• Journal of Adhesion and Interface
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• v.11 no.4
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• pp.162-167
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• 2010

In the present work, the effect of electron beam irradiation on the chemical and thermal characteristics of cellulose-based jute fibers was explored by means of chemical analysis, electron spin resonance analysis, ATR-FTIR spectroscopy, thermogravimetric analysis and thermomechanical analysis. Jute fiber bundles were uniformly irradiated in the range of 2~100 kGy by a continuous method using a conveyor cartin an electron beam tunnel. Electron beam treatment, which is a physical approach to change the surfaces, more or less changed the chemical composition of jute fibers. It was also found that the radicals on the jute fibers can be increasingly formed with increasing electron beam intensity. However, the electron beam irradiation did not change significantly the chemical functional groups existing on the jute fiber surfaces. The electron beam irradiation influenced the thermal stability and thermal shrinkage/expansion behavior and the behavior depended on the electron beam intensity.

• Tunnel and Underground Space
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• v.5 no.1
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• pp.22-40
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• 1995

Thermomechanical characteristics of rocks such as thermal shock, thermal expansion, thermal cracking were experimentally investigaed using Iksan granite, Cheonan tonalite and Chung-ju dolomite to obtain the basic data for proper design and Chung-ju dolomite to obtain the basic data for proper design and stability analysis of underground structures subjected to temperature changes. The effect of thermal shock did not appear when the heating speed was under 3$^{\circ}C$/min. and there existed little difference between multi-staged cyclic heating and single-cycled heating. Thermal expansion of rocks was affected by mineral composition, crack porosity and the degree of thermal craking. In quartz-beraring multimineralic rocks such as Iksan granite and Cheonan tonalite, the thermal expansion coefficient increaseed continuously with temperature rise, but that of Chung-ju dolomite which was a monomineralic rock showed a constant value for the temperature above 250$^{\circ}C$, Chung-ju dolomite yielded the lowest critical threshold temperature(Tc) of 100$^{\circ}C$ and unstable thermal cracking was initiated above the new threshold temperature(Tc')of 300$^{\circ}C$. Above Tc' thermal cracks grew but they were not interconnected. Iksan granite showed closing of microcracks to the temperature of 100$^{\circ}C$, then expanded linearly to Tc of 200$^{\circ}C$. Above Tc, thermal cracking was initiated and progressed rapidly and almost all the grain boundaries were cracked at 600$^{\circ}C$. Cheonan tonalite also showed similar behavior to iksan granite except that Tc was 350$^{\circ}C$ and that thermal cracks propagated more rapidly. Thermal expansions calculated by Turner's equation were found to be valid in predicting the thermal expansion and cracking behavior of rocks.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.36 no.12
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• pp.1585-1590
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• 2012

Engineering plastics are used in instrument panels, interior trim, and other vehicle applications, and the thermomechanical behaviors of plastic materials are strongly influenced by many environmental factors such as temperature, sunlight, and rain. As the material properties change, the mechanical parts create unexpected noise. In this study, the dynamic mechanical property changes of plastics used in automobiles are measured to investigate the temperature effects. Viscoelastic properties such as the glass transition temperature and storage modulus and loss factor under temperature and frequency sweeps were measured. The data were compared with the original ones before aging to analyze the behavior changes. It was found that as the temperature increased, the storage modulus decreased and the loss factor increased slightly.

• Elastomers and Composites
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• v.44 no.3
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• pp.269-273
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• 2009

A study on the life-time expectation of a CR-modified NR rubber composite through the change of thermal degradation characteristics was performed using both isothermal thermogravimetric analysis (TGA) and thermomechanical analysis (TMA). Master curves at reference temperature of $90^{\circ}C$ could be obtained with shift factor $a_T$, which was determined empirically using Time-Temperature Superposition Principle (TTSP). Activation energies could be calculated from the slope of Arrhenius plot of shift factor and showed similar values of $E_{a,TGA}$= 41.2 and $E_{a,TMA}$= 54.5 kJ/mol, respectively. It was considered from the results that chemical degradation resulting weight loss of the sample might be closely related to a physical degradation such as the dimensional change of the sample.

• Journal of the Society of Naval Architects of Korea
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• v.58 no.1
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• pp.17-23
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• 2021

The membrane-type Liquefied Natural Gas (LNG) cargo tank is equipped with a double barrier to seal the LNG, of which the secondary barrier serves to prevent LNG leakage and mainly uses fiber-reinforced composite materials. However, the composite materials have thermal expansion anisotropy, which deteriorates shape distortion and mechanical performance due to repeated thermal loads caused by temperature changes between cryogenic and ambient during the unloading of LNG. Therefore, in this study, the longitudinal thermal expansion characteristics of the composite materials were obtained using a vertical thermo-mechanical analyzer, and the elastic modulus was obtained through the tensile test for each temperature to perform thermal load analysis for each direction. This is considered that it is useful to secure reliability from the viewpoint of the design of materials for a LNG cargo hold.

• Polymer(Korea)
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• v.25 no.1
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• pp.98-107
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• 2001

Dielectric properties and shape memory characteristics of SBS composites filled with carbon black as conductive filler and (Ba,Ca)$(Sn,Ti)O_3$ or $SrTiO_3$ as dielectrics were investigated for the development of phantom model. SBS/carbon black composite showed an increment of complex dielectric constant with increasing the content of carbon black and the frequency dependence that the dielectric constant decreases with the frequency. The complex dielectric constant and the conductivity of SBS/carbon black/dielectrics composites increased with the increase of dielectrics and the characteristics of the frequency dependence also occurred by the effect of carbon black. Phantom materials with the dielectric properties and the conductivity corresponding to human tissues for the measurement of specific absorption rate(SAR) within the frequency range of current mobile phones(775MHz~2GHz) could be developed by adjusting the composition ratios of carbon black, dielectrics and SBS and by controlling the characteristic of frequency dependence of composite. From thermomechanical cycling test good shape recoverability could be obtained in SBS composite even though the residual strain was increased by the effect of filler.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.39 no.3
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• pp.249-257
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• 2015

A fuel assembly consists of fuel rods composed of pellets (UO2) and a cladding tube (Zircaloy). The role of the fuel rods in the reactor is to generate heat by nuclear fission, as well as to retain fission products during operation. A simulation method using a computer program was used to evaluate the safety of the nuclear fuel rods. This computer program has been called the fuel performance code. In the analysis of a light water reactor fuel rod, the gap conductance, which depended on the distance between the pellets and cladding tube, mainly influenced the thermomechanical behavior of the fuel rod. In this work, a 3D gap element was proposed to simulate the thermo-mechanical behavior of the nuclear fuel rod, considering the gap conductance. To implement the proposed 3D gap element, a 3D thermo-mechanical module was also developed using FORTRAN90. The asymmetric characteristics of the nuclear fuel rod, such as the MPS (missing pellet surface) and eccentricity, were simulated to evaluate the proposed 3D gap element.

• International Journal of Highway Engineering
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• v.2 no.3
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• pp.129-144
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• 2000

This paper presents the characteristics of viscoelastic properties and fatigue performance of SBS modified asphalt mixtures depending on the aggregate gradation. Dynamic shear rheometer (DSR) and uniaxial tensile creep tests are performed to analyze the thermomechanical behavior of asphalt binders and mixtures, respectively. Uniaxial tensile fatigue tests for seven different asphalt mixtures are conducted to evaluate the effects of aggregate gradations and SBS modifier on the fatigue performance of the mixtures. DSR and uniaxial tensile creep tests results show that the SBS modified asphalt mixtures have better rutting resistance than the unmodified mixtures at high temperatures regardless of the aggregate gradations used. Fatigue factor $G^*sin\delta$ in Superpave binder specification may not be adequate for evaluating the fatigue Performance of asphalt mixtures. It is observed from uniaxial tensile fatigue tests that SBS modified asphalt mixtures compared to unmodified mixtures have ten times longer fatigue lives regardless of the aggregate gradations(dense, SMA, and Superpave gradations) used in the mixtures. The better fatigue performance of the SBS modified mixtures is observed even after long-term aging process. The effect of aggregate gradations on the fatigue performance is not as significant as the SBS modifier. The cellulose fiber added in the SMA mixture has negligible effects on the viscoelastic Properties and fatigue performance of the mixture, but is effective in reducing draindown. Although the SBS modified asphalt binder is used, it may be necessary to add the cellulose fiber into the SMA mixture to prevent the draindown.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.48 no.1
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• pp.100-110
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• 2016

Alkaline Peroxide Mechanical Pulping (APMP) of Pinus densiflora harvested from domestic mountains was explored. APMP contributes to various advantages including pulp quality, elimination of the need for a bleaching process, and energy savings. Sequential treatment of impregnation of bleaching chemicals and refining not only overcome the concern of alkaline darkening of wood chips during chemical impregnation, but it also brightens the chips to the desired brightness levels suitable for writing and printing papers. APMP pulping from Pinus densiflora was greatly influenced by the dosage levels of hydrogen peroxide and sodium hydroxide. Alkaline peroxide treatment was carried out by applying one of three levels of hydrogen peroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips) and one of three levels of sodium hydroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips). Other chemicals including a peroxide stabilizers and metal chelation were constantly added for all treatments. Chemical treatment with a liquor-to-wood ration of 9:1 was carried out in a laboratory digestor. Compared to BTMP, APMP pulping displayed outstanding characteristics including the less requirement of refining energy, the better improvement of tensile strength, the more reduction of shives, and the greater increase of pulp brightness. In particular, when 4.5% of hydrogen peroxide with impregnation during 90 minutes was used, the brightness of APMP reached 64.9% ISO. Even though bulk of APMP was decreased with the increase of sodium hydroxide, a better and improved balance could be achieved between optical and strength properties. The spent liquor obtained from the discharge of the impregnation process at the dosage level of 4.5% hydrogen peroxide exhibited an equal level of residual peroxide with BTMP. In conclusion, APMP pulping showed successful results with Pinus densiflora due to its better response to the development of optical and physical properties compared to TMP pulping.

• Polymer(Korea)
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• v.29 no.2
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• pp.183-189
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• 2005

Films of poly(vinyl alcohol)(PVA)/chitosan blends and its blend hydrogels were prepared by the solution casting method. The state of miscibility of the blends and blend hydrogels were examined over the entire composition range by differential scanning carorimetry (DSC), thermogravimetry (TGA), and dynamic mechanical analysis (DMA). DSC analysis shows the depression of melting point of PVA in the blends and the decrease of crystallization temperature of PVA in the blends were observed with increasing chitosan content in the blends. TGA analysis indicates that chitosan was thermally more stable than PVA and the thermal stability of PVA in the blends was higher than that of pure PVA, due to some interactions between two component polymers in the blend. The glass transition temperature $(T_g)$ of the chitosan and of PVA, measured by DMA, were at 160 and $90^{\circ}C$, respectively. The $T_g$ of the blends was changed with the content of chitosan in the blends. The results of thermal and viscoelastic analysis indicate some miscibility between component polymers in the blend exists. Moisture and cross linking in the blend and blend hydrogel, which strongly change thermal and physical properties of hydrophilic polymers, affected the miscibility of chitosan and PVA to a small extent.