• Title/Summary/Keyword: TiO

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Evaluation of standardized ileal digestibility of amino acids in fermented soybean meal for nursery pigs using direct and difference procedures

  • Ki Beom, Jang;Sung Woo, Kim
    • Animal Bioscience
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    • v.36 no.2
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    • pp.275-283
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    • 2023
  • Objective: This study was to evaluate standardized ileal digestibility (SID) of amino acids (AA) in fermented soybean meal (FSBM) for nursery pigs using both direct procedure and difference procedure when FSBM was added at 20% in diets. Methods: Forty-eight pigs at 9.2±0.9 kg body weight (BW) were individually housed and allotted to 4 treatments. Treatments included NFD (a semi-purified N free diet), FSD (a diet with 20% FSBM), CBD (corn basal diet), and CFD (corn basal diet:FSBM at 80:20). The FSD was used to measure AA digestibility in FSBM using the direct procedure, whereas CBD and CFD were used in the difference procedure. Pigs were fed for 10 days (0.09×BW0.75 kg per day) and euthanized to collect ileal digesta for TiO2 and AA. Results: Total endogenous AA loss was 12.1 g/kg of dry matter intake. The apparent ileal digestibility (AID) Thr was greater (p<0.05) and AID His (p = 0.073) and Leu (p = 0.052) tended to be greater using the direct procedure compared with the difference procedure. The SID Thr were greater (p<0.05) in FSBM for nursery pigs calculated using a direct procedure compared with a difference procedure. In addition, SID Lys in FSBM was about 83% to 88% for nursery pigs higher than SID Lys described in National Research Council (2012). Conclusion: The SID of AA in FSBM when included at practical levels using the direct procedure were similar to those from the difference procedure. Considering the SID of AA obtained using both direct and difference procedures, FSBM is an effective protein supplement providing highly digestible AA to nursery pigs. The SID of AA from this study was considerably higher than those previous reported. This study also indicates the importance of including the test feedstuffs at practical levels when evaluating digestibility.

Experiment on Reduction of Pollutants in Titanium Dioxide Photocatalytic Ventilation System (이산화티탄 광촉매 환기장치의 오염물질 저감 실험)

  • Song, Yong Woo
    • Land and Housing Review
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    • v.13 no.2
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    • pp.117-123
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    • 2022
  • In this study, titanium dioxide photocatalyst was applied to the ventilation system to reduce particulate matter and nitrogen oxides (NOx), which are representative indoor harmful substances. A reaction device capable of installing an ultraviolet lamp was designed and manufactured so that the pollutant decomposition effect of the titanium dioxide photocatalyst identified through previous studies could be applied indoors. The reaction device was used on the indoor ventilation system and applied to the Mock-Up test. As a result of the Mock-up test, the NOx reduction performance according to the change in air volume once per hour and five times per hour was confirmed. As a result, it was confirmed that as the number of ventilation increases, the NOx reduction time decreases proportionally, and the reduction performance increases.

Corrosion Resistance of Al6061-T6 by Organic/Inorganic Hybrid Coating Solution (유/무기하이브리드 코팅액에 의한 Al6061-T6의 내식 특성)

  • Mi-Hyang Park;Ki-Hang Shin;Byoung-Chul Choi;Byung-Hyun Ahn;Gum-Hwa Lee;Ki-Woo Nam
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.4_2
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    • pp.591-598
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    • 2023
  • In this study, the corrosion resistance by salt spray was evaluated using A6061-T6 for an electric vehicle battery pack case coated with an organic/inorganic hybrid solution. The lowest curing temperature of 190 ℃ resulted in significant corrosion and pitting. Meanwhile, no corrosion was observed in the coated specimens at 210 ℃ and 230 ℃ except at 210 ℃ - 6 min and 8 min. The surface of the as-received coating specimen observed by FE-SEM exhibited streaks and dents in the rolling direction, but the coating surface was clean. On the 190 ℃ - 6 min coating specimen, which had a lot of corrosion, rolling streaks spread, and dents were caused by corrosion. The 200 ℃ - 12 min coating specimen did not show corrosion, but it showed an etched surface. In the line profile, Si, the main component of the coating solution, was detected the most, and Ti was also detected. In the coating specimens with salt spray, O increased and Si decreased, regardless of corrosion. The peeling rate by adhesion evaluation was 26 - 87% for the 190 ℃ coating specimen, 4 - 83% for the 210 ℃ coating specimen, and 94 - 100% for the 230 ℃ coating specimen. The optimal curing conditions for the coating solution used in this study were 210 ℃ for 10 min.

Numerical Analysis on Thermal-Induced Degradation of n-i-p Structure Perovskite Solar Cells Using SCAPS-1D (SCAPS-1D 시뮬레이션을 이용한 n-i-p 구조 페로브스카이트 태양전지의 열적 열화 원인 분석)

  • Kim, Seongtak;Bae, Soohyun;Jeong, Younghun;Han, Dong-Woon;Kim, Donghwan;Mo, Chan Bin
    • Current Photovoltaic Research
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    • v.10 no.1
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    • pp.16-22
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    • 2022
  • The long-term stability of PSCs against visual and UV light, moisture, electrical bias and high temperature is an important issue for commercialization. In particular, since the operation temperature of solar cell can rise above 85℃, a study on thermal stability is required. In this study, the cause of thermal-induced degradation of PSCs was investigated using the SCAPS-1D simulation tool. First, PSCs of TiO2/CH3NH3PbI3/Spiro-OMeTAD/Au structure were exposed to a constant temperature of 85℃ to observe changes in conversion efficiency and quantum efficiency. Because the EQE reduction above 500 nm was remarkable, we simulated PSCs performance as a function of lifetime, doping density of perovskite and spiro-OMeTAD. Consequently, the main cause of thermal-induced degradation is considered to be the change in the perovskite doping concentration and lifetime due to ion migration of perovskite.

Effect of Solution Annealing Heat Treatment on the Localized Corrosion Resistance of Inconel 718 (Inconel 718의 국부 부식 저항성에 미치는 용체화 열처리의 영향)

  • Yoonhwa Lee;Jun-Seob Lee;Soon Il Kwon;Jungho Shin;Je-hyun Lee
    • Corrosion Science and Technology
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    • v.22 no.5
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    • pp.359-367
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    • 2023
  • The localized corrosion resistance of the Ni-based Inconel 718 alloy after solution heat treatment was evaluated using electrochemical techniques in a solution of 25 wt% NaCl and 0.5 wt% acetic acid. Solution heat treatment at 1050 ℃ for 2.5 hours resulted in an increased average grain diameter. Both Ti carbides (10 ㎛ diameter) and Nb-Mo carbides (1 - 9 ㎛ diameter) were distributed throughout the material. Despite heat treatment, the shape and composition of these carbides remained consistent. An increase in solution temperature led to a decrease in pitting potential value. However, the pitting potential value of solution heat-treated Inconel 718 was consistently higher than that of as-received Inconel 718 at all tested temperatures. Localized corrosion initiation occurred at 0.4 VSSE in a temperature environment of 80 ℃ for both as-received and solution heat-treated Inconel 718 alloys. X-ray photoelectron spectroscopic analysis indicated that the composition of the passive film formed on specimen surfaces remained largely unchanged after solution heat treatment, with O1s, Cr2p3/2, Fe2p3/2, and Ni2p3/2 present. The difference in localized corrosion resistance between as-received and solution heat-treated Inconel 718 alloys was attributable to microstructural changes induced by the heat treatment process.

Environmental Geophysical Survey of Abandoned Landfills for Contamination Evaluation: A Case Study (불량 매립지 오염평가를 위한 지구물리 탐사 사례연구)

  • Lee, Sung-Soon;Lee, Jin-Yong;Yoon, Hee-Sung;Lee, Kang-Kun;Kim, Chang-Gyun;Yu, Young-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.463-471
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    • 2006
  • Electrical resistivity surveys were conducted at areas of abandoned landfills in Cheonan and Wonju. Geology and extent of leachate migration around the landfills were evaluated with collected resistivity data by 2-D and 3-D resistivity inverse modeling. The Cheonan landfill is located above the paddy fields and the resistivity survey lines were crossed to examine possible pollution at the paddy fields by leakage of the landfill leachate. In Wonju, the landfill and the downgradient paddy fields are divided by a concrete barrier wall. At the bottom of the landfill, there is a leachate settlement system, which has not been in operation. To evaluate leachate leakage into the paddy fields, a total of 4 survey lines were used. According to the resistivity survey results, the landfill leachate in Cheonan appeared to be restricted only within the interior of the landfill, not to migrate into the subsurface of the paddy fields. These results are well consistent with electrical conductivity values of groundwaters obtained from a periodic analysis of water qualities. In Wonju, however, it was inferred that the leachate emanating from the landfill migrated beneath the abandoned leachate settlement system and the leachate would reach the downgradient paddy fields. Low resistivity area was observed in the old reservoir area and it appeared to be derived from convergence of groundwater flows from the surrounding valley and the moist wet land. In addition, groundwater flow into the paddy fields occurs beneath the old reservoir embankment at depths of $7{\sim}8m$. This paper reports details of the resistivity surveys for the uncontrolled landfills.

Removing High Concentration Nitrogen by Electrolysis (전기분해에 의한 고농도 질소 제거의 특성)

  • Gil, Dae-Soo;Lee, Byung-Hun;Choi, Hae-Kyoung;Kwon, Dong-Min
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.265-277
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    • 2000
  • Laboratory experiments were conducted to investigate characteristics for removing ammonia-nitrogens by electrolysis methods. A stainless steel plate is used as the cathode and either $IrO_2{\backslash}Ti$ plate serves as the anode. Experiments were conducted to examine the effects of the operating conditions, such as the current density, retention time, electrode gap, $Cl^-/NH_4{^+}-N$ on the $NH_4{^+}-N$ removal efficiency. Possible optimum range for these operating variables are experimentally determined. The $NH_4{^+}-N$ removal efficiencies between plate type anode and net type anode were about same effect, but electrolytic power using net type anode is low than plate type anode. The $Cl^-/NH_4{^+}-N$ ratio was about $20.0kgCl^-/kgNH_4{^+}-N$ when $NH_4{^+}-N$ removal obtained 73 %, $Cl^-/NH_4{^+}-N$ ratio needs $27.6kgCl^-/kgNH_4{^+}-N$ so as to $NH_4{^+}-N$ completely remove. The removal efficiency of $NH_4{^+}-N$ increase with current density, retention time and $Cl^-/NH_4{^+}-N$ ratio, but decreased with increasing electrode gap. The relationship of operating conditions and $NH_4{^+}-N$ removal efficiencies are $$NH_4{^+}-N_{re}(%)=14.5364(Current\;density)^{0.7093}{\times}(HRT)^{1.0060}{\times}(Gap)^{-0.9926}{\times}(Cl^-/NH_4{^+}-N)^{1.0024}$$ With adding COD or/and alkalinity, relationships are $$NH_4{^+}-N_{re}(%)=9.8408(Current\;density)^{0.6232}{\times}(HRT)^{1.0534}$$ There existed a competition between the removals for $NH_4{^+}-N$ and $COD_{Cr}$ during electrolysis, the removal of $NH_4{^+}-N$ was shown to be dominant. $NH_4{^+}-N$ removal was high as addition of glucose and alkalinity.

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Characteristics of the ( Pb, La ) $TiO_3$ Thin Films with Pb/La Compositions (Pb/La 조성에 따른 ( Pb, La ) $TiO_3$ 박막의 특성 변화)

  • Kang, Seong-Jun;Joung, Yang-Hee;Yoon, Yung-Sup
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.1
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    • pp.29-37
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    • 1999
  • In this study, we have prepared PLT thin films having various La concentrations by using sol-gel method and studied on the effect of La concentration on the electrical properties of PLT thin films. As the La concentration increases from 5mol% to 28mol%, the dielectric constant at 10kHz increases from 428 to 761, while the loss tangent decreases from 0.063 to 0.024. Also, the leakage current density at 150kV/cm has a tendency to decrease from 6.96${\mu}A/cm^2$ to 0.79${\mu}A/cm^2$. In the result of hysteresis loops of PLT thin films, the remanent polariation and the coercive field decrease from 9.55${\mu}C/cm^2$ to 1.10${\mu}C/cm^2$ and from 46.4kV/cm to 13.7kV/cm, respectively. With the result of the fatigue test on the PLT thin films, we have found that the fatigue properties are improved remarkably as the La concentration increases from 5 mol% to 28mol%. In particular, the PLT28) has paraelectric phase and its charge storage clensity and leakage current density at 5V are 134fC/${\mu}cm^2$ and 1.01${\mu}A/cm^2$, respectively. The remanent polarization and coercive field of the PLT(10) film are 6.96${\mu}C/cm^2$ and 40.2kV/cm, respectively. After applying of $10^9$ square pulses with ${\pm}5V$, the remanent polarilzation of the PLT(10) film decreases about 20% from the initial state. In the results, we conclude that the 10mol% and the 28mol% La doped PLT thin films are very suitable for the capacitor dielectrics of new generation of DRAM and NVFRAM respecitively.

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Recirculating Integrated System for the Treatment of Authentic Integrated-textile-dyeing Wastewater from Dyeing Industrial Complex (염색산업단지 종합폐수처리용 재순환 통합시스템)

  • Lee, Eun Ju;Lim, Kwang-Hee
    • Korean Chemical Engineering Research
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    • v.55 no.6
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    • pp.837-845
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    • 2017
  • A recirculating integrated system composed of a fluidized biofilter filled with waste-tire crumb media fixed with return sludge from wastewater treatment facility of D dyeing industrial center, and a UV/photocatalytic reactor packed with calcined $TiO_2$ coated-glass beads as photocatalyst-support, was constructed and was run to treat authentic textile-dyeing wastewater from D-dyeing industrial center, which was mixed with an alkaline polyester-weight-reducing wastewater and a wastewater from sizing process. As a result, its total removal efficiency(RE(tot)) of $COD_{cr}$ and colors were ca. 81% and 55%, respectively. The synergy effect of the recirculating integrated system to enhance total removal efficiency(RE(tot)) of $COD_{cr}$ and colors were evaluated at most ca. 7% and 3%, respectively. The fluidized biofilter and the UV/photocatalytic reactor were responsible for ca. 94% and 6% of the total $COD_{cr}$ removal efficiency, respectively, and were also responsible for ca. 86% and 14% of the total color-removal efficiency, respectively. Thus, the degree of the UV/photocatalytic reactor-unit process's contribution to RE(tot) of color, was about 2.4 times of that to RE(tot) of $COD_{cr}$. Therefore, the UV/photocatalytic reactor facilitated the more effective elimination of colors by breaking down the chemical bonds oriented from colors of dyes such as azo-bond, than $COD_{cr}$. In addition, the effect of the removal efficiency of each unit process(i.e., the fluidized biofilter or the UV/photocatalytic reactor) of the recirculating integrated system on RE(tot) of $COD_{cr}$ and colors, was analysed by establishing its model equation with an analytic correlation.

Photocatalytic Oxidation of Arsenite Using Goethite and UVC-Lamp (침철석과 UVC-Lamp를 이용한 아비산염의 광촉매 산화)

  • Jeon, Ji-Hun;Kim, Seong-Hee;Cho, Hyen-Goo;Kim, Soon-Oh
    • Economic and Environmental Geology
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    • v.50 no.3
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    • pp.215-224
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    • 2017
  • Arsenic (As) is known to be the most toxic element and frequently detected in groundwater environment. Inorganic As exists as arsenite [As(III)] and arsenate [As(V)] in reduced and oxidized environments, respectively. It has been reported that the toxicity of arsenite is much higher than that of arsenate and furthermore arsenite shows relatively higher mobility in aqueous environments. For this reason, there have been numerous researches on the process for oxidation of arsenite to arsenate to reduce the toxicity of arsenic. In particular, photooxidation has been considered to be simple, economical, and efficient to attain such goal. This study was conducted to evaluate the applicability of naturally-occurring goethite as a photocatalyst to substitute for $TiO_2$ which has been mostly used in the photooxidation processes so far. In addition, the effects of several factors on the overall performance of arsenite photocatalytic oxidation process were evaluated. The results show that the efficiency of the process was affected by total concentration of dissolved cations rather than by the kind of those cations and also the relatively higher pH conditions seemed to be more favorable to the process. In the case of coexistence of arsenite and arsenate, the removal tendency by adsorption onto goethite appeared to be different between arsenite and arsenate due to their different affinities with goethite, but any effect on the photocatalytic oxidation of arsenite was not observed. In terms of effect of humic acid on the process, it is likely that the higher concentration of humic acid reduced the overall performance of the arsenite photocatalytic oxidation as a result of competing interaction of activated oxygen species, such as hydroxyl and superoxide radicals, with arsenite and humic acid. In addition, it is revealed that the injection of oxygen gas improved the process because oxygen contributes to arsenite oxidation as an electron acceptor. Based on the results of the study, consequently, the photocatalytic oxidation of aqueous arsenite using goethite seems to be greatly feasible with the optimization of process.