• 한국재료학회지
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• 제21권7호
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• pp.357-363
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• 2011

In this paper, high temperature oxidation behavior of newly developed alloys, Ti-6Al-4Fe and Ti-6Al-1Fe, is examined. To understand the effect of Fe on the air oxidation behavior of the Ti-Al-Fe alloy system, thermal oxidation tests are carried out at $700^{\circ}C$ and $800^{\circ}C$ for 96 hours. Ti-6Al-4V alloy is also prepared and tested under the same conditions for comparison with the developed alloys. The oxidation resistance of the Ti-Al-Fe alloy system is superior to that of Ti-6Al-4V alloy. Ti-6Al-4V shows the worst oxidation resistance for all test conditions. This is not a result of the addition of Fe, but rather it is due to the elimination of V, which has deleterious effects on high temperature oxidation. The oxidation of the Ti-Al-Fe alloy system follows the parabolic rate law. At $700^{\circ}C$, Fe addition does not have a noticeable influence on the amount of weight gain of all specimens. However, at $800^{\circ}C$, Ti-6Al-4Fe alloy shows remarkable degradation compared to Ti-6Al-1Fe and Ti-6Al. It is discovered that the formation of $Al_2O_3$, a diffusion resistance layer, is remarkably hindered by a relative decrease of the ${\alpha}$ volume fraction. This is because Fe addition increases the volume fraction of ${\beta}$ phase within the Ti-6Al-xFe alloy system. Activities of Al, Ti, and Fe with respect to the formation of oxide layers are calculated and analyzed to explore the oxidation mechanism.

• 한국해양공학회지
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• 제25권6호
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• pp.42-48
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• 2011

The present study makes three original contributions to nanoskinned Ti-6Al-4V materials. The nanoskins were fabricated on Ti-6Al-4V material using various surface treatments: deep rolling (DR), laser shot peening (LSP), and ultrasonic nanocrystal surface modification (UNSM). These surface treatments are newly developed techniques and are becoming more popular in industrial fields. A fatigue strength comparison at up to 106 cycles was conducted on these nanoskinned Ti-6Al-4V materials. Fatigue tests were carried out using MTS under axial loading tension-compression fatigue (R = -1, RT, 5 Hz, sinusoidal wave). The analysis of the crack initiation patterns in the nanoskinned Ti-6Al-4V materials found an interior originating crack pattern and surface originating crack type. Microscopic observation was mainly used to investigate the fatigue fractured sites. These surface modification techniques have been widely adopted, primarily because of the robust grade of their mechanical properties. These are mainly the result of the formation of a large-scale, deep, and useful compressive residual stress, the formation of nanocrystals by the severe plastic deformation (SPD) at the subsurface layer, and the increase in surface hardness.

• 대한치과기공학회지
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• 제27권1호
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• pp.73-78
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• 2005

The surface-reacted layer of titanium castings greatly affects their mechanical properties. This study analyzed the interfacial zone of Ti-20%Zr-5%Cr alloy castings obtained from phosphate bonded investment and examined the relationship between the surface-reacted layer and hardness. The Vickers hardness of cast disks were tested at 20$\mu m$ intervals from the surface to 120$\mu m$ in depth. The cross-section was observed metallurgically, and line profile of the reacted layer was conducted under the EDX. The surface-reacted layer of Ti-20%Zr-5%Cr alloy is showed a similar tendency to Ti-6%Al-4%V alloy in thickness, and also Si diffusion in multiple reacted layer of Ti-20%Zr-5%Cr alloy is less than cp Ti and similar to Ti-6%Al-4%V alloy. The Vickers hardness in the surface layer was greater than in the inner part, and the Vickers hardness of Ti-20%Zr-5%Cr alloy ranged 650 to 390 and cp Ti ranged 810 to 160, Ti-6%Al-4%V alloy ranged 710 to 530 respectively.

• 한국추진공학회지
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• 제4권1호
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• pp.1-12
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• 2000

유도탄의 성능 향상을 위해 추진기관의 경량화가 요구되고 있으며 연소관 모타 마개의 경우, Ti 합금 (Ti-6Al-4V)이 사용되고 있다. 제작 과정 중에 열간 형단조 공정이 이용되나 이 과정에서 Ti alloy의 좁은 성형 온도 구간 관계로 단조시 국부적 소성 변형 집중에 의한 결함이 단조품의 다수 생성되며, 심한 경우 전단 파단까지 이르고 있다. 성형 과정에서 금형과의 접촉에 의한 Ti 합금 온도 하강이 전단 파단 발생과 밀접한 관계를 갖고 있으며 따라서 각 단조 조건에 따른 Ti 합금의 내부 및 표면에 대한 변형 및 온도의 분포가 관찰되었다. 아울러 전단 밴드 형성에 대한 별도의 분석도 포함되었다.

• 열처리공학회지
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• 제36권3호
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• pp.145-152
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• 2023

β titanium alloys containing β stabilizing elements such as V, Nb, Ta, Mo and Fe are widely used etc, due to their excellent specific strength, corrosion resistance, fatigue strength and easy formability. New metastable β titanium alloys are developed containing low-cost elements (Mo and Fe) in this study. Fe element is a strong β-stabilizer which can affect the mechanical and electrochemical properties of Ti-5Mo-xFe (x = 1, 4 wt%) alloys. These properties were analyzed in connection with microstructure and phase distribution. Ti-5Mo-4Fe alloy showed higher compression yield stress and maximum stress than Ti-5Mo-1Fe alloy due to solid-solution hardening and grain refinement hardening effect. As Fe element increased, Fe oxide formation and reduction of ${\bar{Bo}}$ (bond order) value affect the decrease of corrosion resistance. Ti-5Mo-xFe alloys were more excellent than Ti-6Al-4V ELI alloy.

• 대한금속재료학회지
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• 제50권5호
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• pp.395-400
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• 2012

In this study, we have investigated the surface morphology of hydroxyapatite (HA) coated Ti alloy surface using pulsed laser plating. The HA (tooth ash) films were grown by pulsed KrF excimer laser, film surfaces were analyzed for topology, chemical composition, crystal structure and electrochemical behavior. The Ti-6Al-4V alloy showed ${\alpha}$ and ${\beta}$ phase, Cp-Ti showed ${\alpha}$ phase and the HA coated surface showed HA and Ti alloy peaks. The HA coating layer was formed with $1-2{\mu}m$ droplets and grain-like particles, particles which were smaller than the HA target particle, and the composition of the HA coatings were composed of Ca and P. From the electrochemical test, the pitting potential (1580 mV) of HA coated Ti-6Al-4V alloy was higher than those of Cp-Ti (1060 mV) and HA coated Cp-Ti (1350 mV). The HA coated samples showed a lower current density than non-HA coated samples, whereas, the polarization resistance of HA coated samples showed a high value compared to non-HA coated samples.

• Corrosion Science and Technology
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• 제20권6호
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• pp.475-483
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• 2021

Additively manufactured titanium alloy is one of the promising materials in advanced medical industries. However, these additively manufactured alloys show corrosion properties different from those of conventional materials due to their unique microstructure. In this study, the effect of surface roughness and masking conditions on the results of the potentiodynamic polarization tests on additively manufactured or conventional Ti-6Al-4V alloys in artificial saliva solution with or without fluoride was investigated. The results showed that the corrosion potential was slightly lower with a flat cell with an O-ring than with masking tape. The corrosion rate was decreased with decreases in the surface roughness. Localized corrosion involving delamination of the surface layer occurred at 7 ~ 9 V (SSC) on the additively manufactured alloy in solution with or without fluoride when the samples were finished with 1000-grit SiC paper, whereas localized corrosion was not observed in the specimens finished with 1-㎛ alumina paste.

• 구강생물연구
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• 제42권4호
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• pp.187-197
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• 2018

Chemical agents such as minocycline (MC) and citric acid (CA) were suggested in the treatment of contaminated implant surface. In this study, MC-HCl treatment was performed to enhance surface characteristics of titanium alloy surface. The purpose of this study was to assess the characteristics and the biocompatibility of Ti-6Al-4V surface treated by MC. Alpha-beta titanium alloy (Ti-6Al-4V) samples were prepared and they were divided into 6 groups according to chemical concentration and treatment time. These groups include 1) group I, non-treated smooth titanium alloy; 2) group II, MC 1.5 mg/mL for 1 hour; 3) group III, MC 1.5 mg/mL for 24 hours; 4) group IV, MC 15 mg/mL for 10 minutes; 5) group V, MC 100 mg/mL for 5 minutes; 6) group VI, pH1 CA for 3 minutes. The analysis of the surface characteristics of MC-treated titanium alloy was executed using scanning electron microscopy, roughness test, and X-ray photoelectron spectroscopy (XPS). Cell adhesion and MTT assay was done using MC3T3 cell. Titanium surfaces treated with MC indicated a more smoothened surface microstructure. For group II and III, the new peaks of rutile TiO2 were found. Group II and V have more basic group of Ti-OH form in XPS. In MTT assay, all MC-treated groups showed significantly higher cell viability compared to control. The surface roughness, crystal structure, surface hydrophilicity, cell viability of smooth titanium surface was improved by MC treatment. Compared with the control experiment and CA-treated group, smooth titanium surface treated with MC showed improved surface characteristics and cell biocompatibility.

• Journal of Magnetics
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• 제15권1호
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• pp.25-28
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• 2010

This study examined the crystallographic and magnetic properties of vanadium-substituted lithium cobalt titanium ferrite, $Li_{0.7}Co_{0.2}Ti_{0.2}V_{0.2}Fe_{1.7}O_4$. Ferrite was synthesized using a conventional ceramic method. The samples annealed below $1040^{\circ}C$ showed X-ray diffraction peaks for spinel and other phases. However, the sample annealed above $1040^{\circ}C$ showed a single spinel phase. The lattice constant of the sample was $8.351\;{\AA}$, which was relatively unaffected by vanadium-substitution. The average grain size after vanadium-substitution was $13.90\;{\mu}m$, as determined by scanning electron microscopy. The M$\ddot{o}$ssbauer spectrum could be fitted to two Zeeman sextets, which is the typical spinel ferrite spectra of $Fe^{3+}$ with A and B sites, and one doublet. From the absorption area ratio of the M$\ddot{o}$ssbauer spectrum, the cation distribution was found to be ($Co_{0.2}V_{0.2}Fe_{0.6})[Li_{0.7}Ti_{0.2}Fe_{1.1}]O_4$. Vibrating sample magnetometry revealed a saturation magnetization and coercivity of 36.9 emu/g and 88.6 Oe, respectively, which were decreased by vanadium-substitution.

• 한국군사과학기술학회지
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• 제17권4호
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• pp.413-421
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• 2014

Since the structural temperature of a flight vehicle flying at high speed rises rapidly due to aerodynamic heating, it is necessary for optimum structural design to obtain proper material properties at high temperature by taking into account of its operational environment. For a special alloy, analysis data on strength change due to exposure time to high temperature are very limited, and most of them are for an exposure time longer than 30 minutes for long term operations. In this study, base and weld metal samples of Ti-6Al-4V alloy had been prepared and high temperature tensile tests with induction heating were performed, and then high temperature strength characteristics and strength recovery characteristics through cooling have been analyzed. Pre-tests to determine maximum heating rate were performed, and response characteristics for temperature control were confirmed. As a result, high temperature tensile strength appeared to be lower than that of room temperature, but it was higher than that of high temperature of 30 minite exposure listed in MMPDS. In strength recovery through cooling Ti-6Al-4V alloy has shown higher recovery rate compared with other alloys.