• The Journal of Advanced Prosthodontics
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• v.7 no.4
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• pp.278-287
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• 2015

PURPOSE. The aim of this study was to compare the color stability, water sorption and cytotoxicity of thermoplastic acrylic resin for the non-metal clasp dentures to those of thermoplastic polyamide and conventional heat-polymerized denture base resins. MATERIALS AND METHODS. Three types of denture base resin, which are conventional heat-polymerized acrylic resin (Paladent 20), thermoplastic polyamide resin (Bio Tone), thermoplastic acrylic resin (Acrytone) were used as materials for this study. One hundred five specimens were fabricated. For the color stability test, specimens were immersed in the coffee and green tee for 1 and 8 weeks. Color change was measured by spectrometer. Water sorption was tested after 1 and 8 weeks immersion in the water. For the test of cytotoxicity, cell viability assay was measured and cell attachment was analyzed by FE-SEM. RESULTS. All types of denture base resin showed color changes after 1 and 8 weeks immersion. However, there was no significant difference between denture base resins. All specimens showed significant color changes in the coffee than green tee. In water sorption test, thermoplastic acrylic resin showed lower values than conventional heat-polymerized acrylic resin and thermoplastic polyamide resin. Three types of denture base showed low cytotoxicity in cell viability assay. Thermoplastic acrylic resin showed the similar cell attachment but more stable attachment than conventional heat-polymerized acrylic resin. CONCLUSION. Thermoplastic acrylic resin for the non-metal clasp denture showed acceptable color stability, water sorption and cytotoxicity. To verify the long stability in the mouth, additional in vitro studies are needed.

• Journal of Adhesion and Interface
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• v.12 no.1
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• pp.11-15
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• 2011

In this study we synthesized low VOC-solvent soluble thermo plastic polyurethane, The effect of chain extender and NCO/OH ratio for properties of thermoplastic polyurethane was investigated. Also, we prepared low VOC-type primer by TPU and acrylic modified tackifier resin. When NCO/OH ratio was 2 or more, TPU was insoluble in low VOC solvent. And peel strength was higher value using polar type tackifier than non-ploar type tackifier.

• The Journal of Advanced Prosthodontics
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• v.11 no.1
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• pp.32-40
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• 2019

PURPOSE. The purpose of this study was to compare mechanical and physical properties of injection-molded thermoplastic denture base resins. MATERIALS AND METHODS. In this study, six commercially available products (VA; Valplast, LC; Lucitone, ST; Smiltone, ES; Estheshot-Bright, AC; Acrytone, WE; Weldenz) were selected from four types of thermoplastic denture base materials (Polyamide, Polyester, Acrylic resin and Polypropylene). The flexural properties and shore D hardness have been investigated and water sorption and solubility, and color stability have evaluated. RESULTS. For the flexural modulus value, ES showed the highest value and WE showed significantly lower value than all other groups (P<.05). Most of experimental groups showed weak color stability beyond the clinically acceptable range. CONCLUSION. Within the limits of this study, thermoplastic denture base resin did not show sufficient modulus to function as a denture base. In addition, all resins showed discoloration with clinical significance, and especially polyamides showed the lowest color stability.

• The Journal of Advanced Prosthodontics
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• v.9 no.6
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• pp.453-462
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• 2017

PURPOSE. The purpose of this study was to investigate the in vitro cytotoxicity of thermoplastic denture base resins and to identify the possible adverse effects of these resins on oral keratinocytes in response to hot water/ food intake. MATERIALS AND METHODS. Six dental thermoplastic resin materials were evaluated: three polyamide materials (Smile tone, ST; Valplast, VP; and Luciton FRS, LF), two acrylic materials (Acrytone, AT; and Acryshot, AS), and one polypropylene resin material (Unigum, UG). One heat-polymerized acrylic resin (Vertex RS, RS) was chosen for comparison. After obtaining extracts from specimens of the denture resin materials (${\phi}=10$ mm and d=2 mm) under different extraction conditions ($37^{\circ}C$ for 24 hours, $70^{\circ}C$ for 24 hours, and $121^{\circ}C$ for 1 hour), the extracts (50%) or serial dilutions (25%, 12.5%, and 6.25%) in distilled water were co-cultured for 24 hours with immortalized human oral keratinocytes (IHOKs) or mouse fibroblasts (L929s) for the cytotoxicity assay described in ISO 10993. RESULTS. Greater than 70% viability was detected under all test conditions. Significantly lower IHOK and L929 viability was detected in the 50% extract from the VP ($70^{\circ}C$) and AT ($121^{\circ}C$) samples (P<.05), but only L929 showed reduced viability in the 50% and 25% extract from LF ($37^{\circ}C$) (P<.05). CONCLUSION. Extracts obtained from six materials under different extraction conditions ($37^{\circ}C$, $70^{\circ}C$, and $121^{\circ}C$) did not exhibit severe cytotoxicity (less than 70% viability), although their potential risk to oral mucosa at high temperatures should not be ignored.

• The Journal of Korean Academy of Prosthodontics
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• v.54 no.3
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• pp.286-290
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• 2016

Recently, flexible removable prosthesis with thermoplastic resin clasp has increasingly become popular. In comparison with conventionally used acrylic resin, thermoplastic resin has lower flexural strength and elastic modulus. Thus, flexible removable prosthesis has low risk of fracture, so denture base can be made thin and light, increasing patient comfort. Also, it can passively sit at tooth undercut during rest, so abutment teeth need minimum or no preparation. In this case report, a 44 year old female patient with mild velopharyngeal insufficiency was treated with a palatal lift prosthesis made of polyester thermoplastic resin. Since the patient had no missing tooth and desired conservative treatment, the flexible removable prosthesis provided relatively satisfactory results.

• The Journal of Korean Academy of Prosthodontics
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• v.56 no.3
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• pp.199-205
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• 2018

Purpose: This study evaluated the effect of nonthermal plasma treatment on the bond strength of autopolymerizing relining resin to the injection molded thermoplastic denture base resins (TDBRs) with different surface treatments. Materials and methods: Acrylic Resin (Acrytone), Polyester (Estheshot-Bright), Polyamide (Valplast) and Polypropylene (Weldenz) were subjected to various surface treatments: No treatment, Nonthermal plasma, Sandblasting, Sandblasting and nonthermal plasma. Specimens were bonded using an autopolymerizing relining resin. Shear bond strength was tested using universal testing machine with crosshead speed of 1 mm/min. Statistical analysis by two-way analysis of variance with Tukey's test post hoc was used. Results: Acrytone showed significantly higher shear bond strength value among other TDBR group while Weldenz had the lowest. The sandblasting and nonthermal plasma condition had significantly higher shear bond strength value in all of the resin groups (P < .05). Conclusion: The use of nonthermal plasma treatment showed limited effect on the shear bond strength between TDBRs and relining resin, and combination of nonthermal plasma and sandblasting improved the shear bond strength between TDBR and reline material.

• Journal of the Korean Society for Nondestructive Testing
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• v.34 no.2
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• pp.141-147
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• 2014

A nondestructive ultrasonic technique was applied to evaluate the thermal characteristics and degradation of synthetic polymer resin (plastics) with better cost-effectiveness and functionality than glass and metal. Thermoplastic and transparent acrylic resin (PMMA) specimens were annealed at below the glass transition temperature ($T_g$), and the propagation characteristics (attenuation and velocity) were measured. The attenuation increased and the velocity decreased with thermal degradation. The results showed that the thermal aging of the specimens could be evaluated quantitatively and that the Tg could be evaluated qualitatively.

• Journal of Adhesion and Interface
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• v.16 no.1
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• pp.29-34
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• 2015

Hydrocarbon resins, which are defined as low molecular weight, amorphous, and thermoplastic polymers, are widely used as tackifier for various types of adhesives, as processing aids in rubber compounds, and as modifiers for plastics polymers such as isotactic polypropylene. Typically, hydrocarbon resins are non-polar, and thus highly compatible with non-polar rubbers and polymer. However, they are poorly compatible with polar system, such as acrylic copolymer, polyurethanes, and polyamides. Moreover, recently the raw materials of hydrocarbon resin from naphtha cracking had been decreased because of light feed cracking such as gas cracking. To overcome this problem, in this study, novel hydrocarbon resins were designed to have a highly polar chemical structure which material is sustainable. And, it was successfully synthesized by Diels-Alder reaction of dicyclopentadiene monomer and sorbic acid from blueberry as renewable resources. Acrylic resins were formulated with various tackifiers solution including sorbic acid grafted hydrogenated dicyclopentadiene hydrocarbon resins in acrylic adhesive and rolling ball tack, loop tack, $180^{\circ}$ peel adhesion strength, and shear adhesion strength were measured. The properties depend on the softening point and polar content of tackifiers.

• The Journal of Korean Academy of Prosthodontics
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• v.53 no.1
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• pp.58-65
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• 2015

For the rehabilitation of fully edentulous patients, implant-supported removable partial dentures can be considered as one of the treatment options with complete dentures or implant-supported overdentures. If removable partial dentures are used in combination with a small number of implants placed in strategically important positions, it can offer additional stability, retention and support through implants and reduce a burden of surgical procedures compared with fixed implant-supported prostheses with extensive implant placement. Moreover, the economical benefit can be expected as well. The purpose of this case report is to present a treatment in which an implant-supported removable partial denture was fabricated considering residual alveolar bone status and demands after teeth loss in a patient who had been using a distal extension removable partial denture for a long period of time. In anterior area, fixed prostheses were fabricated with implant placement and in posterior area, short implants provide only support for the removable partial denture. In addition, denture base and clasp were made of thermoplastic acrylic resin. Finally, functionally and aesthetically satisfying treatment results can be achieved.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.23 no.2
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• pp.161-167
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• 2009

Organic insulating materials which are utilized as insulating materials for the low voltage show unique carbonization characteristics when they are carbonized by a leakage current. Therefore the use of the carbonization characteristics makes it possible to examine the electrical fire which is caused by a leakage current flowing on the surface of the organic insulating material. In order to understand such carbonization characteristics, in this paper, experiments have been done to carbonize typical organic insulating materials such as phenol resin, PVC, and acrylic resin, and the carbonization patterns and the IR absorption spectrum of specimens have been analyzed. According to the analysis of the carbonization patterns, the phenol resin shows the so-called 'spider-leg' carbonization pattern due to a thermosetting property. In contrast to the phenol resin, the thermoplastic property makes it difficult to observe a clear carbonization pattern to verify carbonizing causes on the surfaces of PVC and acrylic resins. In this case, the IR absorption spectrum can be analyzed to examine the specimen carbonized by a leakage current. The analysis result shows that absorption peaks appear at the wave numbers of $3,400[cm^{-1}]$ and $1,618[cm^{-1}]$, which can be an important factor to verify the carbonizing causes.