• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2018년도 춘계학술대회 논문집
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• pp.124-124
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• 2018

Polydopamine은 수중 접착력, 친환경 접착제, nanoparticle absorption 등 다양한 특성으로 많이 연구되고 있는 소재이다. 본 연구에서는 dopamine을 이용하여 수중 금속을 흡착시키는 thin film을 제작하였다. 종래의 Polydopamine coating 방법으로 wet coating 이 사용되고 있다. 하지만 wet 방식의 경우 시간이 오래 걸릴 뿐만 아니라 in-line, roll to roll 방식을 적용하는 것이 어렵기 때문에 생산적이지 않다. 이에 본 연구에서는 Atmospheric Pressure Plasma(APP)를 이용 하여 Polydopamine-like film을 coating 하였다. APP의 경우 vacuum system, solution tank가 필요 없고 in-line, roll to roll 방식을 적용 할 수 있기 때문에 더 경제적이고 생산적인 공정이다. 또한 기존의 Plasma polymerization 방법은 Plasma energy가 높기 때문에 source의 분자구조가 바뀌거나 atom 단위로 분해된다. source의 분자구조가 바뀌는 "Atomic polymerization", Neiswender-Rosskamp Mechanism이 적용되면 wet 방식 coating한 film과는 다른 특성을 갖게 된다. 하지만 APP polymerization은 Plasma energy가 vacuum plasma 보다 매우 낮기 때문에 stile polymerization mechanism을 구현 하는데 적합 하다. stile polymerization mechanism은 Plasma 내부에서 polymer source를 분해 성장 시켜서 Polymer film 얻는 것이 아닌 source의 분자구조가 깨지지 않으면서 polymer growing 시키는 방법이다. dopamine source의 분자구조를 최대한 유지하려고 하는 이유는 metal absorption과 같은 특성이 dopamine chemical structure에 영향을 받기 때문이다. 많은 논문들에서 dopamine의 catechol group이 metal absorption, adhesion force에 영향을 주는 주요 인자라고 주장하고 있기 때문이다. 그래서 본 논문에서는 Dopamine source의 형태를 보존하면서 Polymerization 하는 방법으로 APP process를 사용 하여 낮은 전압에서 Polydopamine-like film을 제작 하였다. APP system 의 Plasma 방전부 에 Dopamine source를 유입하기 위하여 본 논문에서는 Piezo Spray 방식을 사용 하였다. Dopamine을 evaporator 하는 것이 어렵고 chemical composition이 유사한 monomer를 사용해서 Plasma Polymerization으로 Dopamine 분자 구조를 재현하는 것도 어렵다. 그래서 본 연구에서는 Dopamine을 water에 immerse 하고 Dopamine solution을 mist 상태로 만들어서 Plasma discharge area에 유입하였다. 이러한 방법으로 만들어진 film은 Polydopamine film은 아니지만 Polydopamine film과 유사한 Chemical composition, chemical structure, metal absorption을 갖는 것을 FT-IR, SEM, XPS을 이용 하여 확인 하였다. Dopamine source의 보존에 대하여 명확하게 확인하기 위하여 FT-IR을 측정 하였다. 전압에 따른 Benzene ring, hydroxyl group의 비율을 확인 하였다. 낮은 전압으로 coating 된 Polydopamine-like film 일수록 hydroxyl group peak($3400{\sim}3000cm^{-1}$)과 비교하여 Benzene ring peak($1600{\sim}1580cm^{-1}$ and $1510{\sim}500cm^{-1}$)이 흡수를 더 많이 하는 것을 확인 할 수 있다. 이것은 Benzene ring이 파괴되지 않고 보존되는 것을 보여준다. Dopamine에서 Benzene ring은 absorption main factor인 catechol에 있는 chemical structure이다. 즉 Benzene ring peak이 높을수록 Catechol이 잘 보존 되었다는 의미 이다. Catechol의 보존은 absorption main factor가 보존 된다는 의미 이다. 이러한 Polydopamine-like film으로 As, Cr, Mg, Cu 200ppm solution에 대한 filtration 능력을 확인 하였다. As, Cr, Cu, Mg 의 제거율이 각각 약25%, 35%, 45%, 65%인 것을 확인 하였다. 이 수치는 시중에 판매되는 제품들과 비교했을 때 300%~500% 향상된 수치 이다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.159-165
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• 2003

Self-excited noise generation from laminar flames in thin annular jets of methane/air premixture has been investigated experimentally. Various flames were observed in this flow configuration, including conical shape flames, ring shape flames, steady crown shape flames, and oscillating crown shape flames. Self-excited noise with the total sound pressure level of about 70dB was generated from the oscillating crown shape flames for the equivalence ratio larger than 0.95. Sound pressure and $CH^{\ast}$ chemiluminescence were measured by using a microphone and a photomultiplier tube. The frequency of generated noise was measured as functions of equivalence ratio and premixture velocity. A frequency doubling phenomena have also been observed. The measured $CH^{\ast}$ chemiluminescence data were analyzed from which the corresponding sound pressure has been calculated. By comparing the data with those of measured ones, the noise source can be attributed to the flame front fluctuation near the edge of the oscillating crown-shape flames. The flame stability regime was influenced sensitively to the supplying air through the inner tube.

• Progress in Superconductivity
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• 제11권1호
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• pp.36-41
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• 2009

Superconducting quantum phenomena are getting attention from the field of metrology area. Following its first successful application of Josephson effect to voltage standard, piconewton force standard was suggested as a candidate for the next application of superconducting quantum effects in metrology. It is predicted that a micron-sized superconducting Nb ring in a strong magnetic field gradient generates a quantized force of the order of sub-piconewtons. In this work, we studied the design and fabrication of Nb superconducting quantum interference device (SQUID) on an ultra-thin silicon cantilever. The Nb SQUID and electrodes were structured on a silicon-on-insulator (SOI) wafer by dc magnetron sputtering and lift-off lithography. Using the resulting SOI wafer, we fabricated V-shaped and parallel-beam cantilevers, each with a $30-{\mu}m$-wide paddle; the length, width, and thickness of each cantilever arm were typically $440{\mu}m,\;4.5{\mu}m$, and $0.34{\mu}m$, respectively. However, the cantilevers underwent bending, a technical difficulty commonly encountered during the fabrication of electrical circuits on ultra-soft mechanical substrates. In order to circumvent this difficulty, we controlled the Ar pressure during Nb sputtering to minimize the intrinsic stress in the Nb film and studied the effect of residual stress on the resultant device.

• Bulletin of the Korean Chemical Society
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• 제31권8호
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• pp.2247-2254
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• 2010

The surface structures of copper phthalocyanine (CuPc) thin films deposited on sulphur-passivated and plane perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA)-covered InAs(100) surfaces have been studied by low energy electron diffraction (LEED) and van der Waals (vdW) intermolecular interaction energy calculations. The annealing to $300^{\circ}C$ and $450^{\circ}C$ of $(NH_4)_2S_x$-treated InAs(100) substrates produces a ($1{\times}1$) and ($2{\times}1$) S-passivated surface respectively. The CuPc deposition onto the PTCDA-covered InAs(100) surface leads to a ring-like diffraction pattern, indicating that the 2D ordered overlayer exists and the structure is dominantly determined by the intermolecular interactions rather than substrate-molecule interactions. However, no ordered LEED patterns were observed for the CuPc on S-passivated InAs(100) surface. The intermolecular interaction energy calculations have been carried out to rationalise this structural difference. In the case of CuPc unit cells on PTCDA layer, the planar layered CuPc structure is more stable than the $\alpha$-herringbone structure, consistent with the experimental LEED results. For CuPc unit cells on a S-($1{\times}1$) layer, however, the $\alpha$-herringbone structure is more stable than the planar layered structure, consistent with the absence of diffraction pattern. The results show that the lattice structure during the initial stages of thin film growth is influenced strongly by the intermolecular interactions at the interface.

• 한국분무공학회지
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• 제11권3호
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• pp.176-189
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• 2006

In the present study, capability of improving the liquid atomization of a high-speed liquid jet by using wall impingement is explored, and its application to a jet engine atomize. is demonstrated. Water is injected from a thin nozzle. The liquid jet impinges on a wall positioned close to the nozzle exit, forming a liquid film. The liquid film velocity and the SMD were measured with PDA and LDSA, respectively. It was shown that the SMD of the droplets was determined by the liquid film velocity and impingement angle, regardless of the injection pressure or impingement wall diameter. When the liquid film velocity was smaller than 300m/s, a smaller SMD was obtained, compared with a simple free jet. This wall impingement technique was applied to a conventional air-blasting nozzle for jet engines. A real-size air-blasting burner was installed in a test rig in which three thin holes were made to accommodate liquid injection toward the intermediate ring, as an impingement wall. The air velocity was varied from 41 to 92m/s, and the liquid injection pressure was varied from 0.5 to 7.5 MPa. Combining wall impinging pressure atomization with gas-blasting produces remarkable improvement in atomization, which is contributed by the droplets produced in the pressure atomization mode. Comparison with the previous formulation for conventional gas-blasting atomization is also made, and the effectiveness of utilizing pressure atomization with wall impingement is shown.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2004년도 Proceedings of 2004 Korea-Japan Joint Seminar on Particle Image Velocimetry
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• pp.147-155
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• 2004

Self-excited noise generation from laminar flames in thin annular jets of methane/air premixture has been investigated experimentally. Various flames were observed in this flow configuration, including conical shape flames, ring shape flames, steady crown shape flames, and oscillating crown shape flames. Self-excited noise with the total sound pressure level of about 70dB was generated from the oscillating crown shape flames for the equivalence ratio larger than 0.95. Sound pressure and $CH^*$ chemiluminescence were measured by using a microphone and a photomultiplier tube. The frequency of generated noise was measured as functions of equivalence ratio and premixture velocity. A frequency doubling phenomena have also been observed. The flame shape during flame oscillation was reconfirmed by a synchronized PIV experiment. The velocity and pressure field were obtained from PIV. The minimum pressure was formed near the edge of flame representing circulation. By comparing the results of sound pressure, flame luminosity and PIV, the noise source can be attributed to the flame front fluctuation near the edge of the oscillating crown-shape flames.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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• pp.446-448
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• 2000

Organic semiconductors based on vacuum-deposited films of fused-ring polycyclic aromatic hydrocarbon have great potential to be utilized as an active layer for electronic and optoelectronic devices. In this study, pentacene thin films and electrode materials were deposited by Organic Molecular Beam Deposition (OMBD) and vacuum evaporation respectively. For the gate dielectric layer, OPTMER PC403 photo acryl (JSR Coporation.) was spin-coated and cured at $220^{\circ}C$. Electrical characteristics of the devices were investigated, where the channel length and width was $50{\mu}m$ and 5 mm. It was found that field effect mobility was $0.039\;cm^2V^{-1}s^{-1}$, threshold voltage was -7 V, and on/off current ratio was $10^6$.

• 한국응용과학기술학회지
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• 제18권3호
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• pp.191-196
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• 2001

Organic semiconductors based on vacuum-deposited films of fused-ring polycyclic aromatic hydrocarbon have great potential to be utilized as an active layer for electronic and optoelectronic devices. In this study, pentacene thin films and electrode materials were deposited by Organic Molecular Beam Deposition (OMBD) and vacuum evaporation respectively. For the gate dielectric layer, photoacryl (OPTMER PC403 from JSR Co.) was spin-coated and cured at $220^{\circ}C$. Electrical characteristics of the device were investigated, where the channel length and width was 50 ${\mu}m$ and 5 mm. It was found that field effect mobility was 0.039 $cm^{2}V^{-1}s^{-1}$, threshold voltage was -8 V, and on/off current ratio was $10^{6}$. Further details will be discussed.

• 한국진공학회지
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• 제5권2호
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• pp.139-146
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• 1996

rf 마그네트론 스파터링법을 이용하여 투명 전도성 Sb-doped $SnO_2$ 박막을 증착하였으나 박막표면에서 막손상현상이 발생하였다. 특히 기판 중심부 및 타게트 부식부위에 대응하는 부분에서 발생된 막손상을 방지하고자 , 환원형의 마스크 유리가 타게트표면에서 1.5cm지점에 설치되었다. 또한 마그네트론 스파터링의 작동조건인 rf전력, 스파터링 가스압력 및 기판온도를 최적으로 조절하면서 박막의 균일성과 전기적 특성을 평가하였다. 작동조건을 이용한 실험결과에서 균일하고 막손상이 없는 박막을 증착하는 최적온도는 압력 변화에 따라 변하며, 비율은 50w의 rf전력에서 5mTorr당 약 $100^{\circ}C$정도였다. 유사하게 rf 전력？ md가에 대한 보상에서 최적온도는 적절한 비율로 내려간다.

• 한국광학회지
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• 제16권4호
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• pp.384-391
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• 2005

본 논문에서는 나노 임프린트 기술을 이용한 폴리머 링 광공진기를 제안하고 구현하였다. 공진기 역할을 하는 링 도파로에서의 전파손실과 링 및 버스 도파로 간의 광파워 결합계수를 빔전파방법을 도입하여 계산하였으며, 또한 전달 매트릭스 방법을 도입하여 이들이 소자에 미치는 영향을 분석하고 소자를 설계하였다. 특히, smoothing buffor layer를 갖는 임프린트용 스탬프를 도입하여 다음과 같은 성과를 얻을 수 있었다. 먼저 식각공정으로 얻어진 스탬프 상의 도파로 패턴의 측면 거칠기를 링 도파로의 산란손실을 개선함으로써 Q값을 획기적으로 향상시켰다. 또한, 결합영역에서 버스와 링 도파로 간의 간격을 기존 lithography 공정에서는 불가능하였던 $0.2{\mu}m$정도까지 효과적으로 줄이고 제어함으로써 링과 도파로 간의 광파워 결합을 정밀하게 조절할 수 있게 되었다. 제작된 소자의 성능을 살펴보면, 링 반경이 $200{\mu}m$인 경우에 대해 1550 nm 파장 대역에서 Q값은 ~103800이고, 소멸비는 ~11 dB, free spectral range는 1.16 nm였다.