• Title/Summary/Keyword: TiB$_2$-Fe-Mo

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Effect of Mo Addition on the Sinterability and Mechanical Properties of TiB$_2$-Fe Cermets (TiB$_2$-Fe 서메트의 소결성 및 기계적성질에 미치는 Mo첨가의 영향)

  • 최덕순
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.471-477
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    • 1999
  • Fe and Fe-Mo binder were used to produce TiB2 based cermet by a pressureless sintering. The densification behaviour of TiB2-Fe-Mo cermet during liquid-phase sintering in argon was studied in relation to binder phase charactertics. The effects of Mo addition and sintering condition on the sintering behaviour and mechanical properties were also investigated. TiB2-based cermets with Fe-Mo binder composition showed a better sinterability than the cermets with only Fe binder. In TiB2-Fe-Mo cermet higher densities in the wide temperature range were obtained and also fully densified sintered cermet were obtained at 1873K The enhancement in the densification phenomenon of TiB2-Fe-Mo system can be explained by improved liquid phase wettability associated with the roles of Mo components as solute atoms. When Fe-Mo binders were used cermets with a finer grain size and enhanced mechanical properties wereproduced and new phases such as Fe2B and Mo2FeB2 were observed in the sintered cermet. The highest bending strength was obtained from the 20vol% Fe-Mo cermet and these hardness-fracture toughness combination in the wide binder compositions is better than that of TiB2-Fe cermet. In order to improve mechanical properties microstructure control with high purity powders is desirable because high purity powders prevent the formation of Fe2B and Mo2FeB2 phase which comsume the ductile binder phase.

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Magnetic Properties of $NdFe_{10.7}TiB_{0.3}N_x$ and $NdFe_{10.7}TiMo_{0.3}N_x$ ($NdFe_{10.7}TiB_{0.3}N_x$$NdFe_{10.7}TiMo_{0.3}N_x$의 자기특성)

  • Kim, Yun-Bae;Kim, Hui-Tae;Kim, Chang-Seok;Kim, Taek-Gi
    • Journal of the Korean Magnetics Society
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    • v.2 no.3
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    • pp.239-243
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    • 1992
  • It has been found that B is very effective for the increase of magnetization and Curie temperature in $NdFe_{11}TiN_x$-type compounds having $ThMN_{12}$-type structure. Experimental results have shown that magnetization and Curie temperature of $NdFe_{10.7}TiB_{0.3}N_x$ are 148 $Am^2$/kg and $560^{\circ}C,$ respectively, by about 20 $Am^2$/kg and $90^{\circ}C$ higher than those of $NdFe_{10.7}Ti_{1.3}N_x.$ On the other hand, Mo is effective for the increase of anisotropy field, and it seems to strongly inhibit the formation of ${\alpha}-Fe$ phase during the nitrification treatement. The anisotropy field of $NdFe_{10.7}TiMo_{0.3}N_x$ is about 7960 kA/m (100 kOe) which is about 1590 kA/m (20 kOe) higher than that of $NdFe_{10.7}Ti_{1.3}N_x$.

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Magnetic Hardening of Rapidly Solidified $SmFe_{7+x}M_{x}(M=Mo,\;V,\;Ti)$ Compounds (급속냉각된 $SmFe_{7+x}M_{x}(M=Mo,\;V,\;Ti)$ 화합물에서 생성된 신 강자성상)

  • Choong-Jin Yang;E. B. Park;S. D. Choi
    • Journal of the Korean Magnetics Society
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    • v.4 no.3
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    • pp.226-232
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    • 1994
  • Rapidly solidified $SmFe_{7+x}M_{x}(M=Mo,\;V,\;Ti)$ compound were found to crystallize in the ${Sm(Fe,\;M)}_{7}$ based stable magnetic phase by introducing a second transition element into the Sm-Fe binary system. The ${Sm(Fe,\;M)}_{7}$ phase exhibits the highest Curie temperatuer ($T_{c}=355^{\circ}C$) ever Known in the Sm-Fe magnetic systems with a quite high intrinsic coercivity($_{i}H_{c}=3~6\;kOe $). The ${Sm(Fe,\;M)}_{7}$ phase remains stable even after annealing if once form during the rapid solidification. The primary reason for the high coercive force is due to the fine grain size($2000~8000\;{\AA}$)of the magnetic ${Sm(Fe,\;M)}_{7}$ matrix phase, and the enhanced Curie temperature is attributed to the extended solid-solubility of the additive transition elements in Fe matrix, which leads to volume expansion of the ${Sm(Fe,\;M)}_{7}$ cell causing an enhanced coupling constant of Fe atoms.

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The Photocatalytic Decomposition of Different Organic Dyes under UV Irradiation with and without H2O2 on Fe-ACF/TiO2 Photocatalysts

  • Zhang, Kan;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.561-567
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    • 2009
  • The Fe-ACF/$TiO_2$ composites were prepared by a sol-gel method and were characterized by nitrogen adsorption, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), and Energy Dispersive X-ray (EDX). The Fe-ACF/$TiO_2$ composites were developed for the decomposition of organic dyes by using a UV lamp. The decomposition effect was investigated under various conditions, such as three selected non-biodegradable organic dyes like Methylene Blue (MB), Methyl Orange (MO), Rhodamine B (Rh.B), and in the presence of Fe and hydrogen peroxide ($H_2O_2$). The photocatalytic activity was derived from possible combination effects, such as (1) adsorption of ACF, (2) generation of electron/hole by $TiO_2$, (3) photo-Fenton reaction of Fe, and (4) oxidation of $Fe^{2+}\;to\;Fe^{3+}\;by\;H_2O_2$.

Photodecomposition of Different Organic Dyes Using Fe-CNT/TiO2 Composites under UV and Visible Light

  • Zhang, Kan;Meng, Ze-Da;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.169-176
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    • 2010
  • The Fe-treated CNT/$TiO_2$ photocatalysts mixed with anatase and rutile phase have been developed for the decomposition of non-biodegradable different organic dyes like methylene blue (MB), rhodamine B (Rh.B), and methyl orange (MO) in two conditions as ultraviolet and visible light respectively. The results indicate that all the Fe-CNT/$TiO_2$ composites proved to be more efficient photocatalysts since degradation of MB at higher reaction rates, tthe decomposition rate of different dyes increases with an increase of $Fe^{3+}$ concentration in composites the highest rate of decomposition of different dyes was noted under UV irradiation. These results can indicate that the large CNT network is facilitate the electron transfer and strongly adsorb dye molecules on the texted photocatalysts, iron is reactive in the photo-Fenton process resulting in high production of OH radicals and also high activity of the photocatalyst. And Fe particles can generate more photoinduced electrons to conduction band of $TiO_2$ under visible light irradiation. The composites of Fe-CNT/$TiO_2$ photocatalysts synthesized by a sol-gel method were characterized by BET, TEM, SEM, XRD and EDX.

Blended Elemental P/M Synthesis of Titanium Alloys and Titanium Alloy-based Particulate Composites

  • Hagiwara, Masuo;Emura, Satoshi
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1030-1031
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    • 2006
  • Titanium alloys and Titanium alloy-based particulate composites were synthesized using the blended elemental P/M route. First, processing conditions such as the fabrication of master alloy powder were investigated. Ti-6Al-4V, Ti-5Al-2.5Fe, Ti-6Al-2Sn-4Zr-2Mo, IMI685, IMI829, Timetal 1100 and Timetal 62S, and Ti-6Al-2Sn-4Zr-2Mo/ 10%TiB and Timetal 62S/10%TiB were then synthesized using the optimal processing conditions obtained. The microstructures and mechanical properties such as tensile strength and high cycle fatigue strength were evaluated.

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Effect of Boron on the Manufacturing Properties of Ti-2Al-9.2Mo-2Fe Alloy (Ti-2Al-9.2Mo-2Fe 합금의 후공정 특성에 미치는 보론의 영향)

  • Kim, Tae-Yong;Lim, Ka-Ram;Lee, Yong-Tai;Cho, Kyung-Mok;Lee, Dong-Geun
    • Korean Journal of Materials Research
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    • v.25 no.11
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    • pp.636-641
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    • 2015
  • Titanium has many special characteristics such as specific high strength, low elastic modulus, excellent corrosion and oxidation resistance, etc. Beta titanium alloys, because of their good formability and strength, are used for jet engines, and as turbine blades in the automobile and aerospace industries. Low cost beta titanium alloys were developed to take economic advantage of the use of low-cost beta stabilizers such as Mo, Fe, and Cr. Generally, adding a trace of boron leads to grain refinement in casted titanium alloys due to the pinning effect of the TiB phases. This study analyzed and evaluated the microstructural and mechanical properties after plastic deformation and heat treatment in boron-modified Ti-2Al-9.2Mo-2Fe alloy. The results indicate that a trace of boron addition made grains finer; this refinement effect was found to be maintained after subsequent processes such as hot forging and solution treatment. This can effectively reduce the number of required manufacturing process steps and lead to savings in the overall cost as well as low-cost beta elements.

Fabrication and characteristics of alcohol sensor using Fe2O3 (Fe2O3후막을 이용한 alcohol sensor 제작 및 감응특성)

  • Lee, Y.S.;Song, K.D.;Lee, S.M.;Shim, C.H.;Choi, N.J.;Joo, B.S.;Lee, D.D.;Huh, J.S.
    • Journal of Sensor Science and Technology
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    • v.11 no.2
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    • pp.77-83
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    • 2002
  • In order to get low cost and portability, semiconductor gas sensor need to have low operating temperature and high sensitivity. $Fe_2O_3$ based sensors which were doped with metal oxide catalysts($MoO_3$, $V_2O_5$, $TiO_2$, and CdO) were fabricated by screen printing method. To improve electrical stability of sensors, the $Fe_2O_3$ sensors were annealed in $N_2$ at $700^{\circ}C$ for 2 hours. The $V_2O_5$ doped $Fe_2O_3$ sensor showed about $80{\sim}90%$ sensitivity at alcohol 1,000 ppm and have good selectivity to hydrocarbon gas and tobacco odors. The fabricated sensor and PIC-chip were employed for portable alarm system.

Ion Exchange Separation of Minor Elements from Iron for the Analysis of S/G Sludge

  • Park, Kyoung-Kyun;Choi, Kwang-Soon;Kim, Jong-Goo
    • Proceedings of the Korean Nuclear Society Conference
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    • 2005.05a
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    • pp.309-310
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    • 2005
  • Some minor elements(Al, B, Ba, Ca, Cd, Co, Cr, Cu, Gd, Mg, Mn, Mo, Nd, Ni, P, Pb, Si, Sn, Sr, Ti, V, Yb, Zn and Zr) in iron compounds such as the S/G sludge of a power plant were separated from iron by anionic and cationic exchange methods. If a ICP-AES or AAS determination follows this method, minor elements of more than 2 or 20 ppm of Fe can be determined with an error less than 20% except Sn and Mo. Alkaline elements were excluded from this study since they can be easily recovered from an anionic exchange. Application to real sludge samples is ongoing.

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더덕 ( 사삼 )의 재배방법별 일반성분 및 무기성분에 관한 연구 ( Proximate and Mineral of Dried Wild and Cultivated Codonopsis lanceolata Benth , et Hook , Fil , of Different Cultivated Groups )

  • 신수철
    • Korean Journal of Plant Resources
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    • v.4 no.2
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    • pp.39-45
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    • 1991
  • Proximate compositions of the roots of cultured and wild Codonopsis lanceolata were examined as tile basic reasearch for the study of their source of processed foods.No significant difference in the contents was found between the wild root and thecultivated at 3$0^{\circ}C$ in biotronroom. In view of the results to have measured mineralswhich is included in 14 sorts of Codonopsis lanceolata and surveyed their distribution.12 kinds of minerals including T1, Co, Ge, Sm, Mo, Sc, Be, Cd, As, Ga, Bi, ph are ne-vel or little included in almost source. Other twenty-one sorts of minerals (Ni, Se,Ba, Sb, Si, Ti, B, Li, Ifs, Ca, Sr, Mn, Fe, Cu, Zn, p, Al, Na, V, Cr, K) are more or less in-cluded in all source and Ca, Mg, p, K, and Fe are metals that are included in large qu-entities in comparison with others. No minerals difference in the contents was foundbetween the cultivated temperature. The content of elements of inorganic metal differsaccording to the part of C. lanceolata.

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