• Journal of Advanced Marine Engineering and Technology
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• 제28권6호
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• pp.962-971
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• 2004

This paper has dealt with thermo-physical properties of microencapsulated phase change material slurry as a latent heat storage material having a low melting point. The measured results of the thermo-physical properties of the test microencapsulated phase change material slurry, those are, density, specific heat, thermal conductivity and viscosity, were discussed for the temperature region of solid and liquid phases of the dispersion material (paraffin). The measurements of these properties of microencapsulated phase change material slurry have been carried out by using a specific-gravity meter, a water calorimeter, a differential scanning calorimeter(DSC), a transient hot wire method and rotating type viscometer, respectively. It was clarified that the additional properties law could be applied to the estimation of the density and specific heat of microencapsulated phase change material slurry and also the Euckens equation could be applied to the estimation of the thermal conductivity of this slurry.

• 한국분말재료학회지
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• 제18권6호
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• pp.568-574
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• 2011

As operating temperatures of engines or turbines continually increase for higher efficiency, significant amounts of researches have been focused on finding new materials, which would be alternatives to conventional yttria-stabilized zirconia (YSZ) for thermal barrier coatings (TBCs). In this study, phase evolution and thermo-physical properties of $La_2(Zr_{1-x}Hf_x)_2O_7$ pyrochlore systems are investigated for TBC applications. $La_2(Zr_{1-x}Hf_x)_2O_7$ systems are comprised by selecting $La^{3+}$ as A-site ions and $Zr^{4+}/Hf^{4+}$ as B-site ions in $A_2B_2O_7$ pyrochlore structures. For the developed phases in $La_2(Zr_{1-x}Hf_x)_2O_7$ compositions, thermo-physical properties such as thermal conductivity, thermal expansion coefficient are examined. The potential of these $La_2(Zr_{1-x}Hf_x)_2O_7$ compositions for TBC application is also discussed.

• Korean Chemical Engineering Research
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• 제48권1호
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• pp.93-97
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• 2010

본 연구에서는 수정된 T-history 법을 사용하여 백신 또는 의약품들의 수송 시 냉매로 사용될 수 있는 $0{\sim}15^{\circ}C$의 상전이 온도를 갖는 유기 상전이 소재들과 이중 두 물질의 혼합물들의 열용량, 잠열, 비열과 같은 열 물성을 측정하였다. 순수한 파라핀들을 측정한 결과, 각 물질들의 상전이 온도를 고려하여 최적의 냉각 속도를 유지하며 측정을 하는 것이 열물성의 신뢰성을 향상시킬 수 있음을 알 수 있었고, 특히 혼합물의 열 물성 측정에 적용할 경우, 수정된 T-history 법의 사용은 기존의 DSC 분석에 사용하는 시료의 양이 소량이므로 유발될 수 있는 결과의 부정확성 등의 문제점을 해결하는데 기여할 수 있음을 알 수 있었다.

• 한국분말재료학회지
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• 제22권6호
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• pp.420-425
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• 2015

Rare-earth zirconates, such as lanthanum zirconates and gadolinium zirconates, have been intensively investigated due to their excellent properties of low thermal conductivity as well as chemical stability at high temperature, which can make these materials ones of the most promising candidates for next-generation thermal barrier coating applications. In this study, three compositions, lanthanum/gadolinium zirconates with reduced rare-earth contents from stoichiometric $RE_2Zr_2O_7$ compositions, are fabricated via solid state reaction as well as sintering at $1600^{\circ}C$ for 4 hrs. The phase formation, microstructure, and thermo-physical properties of three oxide ceramics are examined. In particular, each oxide ceramics exhibits composite structures between pyrochlore and fluorite phases. The potential of lanthanum/gadolinium zirconate ceramics for TBC applications is also discussed.

• 한국분말재료학회지
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• 제17권2호
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• pp.148-153
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• 2010

Thermal barrier systems have been widely investigated over the past decades, in order to enhance reliability and efficiency of gas turbines at higher temperatures. Yttria-stabilized zirconia (YSZ) is one of the most leading materials as the thermal barriers due to its low thermal conductivity, thermodynamic stability, and thermal compatibility with metal substrates. In this work, rare-earth oxides with pyrochlore phases for thermal barrier systems were investigated. Pyrochlore phases were successfully formed via solid-state reactions started from rare-earth oxide powders. For the heat-treated samples, thermo-physical properties were examined. These rare-oxide oxides showed thermal expansion of $9{\sim}12{\times}10^{-6}/K$ and thermal conductivity of 1.2~2.4 W/mK, which is comparable with the thermal properties of YSZ.

• 한국결정성장학회지
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• 제20권3호
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• pp.125-132
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• 2010

For typical governing dimensionless parameters of Ar = 5, Pr = 1.16, Le = 0.14, Pe = 3.57, Cv = 1.02, $Gr_s=2.65{\times}10^6$, the effects of thermo physical properties such as a molecular weight, a binary diffusivity coefficient, a partial pressure of component B on solutally buoyancy-driven convection (solutal Grashof number $Gr_s=2.65{\times}10^6$) are theoretically investigated for further understanding and insight into an essence of solutal convection occurring in the vapor phase during the physical vapor transport of a $Hg_2Cl_2-N_2$ system. The solutally buoyancy-driven convection is significantly affected by any significant disparity in the molecular weight of the crystal components and the impurity gas of nitrogen. The solutal convection in a vertical orientation is found to be more suppressed than a tenth reduction of gravitational accelerations in a horizontal orientation. For crystal growth parameters under consideration, the greater uniformity in the growth rate is obtained for either solutal convection mode in a vertical orientation or thermal convection mode in horizontal geometry. The growth rate is also found to be first order exponentially decayed for $10{\leq}P_B{\leq}200$ Torr.

• Journal of Mechanical Science and Technology
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• 제17권11호
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• pp.1756-1766
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• 2003

Numerical modeling is carried out to investigate forced convective heat transfer to near-critical water in developing laminar flow through a circular tube. Due to large variations of thermo-physical properties such as density, specific heat, viscosity, and thermal conductivity near thermodynamic critical point, heat transfer characteristics show quite different behavior compared with pure forced convection. With flow acceleration along the tube unusual behavior of heat transfer coefficient and friction factor occurs when the fluid enthalpy passes through pseudocritical point of pressure in the tube. There is also a transition behavior from liquid-like phase to gas-like phase in the developing region. Numerical results with constant heat flux boundary conditions are obtained for reduced pressures from 1.09 to 1.99. Graphical results for velocity, temperature, and heat transfer coefficient with Stanton number are presented and analyzed.

• 한국식품과학회지
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• 제20권6호
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• pp.827-833
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• 1988

본 연구는 식품의 동결시간에 영향을 미치는 요인에 대해 비교 검토하고. 시료 두께에 따른 동결시간 예측 모델을 유도하기 위해 정지공기식 동결법을 이용하여 피조개 등 4종의 시료에 대하여 실험하였다. 그 결과, 시료의 두께가 두꺼울수록, 표면열전달계수 및 초기온도에 의한 영향은 상당히 급증하였으며, 표면열전달계수의 값이 낮을수록 시료 두께에 미치는 영향은 크며. $150W/m^2^{\circ}C$ 이상에서는 동결시간에 미치는 영향이 거의 유사하게 나타났다. 또한 각 시료에 있어 초기 빙결점이 낮을수록 초기 수분함량이 많을수록, 밀도가 높을수록 동결시간이 길게 나타났고. 열적 물성치의 영향은 밀도, 수분함량, 비열 및 열전도도의 순으로 나타났다. 그리고 시료 초기온도, 초기 빙결점, 동결매체 온도에 따른 시료 두께별 동결 시간을 예측할 수 있는 중직선 회귀방정식을 유도한 결과 실험치와 비교하여 ${\pm}5%$의 오차를 보여 주었다.

• 한국세라믹학회지
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• 제51권6호
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• pp.554-559
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• 2014

Gadolinium zirconate, $Gd_2Zr_2O_7$, is one of the most promising candidates for replacing yttira-stabilized zirconia (YSZ) in thermal barrier coating (TBC) applications due to its low thermal conductivity and chemical stability at high temperature. In this study, rare-earth zirconate ceramics in the $GdO_{1.5}-ZrO_2$ system with reduced gadolinia contents were fabricated via solid-state reaction as well as hot-pressing at $1800^{\circ}C$. The phase formation, microstructure, and thermo-physical properties of these oxides were examined. The potential application of $GdO_{1.5}-ZrO_2$ ceramics for TBC was also discussed.

• Advanced Composite Materials
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• 제18권2호
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• pp.153-166
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• 2009

A matrix method for evaluating effective electro-magneto-thermo-elastic properties of a generally anisotropic multilayered composite is presented. Physical variables are categorized into two groups: one that satisfies the continuity across the interface between layers and another that satisfies an average inter-layer compatibility (which is also exact). The coupled electro-magneto-thermo-elastic constitutive equation is accordingly reassembled into submatrices, which leads to the derivation of concise and exact matrix expressions for effective properties of a multilayered composite having the coupled physical effects. Comparing the results for a purely elastic multiplayer with those from other theoretical approaches validates the developed method. Examples are given for a PZT-graphite/epoxy composite and a $BaTiO_3-CoFe_2O_4$ multiplayer which exhibit piezo-thermoelastic and magnetoelectric properties, respectively. The result shows how a strong magnetoelectric effect can be achieved by combining piezoelectric and piezomagnetic materials in a multilayered structure. The magnetoelectric coefficient of the $BaTiO_3-CoFe_2O_4$ multiplayer is compared with those for fibrous and particulate composites fabricated with the same constituents.