• Title/Summary/Keyword: Through-Diffusion

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PERFORMANCE CHARACTERISTICS OF A PROTON EXCHANGE MEMBRANE FUEL CELL(PEMFC) WITH AN INTERDIGITATED FLOW CHANNEL

  • Lee, P.H.;Cho, S.A.;Han, S.S.;Hwang, S.S.
    • International Journal of Automotive Technology
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    • v.8 no.6
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    • pp.761-769
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    • 2007
  • The configuration of the flow channel on a bipolar plate of a proton exchange membrane fuel cell(PEMFC) for efficient reactant supply has great influence on the performance of the fuel cell. Recent demand for higher energy density fuel cells requires an increase in current density at mid voltage range and a decrease in concentration overvoltage at high current density. Therefore, an interdigitated flow channel where mass transfer rate by convection through a gas diffusion layer is greater than the mass transfer by a diffusion mechanism through a gas diffusion layer was recently proposed. This study attempts to analyze the i-V performance, mass transfer and pressure drop in interdigitated flow channels by developing a fully three dimensional simulation model for PEMFC that can deal with anode and cathode flow together. The results indicate that the trade off between performance and pressure loss should be considered for efficient design of flow channels. Although the performance of the fuel cell with interdigitated flow is better than that with conventional flow channels due to a strong mass transfer rate by convection across a gas diffusion layer, there is also an increase in friction due to the strong convection through the porous diffusion layer accompanied by a larger pressure drop along the flow channel. It was evident that the proper selection of the ratio of channel and rib width under counter flow conditions in the fuel cell with interdigitated flow are necessary to optimize the interdigitated flow field design.

Visualization of Water Droplets in the Simple Flow Channel and Rib Geometry for Polymer Electrolyte Membrane Fuel Cells (PEMFCs) (고분자전해질형 연료전지의 단순 채널 리브 형상에서의 물방울 가시화 연구)

  • Choi, Min Wook;Kim, Han-Sang
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.4
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    • pp.386-392
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    • 2014
  • The effective water management in a polymer electrolyte membrane fuel cell (PEMFC) is one of the key strategies for improving cell performance and durability. In this work, an ex situ measurement was carried out to understand the water droplet behavior on the surface of gas diffusion layer (GDL) as a fundamental study for establishing novel water management. For that purpose, simplified cell including one rib and two flow channels was designed and fabricated. Using this ex situ device, the water droplet emergence through the GDL of the PEMFC was emulated to understand liquid water transport through the porous diffusion medium. Through the visualization experiment, the emergence and growth of water droplets at the channel/GDL interface are mainly observed with the surface characteristics of GDL (SGL 10BA, 24BA) and rib when the liquid water passes through the GDL and is expelled to the flow channel. It is expected that the results obtained from this study can contribute to the better understanding on the water droplet behavior (emergence and removal) in the flow channels of PEMFC.

Dissolution Kinetics of Sphalerite in Aqueous Ferric Chloride Solution (염화제이철 수용액에서 섬아연광의 용해에 관한 속도론적 연구)

  • Yoo, Seung-Joon;Park, Hyung-Sang;Choi, Cheong-Song;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.421-429
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    • 1993
  • Dissolution reactions of chemical grade zinc sulfide and natural sphalerite were studied in ferric chloride solution as an oxidant. To enhance the leaching reaction, ultrasonic technique was employed in this investigation. For the reaction with pure zinc sulfide, chemical reaction was the rate limiting step in the range of low conversion irrespective of applying ultrasonic wave. And the diffusion through liquid film instead of diffusion through product layer of free sulfur was the rate determining step because ultrasonic vibration removes the product from reaction zone. In the case of sphalerite with the ultrasonic vibrator, it was found that inert mineral layer diffusion was the rate determining step, in which the elemental sulfurs formed were removed by the ultrasonic action. Experimental results showed that the ultrasonic technique proved to be the methods which can significants improve the leaching performance.

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A Study of low cost and high efficiency Solar Cell using SOD(spin on doping) (SOD(Spin On Doping)법을 이용한 저가 고효율 태양전지에 관한 연구)

  • Park, Sung-Hyun;Kim, Kyoung-Hae;Mon, Sang-Il;Kim, Dae-Won;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1054-1056
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    • 2002
  • High temperature Kermal diffusion from $POCl_3$ source usually used for conventional process through put of a cell manufacturing line and potentially reduce cell efficiency through bulk like time degradation. To fabricate high efficiency solar cells with minimal thermal processing, spin-on-doping(SOD) technique can be employed to emitter diffusion of a silicon solar cell. A technique is presented to emitter doping of a mono-crystalline solar cell using spin-on doping (SOD). Moreover it is shown that the sheet resistance variation with RTA temperature and time fer mono-crystalline and multi-crystalline silicon samples. This novel SOD technique was successfully used to produces 11.3% efficiency l04mm by 104mm size mono-crystalline silicon solar cells.

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Influence of Blending Materials on C1- Diffusion and pH of Pore Solution in Cement Pastes (시멘트 경화체 중에서의 C1-의 확산과 세공용액의 pH에 미치는 혼화재의 영향)

  • 김남중;최상흘;정재동;한기성
    • Magazine of the Korea Concrete Institute
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    • v.4 no.1
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    • pp.97-106
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    • 1992
  • Apparent diffusion coefficients of Cl- ions through hardened cement pastes(HCP), which were partly subs¬tituted blast furnace slag, fly ash and silicafume for ordinary Portland cement, were determined. Also. Cl- and OW concentration of pore solutions which were extracted from HCP and the capacities of the HCP to bind CI were determined. Diffusion coefficients of Cl- ions through HCP were increased with water cement ratio(WfC), but decreased with addition of the blending materials. On the contrary, Cl- and OH concentration of the pore solutions were reduced by adding the blending materials.

Research on Information Spread impact of SNS(Study of Twitter) (SNS 정보확산력 산출에 관한 연구 - 트위터를 중심으로 -)

  • Park, Sang Min;Park, Tae Hyoung;Lee, Kyung Ho
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.8 no.3
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    • pp.157-169
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    • 2012
  • As of 2006. 3. the twitter offered in the USA has been one of the propaganda instrument used with ads and politics functioning speedy information diffusion on SNS communicated with others through 140 letters of short messages. and while twitter is using propaganda instrument, it keeps on trying to verify how it has an effect on. So, on the paper, I suggest new simulation model of information diffusion based on probability being able to predict the range of proliferation after it analyze the existing influence and the diffusion force on verification methods. It designed algorithm of verification and algorithm of prediction to use twitter's Open API with Python basement. It proved effectiveness on the model through the analysis to operate the twitter of practical local autonomous entity.

PROPERTIES OF Mo COMPOUNDS AS A DIFFUSION BARRIER BETWEEN Cu AND Si PREPARED BY CO-SPUTTERING

  • Lee, Yong-Hyuk;Park, Jun-Yong;Bae, Jeong-Woon;Yeom, Geun-Young
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.433-439
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    • 1999
  • In this study, the diffusion barrier properties of $1000\AA$ thick molybdenum compounds (Mox=1-5 Si) were investigated using sheet resistance measurements, X-ray diffractometry (XRD), and Rutherford back scattering spectrometry (RBS). Each barrier material was deposited by the de and rf magnetron co-sputtering of Mo and Si, respectively, and annealed at $500-700^{\circ}C$ for 30 min in vacuum. Each barrier material was failed at low temperatures due to Cu diffusion through grain boundaries and defects of barrier thin films or through the reaction of Cu with Si within Mo-barrier thin films. It was found that Mo rich thin films were less effective than Si rich films to Cu penetration activating Cu reaction with the substrate at a temperature higher than $500^{\circ}C$.

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Research of the Performance Improvement of a Light Shelf Depending on the Diffusion Film Installation Position (확산필름 부착 위치에 따른 광선반 성능개선 연구)

  • Park, Eunsu;Lee, Heangwoo;Song, Seonkjae;Kim, Yongseong
    • KIEAE Journal
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    • v.17 no.3
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    • pp.91-97
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    • 2017
  • Purpose: Various studies on a light shelf are in progress, but it has the problem of glare occurrence. The present study suggested a diffusion film as the method for resolving the glare problem, and aimed to establish light shelf-related basic data by conducting the performance evaluation of a light shelf depending on the installation position of the diffusion film. Method: To carry out the light shelf performance evaluation depending on the diffusion film installation position, three cases were established: no diffusion film installation (Case 1), diffusion film installation on the reflector (Case 2), and diffusion film installation on the upper glass surface of the window for light shelf installation (Case 3); and the energy reduction performance, luminance, and luminance contrast were analyzed based on a testbed. Result: The conclusions of this study are as follows. 1) When the diffusion film was applied, the amount of light introduced through the light shelf decreased, and the average indoor illumination decreased accordingly. 2) For Case 3, the lighting energy reduction performance was identical to the lighting energy reduction efficiency of the existing light shelf; and for Case 2, it was found to be inappropriate as the lighting energy consumption increased compared to that of the existing light shelf. 3) The analysis of the glare for the cases established in this study showed that the luminance contrast was low for Case 3, and thus the glare problem could be minimized. 4) The specific angle of the light shelf could induce the glare problem by increasing the luminance depending on the external condition. 5) Based on the aforementioned contents, the installation position of the diffusion film for improving the lighting performance and glare problem of the light shelf was found to be the upper glass surface of the window for light shelf installation.

Diffusion Characteristics of Iodide in a Domestic Bentonite of Korea (국산벤토나이트에서의 요오드이온의 확산특성)

  • Lee, J.O.;Cho, W.J.;Hahn, P.S.;Park, H.H.
    • Nuclear Engineering and Technology
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    • v.26 no.2
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    • pp.285-293
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    • 1994
  • The transport of radionuclides in a compacted bentonite is dominated by diffusion. Through-diffusion tests for iodide were performed to investigate the diffusion characteristics of anionic radionuclides in a domestic bentonite. The bentonite used was sampled from the southeastern area of Korea and the solution was synthetic groundwater spiked with a tracer of I -125(as Na$^{125}$ I). The dry densities of compacted bentonite were 1.2, 1.4, and 1.7 Mg/㎥. The apparent diffusion coefficients and the effective diffusion coefficients of the iodide decrease with increasing dry density. The values were from 3.80 to 7.12$\times$10$^{-11}$ $m^2$/s for the apparent diffusion coefficients and from 1.25 to 7.97$\times$10$^{-12}$ $m^2$/s for the effective diffusion coefficient, respectively. The experimental results also showed that the apparent diffusion coefficients depended on the pore structure of compacted bentonite and the effective diffusion coefficients were attributed to the pore structure and the effective porosity that represents the available pathway for the diffusional transport of iodide. The results obtained will be used as basic data for the safety assessment of a repository.

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