• Title/Summary/Keyword: Thermodynamic Models

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Preliminary Design Program for a High Thrust Liquid Rocket-Engine : Components Design for Static Performance Design (대추력 액체로켓엔진 예비설계 프로그램 : 정상성능 설계를 위한 구성품 모델링)

  • Ko, Tae-Ho;Kim, Sang-Min;Kim, Hyung-Min;Yoon, Woong-Sup
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.414-416
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    • 2009
  • In order to build a transient simulation program for a high thrust liquid rocket engine(LRE), a static performance simulation program for components were made. The components were the thrust chamber (combustion chamber and supersonic nozzle), centrifugal pump (impeller and volute casing), impulse turbine, and flow control devices (control valve and orifice). Simplified mathematical models based on classical thermodynamic and inviscid theories were used to remove complexity and enhance the utility of the program. We examined the results of each program qualitatively for validate each component modeling.

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Off-Design Performance Prediction of a Gas Turbine Engine (가스터빈 기관의 탈설계점 해석)

  • Kang, D.J.;Ryu, J.W.;Jung, P.S.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.7 s.94
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    • pp.1851-1863
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    • 1993
  • A procedure for the prediction of the off-design performance of a gas turbine engine is proposed. The system performance at off-design speed is predicted by coupling the thermodynamic models of a compressor and a turbine. The off-design performance of a compressor is obtained using the stage-stackimg method, while the Ainlay-Mathieson method is used for a turbine. The procedure is applied to a single-shaft gas turbine and its predictability is found satisfactory. The results also show that the net work output increases with the increase of the turbine inlet temperature, while the thermal efficiency is marginal. The maximum thermal efficiency at design point is obtained between the highest pressure ratio and design pressure ratio.

The prediction of performance, exhaust emissions and EGR effect of a spark ignition engine by cycle simmulation and experimental method (스파아크 점화기관의 사이클 시뮬레이션과 실험적 방법에 의한 성능, 배출가스, EGR효과의 예측에 관한 연구)

  • 정용일;성낙원
    • Journal of the korean Society of Automotive Engineers
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    • v.8 no.2
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    • pp.31-42
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    • 1986
  • The prediction of performance, exhaust emissions and EGR effect is made by the SI engine cycle simulation. In this simulation several models are employed - two zome, thermodynamic combustion, mass fraction burned, heat transfer, chemical equilibrium, chemical kinetics for NOx, laminar flame speed for ignition delay. The chemical species in burned gas considered are 13 species-CO$_{2}$, CO, $O_{2}$, H$_{2}$O, H$_{2}$,OH, H, O, N$_{2}$, NO$_{2}$, N, Ar - and the cylinder pressure, burned and unburned zone temperature and composition of gas are calculated at each crank angle through the compression, ignition delay, combustion and expansion process. To check the validity of the model, experimental study is done for measuring emissions, combustion pressure and engine output. The predicted values for pressure and emissions show qualitative agreement with the measured data and the EGR effect also shows similar tendency.

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Investigation on the Self-Pressurization in Cryogenic Liquid Storage System (극저온 유체 저장 시스템의 압력 증가에 대한 연구)

  • Seo, Man-Su;Kim, Young-Kwon;In, Se-Hwan;Jeong, Sang-Kwon
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.142-147
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    • 2008
  • This paper reports an analysis of self-pressurization in a closed cryogenic liquid storage system and its comparison with experimental data using liquid nitrogen. Partial equilibrium model(PEM), revised thermodynamic analysis of homogeneous model, has been applied for the pressurization in a closed tank. The vapor and liquid bulk temperature and the liquid-vapor interface temperature are separately calculated as their own representative values in this analysis. The analysis results of the partial equilibrium model are compared with the experimental data and other preceding homogeneous temperature models for validation.

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New GGNMOS I/O Cell Array for Improved Electrical Overstress Robustness

  • Pang, Yon-Sup;Kim, Youngju
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.13 no.1
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    • pp.65-70
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    • 2013
  • A 0.18-${\mu}m$ 3.3 V grounded-gate NMOS (GGNMOS) I/O cell array for timing controller (TCON) application is proposed for improving electrical overstress (EOS) robustness. The improved cell array consists of 20 GGNMOS, 4 inserted well taps, 2 end-well taps and shallow trench isolation (STI). Technology computer-aided design (TCAD) simulation results show that the inserted well taps and extended drain contact gate spacing (DCGS) is effective in preventing EOS failure, e.g. local burnout. Thermodynamic models for device simulation enable us to obtain lattice temperature distributions inside the cells. The peak value of the maximum lattice temperature in the improved GGNMOS cell array is lower than that in a conventional GGNMOS cell array. The inserted well taps also improve the uniformity of turn-on of GGNMOS cells. EOS test results show the validity of the simulation results on improvement of EOS robustness of the new GGNMOS I/O cell array.

A Study on the Application of Ecological Structural Dynamic Modelling (생태 모델링기법으로서 동적구조모형의 고찰)

  • Kim, Jwa-Kwan
    • Journal of Environmental Impact Assessment
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    • v.13 no.4
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    • pp.213-222
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    • 2004
  • Exergy is defined as the amount of work (entropy-free energy) a system can perform when it is brought into thermodynamic equilibrium with its environment. Exergy measures the distance from the inorganic soup in energy terms. Therefore, exergy can be considered as fuel for any system that converts energy and matter in a metabolic process. The aim of this study is to introduce structural dynamic modelling which is based on maximum exergy principle. Especially, almost ecological models couldn't explain algal succession until now. New model (structural dynamic model) is anticipated to predict or explain the succession theory. If the new concept using maximum exergy principle is used, algal succession can be explained in many actual cases. Therefore, It is estimated that structural dynamic model using maximum exergy principle might be a excellent tool to understand succession of nature from now on.

Highly efficient adsorptive removal of uranyl ions from aqueous solutions using dicalcium phosphate nanoparticles as a superabsorbent

  • Saghatchi, Hadis;Ansari, Reza;Mousavi, H. Zavvar
    • Nuclear Engineering and Technology
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    • v.50 no.7
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    • pp.1112-1119
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    • 2018
  • Dicalcium phosphate nanoparticles (DCP-NPs) was synthesized chemically and used for adsorptive removal of uranyl ions from aqueous solutions in a batch system. A commercial grade of DCP (monetite) was also employed for comparison. The synthesized and commercial adsorbents (S-DCP and C-DCP) were characterized by FT-IR, SEM and XRD techniques. The investigation of adsorption isotherms indicated that the maximum adsorption capacities ($q_m$) for C-DCP and S-DCP were 714.3 and $666.7mg\;g^{-1}$ (at 293 K), respectively. The experimental kinetics were well-described by the pseudo-second-order kinetic and the equilibrium data were fitted with both Langmuir and Freundlich adsorption models. Thermodynamic studies indicated that the adsorption of uranyl ions on the monetite surface was a spontaneous exothermic process. The exhausted adsorbents could be regenerated by washing with $0.10mol\;L^{-1}$ NaOH.

Characteristics of Isotherm, Kinetic, and Thermodynamic Parameters for Reactive Blue 4 Dye Adsorption by Activated Carbon (활성탄에 의한 Reactive Blue 4 염료의 흡착에 대한 등온선, 동력학 및 열역학적 특성)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.26 no.2
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    • pp.122-130
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    • 2020
  • The isotherm, kinetic, and thermodynamic parameters of reactive blue 4 adsorbed by activated carbon were investigated for activated carbon dose, pH, initial concentration, contact time, and temperature data. The adsorption of the RB 4 dye by activated carbon showed a concave shape in which the percentage of adsorption increased in both directions starting from pH 7. The isothermal adsorption data were applied to Langmuir, Freundlich, and Temkin isotherms. Both Freundlich and Langmuir isothermal adsorption models fit well. From determined Freundlich separation factor (1/n = 0.125 ~ 0.232) and Langmuir separation factor (RL = 1.53 ~ 1.59), adsorption of RB 4 by activated carbon could be employed as an effective treatment method. The constant related to the adsorption heat (BT = 2.147 ~ 2.562 J mol-1) of Temkin showed that this process was physical adsorption. From kinetic experiments, the adsorption process followed the pseudo second order model with good agreement. The results of the intraparticle diffusion model showed that the inclination of the first straight line representing the surface diffusion was smaller than that of the second straight line representing the intraparticle pore diffusion. Therefore, it was confirmed that intraparticle pore diffusion is the rate-controlling step. The negative Gibbs free energy change (ΔG = -3.262 ~ -7.581 kJ mol-1) and the positive enthalpy change (ΔH = 61.08 kJ mol-1) indicated the spontaneous and endothermic nature of the adsorption process, proving this process to be spontaneous and endothermic.

Adsorption Characteristics of Brilliant Green by Coconut Based Activated Carbon : Equilibrium, Kinetic and Thermodynamic Parameter Studies (야자계 입상 활성탄에 의한 brilliant green의 흡착 특성 : 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.25 no.3
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    • pp.198-205
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    • 2019
  • The adsorption equilibrium, kinetic, and thermodynamic parameters of brilliant green adsorbed by coconut based granular activated carbon were determined from various initial concentrations ($300{\sim}500mg\;L^{-1}$), contact time (1 ~ 12 h), and adsorption temperature (303 ~ 323 K) through batch experiments. The equilibrium adsorption data were analyzed by Langmuir, Freundlich, Temkin, Harkins-Jura, and Elovich isotherm models. The estimated Langmuir dimensionless separation factor ($R_L=0.018{\sim}0.040$) and Freundlich constant ($n^{-1}=0.176{\sim}0.206$) show that adsorption of brilliant green by activated carbon is an effective treatment process. Adsorption heat constants ($B=12.43{\sim}17.15J\;mol^{-1}$) estimated by the Temkin equation corresponded to physical adsorption. The isothermal parameter ($A_{HJ}$) by the Harkins-Jura equation showed that the heterogeneous pore distribution increased with increasing temperature. The maximum adsorption capacity by the Elovich equation was found to be much smaller than the experimental value. The adsorption process was best described by the pseudo second order model, and intraparticle diffusion was a rate limiting step in the adsorption process. The intraparticle diffusion rate constant increased because the dye activity increased with increases in the initial concentration. Also, as the initial concentration increased, the influence of the boundary layer also increased. Negative Gibbs free energy ($-10.3{\sim}-11.4kJ\;mol^{-1}$), positive enthalpy change ($18.63kJ\;mol^{-1}$), and activation energy ($26.28kJ\;mol^{-1}$) indicate respectively that the adsorption process is spontaneous, endothermic, and physical adsorption.

Evaluation of high-velocity impact welding's interfacial morphology between Cu and CP-Ti using SPH numerical analysis method (SPH 해석기법을 이용한 Cu와 CP-Ti 고속 충돌 접합 단면의 형상학적 평가)

  • Park, Ki Hwan;Kang, Beom Soo;Kim, Jeong
    • Journal of Aerospace System Engineering
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    • v.13 no.2
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    • pp.34-42
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    • 2019
  • The existence of different thermodynamic properties results in various undesirable effects, such as thermal deformation and residual stress, in heat-welding processes. The solid-state junction, by using explosive or electromagnetic forces, i.e., high-velocity impact welding without employing heat is advantageous in joining materials with different thermodynamic properties. In the solid-state junction, the joining is performed within a short time, a high velocity and large deformations are accompanied by interfacial surfaces. The numerical analysis models play an important role in the understanding of the mechanism of high-velocity impact welding. However, in the analysis of high velocity and large deformations, the conventional Lagrangian method has low reliability due to the occurrence of entanglements. In this study, high-velocity impact welding between Cu and CP-Ti with different thermodynamic properties was performed using a un-gridded numerical method, SPH (Smoothed Particle Hydrodynamics), and interfacial morphology occurred. As a result of the analysis, the interfacial morphology was confirmed and the compared degree of shape (straight, vortex), period, length, and so on appeared differently depending on the relationship between the parameters (impact angle and speed).