• Title/Summary/Keyword: Thermoplastic Elastomer

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Overview on Development for Thermoplastic Solid Propellants (열가소성 고체추진제 개발 현황)

  • Cho, Joonhyun;Heo, Jinwook;Kim, Dukhyun;Lee, Hyoungjin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.495-497
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    • 2017
  • Thermoplastic propellants using thermoplastic elastomer binders show moderate performance and mechanical properties compared to thermoset propellants, but these propellants are widely used in a variety of fields due to low cost of raw materials, simple manufacturing process and stable handling process. In order to utilize thermoplastic solid propellants in various fields, we will study properties depending on the content of oxidants, metal fuels and additives.

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Preparation and Chain-extension of P(LLA-b-TMC-b-LLA) Triblock Copolymers and Their Elastomeric Properties

  • Kim, Ji-Heung;Lee, Ju-Hee
    • Macromolecular Research
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    • v.10 no.2
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    • pp.54-59
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    • 2002
  • ABA triblock copolymers of L-lactide and trimethylene carbonate with several different compositions were prepared by sequential ring-opening polymerization in the presence of diethylene glycol. Also chain-extension reactions of the resulting copolymers were carried out using hexamethylene diisocyanate to produce relatively high molecular weight polymers, which could be cast into elastomeric tough films. The polymers with certain L-lactide contents were partially crystalline, exhibiting two-phase morphology. The polymer films showed reversible elastic behavior under tensile tension, providing a novel thermoplastic elastomer possessing desirable properties such as biodegradability and good mechanical properties.

Variation of Mechanical Properties on Polystyrene Elastomer According to Injection Molding Conditions (폴리스틸렌계 엘라스토머의 사출성형조건에 따른 기계적 물성 변화)

  • Han, Seong-Ryeol;Kim, Joon-Hyung;Jeon, Seung-Gyeong;Jeong, Yeong-Deug
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.5 no.4
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    • pp.46-52
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    • 2006
  • From the past, most of the studies about thermoplastic elastomers(TPEs) have been conducted for theirs compounded materials and morphology. However these studies do not directly affect on injection molding processing. Therefor this study is focus on the variation of mechanical properties on TPEs moldings by increasing injection molding conditions which included injection molding conditions include injection pressure, holding pressure, melt temperature, mold temperature. The used experimental TPEs is a group of styrene(TPS). Injection pressure slightly affected on tensile strength, shrinkage and hardness. Holding pressure only affected on hardness. The melt temperature was the most affective condition on tensile strength.

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Characterization and 3D Analysis of PETG/POE Thermoplastic Composites (PETG/POE 열가소성 복합재료의 특성평가 및 전산해석)

  • Yu, Seong-Hun;Lee, Jong-Hyuk;Sim, Ji-Hyun
    • Composites Research
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    • v.32 no.6
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    • pp.360-367
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    • 2019
  • In order to apply thermoplastic composites using PETG resin to various industrial fields such as bicycle frames and industrial parts, it is necessary to verify the impact resistance, durability, mechanical properties and 3D analysis of the manufactured composite materials. To improve the mechanical properties, durability and impact resistance of PETG resin, an amorphous resin, in this study, compound and injection molding process were carried out enhanced various weight percent POE(polyolefin elastomer). The thermal and mechanical properties of the thermoplastic composites, and the charpy impact strength, The analysis was performed to evaluate the characteristics according to weight percent of POE. Charpy impact strength test was conducted to analyze the impact characteristics, and the fracture section was analyzed after the impact strength test. In the case of POE material-added thermoplastic composites, thermal and mechanical properties tend to decrease, but workability and impact resistance tend to be superior to those of PETG materials.

Study on the Formulation of an Energetic Thermoplastic Propellant and its Properties(II) (고에너지 열가소성 추진제 제조 및 특성연구(II))

  • Kim, Han-cheol;Park, Eui-Yong;Jeong, Jea-Yun;Kim, Yoon-Gon;Choi, Sung-han;Kang, Tae-won;Oh, Kyeong-won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.3
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    • pp.41-46
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    • 2020
  • In this study, measurement and analysis results from Differential scanning calorimetry(DSC) and Thermogravimetric analysis(TGA) on the newly developed high-energy thermoplastic elastomer(ETPE) propellant are described, followed by the previous study done under the same title as this paper [1]. The characteristics of high-energy thermoplastic propellant were also verified by conducting thermal analysis, and the LSGT, Shotgun & RQ Bomb test, was carried out as well. High energetic thermoplastic binders containing 45% of GAP(Glycidyl Azide Polymer), energetic plasticizer(DEGDN) and Oxidizer Aonium Perchlorate), RDX(reseach development explosive, cyclotrimethylenetrinitramine) were used to formulate the propellant.

Present and Future of Thermoplastic Elastomers As Environmentally Friendly Organic Materials (친환경 유기 소재로서 열가소성 탄성체의 오늘과 내일)

  • Choi, Eun-Ji;Yoon, Ji-Hwan;Jo, Jung-Kyu;Shim, Sang-Eun;Yun, Ju-Ho;Kim, Il
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.170-187
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    • 2010
  • Much interest on the thermoplastic elastomers (TPEs) has recently been attracted in commercial fields as well as scientific and applied researches. The TPEs have their own characteristic area especially in relation with block copolymers as well as many other polymeric materials, since they show interesting features displayed by the conventional vulcanized rubber, and at the same time, by the thermoplastics. In addition, they are characterized by a set of interesting properties inherent to block and graft copolymers, variety of blends and vulcanized materials. The importance of TPE as organic materials can be evaluated by the number of published reports (papers, patents, technical reports, etc). The input of the concept 'thermoplastic elastomer' to SciFinderScholar yields 18,508 results between 1939 and July 10, 2010, and the number increased exponentially after the mid of 1990. For the suitable introduction of the TPE, historic, scientific, technical and commercial considerations should be taken into account. This review article starts with a brief discussion on historical considerations, followed by a introduction of the main preparations and analytical techniques utilized in chemical, structural, and morphological studies. The properties, processing tools, the position among organic materials, and applications of TPEs are also briefly reviewed. Finally, the most probable trends of their future development are discussed in a short final remarks.

Thermo-reversible Crosslinking Elastomer through Supramolecular Networks (초분자 네트워크를 이용한 열가역성 가교 탄성체)

  • Bae, Jong-Woo;Oh, Sang-Taek;Kim, Gu-Ni;Baik, Hyen-Jong;Kim, Won-Ho;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.165-169
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    • 2010
  • Recently supramolecular network thermo-reversible crosslinking elastomer having flexibility, various functionality, and advantages of thermoplastic elastomer (TPE) such as recycle and easy processbility is introduced. Although thermo-reversible bonds such as hydrogen bond and ionic cluster is recognized as a common technology since 1990, control technology of bonding and dissociation of crosslink in supramolecular network is a recent technology. In this review, characteristics of thermo-reversible crosslinking elastomer having rheological properties of TPE and reinforcing behaviors of thermoset elastomer are summarized.

Study on Rear Door Fixed Glass Weather-strip for Automobiles Using EPDM/Polypropylene Blend (I) (자동차용 Rear Door Fixed Glass Weather-strip 성형을 위한 EPDM과 Polypropylene의 Blend에 관한 연구 (I))

  • Park, Jong-Yun;Hwang, Sung-Hyuk;Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.35 no.2
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    • pp.115-121
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    • 2000
  • In comparison with thermosetting rubber, thermoplastic elastomer (TPE) has various advantages such as simple processing, short cycle time and recycling of scrap. These advantages can lead to development of the high value-added rubber products due to reduction of the waste material, manufacturing cost and the defected product. This article involves a dynamic vulcanization method for EPDM/polypropylene blend, and the manufacturing of a fixed glass weather-strip by glass insert molding method using the blend. In order to investigate mechanical properties of the product, tensile strength, elongation, hardness and specific gravity were measured. Also morphological study was carried out using SEM. Developments of an efficient system of production and automatic process by molding of TPE and glass simultaneously are expected.

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