversion with increasing curing dept h and all experimental groups showed lower degree of conversion than CHEMICAL group which cured in dark room with no light, so the weak light-curing of dual cure resin cement prevented the chemical cure. (P<0.05) 3. CR INLAY CEMENT and DUAL CEMENT showed increasing degree of conversion in 1 mm and 3 mm, according to the increasing cure times, but in 2 mm depth the degree of conversion decreased with increasing light-curing times and OPTEC BOND showed contrary tendency, but there was no ststistical importance in the differences among the experimental group.(P>0.05) 4. The optical density by MTT assay of extractions of CR INLAY CEMENT, DUAL CEMENT and OPTEC BOND revealed no statitically important differences comparing with optical density of negative control.(P>0.05) 5. CR INLAY CEMENT showed a tendency of increaing cytotoxicity with days and DUAL CEMENT and OPTEC BOND showed higher cytotoxicity in 2 days than in 4 days, but there was no statistical importance in the differences.(P>0.05).

• Proceedings of the IEEK Conference
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• 1998.06a
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• pp.962-965
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• 1998

In this paper, single-phase PWM AC to AC converter that operates with unit powr factor and sinusidal input line currents is presented. The currentcontrol of this converter is based on the predicted current control method with fixed switching frequency and the line currents track to reference currents within sampling time interval.

• Journal of Pharmacopuncture
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• v.23 no.2
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• pp.79-87
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• 2020

Objectives: Ginsenosides found in ginseng, and the hydrolysates derived from their conversion, exhibit diverse pharmacological characteristics [1]. These have been shown to include anti-cancer, anti-angiogenic, and anti-metastatic effects, as well as being able to provide hepatic and neuroprotective effects, immunomodulation, vasodilation, promotion of insulin secretion, and antioxidant activity. Therefore, the purpose of this study was to examine how quickly the ginsenosides decompose and what kinds of degradation products are created under physicochemical processing conditions that don't involve toxic chemicals or other treatments that may be harmful. Methods: The formation of ginsenoside-Rg2 and ginsenoside-Rg3 was examined. These demonstrated diverse pharmacological effects. Results: We also investigated physicochemical factors affecting their conversion. The heating temperatures and times yielding the highest concentration of ginsenosides (-Rb1, -Rb2, -Rc, -Rd, -Rf, -Rg1, and -Re) were examined. Additionally, the heating temperatures and rates of conversion of these ginsenosides into new 'ginseng saponins', were examined. Conclusion: In conclusion, obtained provide us with effective technology to control the concentration of both ginsenosides and the downstream converted saponins (ginsenoside-Rg2, Rg3, Rg5, and Rk1 etc.), as well as identifying the processing conditions which enable an enrichment in concentration of these compounds.

• Journal of the Korean Society of Industry Convergence
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• v.27 no.3
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• pp.609-618
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• 2024

System reliability prediction in the development stage is increasingly crucial to reliability growth management to satisfy its target reliability, since modern system usually takes a form of complex composition and various complicated functions. In most cases of development stage, however, the information available for system reliability prediction is very limited, making it difficult to predict system reliability more precisely as in the production and operating stages. In this study, a system reliability prediction process is considered when the reliability-related information such as SIL (Safety Integrity Level) and MTTFd (Mean Time to Dangerous Failure) is available in the development stage. It is suggested that when the SIL or MTTFd of a system component is known and the field operational data of similar system is given, the reliability prediction could be performed using the scaling factor for the SIL or MTTFd value of the component based on the similar system's field operational data analysis. Predicting a system reliability is then adjusted with the conversion factor reflecting the temperature condition of the environment in which the system actually operates. Finally, the case of applying the proposed system reliability prediction process to a high performance mooring platform is dealt with.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.942-943
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• 2008

The boost converter is usually used in power factor correction. The dynamic losses of its output diode are produced during the reverse recovery time. The power efficiency is decreased due to the losses and also it generates the noise. These disadvantages have been remarkably improved by ZCS and ZVS techniques of power factor improvement circuit. Some benefits lead to the achievement of higher power density and the development cost can be decreased. In this paper work, the reverse recovery suppression(RS) PFC method is used. A inductor and a diode are added into the conventional circuit. The switching device, MOSFET is turned off after the reverse recovery current has come to the zero level. The Zero Current Switching(ZCS) is implemented at that time. This power conversion technique improves the efficiency to about 1% and reduces the noise obviously. And the additional inductor can be designed using an original filter core in the circuit. The converter size is reduced effectively.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.9
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• pp.709-717
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• 2009

Heat transfer rate is a very important factor for the performance of a steam reformer because a steam reforming reaction is an endothermic reaction. Coaxial cylindrical reactor is the reactor design which can improve the heat transfer rate. Temperature, fuel conversion and heat flux in the coaxial cylindrical steam reformer are studied in this paper using numerical method under various operating conditions. Langmuir-Hinshelwood model and pseudo-homogeneous model are incorporated for the catalytic surface reaction. Dominant chemical reactions are assumed as a Steam Reforming (SR) reaction, a Water-Gas Shift (WGS) reaction, and a Direct Steam Reforming (DSR) reaction. Although coaxial cylindrical steam reformer uses 33% less amount of catalyst than cylindrical steam reformer, its fuel conversion is increased 10 % more and its temperature is also high as about 30 degree. There is no heat transfer limitation near the inlet area at coaxial-type reactor. However, pressure drop of the coaxial cylindrical reactor is 10 times higher than that of cylindrical reactor. Operating parameters of coaxial cylindrical steam reformer are the wall temperature, the inlet temperature, and the Gas Hourly Space Velocity (GHSV). When the wall temperature is high, the temperature and the fuel conversion are increased due to the high heat transfer rate. The fuel conversion rate is increased with the high inlet temperature. However, temperature drop clearly occurs near the inlet area since an endothermic reaction is active due to the high inlet temperature. When GHSV is increased, the fuel conversion is decreased because of the heat transfer limitation and short residence time.

• Journal of Biomedical Engineering Research
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• v.39 no.6
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• pp.243-249
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• 2018

The indoor radon concentration was measured in the lecture room of the university and the radon concentration was converted to the amount related to the radon exposure using the dose conversion convention and compared with the reference levels for the radon concentration control. The effect of indoor radon inhalation was evaluated by estimating the life effective dose and the risk of exposure. To measure the radon concentration, measurements were made with a radon meter and a dedicated analysis Capture Ver. 5.5 program in a university lecture room from January to February 2018. The radon concentration measurement was carried out for 5 consecutive hours for 24 hours after keeping the airtight condition for 12 hours before the measurement. Radon exposure risk was calculated using the radon dose and dose conversion factor. Indoor radon concentration, radon exposure risk, and annual effective dose were found within the 95% confidence interval as the minimum and maximum boundary ranges. The radon concentration in the lecture room was $43.1-79.1Bq/m^3$, and the maximum boundary range within the 95% confidence interval was $77.7Bq/m^3$. The annual effective dose was estimated to be 0.20-0.36 mSv/y (mean 0.28 mSv/y). The life-time effective dose was estimated to be 0.66-1.18 mSv (mean $0.93{\pm}0.08mSv$). Life effective doses were estimated to be 0.88-0.99 mSv and radon exposure risk was estimated to be 12.4 out of 10.9 per 100,000. Radon concentration was measured, dose effective dose was evaluated using dose conversion convention, and degree of health hazard by indoor radon exposure was evaluated by predicting radon exposure risk using nominal hazard coefficient. It was concluded that indoor living environment could be applied to other specific exposure situations.