• Proceedings of the KIPE Conference
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• 2020.08a
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• pp.37-39
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• 2020

리튬이온 배터리는 동작하는 과정에서 필연적으로 열이 발생하기 때문에 적절한 열 관리에 대한 전략이 필요하다. 배터리에서의 발열은 가역적인 발열과 비가역적인 발열로 분류될 수 있으며 배터리의 용도별, 동작 조건 별 발열 특성이 상이하기 때문에, 배터리의 열적 안전성 확보를 위해서는 열적 특성에 대한 분석이 필수적이다. 본 연구에서는 고용량/고출력 리튬이온 배터리의 전기적 특성 실험을 수행하고 열적 안전성 분석을 위하여 발열 특성 분석을 수행하였다. 고용량/고출력 배터리 특성에 따라 가역적 발열과 비가역적 발열이 나타나는 특성이 상이한 것으로 확인되었으며, 또한 온도 측정 정보로부터 배터리의 내부 상태 특성을 추정하고 고장 진단 및 수명 특성에 활용될 수 있음을 확인하였다.

• 유체기계공업학회:학술대회논문집
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• 1998.12a
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• pp.209-214
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• 1998

A thermodynamic simulation method is developed for the process design and the performance evaluation of the gas turbine in IGCC power plant. The present study adopts four clean coal gases derived from four different coal gasification and gas clean-up processes as IGCC gas turbine fuel, and considers the integration design condition of the gas turbine with ASU(Air Separation Unit). In addition, the present simulation method includes compressor performance map and expander choking models for considering the off-design effects due to coal gas firing and ASU integration. The present prediction results show that the efficiency and the net power of the IGCC gas turbines are seperior to those of the natural gas fired one but they are decreased with the air extraction from gas turbine to ASU. The operation point of the IGCC gas turbine compressor is shifted to the higher pressure ratio condition far from the design point by reducing the air extraction ratio. The exhaust gas of the IGCC gas turbine has more abundant wast heat for the heat recovery steam generator than that of the natural gas fired gas turbine.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.1
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• pp.1-7
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• 2005

The heat transfer characteristics of an internal heat exchanger for $CO_2$ refrigeration cycle are numerically investigated. The numerical model is verified using the published experimental results for the concentric tube type internal heat exchanger. The Hardy-Cross Method gives very good agreement between the calculation and experimental results on the heat transfer rates and exit temperatures. Also, appropriate combination of heat transfer correlations is found. The operating parameters of the heat exchanger are calculated at transcritical region of $CO_2.$ The heat transfer rate of the counter flow type heat exchanger shows the $32\%$ greater than that of the parallel flow type heat exchanger. The increase of heat exchanger length enhances the heat transfer rate. The thermodynamic characteristics and heat transfer coefficient of $CO_2$ in the internal heat exchanger are estimated.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.673-680
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• 2011

The compound 3-(2-Mercaptopyridine)phthalonitrile has been synthesized and characterized by IR, UV-vis, and X-ray single-crystal determination. The molecular geometry from X-ray determination of the title compound in the ground state has been compared using the Hartree-Fock (HF) and density functional theory (DFT) with the 6-31G(d) basis set. The calculated results show that the DFT and HF can well reproduce the structure of the title compound. The energetic behavior of the title compound in solvent media was examined using the B3LYP method with the 6-31G(d) basis set by applying the Onsager and polarizable continuum model. Using the TD-DFT and TD-HF methods, electronic absorption spectra of the title compound have been predicted and good agreement with the TD-DFT method and the experimental determination was found. The predicted nonlinear optical properties of the title compound are much greater than those of urea. Besides, molecular electrostatic potential of the title compound were investigated by theoretical calculations. The thermodynamic properties of the compound at different temperatures have been calculated and corresponding relations between the properties and temperature have also been obtained.

• Journal of Industrial Technology
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• v.19
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• pp.253-260
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• 1999

Two thermodynamic models were used to predict the partial molar volumes of solutes in supercritical carbon dioxide at infinite dilution: (1) the Peng-Robinson equation of state with various mixing rules including those based on $EOS/G^E$ (2) the Kirkwood Buff fluctuation integral with the hard sphere expansion (HSE) method. The Kirkwood-Buff fluctuation integral method, in which an equation of state for pure component and molecular parameters are required, produced better results especially near the critical point than the Peng-Robinson equation of state with the several mixing rules based an $EOS/G^E$. When the $EOS/G^E$ mixing rules were used, poorer results were obtained compared with the classical mixing rule and Kirkwood-Buff model.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.1
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• pp.132-136
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• 2009

Recently, for improvement of the magnetic field of high temperature superconductor (HTS) apparatus, many studies investigating on operating in the range of $20{\sim}65\;K$ with liquid helium or the conducting method using cryocooler are actively reviewed. Also, the cooling method using solid nitrogen as cryogen is being suggested. Since the nitrogen has very large specific heat in solid state, it is expected that it can be operated for a long time without a continuous supply of cooling energy. However, there are still insufficient data on the characteristics of solid nitrogen such as thermodynamic properties and liquid-solid phase change. Especially, there was almost no study done on the electrical insulation properties of solid nitrogen so far. In this study, solid nitrogen to find the electrical characteristics was made by using cryocooler and cryostat, and investigated the flashover discharge and breakdown. The results of this study will be useful as a basic data for electrical insulation design of the HTS system using solid nitrogen as cryogen.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.12
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• pp.1730-1738
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• 2001

This paper presents an overview of testing and analyzing field performance of a centrifugal chiller which has a rated capacity of 200 RT(703 kW). Field data of a chiller installed in the cleanroom research building of KIST has been collected far performance analysis. The operating data included start-up, shut-down, and quasi-static state where cooling capacity and compressor power consumption varied cyclically. It was found that the steady-state thermodynamic model could be applied to relate the cooling capacity and COP under quasi-static conditions. The results led to finding the required cooling load pattern and a possible energy saving method. This study provides a method of evaluating performance of a large capacity centrifugal chiller in which field test is necessary.

• International Journal of Aeronautical and Space Sciences
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• v.2 no.2
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• pp.65-72
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• 2001

This paper demonstrates an explicit-implicit, finite element analysis for linear as well as nonlinear hygrothermal stress problems. Additional features, such as moisture diffusion equation, crack element and virtual crack extension(VCE) method for evaluating J-integral are implemented in this program. The Linear Elastic Fracture Mechanics(LEFM) Theory is employed to estimate the crack driving force under the transient condition for an existing crack. Pores in materials are assumed to be saturated with moisture in the liquid form at the room temperature, which may vaporize as the temperature increases. The vaporization effects on the crack driving force are also studied. The ideal gas equation is employed to estimate the thermodynamic pressure due to vaporization at each time step after solving basic nodal values. A set of field equations governing the time dependent response of porous media are derived from balance laws based on the mixture theory. Darcy's law is assumed for the fluid flow through the porous media. Perzyna's viscoplastic model incorporating the Von-Mises yield criterion are implemented. The Green-Naghdi stress rate is used for the invariant of stress tensor under superposed rigid body motion. Isotropic elements are used for the spatial discretization and an iterative scheme based on the full Newton-Raphson method is used for solving the nonlinear governing equations.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.1
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• pp.31-37
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• 1999

In order to predict thermodynamic performance of refrigeration system, it is required to know the oil concentration of the refrigerant/oil mixture. The current method to measure the oil concentration is to extract the working mixture and then to measure the oil weight. However, it is Quite necessary to estimate oil concentration without any extraction of the working fluid. In this study a new method and working equation is presented as follows. It is based on the measurement of spedific gravity and temperature : $$C=a+b{\times}t+c{\times}t^2+(d+e{\times}t+f{\times}t^2){\times}SG$$ C is oil concentration, t is temperature($^{\circ}C$), SG is specific gravity of mixture and a~f is coefficients. The oil concentration ranges over 0~12 wt% and the temperature ranges over $20{\sim}50^{\circ}C$. The specific gravity and temperature are measured using the on-line densimeter and thermometer. This working equation enables to predict the oil concentration without any extraction of the mixture. This equation can be applied for R-12/Naphthenic oil and R-134a/POE oil oiquid mixtures.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.136-141
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• 2008

Due to environmental concerns $CO_2$ has been reintroduced as a potential candidate to replace HFCs in refrigeration systems since 1990s. In a refrigeration cycle, oil is utilized in lubricating a compressor. However, although oil separators are installed after a compressor oil is prone to leak to the whole system. The mixing of $CO_2$ and oil, even a small amount of oil, the heat transfer performance in heat exchanger deteriorated and the pressure drop inside tube increases. Therefore, it is needed to precisely estimate the mixture thermodynamic properties of $CO_2$-lubricant oil to correctly design a $CO_2$ refrigeration system. The commonly used method in estimating the mixture properties is the mole based weighting model. However, the accuracy of the method can not be assured. In the present study, $CO_2$-lubricant oil mixture properties including viscosity and density were estimated by using the mixture models, based on the equation of state (EOS).