• Title/Summary/Keyword: Three-Dimensional Network Structures

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Effect of associating polymer on the dispersion stability and rheology of suspensions

  • Otsubo, Yasufumi;Horigome, Misao
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.27-33
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    • 2003
  • Associating polymers are hydrophilic long-chain molecules to which a small amount of hydrophobic groups (hydrophobes) is incorporated. In aqueous solution, the association interactions result in the formation of three-dimensional network through flowerlike micelles at high concentrations. In colloidal suspensions, the associating polymers act as flocculated by bridging mechanism. The rheological properties of suspensions flocculated by associating polymers end-capped with hydrophobes are studied in relation to the bridging conformation. At low polymer concentrations, the polymer chains effectively form bridges between particles by multichain association. The suspensions are highly flocculated and show typical viscoelastic responses. When the polymer concentration is increased above the absorbance at saturation, the excess polymer chains remaining in the solution phase build up three-dimensional network by associating interactions. Since the presence of particles does not significantly influence the network structures in the medium, the relative viscosity, which gives a measure of the degree of flocculation is decreased with increasing polymer concentration. The bridging conformation and flocculation level vary strongly depending on the polymer concentrations.

Mechanism of Formation of Three Dimensional Structures of Particles in a Liquid Crystal

  • West, John L.;Zhang, Ke;Liao, Guangxun;Reznikov, Yuri;Andrienko, Denis;Glushchenko, Anatoliy V.
    • Journal of Information Display
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    • v.3 no.3
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    • pp.17-23
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    • 2002
  • In this work we report methods of formation of three-dimensional structures of particles in a liquid crystal host. We found that, under the appropriate conditions, the particles are captured and dragged by the moving isotropic/nematic front during the phase transition process. This movement of the particles can be enhanced significantly or suppressed drastically with the influence of an electric field and/or with changing the conditions of the phase transition, such as the rate of cooling. As a result, a wide variety of particle structures can be obtained ranging from a fine-grained cellular structure to stripes of varying periods to a course-grained "root" structures. Changing the properties of the materials, such as the size and density of the particles and the surface anchoring of the liquid crystal at the particle surface, can also be used to control the morphology of the three-dimensional particle network and adjust the physical properties of the resulting dispersions. These particle structures may be used to affect the performance of LCD's much as polymers have been used in the past.

Active shape control of a cantilever by resistively interconnected piezoelectric patches

  • Schoeftner, J.;Buchberger, G.
    • Smart Structures and Systems
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    • v.12 no.5
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    • pp.501-521
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    • 2013
  • This paper is concerned with static and dynamic shape control of a laminated Bernoulli-Euler beam hosting a uniformly distributed array of resistively interconnected piezoelectric patches. We present an analytical one-dimensional model for a laminated piezoelectric beam with material discontinuities within the framework of Bernoulli-Euler and extent the model by a network of resistors which are connected to several piezoelectric patch actuators. The voltage of only one piezoelectric patch is prescribed: we answer the question how to design the interconnected resistive electric network in order to annihilate lateral vibrations of a cantilever. As a practical example, a cantilever with eight patch actuators under the influence of a tip-force is studied. It is found that the deflection at eight arbitrary points along the beam axis may be controlled independently, if the local action of the piezoelectric patches is equal in magnitude, but opposite in sign, to the external load. This is achieved by the proper design of the resistive network and a suitable choice of the input voltage signal. The validity of our method is exact in the static case for a Bernoulli-Euler beam, but it also gives satisfactory results at higher frequencies and for transient excitations. As long as a certain non-dimensional parameter, involving the number of the piezoelectric patches, the sum of the resistances in the electric network and the excitation frequency, is small, the proposed shape control method is approximately fulfilled for dynamic load excitations. We evaluate the feasibility of the proposed shape control method with a more refined model, by comparing the results of our one-dimensional calculations based on the extended Bernoulli-Euler equations to three-dimensional electromechanically coupled finite element results in ANSYS 12.0. The results with the simple Bernoulli-Euler model agree well with the three-dimensional finite element results.

Semi-active control on long-span reticulated steel structures using MR dampers under multi-dimensional earthquake excitations

  • Zhou, Zhen;Meng, Shao-Ping;Wu, Jing;Zhao, Yong
    • Smart Structures and Systems
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    • v.10 no.6
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    • pp.557-572
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    • 2012
  • This paper focuses on the vibration control of long-span reticulated steel structures under multi-dimensional earthquake excitation. The control system and strategy are constructed based on Magneto-Rheological (MR) dampers. The LQR and Hrovat controlling algorithm is adopted to determine optimal MR damping force, while the modified Bingham model (MBM) and inverse neural network (INN) is proposed to solve the real-time controlling current. Three typical long-span reticulated structural systems are detailedly analyzed, including the double-layer cylindrical reticulated shell, single-layer spherical reticulated shell, and cable suspended arch-truss structure. Results show that the proposed control strategy can reduce the displacement and acceleration effectively for three typical structural systems. The displacement control effect under the earthquake excitation with different PGA is similar, while for the cable suspended arch-truss, the acceleration control effect increase distinctly with the earthquake excitation intensity. Moreover, for the cable suspended arch-truss, the strand stress variation can also be effectively reduced by the MR dampers, which is very important for this kind of structure to ensure that the cable would not be destroyed or relaxed.

Development of energy based Neuro-Wavelet algorithm to suppress structural vibration

  • Bigdeli, Yasser;Kim, Dookie
    • Structural Engineering and Mechanics
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    • v.62 no.2
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    • pp.237-246
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    • 2017
  • In the present paper a new Neuro-Wavelet control algorithm is proposed based on a cost function to actively control the vibrations of structures under earthquake loads. A wavelet neural network (WNN) was developed to train the control algorithm. This algorithm is designed to control multi-degree-of-freedom (MDOF) structures which consider the geometric and material non-linearity, structural irregularity, and the incident direction of an earthquake load. The training process of the algorithm was performed by using the El-Centro 1940 earthquake record. A numerical model of a three dimensional (3D) three story building was used to accredit the control algorithm under three different seismic loads. Displacement responses and hysteretic behavior of the structure before and after the application of the controller showed that the proposed strategy can be applied effectively to suppress the structural vibrations.

Automated Structural Design System Using Fuzzy Theory and Neural Network

  • Lee, Joon-Seong
    • International Journal of Precision Engineering and Manufacturing
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    • v.3 no.1
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    • pp.43-48
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    • 2002
  • This paper describes an automated computer-aided engineering (CAE) system for three-dimensional structures. An automatic finite element mesh-generation technique, which is based on fuzzy knowledge processing and computational geometry techniques, is incorporated into the system, together with a commercial FE analysis code, and a commercial solid modeler. The system allows a geometry model of interest to be automatically converted to different FE models, depending on the physical phenomena of the structures to be analyzed, i.e., electrostatic analysis, stress analysis, modal analysis, and so on. Also, with the aid of multilayer neural networks, the present system allows us to obtain automatically a design window in which a number of satisfactory design solutions exist in a multi-dimensional design parameter space. The developed CAE system is successfully applied to evaluate an electrostatic micromachines.

Fabrication of Three-Dimensional Network Structures by an Electrochemical Method (전기화학적 방법을 통한 3차원 금속 다공성 막의 제조)

  • Kang, Dae-Keun;Heo, Jung-Ho;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.18 no.3
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    • pp.163-168
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    • 2008
  • The morphology of three-dimensional (3D) cross-linked electrodeposits of copper and tin was investigated as a function of the content of metal sulfate and acetic acid in a deposition bath. The composition of copper sulfate had little effect on the overall copper network structure, whereas that of tin sulfate produced significant differences in the tin network structure. The effect of the metal sulfate content on the copper and tin network is discussed in terms of whether or not hydrogen evolution occurs on electrodeposits. In addition, the hydrophobic additive, i.e., acetic acid, which suppresses the coalescence of evolved hydrogen bubbles and thereby makes the pore size controllable, proved to be detrimental to the formation of a well-defined network structure. This led to a non-uniform or discontinuous copper network. This implies that acetic acid critically retards the electrodeposition of copper.

Structures and Sorption Properties of 2-Methylbenzimidazolate-Based Zn(II) Frameworks

  • Phang, Won Ju;Lee, Woo Ram;Hong, Chang Seop
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2419-2422
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    • 2014
  • The syntheses and crystal structures of a three-dimensional (3D) coordination network $[Zn_4(2-mBIM)_5-(C_2H_6NCOO)(HCOO)({\mu}-OH)]{\cdot}DMF$ ($1{\cdot}$DMF; 2-mBIM = 2-methylbenzimidazolate) and a two-dimensional (2D) layer $[Zn_2(2-mBIM)_3(HCOO)(H_2O)]{\cdot}DMF$ ($2{\cdot}DMF$) are reported. Different structures were produced depending on the ratio of reactants. Structurally, 1 illustrates the formation of a unique framework based on a 2-mBIM bridge with the side group on an imidazole ring, while 2 possesses a honeycomb layer built up purely from imidazolates. For gas sorption, $CO_2$ is adsorbed on the activated phase of 1 but $N_2$ is not taken up.

Composite Surface Modeling of Three-Dimensional Structures -Theory and Algorithms- (3차원(次元) 구조물(構造物)의 복합곡면(複合曲面)모델링-이론(理論) 및 알고리즘)

  • Koh, Hyun Moo;Park, Young Ha
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.4
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    • pp.43-52
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    • 1990
  • Theoretical foundation and algorithms are presented of a new surface modeling and pre-processing system for the three-dimensional structures. The modeling method is based on the boundary representation scheme and composed of two hierarchical model structures: curve-network and surface models. The concept of modeling curve as a union of links is introduced to facilitate surface modeling via various transfinite mapping techniques or Coons Patches. Efficiency and novel aspects of the present method are discussed. Finite element mesh genceration and application procedures will be reported in a later paper.

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Phage Assembly Using APTES-Conjugation of Major Coat p8 Protein for Possible Scaffolds

  • Kim, Young Jun;Korkmaz, Nuriye;Nam, Chang Hoon
    • Interdisciplinary Bio Central
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    • v.4 no.3
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    • pp.9.1-9.7
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    • 2012
  • Filamentous phages have been in the limelight as a new type of nanomaterial. In this study, genetically and chemically modified fd phage was used to generate a biomimetic phage self-assembly product. Positively charged fd phage (p8-SSG) was engineered by conjugating 3-aminopropyltriethoxysilane (APTES) to hydroxyl groups of two serine amino acid residues introduced at the N-terminus of major coat protein, p8. In particular, formation of a phage network was controlled by changing mixed ratios between wild type fd phage and APTES conjugated fd-SSG phage. Assembled phages showed unique bundle and network like structures. The bacteriophage based self-assembly approach illustrated in this study might contribute to the design of three dimensional microporous structures. In this work, we demonstrated that the positively charged APTES conjugated fd-SSG phages can assemble into microstructures when they are exposed to negatively charged wild-type fd phages through electrostatic interaction. In summary, since we can control the phage self-assembly process in order to obtain bundle or network like structures and since they can be functionalized by means of chemical or genetic modifications, bacteriophages are good candidates for use as bio-compatible scaffolds. Such new type of phage-based artificial 3D architectures can be applied in tuning of cellular structures and functions for tissue engineering studies.