• Journal of the Korean Electrochemical Society
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• v.10 no.3
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• pp.219-228
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• 2007

The phase-shift method and correlation constants, i.e., the electrochemical impedance spectroscopy (EIS) techniques for studying linear relationships between the behaviors (${\varphi}\;vs.\;E$) of the phase shift ($0^{\circ}{\leq}-{\varphi}{\leq}90^{\circ}$) for the optimum intermediate frequency and those (${\theta}\;vs.\;E$) of the fractional surface coverage ($1{\geq}{\theta}{\geq}0$), have been proposed and verified to determine the Langmuir, Frumkin, and Temkin adsorption isotherms (${\theta}\;vs.\;E$) of H for the cathodic $H_2$ evolution reaction (HER) at noble and transition-metal/aqueous solution interfaces. At the Pt/0.1 MKOH aqueous solution interface, the Langmuir, Frumkin, and Temkin adsorption isotherms (${\theta}\;vs.\;E$), equilibrium constants ($K=5.6{\times}10^{-10}\;mol^{-1}\;at\;0{\leq}{\theta}<0.81$, $K=5.6{\times}10^{-9}{\exp}(-4.6{\theta})\;mol^{-1}\;at\;0.2<{\theta}<0.8$, and $K=5.6{\times}10^{-10}{\exp}(-12{\theta})\;mol^{-1}\;at\;0.919<{\theta}{\leq}1$, interaction parameters (g = 4.6 for the Temkin and g = 12 for the Frumkin adsorption isotherm), rates of change of the standard free energy ($r=11.4\;kJ\;mol^{-1}$ for g=4.6 and $r=29.8\;kJ\;mol^{-1}$ for g=12), and standard free energies (${\Delta}G_{ads}^0=52.8\;kJ\;mol^{-1}\;at\;0{\leq}{\theta}<0.81,\;49.4<{\Delta}G_{\theta}^0<56.2\;kJ\;mol^{-1}\;at\;0.2<{\theta}<0.8$ and $80.1<{\Delta}_{\theta}^0{\leq}82.5\;kJ\;mol^{-1}\;at\;0.919<{\theta}{\leq}1$) of OH for the anodic $O_2$ evolution reaction (OER) are also determined using the phase-shift method and correlation constants. The adsorption of OH transits from the Langmuir to the Frumkin adsorption isotherm (${\theta}\;vs.E$), and vice versa, depending on the electrode potential (E) or the fractional surface coverage (${\theta}$). At the intermediate values of ${\theta}$, i.e., $0.2<{\theta}<0.8$, the Temkin adsorption isotherm (${\theta}\;vs.\;E$) correlating with the Langmuir or the Frumkin adsorption isotherm (${\theta}\;vs.\;E$), and vice versa, is readily determined using the correlation constants. The phase-shift method and correlation constants are accurate and reliable techniques to determine the adsorption isotherms and related electrode kinetic and thermodynamic parameters. They are useful and effective ways to study the adsorptions of intermediates (H, OH) for the sequential reactions (HER, OER) at the interfaces.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.16 no.3 s.94
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• pp.260-269
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• 2005

In this paper, we propose a microstrip line fed printed monopole antenna which has an ultra-wideband characteristic. Proposed antenna can improve the bandwidth characteristic with the taper structure formed by modified ground plane and radiating element. Measured impedance bandwidth ratio of the antenna is more than 30:1; from the lower frequency of 0.89 GHz to the upper frequency of more than 30 GHz for VSRW$\leq$2. The antenna has conical radiation pattern that has low radiation gain to $\theta$=0$^{\circ}$ direction and higher radiation gains as $\theta$ increases.

• Journal of Korean Society for Atmospheric Environment
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• v.8 no.2
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• pp.138-145
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• 1992

Dependence of the standard deviation of wind direction fluctuations, ${\sigma}_{\theta}$, on atmospheric stability, averaging time and topography were analysed with the data measured at three sites, Youngjongdo beach of the Yellow Sea, Chuncheon basin and Doam-Dam valley. The results show that the mean value of ${\sigma}_{\theta}$ is large in complex terrain, the Doam-Dam site. It is notable that the large value of ${\sigma}_{\theta}$ at night is associated with the low wind speed and the strong stable condition. In order to study the long-period fluctuations of the wind direction, ${\sigma}_{\theta}$ for longer than 10 minutes averaging time was further analysed using the data obtained at the Chuncheon basin. At the averaging time shorter than 60 minutes, larger ${\sigma}_{\theta}$ is associated with longer averaging time in the strong stable condition. However, ${\sigma}_{\theta}$ was not affected significantly by wind speed and averaging time in neutral conditions. The results of the spectrum analysis for the time series data of wind direction showed that low-frequency fluctuations ranging from 10 to 60 minutes were dominated at the Chuncheon basin in strong stable condition.

• Transactions of the Korean Society of Mechanical Engineers
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• v.9 no.5
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• pp.548-554
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• 1985

This research is to find a means of reducing diesel engine combustion noise with none or minimum sacrifice of engine performance by investigating the influence of Cylinder Pressure Level(CPL). For this purpose, modified Wiebe's combustion function, considering the heat release curve as a combustion of both premixed and diffusive combustion portion, was exclusively used to obtain the indicator diagram and computer coeds were developed for the numerical analysis. Following are the results of this research. (1) CPL increases almostly with lag of ignition timing increasing .alpha. and decreasing. theta.$_{d}$, but at the crank angle with the maximal efficiency, CPL is independent of .alpha. and .theta.$_{d}$ with constant value of 200 dB especially at the low frequency. (2) For the constant ignition timing, the effects of .alpha. and .theta.$_{d}$ on CPL were the most significant at the frequency of about 1KHz and 300Hz respectively. (3) For the constant value of .alpha. and .theta.$_{d}$, CPL increases linearly with load but thermal efficiency increase very rapidly with maximum value of load Q$_{T}$=30-40 MJ/Kmol, then starts to decrease slowly. (4) The most effective way of reducing combustion noise without sacrificing thermal efficiency, is to decrease .alpha.. In the case of constant .alpha., there always exists a optimum value of .theta.$_{d}$ with respect to the various compression ratio.o..atio.o..

• Journal of the Korean Electrochemical Society
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• v.2 no.1
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• pp.23-26
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• 1999

The Langmuir adsorption isotherm at the $(Pt)/0.1M\;H_2SO_4$ electrolyte interface has been qualitatively analyzed using the ac impedance measurement and phase-shift method. The phase shift $(\phi)$ depends on both the cathode potential (E<0) and frequency (f) and is inversely proportional to the factional surface coverage $(\theta)$. At an intermediate frequency band (ca. $1\~100$ Hz), the phase-shift profile $(\phi\;vs.\;E)$ can be related to the fractional surface coverage $(\theta\;vs.\;E)$. The phase-shift profile $(\phi\;vs.\;E)$ can be used as an experimental method to estimate and analyze the Langmuir adsorption isotherm $(\theta\;vs.\;E)$. The equilibrium constant (K) and the standard free energy $({\Delta}G_{ads})$ of the adsorbed hydrogen atom $(H_{ads})\;and\;3\times10^{-4}$ and 20.1 kJ/mol, respectively.

• 한국가시화정보학회:학술대회논문집
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• 2004.11a
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• pp.18-21
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• 2004

Lock-on characteristics of the flow around a circular cylinder performing a rotationally oscillation with a relatively high forcing frequency have been investigated experimentally using flow visualization and hot-wire measurements. Dominant parameters are Reynolds number (Re), amplitude of oscillation $(\theta_A)$, and frequency ratio $F_R=f_f\;/\;f_n$, where $f_f$ is the forcing frequency and if is the natural frequency of vortex shedding. Experiments were carried out under the conditions of $Re=4.14\times10^3,\;\pi/15\leq\theta_A\leq\pi/3$, and $F_R=1.0$. The effects of this active control technique on the lock-on flow regime of the cylinder wake were evaluated through wake velocity measurements and spectral analysis of hot-wire signals. The rotary oscillation modified the flow structure of near wake significantly. The lock-on phenomenon was found to occur in the range of frequency encompassing the natural vortex shedding frequency. In addition, when the amplitude of oscillation is less than a certain value, the lock-on phenomenon was occurred only at $F_R=1.0$. The lock-on range expanded and vortex formation length decreased as the amplitude of oscillation increases. The rotary oscillation generated small-scale vortex structure just near the cylinder surface.

• Korean Journal of Applied Biomechanics
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• v.25 no.3
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• pp.241-248
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• 2015

Objective : The purpose of this study was to investigate the theta on the components of ground reaction force according to the ground conditions during gait. Method : Six healthy women(mean age: 22 yrs, mean height: $166.14{\pm}2.51cm$, mean body weights: $56.61{\pm}4.58kg$) participated in this study. The medial-lateral GRF(Fx 1), anterior-posterior GRF(Fy 1, Fy 2), vertical GRF(Fz 1, Fz 2, Fz 3), and impact loading rate were determined from time function and frequency domain. Also, GRF theta were time function and forces. Results : Fx 1, Fy 1 and Fy 2 of stair descending showed significant statistically higher forces than that of level walking, and ascending. Fz 1 of stairs descending showed significant statistically higher forces than that of level walking and stairs ascending(theta $88.62^{\circ}$). Also, Fz 2 of level walking showed significant statistically higher forces than that of stairs ascending and descending(theta $65.78^{\circ}$). Fz 3 of stairs ascending showed significant statistically higher forces than that of level walking and stairs descending($65.26^{\circ}$). Impact loading rate of stairs descending showed significant statistically higher forces than that of level and ascending walking. The GRF showed similar correlation with GRF theta(r=.603) according to the ground conditions during gait. Conclusion : These results suggest that the GRF theta can be used in conjunction with a gait characteristics, prediction of loading rate and dynamic stability.

• Journal of the Korean Electrochemical Society
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• v.15 no.1
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• pp.54-66
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• 2012

The phase-shift method and correlation constants, which are unique electrochemical impedance spectroscopy techniques for studying the linear relationship between the phase shift ($90^{\circ}{\geq}-{\varphi}{\geq}0^{\circ}$) vs. potential (E) behavior for the optimum intermediate frequency ($f_o$) and the fractional surface coverage ($0{\leq}{\theta}{\leq}1$) vs. E behavior, are proposed and verified to determine the Frumkin, Langmuir, and Temkin adsorption isotherms and the related electrode kinetic and thermodynamic parameters. At Ni/0.5 M $H_2SO_4$ and 0.1M LiOH aqueous solution interfaces, the Frumkin and Temkin adsorption isotherms (${\theta}$ vs. E) of H for the cathodic hydrogen ($H_2$) evolution, interaction parameters (g), equilibrium constants (K), standard Gibbs energies (${\Delta}G^0_{\theta}$) of H adsorption, and rates of change (r) of ${\Delta}G^0_{\theta}$ with ${\theta}$ have been determined using the phase-shift method and correlation constants. A lateral repulsive interaction (g>0) between the adsorbed H species appears. The value of K in the alkaline aqueous solution is much greater than that in the acidic aqueous solution.

• Journal of Magnetics
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• v.5 no.3
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• pp.85-89
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• 2000

The hysteretic characteristics of giant magnetoimpedance (GMI) profiles have been measured in Co-based amorphous ribbon with various anisotropy angles $\theta_k$, and they have been analyzed by using the Stoner-Wohl-farth model. Two-peaks behavior with a dip near zero field is revealed in the measured GMI profile at 10 MHz irrespective of $\theta_k$. The negligible hysteresis of the field fur the dip is close to the calculation assuming the magnetization jump from a metastable to stable state. However, the hysteretic asymmetry far the angle range of $20^\circ\leq\theta_k < 60^\circ$ is well described by the divergence in the calculation without the magnetization jump. The asymmetry for $\theta_k\geq60^\circ$ may be due to the divergence, but the shapes of measured profiles are quite different from the calculations with single peak near zero field, indicating that Stoner-Wohlfarth model can be well used to describe GMI characteristics for the anisotropy angle range of $20^\circ\leq\theta_k < 60^\circ$at the frequency of 10 MHz in Co-based amorphous ribbons.

• Journal of Advanced Navigation Technology
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• v.9 no.2
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• pp.140-146
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• 2005

In this paper, we proposed the frequency offset compensation algorithm and tracking algorithm which could improve the accumulated phase error for HDR-WPAN system. The proposed frequency offset compensation technique estimated each sample phase error by autocorrelation characteristics of CAZAC sequence, estimated phase error multiple each sample in a symbol, and finally compensated for the frequency offset. After frequency offset compensation using two steps, coarse and fine frequency offset, tracking algorithm have to use to compensate for the accumulated phase error. Because there is no pilot symbol in payload, more phase rotation occurred in received signal constellations due to the accumulated phase error as the payload length increase. Tracking algorithm compensates for a cumulative phase error ${\theta}$ between payload data.