• Title/Summary/Keyword: Thermosetting

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Development of Vitrified Diamond Wheel for Grinding Tungsten Carbide (초경합금 연삭용 비트리파이드 다이아몬드숫돌의 개발)

  • 이재우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.185-188
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    • 2002
  • An abrasive vitreous bonded solid mass having a vitrified abrasive structure comprising diamond grains which are held by an in inorganic bonding agent, the vitrified diamond wheel is impregnated with a composition which comprises a thermosetting synthetic resin and a surfactant. The vitrified diamond wheel is manufactured by preparing the composition including the resin and the surfactant, impregnating the abrasive structure with the composition, and curing the composition. The diamond wheel newly developed showed excellent performance in grinding carbide.

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Functionally Graded Polymer Composites : Simulation of Fiber Distribution

  • Choe, Chul-Rim;C. Klingshirn;K. Friedrich
    • Macromolecular Research
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    • v.10 no.4
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    • pp.236-239
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    • 2002
  • Centrifugation is a method to create functionally graded materials (FGM) with a thermosetting matrix. In this study the movement of short carbon fibers in an epoxy resin during the centrifugation process was modeled to determine the fiber distribution in the final product. For this purpose a form factor K was introduced to modify a set of equations that was previously shown to be valid for the motion of spheres. It was shown that the results of the simulation were in good agreement with the experimental data, when an empirical K factor of four was chosen.

A Study on the Behavior of Buried Flexible Pipes with Soil Condition (지반조건에 따른 지중매설 연성관의 거동에 관한 연구)

  • Lee, Hyoung-Kyu;Park, Joon-Seok
    • Journal of the Korean Geosynthetics Society
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    • v.13 no.1
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    • pp.33-40
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    • 2014
  • In general, pipes buried underground can be classified into either rigid or flexible pipe. Glass fiber reinforced thermosetting polymer plastic (GFRP) pipe can be considered as one of typical flexible pipes for which the soil-pipe structure interaction must be taked into account in the design. In this paper, we present the result of an investigation pertaining to the short-term and long-term behavior of buried GFRP pipe. The mechanical properties of the GFRP pipe produced in the domestic manufacturer are determined and the results are reported in this paper. In addition, Ring deflection is measured by the field tests and the finite element analysis. Also, the extrapolation using these techniques typically extends the trend from data gathered over a period of approximately 5,232 hours, to a prediction of the property at 50 years, which is the typical maximum extrapolation time. Therefore, it was investigated that the long-term ring deflection of GFRP pipe estimated by methods for Monod-type.

A Preliminary Study on Fatigue Strength of High Toughness Thermoplastic Composite Material AS4/PEEK (고인성 열가소성 복합재료 AS4/PEEK의 피로강도에 관한 기초적 검토)

  • Song, Ji-Ho;Gang, Jae-Yun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.4 s.175
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    • pp.1055-1064
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    • 2000
  • First, various specimen geometries, namely, coupon type, waisted type and dog-bone type, were examined to determine appropriate fatigue specimen of thermoplastic composite material AS4/PEEK and the n, fatigue strength of smooth and notched specimens of AS4/PEEK [-45/0/+45/90]2s was investigated. Fatigue tests were performed under load controlled condition at a stress ratio of 0. 1 at a frequency of 5Hz. Stiffness degradation of specimens with fatigue cycling was monitored using an automated unloading compliance technique. The waisted type specimen is found appropriate for smooth fatigue specimen geometry of AS4/PEEK. As for the effect of stress concentration, it is found that fatigue strength is higher for a 2mm-diameter hole notched specimen than a 5mm-diameter one. Fatigue notch factor decreases with the increase of fatigue life. These results are far different from the trend of fatigue strength of metallic materials. The stiffness variation of smooth specimen was only 4% at maximum until final fracture. On the other hand, the stiffness of hole notched specimen was reduced by 45% at maximum. Notched fatigue strength was compared between thermoplastic composite AS4/PEEK and thermosetting composite Graphite/Epoxy. In long-life fatigue (>104), the AS4/PEEK composite shows superior fatigue strength, but in short-life fatigue, the fatigue strength of the Graphite/Epoxy composite is nearly equal or somewhat higher than that of the AS4/PEEK composite.

The Recovery of Carbon Fiber from Carbon Fiber Reinforced Epoxy Composites Applied to Railway Vehicles (철도차량용 폐 복합소재로부터 탄소섬유 회수)

  • Lee, Suk-Ho;Kim, Jung-Seok;Lee, Cheul-Kyu;Kim, Yong-Ki;Ju, Chang-Sik
    • Journal of the Korean Society for Railway
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    • v.12 no.6
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    • pp.1059-1066
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    • 2009
  • Recently, the amount of thermosetting plastic wastes has increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy resins, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that decompose epoxy resin and recover carbon fibers from carbon fiber reinforced epoxy composites applied to railway vehicles was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

Characteristics of Thermoplastic Vulcanizate Weatherstrip Prepared by Water-Foaming Technique (수발포 기술을 적용한 열가소성 고무 Weatherstrip 특성)

  • 이성훈;김진국
    • Polymer(Korea)
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    • v.27 no.5
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    • pp.436-442
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    • 2003
  • Thermosetting elastomer such as EPDM (Ethylene Propylene Dien Rubber) has been applied to the sponge weatherstrip of a vehicle as a main material. However, the thermosetting elastomers have limited recycling and have brought about the environmental problems. Furthermore, many steps of the manufacturing process such as formulation, mastication and vulcanization make difficult to control uniformity of the endproducts. These problems of current EPDM weatherstrip necessitated development of a new recyclable material, Thermoplastic Vulcanizates (TPV). In this study the influence of the water contents, and the processing conditions. On the foam density and structure in water blowing process was carried out. We found that TPV also can be foamed with water, maintaining the uniformity form this study. Therefore, many inevitable problems of EPDM weatherstrip can be solved, and this new technique is expected to take a roll of making a breakthrough in the rubber industry.

A Molecular Dynamics Simulation Study on Hygroelastic behavior of Thermosetting Epoxy (열경화성 에폭시 기지의 흡습탄성 거동에 관한 분자동역학 전산모사)

  • Kwon, Sunyong;Lee, Man Young;Yang, Seunghwa
    • Composites Research
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    • v.30 no.6
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    • pp.371-378
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    • 2017
  • In this study, hygroelastic behavior of thermosetting epoxy is predicted by molecular dynamics simulations. Since consistent exposures to humid environments lead to macroscopic degradation of polymer composite, computational simulation study of the hygroscopically aged epoxy cell is essential for long-time durability. Therefore, we modeled amorphous epoxy molecular unit cell structures at a crosslinking ratio of 30, 90% and with the moisture weight fraction of 0, 4 wt% respectively. Diglycidyl ether of bisphenol F (EPON862) and triethylenetetramine (TETA) are chosen as resin and curing agent respectively. Incorporating equilibrium and non-equilibrium ensemble simulation with a classical interatomic potential, various hygroelastic properties including diffusion coefficient of water, coefficient of moisture expansion (CME), stress-strain curve and elastic modulus are predicted. To establish the structural property relationship of pure epoxy, free volume and internal non-bond potential energy of epoxy are examined.

The Measurement of Minimum Ignition Energy and Explosion Limit for Pine Tree Dust (소나무 분진의 최소착화에너지와 폭발한계 측정에 관한 연구)

  • Choi Il-Gon;Cho Il-Keon;Mok Yun-Soo;Lee Dong-Hoon;Choi Jae-Wook;Ha Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.2 no.2
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    • pp.55-60
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    • 1998
  • In this study, we investigated the dust explosion characteristics by determining minimum ignition energy and explosion limit for this experiment, we used pine-tree dust which was used widely for the filler of thermosetting resin. The experiment was accomplished according to the variation of discharge gap, dust concentration, particle size and humidity. The result of this experiment are as follows; (1) The relation between the discharge gap and ignition energy was that ignition energy decreased according as the discharge gap became small, but increased when the discharge gap was below 4mm and suddenly became infinite when the discharge gap was below. So, we knew that this infinite value was limit discharge gap. (2) When the dust concentration increase and the particle size became microscopic it was easy to explore and in the same particle size, if the humidity increase the minimum ingnition energy decreased.

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Development of Solid Lubricants for Oil-less Bush (오일리스 부시용 고체윤활제 개발)

  • Kong, Hosung;Han, Hung-Gu;Kim, Jin Uk;Kim, Kyoung Seok;Park, Jong Sik
    • Tribology and Lubricants
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    • v.35 no.2
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    • pp.87-93
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    • 2019
  • This work aims to develop a dry lubricant for oilless bush, especially a solid lubricant, thereby creating a coating method with improved properties of anti-friction and load-carrying capacity without oil lubrication. In this work, spherical-shaped powders of thermosetting resin such as polyimide (PI) are mixed with a binder matrix obtained by mixing a fluorocarbon compound resin such as Polytetrafluoroethylene (PTFE) or Ethylene tetra fluoro ethylene (ETFE) with itself or with a non-fluorocarbon thermoplastic resin such as Polyether ether ketone (PEEK). And these dry lubricant mixtures are thickly coated (200-300 mm in the thickness) on the inner surface of the bush by using a wet-typed air-spray deposition method. It was found that the load-carrying capacity of the solid lubricant for excavator bush (60 mm in diameter) that operates under a high load condition (at 40 MPa) is greatly improved owing to the spherical-shaped powders of thermosetting resin. In addition, the coefficient of friction at the sliding surface is also reduced less than 0.1. Thick coating also lowers the contact stress at the edge of a bush that results in better tribological performances. The result suggests that the lubrication performance and durability life of the bush can be remarkably improved even without lubrication (oil or grease).

A Study on the Improvement of Bending Characteristics of 3D Printed Thermoplastic Structures Reinforced at the Lateral Surface using Continuous Fiber Reinforced Thermosetting Composites (열경화성 연속섬유 복합재를 이용해 외측 보강된 3D 프린팅 열가소성 복합재 구조물의 굽힘 특성 향상에 대한 연구)

  • Baek, Un-Gyeong;Nam, Gibeop;Roh, Jae-Seung;Park, Sung-Eun;Roh, Jeong-U
    • Composites Research
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    • v.34 no.2
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    • pp.136-142
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    • 2021
  • 3D printing technology has the advantage of easy to make various shapes of products without a mold. However, it has a problem such as mechanical properties vary greatly depending on materials and manufacturing conditions. Thus, the need for research of 3D printing technology on ways to reduce manufacturing cost compared to physical properties is increasing. In this study, a 3D printing thermoplastic structure was fabricated using short fiber carbon fiber reinforced nylon filaments. And a method of improving mechanical properties was proposed by reinforcing the outer surface using pultruded continuous fiber-type carbon fiber or glass fiber-reinforced thermosetting composite material. It was confirmed that the bending properties were improved according to the reinforcing position of the stiffener and the type of fiber in the stiffener.