• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.1030-1032
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• 2011

• Journal of Power System Engineering
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• v.20 no.2
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• pp.79-84
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• 2016

The thermodynamic performance of ocean thermal energy conversion with 1 kg/s geothermal water flow rate as a heat source was evaluated to obtain the basic data for the optimal design of cycle with respect to the classification of the working fluid. The basic thermodynamic model for cycle is rankine cycle and the geothermal water and deep seawater were adapted for the heat source of evaporator and condenser, respectively. R245fa, R134a are better to use as a working fluid than others in view of the use of geothermal water. It is important to select the proper working fluid to operate the ocean thermal energy conversion. So, this paper can be used as the basic data for the design of ocean thermal energy conversion with geothermal water and deep seawater.

• Journal of Hydrogen and New Energy
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• v.31 no.1
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• pp.41-48
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• 2020

The present study discussed the thermodynamic analysis of the hydrogen liquefaction process to build a hydrogen liquefaction pilot plant with a small capacity (0.5 ton/day). A 2-stage Brayton cycle utilizing LNG/LN2 cold energy was suggested to be built in Korea for the hydrogen liquefaction pilot plant with a small capacity. Thermodynamic analysis on the effect of various variables on the efficiency of hydrogen liquefaction process was performed. As a result, the CASE in which the ortho-para conversion catalyst was infiltrated inside the heat exchanger showed the best process efficiency. Finally, thermodynamic analysis was performed on the effect of turbo expander compression ratio on the hydrogen liquefaction process and it was confirmed that an optimal turbo expander compression ratio exists.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.6
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• pp.476-483
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• 2016

An organic Rankine cycle for ocean thermal energy conversion system is a generating cycle using the temperature difference between surface water and deep water of the ocean. The working fluid is an important factor in the thermodynamic performance of an organic Rankine cycle. There is pinch point analysis as thermodynamic analysis of an organic Rankine cycle. This study performed a thermodynamic performance analysis according to variation in the pinch point temperature difference in heat exchangers and variation of outlet temperature of heat source and heat sink. It analyzed the thermodynamic performance by applying seven types of simple working fluids in a simple Rankine cycle for ocean thermal energy conversion that was designed according to pinch point analysis. As a result of the performance analysis, cycle irreversibility and total exergy destruction factor more decreased, and second law efficiency more increased in the lower pinch point temperature difference and temperature variation of heat source and heat sink in heat exchangers. In addition, the irreversibility changed greatly at a point that occurred in the thermodynamic variation. Among the selected working fluids, RE245fa2 showed the best thermodynamic performance, and the performance of all working fluids was observed to be similar. It needs a strict theoretical basis about diverse factors with thermodynamic performances in selecting heat exchangers and working fluids.

• Nuclear Engineering and Technology
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• v.25 no.2
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• pp.265-275
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• 1993

A vapor explosion has been a concern in nuclear reactor safety due to its potential for a destructive mechanical energy release. In order to properly assess the hazard of a vapor explosion, it is necessary to accurately estimate the conversion efficiency of the thermal energy to mechanical energy. In the absence of a complete model to determine the explosive energy yield, one may have to rely on a simpler upper bound estimate such as a thermodynamic model. This paper discusses various thermodynamic models and presents a clarification of each model in their mathematical formulation and the thermodynamic work conversion. It is shown that the work release in the shock adiabatic model of Board and Hall is essentially equal to that of Hicks-Menzies thermodynamic model. The effect of coolant void fraction on the explosion efficiency is also predicted based on these thermodynamic models. Finally, the Hicks-Menzies model is modified to account for the chemical reaction between a metallic fuel and water and the resultant effects on the explosion expansion work are discussed.

• International Journal of Air-Conditioning and Refrigeration
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• v.6
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• pp.124-135
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• 1998

A thermodynamic cycle analysis is performed for refrigerator-precooled Linde-Hampson hydrogen liquefiers, including catalysts for the ortho-to-para conversion. Three different configurations of the liquefying system, depending upon the method of the o-p conversion, are selected for the analysis. After some simplifying and justifiable assumptions are made, a general analysis program to predict the liquid yield and the figure of merit (FOM) is developed with incorporating the commercial computer code for the thermodynamic properties of hydrogen. The discussion is focused on the effect of the two primary design parameters - the precooling temperature and the high pressure of the cycle. When the precooling temperature is in a range between 45 and 60 K, the optimal high pressure for the maximal liquid yield is found to be about 100 to 140 bar, regardless of the ortho-to-para conversion. However, the FOM can be maximized at slightly lower high pressures, 75 to 130 bar. It is concluded that the good performance of the precooling refrigerator is significant in the liquefiers, because at low precooling temperatures high values of the liquid yield and the FOM can be achieved without compression of gas to a very high pressure.

• Journal of Energy Engineering
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• v.24 no.2
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• pp.84-90
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• 2015

Hydrogen has some remarkably high values of the key properties for transport processes, such as kinematic viscosity, thermal conductivity and diffusion coefficient. Hydrogen, as an energy medium, has some distinct benefits for its high efficiency and convenience in storage, transportation and conversion. Hydrogen has much wider limits of flammability in air than methane, propane or gasoline and the minimum ignition energy is about an order of magnitude lower than for other combustibles. Statistical thermodynamics provides the relationships that we need in order to bridge this gap between the macro and the micro. Our most important application will involve the calculation of the thermodynamic properties of the ideal gas.

• Journal of Ocean Engineering and Technology
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• v.10 no.2
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• pp.136-145
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• 1996

The theory is based on two thermodynamic equations for the air mass in the air column and bydrodynamic equation for the relation between the response of the air in the water column and the incident wave. The numerical model is experimented in a two dimensional water tank and the caisson model with sloped front wall is tested in the large towing tank.

• Journal of Hydrogen and New Energy
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• v.24 no.6
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• pp.510-517
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• 2013

The ammonia-water based power generation cycle utilizing liquefied natural gas (LNG) as its heat sink has attracted much attention, since the ammonia-water cycle has many thermodynamic advantages in conversion of low-grade heat source in the form of sensible energy and LNG has a great cold energy. In this paper, we carry out thermodynamic performance analysis of a combined power generation cycle which is consisted of an ammonia-water regenerative Rankine cycle and LNG power generation cycle. LNG is able to condense the ammonia-water mixture at a very low condensing temperature in a heat exchanger, which leads to an increased power output. Based on the thermodynamic models, the effects of the key parameters such as source temperature, ammonia concentration and turbine inlet pressure on the characteristics of system are throughly investigated. The results show that the thermodynamic performance of the ammonia-water power generation cycle can be improved by the LNG cold energy and there exist an optimum ammonia concentration to reach the maximum system net work production.

• Korean Membrane Journal
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• v.5 no.1
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• pp.68-74
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• 2003

Methane steam reforming (MSR) reaction for hydrogen production was studied in a membrane reactor (MR) using two tubular membranes, one Pd-based and one of porous alumina. A higher methane conversion than the thermodynamic equilibrium for a traditional reactor (TR) was achieved using MRs. The experimental temperature range was 350-500$^{\circ}C$; no sweep-gas was employed during reaction tests to avoid its back-permeation through the membrane and the steam/methane molar feed ratio (m) varied in the range 3.5-5.9. The best results (the difference between the MR conversion and the thermodynamic equilibrium was of about 7%) were achieved with the alumina membrane, working with the highest steam/methane ratio and at 450$^{\circ}C$. Silica membranes prepared at KRICT laboratories were characterized with permeation tests on single gases (N$_2$, H$_2$ and CH$_4$). These membranes are suited for H$_2$ separation at high temperature.