• Title/Summary/Keyword: Thermoplastic Composite

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A Study on Crystallization of Thermoplastic Aromatic Polymer (열가소성 방향족 폴리머의 결정화 특성에 대한 연구)

  • Park, Dong-Cheol;Park, Chang-Wook;Shin, Do-Hoon;Kim, Yun-Hae
    • Composites Research
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    • v.31 no.2
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    • pp.63-68
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    • 2018
  • Thermoplastic composite has been limitedly used in high performance aerospace industry due to relatively low mechanical properties even though it has various advantages. But, thermoplastic aromatic polymer composite has recently been researched and utilized much. In this study, PEEK and PPS neat resin film as representative thermoplastic aromatic polymer were processed through continuous heating, cooling and reheating cycle. Property change such as glass transition temperature and melting temperature were identified and crystallinity variation by different cooling rate were evaluated. In the first (heating) run, polymer specimens were kept for 5 minutes at higher temperature than melting point to remove previous thermal history, and crystallization reaction was controlled by adjusting cooling rate to 2, 5, 10, 20 and $40^{\circ}C/minute$ in the second (cooling) run. In the third (heating) run, specimen crystallinity were verified by measuring the melting enthalpy. The initial specimens containing high portion of amorphous structure exhibited cold crystallization and clear glass transition in the first run whereas they did not show in the third run due to the increase of crystalline structure portion. As cooling rate decreases through the second cooling run, the crystallinity of the specimen increased. PEEK polymer had 21.9~39.3% crystallinity depending on cooling rate change whereas PPS polymer showed 29.1~31.2%.

Effect of Fiber Orientation and Fiber Contents on the Tensile Strength in Fiber-reinforced Thermoplastic Composites (섬유배향과 섬유함유량이 섬유강화 열가소성수지 복합재료의 인장강도에 미치는 영향)

  • Kim, Jin-Woo;Lee, Dong-Gi
    • Composites Research
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    • v.20 no.5
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    • pp.13-19
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    • 2007
  • Fiber-reinforced thermoplastic composites not only approach almost near to the strength of thermosetting composite but also has excellent productivity, recycling property, and impact resistance, which are pointed as weaknesses of thermosetting composites. The study for strength calculation of one direction fiber-reinforced thermoplastic composites and the study measuring precisely fiber orientation distribution were presented. Need the systematic study for the data base that can predict mechanical properties of composite material and fiber orientation distribution by the fiber content ratio was not constructed. Therefore, this study was investigated what affect the fiber content ratio and fiber orientation distribution have on the strength of composites. Fiber-reinforced thermoplastic composites by changing fiber orientation distribution and the fiber content ratio were made. Tensile strength ratio of $0^{\circ}$ direction of fiber-reinforced composites increased being proportional the fiber content and fiber orientation function as change from isotropy(J=0) to anisotropy(J=1). But, tensile strength ratio of $90^{\circ}$ direction by separation of fiber filament decreased when tensile load is imposed fur width direction of reinforcement fiber length direction.

The Effects of Pre-strainon Tensile Properties in Solid-Phase Forming of Thermoplastic Composite (고상성형시 변형률이 열가소성 복합재료의 인장특성에 미치는 영향)

  • 조현철;이중희;김병선
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.194-197
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    • 1999
  • 고분자 복합재료는 금속에 비하여 경량, 고강도, 고탄성율 등의 장점을 가지고 있어 여러 산업에서 기존의 금속 재료를 대체할 수 있는 재료로서 그 사용이 점차 증가하고 있다[1-5]. 특히 사회적으로 환경 문제가 대두되면서 열가소성 복합재료에 대한 관심이 높아지고 있으며 이에 대한 연구가 더욱 요구되고 있다. (중략)

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Electrical Conductivity of Polypyrrole/Copolyester Composite Films. 1. Composite Films Prepared from $FeCl_3$/Copolyester Solution

  • Lee, Seong-Mo;Baik, Doo-Hyun
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.49-52
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    • 1998
  • Preparation of conducting Polymer composites by Polymerizing Polypyrrole in thermoplastic polymer matrices has been studied by many researchers in order to enhance the stability and the Physical Properties of polypyrrole. In the previous study4 we examined the effects of the ionic group content and the copolyester molecular structures on the electrical conductivity of conductivity of polypyrrole(PPy)/copolyester composite films. (omitted)

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Tensile Properties of Rapid Consolidated Thermoplastic Composites (고속압밀 열가소성수지 복합재료의 인장 특성)

  • 김홍건;최창용;유기현;김성철;양성모;노홍길
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2002.10a
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    • pp.504-507
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    • 2002
  • Glass fiber reinforced PET (Poly-Ethylene-Terephthalate) matrix composite was manufactured by rapid press consolidation technique as functions of temperature, pressure and time in pre-heating, consolidation and solidification stages. The optimal manufacturing conditions for this composite were discussed based on the void content, tensile, interlaminar shear, and impact properties. A tensile test was attempted to investigate the mechanical properties of the composite. It is found that the level of crystallinity and microstructure affects on the tensile properties substantially.

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Study of Single Screw Extrusion Conditions on the Formability of TPE-800L Tube (TPE-800L 튜브 성형성에 대한 단축 압출기의 제조공정에 관한 연구)

  • Yoon, Juil;Kang, Sang-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.77-83
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    • 2018
  • Thermoplastic elastomers are being used increasingly throughout industry owing to their superior properties, such as superior elasticity, formability, and recoverability. Currently, research related to thermoplastic elastomers is focused on the development of composite elastomers by combining with various materials and the development of equipment. On the other hand, in the field of small and medium sized companies, it is necessary to study not only the application of these new materials, but also the process conditions that enable the extrusion of thermoplastic elastomers in inexpensive uniaxial screwing equipment. If extrusion is performed in a single screw extruder, it is important to maintain a uniform thickness through process control of the extruder. This study examined the effects of the processing temperature, which is an extrusion process variable, on the formability of a tube in the thermoplastic elastomer TPE-800L uniaxial extrusion process. The nozzle zone temperature is the most important factor in the extrusion of thermoplastic elastomer TPE-800L; the most excellent moldability was confirmed at $165-170^{\circ}C$.

A Study on the Polyamide Based Thermoplastic Composites for Fuel Cell Separators (연료전지 분리판용 폴리아미드계 복합체의 특성 연구)

  • Lee, Kwang-Yong;Kim, Jeong-Heon;Ryu, Sung-Hun
    • Elastomers and Composites
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    • v.43 no.4
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    • pp.253-258
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    • 2008
  • In this study polyamide 6,6 based thermoplastic composite with graphite and carbon black had been examined feasibility for separators of fuel cell which requires good mechanical and electrical properties with gas impermeability. The effects of molding pressure and filler content on the properties of the composite were investigated. Maximum flexural modulus was obtained about 80 wt% graphite, while electrical conductivity increased with graphite content. Flexural strength increased with molding pressure and tended to level-off from $400\;kgf/cm^2$. Molding pressure did not affect the electrical conductivity. The addition of carbon black enhanced the electrical conductivity of the composite. Mechanical properties were decreased under acidic condition.

Improvement of Physical Properties for Carbon Fiber/PA 6,6 Composites (탄소섬유/폴리아마이드 6,6 복합재료의 기계적 물성 향상)

  • Song, Seung A;On, Seung Yoon;Park, Go Eun;Kim, Seong Su
    • Composites Research
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    • v.30 no.6
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    • pp.365-370
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    • 2017
  • Mechanical properties of carbon fiber reinforced thermoplastic composites (CFRTPs) are affected by various factors. One of the them are poor compatibility of the epoxy sizing layer on the carbon fiber surface with thermoplastic matrix, which causes the inferior interfacial strength between fibers and matrix. In addition, the high molten-viscosity of thermoplastics attributes to the poor impregnation state. Consequently, many voids in the composite materials were generated, which leads to poor mechanical properties of the thermoplastic composites. In this study, the epoxy sizing on the carbon fiber surface was removed and the polyamide 6,6 solution was coated on the de-sized carbon fiber surface to improve the impregnation state and mechanical properties. Interlaminar shear strength (ILSS) of CFRPTs was estimated by implementing short beam shear tests. In addition, flexural strength was measured and the impregnation state of the composites was evaluated by calculating void content.

Evaluation of Impregnating and Mechanical Properties for Glass Fiber/Polycarbonate Composites Depending on Molecular Weight of Matrix (유리섬유/폴리카보네이트 복합재료의 기지 분자량에 따른 함침 및 기계적 물성 평가)

  • Kim, Neul-Sae-Rom;Jang, Yeong-Jin;Lee, Eun-Soo;Kwon, Dong-Jun;Yang, Seong Baek;Lee, Jungeon;Yeum, Jeong Hyun
    • Composites Research
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    • v.34 no.1
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    • pp.1-7
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    • 2021
  • Fiber-reinforced thermoplastic composites are applied to transport industries to lightweight of body, and applications will be expanded gradually. In this study, the impregnation and mechanical properties of continuous glass fiber (GF) reinforced polycarbonate (PC) composites were evaluated with different molecular weights of PC. The continuous GF reinforced PC composite were prepared by using GF fabric and PC film via continuous compression molding method. The melting flow index and tensile strength of PC matrix were evaluated with different molecular weights. Mechanical properties (tensile, flexural, and compressive) and pore rate of GF/PC composite were evaluated with different molecular weights of PC. The fracture behavior was analyzed to fracture surface of GF/PC composite using FE-SEM images. As these results, it was condition of representing the best mechanical property that the GF/PC composite was prepared by using PC of 20,000 g/mol as matrix.

Evaluation of Multi-axis Robotic Manufactured Thermoplastic Composite Structure Using Stamp-forming Process (다관절 로봇 암 기반 고속 열 성형 공정을 활용한 열가소성 복합재 부품 평가)

  • Ho-Young Shin;Ji-Sub Noh;Gyu-Beom Park;Chang-Min Seok;Jin-Hwe Kweon;Byeong-Su Kwak;Young-Woo Nam
    • Composites Research
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    • v.36 no.5
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    • pp.321-328
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    • 2023
  • This study developed the in-situ stamp-forming process using the multi-axis robotic arm to fabricate thermal composite parts. Optimal fabrication parameters with the multi-axis robotic arm were determined using finite element analysis and these parameters were further refined through the practical manufacturing process. A comparison between the manufactured parts and finite element analysis results was conducted regarding thickness uniformity and wrinkle distribution to confirm the validity of the finite element analysis. Additionally, to evaluate the formability of the manufactured composite parts, measurements of crystallinity and porosity were taken. Consequently, this study establishes the feasibility of the In-situ stamp-forming consolidation using a robotic arm and verifies the potential for producing composite parts through this process.