• 대한치과기공학회지
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• 제31권3호
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• pp.9-14
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• 2009

This study evaluated the mechanical properties of Ti-Cu alloys with the hope of developing an alloy for dental casting with better mechanical properties than unalloyed titanium. Ti-Cu alloys with four concentrations of Cu(2,5,10wt%) were made in an argon-arc melting furnace. The microstructure and micro-Vickers hardness were determined. X-ray diffraction pattern test was performed on the polished specimens. The microstructure of 2%Cu and 5%Cu alloys are shown acicular ${\alpha}Ti$ phase formed on the surfaces of previously formed $\beta$grains. The 10%Cu alloys has essentially a eutectoid structure; this structure includes lamella of ${\alpha}Ti$ and $Ti_2Cu$ phase that transformed from ${\alpha}Ti$ at the eutectoid temperature. The micro-Vickers hardness of CP Ti specimens was significantly(p<0.05) lower than that of any of the other alloys. Among the Ti-Cu alloys, the 10%Cu alloys exhibited a significantly(p<0.05) higher hardness value. but lower than that of Ti-6%Al-4%V alloy. From these results, it was concluded that new alloys for dental castings should be designed as Ti-Cu based alloys if other properties necessary for dental castings were obtained.

• 열처리공학회지
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• 제9권3호
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• pp.177-186
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• 1996

Surface alloying of Ti alloy by $CO_2$ laser is able to produce few hundred micrometers thick TiN or TiC surface-alloyed layer with high hardness on the substrate by injecting reaction gas($N_2$ or $CH_4$). Laser surface alloying by means of process control is in many applications essential in order to obtain predictable hardening layer. This research has been investigated the effect of such parameters on TiN and TiC gas alloying of Ti-6Al-4V alloy by $CO_2$ laser. The maximum surface hardness of TiN layer was obtained 1750Hv on the conditions of 0.8kW laser power, 0.8m/min scanning speed and 100% $N_2$ atmosphere. However, the maximum hardness of TiC formation layer after laser treatment was about 630Hv. As scanning speed was increased, the hardness and depth of these layers were decreased at constant laser power.

• 한국결정성장학회지
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• 제7권2호
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• pp.284-291
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• 1997

V-Ti(V-rich) 수소저장합금을 기초(base)로 하여 2가지 타입(type)의 전극을 제조하였다. 첫째로 V-Ti 합금에 Ni 분말을 혼합하여 성형한 후 급속가열방법으로 소결하여 전극을 제조하였다. 둘째로 Ni을 V-Ti 합금과 합금화한 V-Ti-Ni 3원계 수소저장합금에 Ni, PTFE 분말을 혼합하여 냉간압축으로 성형하여 전극을 제조하였다. 이와같이 제조된 전극으로 싸이클에따른 충/방전 실험을 한 결과, 모든 전극에 있어 10싸이클 이내에 퇴화(degradation)가 일어났다. 충방전 실험후 전해질내의 조성분석결과 Ti에 비해 V이 많이 전해질 내에 용해되었으며 합금원소의 용해에 의한 표면 형상의 변화가 관찰되었고, 전극표면에 매우 passive 한 Ti-oxide($TiO_2$)가 형성되었다. Ti-oxide($TiO_2$)는 전기전도도가 매우 낮고, 수소에대한 확산계수(diffusivity)도 낮기때문에 전극표면에 형성된 $TiO_2$층은 충/방전 싸이클동안 방전용량을 크게 감소시키는 것으로 나타났다.

• 한국수소및신에너지학회논문집
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• 제7권1호
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• pp.19-28
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• 1996

Ti-Mn based hydrogen storage alloy were modified by substituting alloying elements such as Zr, V and Ni in order to design a high capacity MH electrode for Ni/MH rechargeable battery. When V was substituted in Ti-Mn binary system, the crystal structure was maintained as $Cl_4$ Laves phase at a composition of $Ti_{0.2}V_{0.4}Mn_{0.4}$ and $Ti_{0.4}V_{0.2}Mn_{0.4}$ and equilibrium pressure decreased below 1 atm without decreasing hydrogen storage capacity considerably. It was found that Ni should be included in Ti-V-Mn alloy in order to hydrogenate it electrochemically in KOH electrolyte. But substitution of Ni for Mn in Ti-V-Mn system caused the increase of equilibrium pressure above 1atm and decrease of hydrogen storage capacity. Zr was able to increase the reversible hydrogen storage capacity of Ti-V-Mn-Ni alloy without considerable change of hydrogenation properties. The electrochemical discharge capacity of Ti-Zr-V-Mn-Ni system were in the range of 350 - 464mAh/g and among them $Ti_{0.8}Zr_{0.2}V_{0.5}Mn_{0.5}Ni_{1.0}$ alloy had $Cl_4$ Laves single phase and very high electrochemical discharge capacity of 464mAh/g.

• 멤브레인
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• 제21권3호
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• pp.290-298
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• 2011

팔라듐이 코팅된 $V_{53}Ti_{26}Ni_{21}$ 합금 분리막을 통해 수소 투과시 혼합가스의 영향에 대해 알아보았다. 순수 수소, 수소, 이산화탄소 및 일산화탄소의 혼합가스를 공급가스로 주입할 때, $450^{\circ}C$, 1-3 bar의 압력에서 팔라듐이 코팅된 $V_{53}Ti_{26}Ni_{21}$ 합금 분리막의 수소 투과 실험을 수행하였다. 수소만을 공급한 투과 실험에서 팔라듐 코팅된 $V_{53}Ti_{26}Ni_{21}$ 합금 분리막(두께: 0.5 mm)의 수소 투과량은 3 bar, $450^{\circ}C$ 조건에서 $5.36mL/min/cm^2$였다. 또한 수소/이산화탄소, 수소/일산화탄소 및 수소/이산화탄소/일산화탄소를 공급한 투과실험에서 $V_{53}Ti_{26}Ni_{21}$ 합금 분리막의 수소 투과량은 각각 4.46, 5.20, $3.91mL/min/cm^2$였다. 따라서, 수소/이산화탄소, 수소/일산화탄소 및 수소/이산화탄소/일산화탄소 혼합가스를 각각 공급할 때 투과량은 온도와 압력에 상관없이 수소 분압 감소만큼 감소하였고 모든 경우 Sievert 법칙을 잘 만족시켰다. 투과 후 분리막의 XRD 결과로부터 $V_{53}Ti_{26}Ni_{21}$ 합금 분리막은 여러 혼합가스에 대해 안정성과 내구성이 우수하다는 것을 알 수 있었다.

• 한국표면공학회지
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• 제29권6호
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• pp.607-614
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• 1996

Yttrium(Y) coating was incorporated by ion-plating method either directly on the TiAl substrate or after pack aluminizing on TiAl to improve the oxidation resistance of TiAl alloy. After Y-coating, heat treatment at low oxygen partial pressure was carried out. Performance of various coating was evaluated by isothermal and cyclic oxidation tests. A simple Y-coating without pack aluminizing can give a detrimental effect on the. oxidation resistance of TiAl alloy, because it enhances formation of $TiO_2$. On the other hand, a composite coating of aluminide-yttrium has shown excellent oxidation resistance. A continuous protective $Al_2O_3$ scale is formed on the aluminized TiAl, and Y-coating improves $Al_2O_3$ scale adherence and substantially prevents depletion of Al in the aluminide-coating layer.

• 대한치과기공학회지
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• 제23권1호
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• pp.21-30
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• 2001

For biomedical applications. Ti-X%Zr-Y%Pd(X: $10{\sim}20$, Y:0.2 or 0.4) based alloys not containing harmful Al and V were newly designed, and polarization curves for their alloys were measured at $37^{\circ}C$ in 5% HCl solution in order to understand effects of Zr on the corrosion. From the results of anodic polarization behavior, it was found that the corrosion resistance increased with increasing Zr content. The results show their potential to develope Ti-based alloys for biomedical materials. The Ti-20%Zr-0.2%Pd alloy shows excellent corrosion resistance and was superior to those of the Ti. Ti-6%Al-4%V ELI alloy, Co-30%Cr-6%Mo alloy and STS 316L stainless steel.

• 대한기계학회논문집
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• 제18권11호
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• pp.2954-2966
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• 1994

The characteristics and good corrosion resistance at room and elevated temperatures led to increasing application of Ti-alloys such as aircraft, jet engine, turbine wheels. In forging of Ti-alloy at high temperature, die chilling and die speed should be carefully controlled because the flow stress of Ti-alloy is sensitive to temperature, strain and strain-rate. In this study, the forging of turbine disk was numerically simulated by the finite element method for hot-die forging process and isothermal forging process, respectively. The effects of the temperature changes, the die speed and the friction factor were examined. Also, local variation of process parameters, such as temperature, strain and strain-rate were traced during the simulation. It was shown that the isothermal forging with low friction condition produced defect-free disk under low forging load. Consequently, the simulational information will help industrial workers develope the forging of Ti-alloys including 'preform design' and 'processing condition design'. It is also expected that the simulation method can be used in CAE of near net-shape forging.

• 한국재료학회지
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• 제16권4호
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• pp.264-271
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• 2006

RF sputtering process was applied to produce thin hydroxyapatite(HAp) films on Ti-6Al-4V alloy substrates. The effects of different heat treatment conditions on the chemical composites between HAp thin films and Ti-6Al-4V alloy substrates were studied. After deposition, the HAp thin films were heat treated for 1h at $400^{\circ}C,\;600^{\circ}C\;and\;800^{\circ}C$ under the atmosphere, and analyzed O/M, FESEM-EDX and ESCA, respectively. Experimental results represented that interface of HAp thin films and Ti-6Al-4V alloy substrates was composed Ti-OH, TiO, TiN, $Al_2O_3,\;V_2O_3,\;VO_2$. pyrophosphate and decreased carbide followed by the increase of heat treatment temperature.

• 한국분말재료학회지
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• 제25권4호
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• pp.327-330
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• 2018

This study is conducted as a preliminary research to verify the feasibility of Ti-based Oxide dispersion strengthened (ODS) alloy. Pure-Ti powder is mixed with $Y_2O_3$ powder and subsequently, mechanically alloyed at $-150^{\circ}C$. The Ti-based ODS powder is hot-isostatically pressed and subsequently hot-rolled for recrystallization. The microstructure consists of elongated grains and Y excess fine particles. The oxide particle size is larger than that of the typical Fe-based ODS steel. Tensile test shows that the tensile ductility is approximately 25%, while the strength is significantly higher than that of pure Ti. The high-temperature hardness of the Ti-ODS alloy is also significantly higher than that of pure Ti at all temperatures, while being lower than that of Ti-6Al-4V. The dimple structure is well developed, and no evidence of cleavage fracture surface is observed in the fracture surface of the tensile specimen.