• 한국유체기계학회 논문집
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• 제3권3호
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• pp.25-30
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• 2000

Thermodynamic method of pump performance measurement calculates pump efficiency and flowrate by measuring fluid temperature increase and pressure rise through the pump. The theory of this method is investigated and precise comparison experiment with classical hydraulic method was conducted to verify the accuracy. Classical hydraulic pump performance measurement results and Yatesmeter results based on the thermodynamic method showed good agreement in measured performance.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.256-260
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• 2003

A computer program to calculate thermodynamic properties of oxygen is developed. Procedures for the calculation is briefly discussed. The program calculates unknown thermodynamic properties fixing the state with two independent input properties. If input value by user is inappropriate, it displays an error message. In addition user can change units with easy. The program developed in this work can be utilized to calculate parameters required for the simulation and design of an equipment using oxygen.

• 한국주조공학회지
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• 제41권5호
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• pp.445-453
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• 2021

다양한 합금계에 대한 계산열역학은 CALPHAD 기법으로 잘 알려져있다. 실험적으로 측정된 열역학 특성들을 활용하여 각 상에 대한 Gibbs 에너지 모델 파라미터들을 구하여, 주로 실험적으로 측정되지 못한 영역에 대한 예측이나 실험 결과에 대한 열역학 해석에 활용되고 있다. 본 연구에서는 내열 주조 합금 (IN-657)이 장시간 사용 후에 일정 영역에서 파괴되는 현상의 열역학적 해석을 위해 Ni-Cr-Nb-C 사원계 시스템의 열역학 모델링을 수행하였고, Cr 함량에 따른 시스템의 안정상, 온도에 따른 상분율 및 Ni₂Cr상의 long range ordering 파라미터를 계산하였고 실험결과와 비교하였다. 계산된 열역학 물성들은 실험으로 보고된 파괴온도 영역 및 해당 영역에서 생성된 안정상에 대한 결과를 잘 설명한다. CALPHAD 기법을 통한 열역학 모델링은 다양한 주조 합금의 열역학적 거동을 해석하고 예측하는데 유용하게 사용될 수 있을 것으로 기대된다.

• The Korean Journal of Ceramics
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• 제7권1호
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• pp.11-15
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• 2001

A thermodynamic assessment for the ZrO$_2$-TiO$_2$ system has been conducted. An optimal thermodynamic data set for this system is evaluated by the CALPHAD(CALculation of PHAse Diagram) method applied to experimental phase diagram and thermodynamic data. The liquid is described by ionic liquid model with two sublattices. The solubilities of the solid phases, tetragonal ZrO$_2$ and TiO$_2$(rutile), were described by subregular substitutional model with one sublattice. Two compounds, ZrTiO$_4$ and ZrTi$_2$O$_6$, are modeled as stoichiometric compounds.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2007년도 Proceedings of ISRS 2007
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• pp.179-182
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• 2007

COMS (Communication, Ocean and Meteorological Satellite) is a geosynchronous satellite and has been developing by KARI and Astrium for Ka-band communication, ocean observation and meteorological observation. COMS Chemical Propulsion System (CPS) uses a bipropellant propulsion subsystem, which is applied for transferring COMS from GTO to GEO (mission orbit) and implementing station-keeping manoeuvres. In this paper COMS CPS is briefly introduced for understanding. A few of mathematical thermodynamic modelings of bipropellant propulsion system in literatures are reviewed and authors has studied those models for developing a computer program, which predicts variations of thermodynamic properties such as temperature and pressure histories in the helium pressurant tank, MMH propellant tank and NTO propellant tank during LAE firing and on-orbit manoeuvrings. The CPS thermodynamic model may be used to compute pressurant and propellant masses and to size tank volumes.

• Bulletin of the Korean Chemical Society
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• 제7권6호
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• pp.448-453
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• 1986

Two contributions to the activation barrier of the $S_N2$ reaction, intrinsic and thermodynamic, are discussed in connection with the predictive power of various rate-equilibrium relationships. It has been shown that the PES models can only give correct predictions of changes in structure and energy of the transition state if the activation barrier is dictated by the thermodynamic factor. We concluded that the identity and dissociative $S_N2$ reactions are dominated by the intrinsic component while associative $S_N2$ reactions are predominantly of thermodynamic controlled. Thus in the former cases, the PES models fail, whereas in the latter cases predictions based on the intrinsic factor, the quantum mechanical models, fail. Finally in a general case of equal contributions by thermodynamic and intrinsic factors, the $SN_2$ reaction proceeds by a synchronous process with zero net charge on the reaction center, for which predictions of substituent effects will be the same as for the intrinsic control case.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2008년 영문 학술대회
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• pp.243-246
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• 2008

This paper is to consider analytical thermodynamic modeling of bipropellant propulsion system. The objective of thermodynamic modeling is to predict thermodynamic conditions such as pressures, temperatures and densities in the pressurant tank and the propellant tank in which heat and mass transfer occur. In this paper also it shows analytic equations that calculate the evolution of ullage volume and interface areas. Since the ullage interface areas are time-varying,(the liquid propellant volume decreases as the rocket engine is firing; the change of ullage volume correspond to the change of liquid propellant volume) for a numerical convenience non-dimensionalized correlations are commonly used in most literatures with limitations; a few percentages of inherent error. The analytic equations are derived from analytic geometry, subsequently without inherent error. Those equations are important to calculate the heat transfer areas in the heat transfer equations. It presents the comparison result of both analytic equations and correlation method.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2008년도 춘계종합학술대회 A
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• pp.205-208
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• 2008

수치해석에서는 온도, 압력, 비체적, 엔탈피, 엔트로피 등의 수치값이 필요하다. 그런데 증기표의 대부분의 열역학적 성질들은 측정된 값이기 때문에 기본적으로 측정 오차를 가지고 있다. 본 연구에서는 압력 기준의 물의 포화 상태에 대해, 난수를 발생시켜 적절한 크기로 조절한 다음 원래의 성질들에 더하여 인위적으로 노이즈가 포함된 데이터를 만들었다. 이 데이터를 신경회로망과 스플라인 보간법으로 함수 근사를 하였다. 해석 결과 신경회로망이 2차 스플라인 보간법보다 훨씬 더 적은 백분율 오차를 보였으며 이로부터 신경회로망이 측정 오차의 영향을 적게 받는 함수 근사에 적절한 방법임을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제22권6호
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• pp.641-643
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• 2001

• 한국수소및신에너지학회논문집
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• 제31권1호
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• pp.41-48
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• 2020

The present study discussed the thermodynamic analysis of the hydrogen liquefaction process to build a hydrogen liquefaction pilot plant with a small capacity (0.5 ton/day). A 2-stage Brayton cycle utilizing LNG/LN2 cold energy was suggested to be built in Korea for the hydrogen liquefaction pilot plant with a small capacity. Thermodynamic analysis on the effect of various variables on the efficiency of hydrogen liquefaction process was performed. As a result, the CASE in which the ortho-para conversion catalyst was infiltrated inside the heat exchanger showed the best process efficiency. Finally, thermodynamic analysis was performed on the effect of turbo expander compression ratio on the hydrogen liquefaction process and it was confirmed that an optimal turbo expander compression ratio exists.