• Title/Summary/Keyword: Thermodynamic cycle

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Corrosion Behavior of Stainless Steel 316 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2
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    • pp.169-177
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    • 2020
  • Here, the stability of stainless steel 316 (SS-316) was investigated to identify its applicability in the oxide reduction process, as a component in related equipment, to produce a complicated gas mixture composed of O2 and Cl2 under an argon (Ar) atmosphere. The effects of the mixed gas composition were investigated at flow rates of 30 mL/min O2, 20 mL/min O2 + 10 mL/min Cl2, 10 mL/min O2 + 20 mL/min Cl2, and 30 mL/min Cl2, each at 600℃, during a constant argon flow rate of 170 mL/min. It was found that the corrosion of SS-316 by the chlorine gas was suppressed by the presence of oxygen, while the reaction proceeded linearly with the reaction time regardless of gas composition. Surface observation results revealed an uneven surface with circular pits in the samples that were fed mixed gases. Thermodynamic calculations proposed the combination of Fe and Ni chlorination reactions as an explanation for this pit formation phenomenon. An exponential increase in the corrosion rate was observed with an increase in the reaction temperature in a range of 300 ~ 600℃ under a flow of 30 mL/min Cl2 + 170 mL/min Ar.

Propulsion System Modeling and Reduction for Conceptual Truss-Braced Wing Aircraft Design

  • Lee, Kyunghoon;Nam, Taewoo;Kang, Shinseong
    • International Journal of Aeronautical and Space Sciences
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    • v.18 no.4
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    • pp.651-661
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    • 2017
  • A truss-braced wing (TBW) aircraft has recently received increasing attention due to higher aerodynamic efficiency compared to conventional cantilever wing aircraft. For conceptual TBW aircraft design, we developed a propulsion-and-airframe integrated design environment by replacing a semi-empirical turbofan engine model with a thermodynamic cycle-based one built upon the numerical propulsion system simulation (NPSS). The constructed NPSS model benefitted TBW aircraft design study, as it could handle engine installation effects influencing engine fuel efficiency. The NPSS model also contributed to broadening TBW aircraft design space, for it provided turbofan engine design variables involving a technology factor reflecting progress in propulsion technology. To effectively consolidate the NPSS propulsion model with the TBW airframe model, we devised a rapid, approximate substitute of the NPSS model by reduced-order modeling (ROM) to resolve difficulties in model integration. In addition, we formed an artificial neural network (ANN) that associates engine component attributes evaluated by object-oriented weight analysis of turbine engine (WATE++) with engine design variables to determine engine weight and size, both of which bring together the propulsion and airframe system models. Through propulsion-andairframe design space exploration, we optimized TBW aircraft design for fuel saving and revealed that a simple engine model neglecting engine installation effects may overestimate TBW aircraft performance.

A Comparative Study Between One- and Two-Stage Refrigeration System for the Natural Gas Cooling Process (천연가스 냉각을 위한 1단 냉동과 2단 냉동 사이의 비교연구)

  • Cho, Jung-Ho;Kim, Dong-Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.8
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    • pp.3106-3111
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    • 2010
  • In this study, a comparative study was performed between one- and two-stage refrigeration system to cool the natural gas temperature down to $-40^{\circ}C$ using propane as a chilling medium. As a thermodynamic model, Peng-Robinson equation of state equation was applied and PRO/II with PROVISION release 8.3 at Invensys company was utilized for the simulation of the refrigeration system. Through this study, optimization work showed that two-stage refrigeration system was proven to save about 33.5% refrigeration power consumption compared to the one-stage refrigeration cycle.

Analysis of Heat Transfer Characteristics of Internal Heat Exchanger for $CO_2$ Refrigerator using the Hardy-Cross Method (Hardy-Cross법을 이용한 $CO_2$ 냉동기용 내부열교환기의 열전달 특성 연구)

  • Kang Hee-Dong;Kim Ook Joong;Seo Tae-Beom
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.1
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    • pp.1-7
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    • 2005
  • The heat transfer characteristics of an internal heat exchanger for $CO_2$ refrigeration cycle are numerically investigated. The numerical model is verified using the published experimental results for the concentric tube type internal heat exchanger. The Hardy-Cross Method gives very good agreement between the calculation and experimental results on the heat transfer rates and exit temperatures. Also, appropriate combination of heat transfer correlations is found. The operating parameters of the heat exchanger are calculated at transcritical region of $CO_2.$ The heat transfer rate of the counter flow type heat exchanger shows the $32\%$ greater than that of the parallel flow type heat exchanger. The increase of heat exchanger length enhances the heat transfer rate. The thermodynamic characteristics and heat transfer coefficient of $CO_2$ in the internal heat exchanger are estimated.

Environmental analysis of present and future fuels in 2D simple model marine gas tubines

  • El Gohary, M. Morsy
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.5 no.4
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    • pp.559-568
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    • 2013
  • Increased worldwide concerns about fossil fuel costs and effects on the environment lead many governments and scientific societies to consider the hydrogen as the fuel of the future. Many researches have been made to assess the suitability of using the hydrogen gas as fuel for internal combustion engines and gas turbines; this suitability was assessed from several viewpoints including the combustion characteristics, the fuel production and storage and also the thermodynamic cycle changes with the application of hydrogen instead of ordinary fossil fuels. This paper introduces the basic environmental differences happening when changing the fuel of a marine gas turbine from marine diesel fuel to gaseous hydrogen for the same power output. Environmentally, the hydrogen is the best when the $CO_2$ emissions are considered, zero carbon dioxide emissions can be theoretically attained. But when the $NO_x$ emissions are considered, the hydrogen is not the best based on the unit heat input. The hydrogen produces 270% more $NO_x$ than the diesel case without any control measures. This is primarily due to the increased air flow rate bringing more nitrogen into the combustion chamber and the increased combustion temperature (10% more than the diesel case). Efficient and of course expensive $NO_x$ control measures are a must to control these emissions levels.

Study on Performance and Optimal Operating Conditions of Regenerative Steam-Injection Gas Turbine Systems (증기분사 재생 가스터빈 시스템의 성능 및 최적 운전조건에 관한 연구)

  • Kim, Kyoung-Hoon;Kim, Dong-Joo;Park, Sang-Hee;Oh, Man-Soo;Kim, Dong-Myoung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.14 no.1
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    • pp.29-39
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    • 2010
  • The system performance of the regenerative gas-turbine cycle with the steam injection into the combustor has been studied through the thermodynamic cyclic analysis. The effects of the pressure ratio, the steam injection ratio, the ambient temperature, and the turbine inlet temperature are investigated on the thermal efficiency, the fuel consumption, and the specific power as well as the operating conditions for the maximum thermal efficiency of the system. The results of the present analysis find that the use of steam injection in the regenerative gas-turbine system can greatly enhance the thermal efficiency and the specific power of the system.

Basic design of hydrogen liquefier precooled by cryogenic refirgerator (극저온냉동기 예냉 수소액화기의 기초설계)

  • Kim, S.H.;Chang, H.M.;Kang, B.H.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.3
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    • pp.389-400
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    • 1997
  • A thermodynamic cycle analysis is performed for refrigerator-precooled Linde-Hampson hydrogen liquefiers, including catalysts for the ortho-to-para(o-p) conversion. three different configurations of the liquefying system, depending upon the method of the o-p conversion, are selected for the analysis. After some simple and justifiable models are introduced, a general analysis program to predict the liquid yield and the figure of merit(FOM) is developed with incorporating the commercial computer code for the hydrogen properties. The discussion is focused on the effect of the two primary design parameters-the precooling temperature and the high pressrure of hydrogen. When the precooling temperature is in the range between 45 and 60 K, the optimal high pressure for the maximal liquid yield is found to be in the range between 100 to 140 bar, regardless of the o-p conversion. However, the FOM can be maximized at slightly smaller values of high pressures. It is remarkable to observe that the lower precooling temperatures are favorable since both the liquid yield and the FOM can be obtained without compressing hygrogen to extremely high pressures.

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Performance Analysis of Regenerative Gas Turbine System with Afterfogging (압축기 출구 물분사가 있는 재생 가스터빈 시스템의 성능해석)

  • Kim, Kyoung-Hoon;Kim, Se-Woong;Ko, Hyung-Jong
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.8
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    • pp.448-455
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    • 2009
  • A performance analysis of the regenerative gas turbine system with afterfogging is carried out. Because of the high temperature at the outlet of air compressor, afterfogging has a potential of improved recuperation of exhaust heat than inlet fogging. Thermodynamic analysis model of the gas turbine system is developed by using an ideal gas assumption. Using the model, the effects of pressure ratio, water injection ratio, and ambient temperature are investigated parametrically on thermal efficiency and specific power of the cycle. The dependency of pressure ratio giving peak thermal efficiency is also investigated. The results of numerical computation for the typical cases show that the regenerative gas turbine system with afterfogging can make a notable enhancement of thermal efficiency and specific power. In addition, the peak thermal efficiency is shown to decrease almost linearly with ambient temperature.

Performance Evaluation of an Oxy-coal-fired Power Generation System - Thermodynamic Evaluation of Power Cycle (순산소 석탄 연소 발전 시스템의 성능 평가 - 동력 사이클의 열역학적 해석)

  • Lee, Kwang-Jin;Choi, Sang-Min;Kim, Tae-Hyung;Seo, Sang-Il
    • Journal of the Korean Society of Combustion
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    • v.15 no.2
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    • pp.1-11
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    • 2010
  • Power generation systems based on the oxy-coal combustion with carbon dioxide capture and storage (CCS) capability are being proposed and discussed lately. Although a large number of lab scale studies for oxy-coal power plant have been made, studies of pilot scale or commercial scale power plant are not enough. Only a few demonstration projects for oxy-coal power plant are publicized recently. The proposed systems are evolving and various alternatives are to be comparatively evaluated. This paper presents a proposed approach for performance evaluation of a commercial 100 MWe class power plant, which is currently being considered for 'retrofitting' for the demonstration of the concept. The system is configurated based on design and operating conditions with proper assumptions. System components to be included in the discussion are listed. Evaluation criteria in terms of performance are summarized based on the system heat and mass balance and simple performance parameters, such as the fuel to power efficiency and brief introduction of the second law analysis. Also, gas composition is identified for additional analysis to impurities in the system including the purity of oxygen and unwanted gaseous components of nitrogen, argon and oxygen in air separation unit and $CO_2$ processing unit.

The study on kinetic value for simulation in fluidized catalytic gasification (유동층에서의 촉매 석탄가스화 공정 모델 모사를 위한 kinetics에 대한 연구)

  • Jang, Dong-Ha;Jeon, Young-Shin;Kim, Hyung-Taek
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.74.1-74.1
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    • 2011
  • As a demand for energy, many studies are increasing about energy resource. One of these resources is coal which reserves of underground. A lot of research to use coal is going on as method of IGCC (Integrated Gasification Combined Cycle). In addition, SNG(Substitute Natural Gas) and IGFC (Integrated Gasification Fuel Cell) are also being developed for fuel & electricity. This technology which uses synthesis gas after gasification is to produce electricity from the Fuel Cell. At this point, important thing is the components of synthesis gas. The main objective is to increase the proportion of methane and hydrogen in synthesis gas. The catalytic gasification is suitable to enhance the composition of methane and hydrogen. In this study, Exxon Predevelopment catalyst gasification study was served as a good reference and then catalytic gasification simulation process is conducting using Aspen Plus in this research. For this modelling, kinetic value should be calculated from Exxon's report which is used for modeling catalytic gasification. Catalytic gasification model was performed by following above method and was analyzed by thermodynamic method through simulation results.

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