• 약학회지
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• 제38권6호
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• pp.654-663
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• 1994

Lipiodol-anticancer suspensions containing fluorouracil, tegafur, mitomycin C, methotrexate, or adriamycin were prepared by Shinohara method using aluminum monostearate as a dispersing stabilizer. Lipiodol-suspension showed thixotropic property when the concentration of aluminum monostearate was above 2%. Observed thixotropic area which reflects the extent of thixotropic breakdown indicated that the thixotropic property of Lipiodol-suspensions maintained for six weeks in a refrigerator$(4^{\circ}C)$. Lipiodol-anticancer suspensions containing 2% aluminum monostearate maintained a more stable suspension system compared with simple mixtures and Lipiodol-anticancer suspensions without aluminum monostearate. As the concentration of aluminum monostearate increased, the drug release from Lipiodol-anticancer suspensions was more retarded.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2000년도 춘계학술대회논문집
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• pp.56-62
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• 2000

Semi-solid forming process has some advantages such as successful manufacturing of high quality components with less inner defects suitable for less machining high productivity and energy-saving effect. the thixotropic behavior(solid-like in the unperturbed state and liquid-like during shearing) has been the basis for the semi-solid forming process. The main focus of this article is the investigation of the effect of T6 heat treatment and alloying elements on the mechanical properties in the semi-solid formed products using thixotropic hypoeutectic (A357 and ALTHIX 86S) and hypereutectic(A390) materials. The new methods to produce semi-solid formed components with high quality are also proposed and discussed in terms of a die design and the development of a lubricant.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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• pp.725-733
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• 2008

A thixotropic grout has been developed for the use of filling a tail void in the shield TBM and as well as various ground voids. The grout developed in this study is a mixture of inorganic substance, cement and some functional additives. Its engineering characteristics was investigated by measuring a viscosity and unconfined compressive strengths. The optimum mix proportion for an effective thixotropic grout was proposed through several repeated laboratory tests. The various physical properties such as thixotropy, unconfined compressive strengths, and durability of the thixotropic grout and the gels produced from the grout were compared with those of the well-known waterglass-type grout such as L.W.. The thixotropic grout developed in the study exhibited an excellent performance for back-filling of tail voids in the shield TBM based on experimental results compared to the existing waterglass grout.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2005년도 춘계 학술발표회 논문집
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• pp.1283-1290
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• 2005

A thixotropic grout has been newly developed for the use of back-filling a tail void in the shield tunnel and filling up ground voids. The grout developed in the study is a mixture of colloidal silica, cement and some functional additives. Its engineering characteristics was investigated by measuring a viscosity and unconfined compressive strengths. The optimum mixing proportion for an effective thixotropic grout was proposed through several repeated laboratory tests. The various physical properties such as thixotropy, unconfined compressive strengths, and durability of the thixotropic grout and the gels produced from the grout were compared with those of the well-known waterglass grout such as L.W.. The thixotropic grout developed in the study exhibited an excellent performance for back-filling of tail voids, based on experimental results compared to the existing waterglass grout.

• 한국터널지하공간학회 논문집
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• 제12권1호
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• pp.75-85
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• 2010

본 연구는 새로 개발된 쉴드 TBM 테일 보이드 동시주입용 무기계 가소성 그라우트의 현장적용 가능성을 평가하기 위하여 체적변화성 및 투수계수를 측정하였으며, 환경영향성 평가를 실시하였다. 또한, 무기계 가소성 그라우트의 현장 시험 시공에 앞서, 쉴드 TBM 모형주입장치 및 후방주입 공동충전 시험체를 이용하여 실내실험을 실시하였으며, 실제 서울 전력구 쉴드 TBM 시공현장에 시험시공을 수행하였다. 기중에서 14일 양생시킨 공시체를 이용해서 무기계 가소성 그라우트의 체적 변화성을 평가한 결과, 무기계 가소성 그라우트의 체적변화는 거의 발생하지 않았다. 그리고 투수계수를 측정하여 비교한 결과 무기계 가소성 그라우트의 우수한 차수효과를 확인 할 수 있었다. 어독성 시험과 용탈시험을 통한 환경영향성 평가를 수행한 결과, 무기계 가소성 그라우트의 경우 평균 pH가 8.0으로 측정되었으며, 96시간 경과 후 10%의 폐사율을 보였다. 용탈액에 대한 원자흡광분광 시험 결과 용탈에 의한 유해 중금속 성분은 수질관리 기준치 이하로 검출되었다. 가소성 그라우트의 현장 적용성 실험을 위하여 실내 모형실험을 수행한 결과 충전성은 확보되었으며, 실제 시공현장에 적용한 결과 우수한 주입성을 보였다.

• 대한화학회지
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• 제15권6호
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• pp.293-303
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• 1971

The theological properties of aqueous suspensions of Black Hills bentonite were measured by using a Couette-type viscometer. Three kinds of flow units in aqueous bentonite suspension were postulated. Each has a different average relaxation time, one Newtonian. One of the non-Newtonian types is thixotropic, and the other is non-thixotropic. The thixotropic non-Newtonian unit is transformed to a Newtonian unit by shear stress. If the stress is relieved, the transformed unit returns to its original state. Two flow equations were derived by introducing chemical kinetics consideration for such a transition into the generalized theory of viscous flow. One equation describes the "upcurve," a diagram of rate of sheat versus shear stress, obtained by increasing the rate of shear, and the other relates to the "downcurve" obtained by decreasing the shear rate. The equations satisfactorilly describe the experimental thixotropic hysteresis of bentonite suspensions. The equations also were successfully applied to the flow curves of the suspensions containing various amounts of monovalent electrolyte (KCI).

• 한국재료학회지
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• 제12권12호
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• pp.935-940
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• 2002

Magnesium-3, 6wt% Nickel alloys were fabricated by Rotation-Cylinder Method(RCM) in ambient atmosphere. The alloys were divided into two different heat-treating conditions, as-cast and thixotropic treated. Thixotropic heat treatment enhances the separation of primary hydride former of Mg and the catalytic phase of $Mg_2$Ni. Hydrogenation properties of the each alloy were evaluated and compared by PCI(Pressure-Composition Isotherm) measurement. The maximum hydrogen capacity and the reversible capacity of as -cast Mg-6wt% Ni alloy were 5.2wt% and 3.8wt% at 623k, respectively.

• Computers and Concrete
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• 제15권1호
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• pp.73-88
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• 2015

Following previous studies, the current paper describes the results of an experimental program concerning the repair of reinforced concrete columns by thixotropic pseudo plastic mortar, preformed to analyze and quantify the influence of initial construction damage to the behavior of the repaired element. Five columns (section scale 1:2) were designed according to the minimum requirements of reinforcement of ductility orientated codes' design with variables the percentages of initial construction damages. All were tested in axial compression with repeated cycles up to failure. For comparison reasons, another one of the same characteristics, yet healthy, was constructed and tested as a reference specimen. A numerical study (Finite Element Analysis) was conducted for further investigation of the behavior of the thixotropic mortar as repair material. The results indicate that: a) surpassing a specific amount of damage, columns even suitably repaired present lower strain capacity, b) finite element analysis present the same way of deboning of the repaired material taking into consideration the buckling of the reinforcement bars.

• 한국터널지하공간학회 논문집
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• 제11권3호
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• pp.277-286
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• 2009

본 연구는 쉴드 TBM 테일 보이드 동시주입용 가소성 그라우트의 적합성을 규명하기 위하여 강도특성, 수중 재료분리현상 및 점도특성 실험을 실시하였다. 무기계 가소성 그라우트는 쉴드 TBM 뒤채움 그라우트 주입 시 시멘트, 물, MG-A로 구성된 A액과 스칼렛, 물, MG-B로 구성된 B액을 주입하는 2액성 그라우트 주입공법이다. 적정 배합비로 제작된 무기계 가소성 그라우트의 일축압축강도는 초기강도 및 장기강도 기준을 만족하는 결과를 보였다. 지하수가 존재하는 현장에서 그라우트 주입 시 발생하는 재료분리현상을 관찰하기 위하여 기존 현장에서 적용된 규산계 그라우트와 무기계 가소성 그라우트를 비교하였으며, 그 결과 규산계 그라우트에서 발생하는 재료분리 현상이 무기계 가소성 그라우트에서는 관찰되지 않았다. 또한 무기계 가소성 그라우트의 장거리 이송에 대한 현장 적용성을 확인하기 위하여 A, B액의 점도를 측정한 결과 A, B액 모두 120분 이상 2000 cP 이하가 측정되었다. 이러한 결과는 추후 현장적용 시 A, B액의 원활한 이송이 가능한 점도를 확보하고 있음을 확인하였다.

• Computers and Concrete
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• 제15권6호
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• pp.903-919
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• 2015

The flow of freshly mixed cement-based material shows thixotropy, which implies some difficulties on robust measurement of its rheological properties: The flow curve of thixotropic materials depends on the used protocol. For examples, higher viscosity is obtained when the rate of shear strain is more quickly increased. Even though precise measurement and modelling of the concrete rheology needs to consider the thixotropic effect, engineers in the concrete field prefer considering as a non-thixotropic Herschel-Bulkley fluid, even more simply Bingham fluid. That is due to robustness of the measurement and application in casting process. In the aspect of simplification, this papers attempts to mimic the thixoropic flow by the non-thixotropic Herschel-Bulkley model. Disregarding the thixotropy of cement based materials allows us to adopt the rheological concept in the field. An optimized protocol to measure the Bingham parameters was finally found based on the accuracy and reproducibility test of cement paste samples, which minimizes the error of simulation stemming from the assumption of non-thixotropy.