• Journal of Korean Society of Environmental Engineers
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• v.31 no.1
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• pp.21-28
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• 2009

Physico-chemical characteristics of the Ca-based and Na-based dry sorbents were compared using thermo-gravimetric analysis (TGA) and temperature programmed desorption (TPD) methods. The studied characteristics were thermal stability, sulfur dioxide ($SO_2$) absorption capacity and absorption rate at $250^{\circ}C$ which is a typical temperature before a fabric filter, and $SO_2$ absorption capacity at an ambient temperature. Calcium hydroxide ($Ca(OH)_2$) started to decompose into calcium oxide (CaO) at $390^{\circ}C$ and completed at 480~$500^{\circ}C$, showing 76% of an original $Ca(OH)_2$ weight. Sodium bicarbonate ($NaHCO_3$) also converted to sodium carbonate ($Na_2CO_3$) between $95^{\circ}C$ and $190^{\circ}C$, decreasing the weight to 63% of its initial weight. Among four sorbents tested at $250^{\circ}C$, sodium carbonate had the highest capacity, absorbing 0.35 g $SO_2$/g sorbent. Calcium oxide and calcium hydroxide followed that showing 0.156 g and 0.065 g $SO_2$ absorption per absorbent respectively. Ca-based absorbents showed slower rate than sodium carbonate because of initial stagnant step. However, calcium hydroxide caught more $SO_2$ than sodium carbonate at ambient temperature. From this work, it can be concluded that Ca-based absorbent is a proper sorbent for $SO_2$ treatment at low temperature and sodium carbonate, at high temperature.

• Economic and Environmental Geology
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• v.47 no.6
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• pp.625-633
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• 2014

The Aquistore project is the world's first commercial capture, transportation, utilization and storage project of post-combustion $CO_2$ from a coal-fired thermo electric power plant, and the proposed storage is a saline aquifer at a depth of about 3,500 m. Deep saline aquifer, compared to hydrocarbon reservoir, provides the great volumetric potential for storage of $CO_2$ anywhere in the world, therefore the research results from the project may be exported globally to other sites. Geological $CO_2$ storage characterization for saline aquifer instead of hydrocarbon reservoir needs to estimate the geophysical properties of subsurface geology. This study calculated the geophysical property of water-saturated formation by applying amplitude variation analysis developed from oil and gas exploration. We correlated horizon tops at the well logs to seismic traveltime of 1,815 and 1,857 ms as Winnipeg and Deadwood formations. Gradient analysis from seismic traces showed correlation coefficient of 45 - 81 % on amplitude variation with respect to incident angle. Crossplot of intercept and gradient shows the inverse proportional trend which represents typical water saturated sediments. Product attribute of intercept and gradient described the base of wet sediment. Poisson's ratio change attribute increased at the top of target area satisfying with wet sediment and decreased at the top of basement in a dry rock bed.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.2
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• pp.155-162
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• 2008

Inventories to be disposed of, reference turnup, and source terms for CANDU spent fuel were evaluated for geological disposal system design. The historical and projected inventory by 2040 is expected to be 14,600 MtU under the condition of 30-year lifetime for unit 1 and 40-year lifetime for other units in Wolsong site. As a result of statistical analysis for discharge burnup of the spent fuels generated by 2007, average and stand deviation revealed 6,987 MWD/MtU and 1,167, respectively. From this result, the reference burnup was determined as 8,100 MWD/MtU which covers 84% of spent fuels in total. Source terms such as nuclide concentration for a long-term safety analysis, decay heat, thermo-mechanical analysis, and radiation intenity and spectrum was characterized by using ORIGEN-ARP containing conservativeness in the aspect of decay heat up to several thousand years. The results from this study will be useful for the design of storage and disposal facilities.

• Polymer(Korea)
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• v.28 no.3
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• pp.211-217
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• 2004

The sol to gel transition of aqueous solution of block copolymers consisting of methoxy poly (ethylene glycol) (MPEG) and biodegradable polyesters such as $\varepsilon$-caprolactone and L-lactide was investigated as a function of temperature. MPEG-PCL was prepared by ring opening polymerization of $\varepsilon$-caprolactone in the presence of HClㆍEt$_2$O as monomer activator at room temperature. Also, MPEG-PLLA was prepared by ring opening polymerization of L-lactide in the presence of stannous octoate at 115$^{\circ}C$. The properties of block copolymers were investigated by $^1$H-NMR, IR, and GPC as well as the observation of thermo sensitive phase transition in aqueous solution. As the hydrophobic block length increased, the sol to gel transition temperature increased and curve of that steepen to lower concentration. To confirm the gel formation at body temperature, we observed the formation of gel in the mice body after injection of 20 wt% aqueous solution of each block copolymer. After surging, we investigated the gelation in mice. The results obtained in this study confirmed the feasibility as biomaterials of injectable implantation for controlled release of drug and protein delivery.

• Journal of the Korean Wood Science and Technology
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• v.40 no.1
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• pp.10-18
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• 2012

A high airtightness is required for the residential spaces constructed recently to save cooling and heating energy through improving insulation performance. Because the chances to release steam formed by human activity in building and inflow of water vapor in outdoor air to residential space are reduced, the natural humidity control performance of interior materials has become more important. In this study, hygroscopic performance of thermo-physically treated wood (Pinus koraiensis) was estimated. At various relative humidity condition, the water vapor adsorption and desorption rates of wooden materials were measured as well as equilibrium moisture content. Effects of roughness and surface microstructure as physical factors and functional groups as chemical factors on the hygroscopicity were analyzed. It is expected that the results from this study and further study of measuring moisture generation in residential spaces could contribute to install a system for evaluating the hygrothermal performance of wooden building.

• Land and Housing Review
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• v.12 no.3
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• pp.109-119
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• 2021

Global warming caused by greenhouse gas emissions has rapidly increased abnormal climate events and geotechnical engineering hazards in terms of their size and frequency accordingly. Biopolymer-based soil treatment (BPST) in geotechnical engineering has been implemented in recent years as an alternative to reducing carbon footprint. Furthermore, thermo-gelating biopolymers, including agar gum, gellan gum, and xanthan gum, are known to strengthen soils noticeably. However, an explicitly detailed evaluation of the correlation between the factors, that have a significant influence on the strengthening behavior of BPST, has not been explored yet. In this study, machine learning regression analysis was performed using the UCS (unconfined compressive strength) data for BPST tested in the laboratory to evaluate the factors influencing the strengthening behavior of gellan gum-treated soil mixtures. General linear regression, Ridge, and Lasso were used as linear regression methods; the key factors influencing the behavior of BPST were determined by RMSE (root mean squared error) and regression coefficient values. The results of the analysis showed that the concentration of biopolymer and the content of clay have the most significant influence on the strength of BPST.

• Asian-Australasian Journal of Animal Sciences
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• v.32 no.6
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• pp.826-833
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• 2019

Objective: This study was performed to evaluate whether hot temperature and rumen-protected fat (RPF) supplementation affect growth performance, rumen characteristics, and serum metabolites in growing stage of Korean cattle steers. Methods: Twenty Korean cattle steers ($230.4{\pm}4.09kg$ of body weight [BW], $10.7{\pm}0.09months$ of age) were divided into a conventional control diet group (n = 10) and a 0.8% RPF supplementation group (n = 10). Steers were fed 1.5% BW of a concentrate diet and 4 kg of tall fescue hay for 16 weeks (July 10 to August 6 [P1], August 7 to September 3 [P2], September 4 to October 1 [P3], October 2 to 30 [P4], of 2015). Results: The mean temperature-humidity index (THI) was higher (p<0.001) in P1 (76.8), P2 (76.3), and P3 (75.9) than in P4 (50.9). The mean THI of P1-3 were within the alert heat stress (HS) category range according to previously reported categories for feedlot cattle, and the mean THI of P4 was under the thermo-neutral range. Neither month nor RPF supplementation affected (p>0.05) average daily gain and gain to feed ratio. Month and RPF supplementation affected concentrations of glucose, albumin, and high-density lipoprotein (HDL); those of albumin and glucose tended to decrease (p<0.10), but HDL concentration increased (p<0.01) by RPF supplementation. Neither month nor RPF affected (p>0.05) ruminal pH, $NH_3-N$, and volatile fatty acid concentrations, whereas the C2:C3 ratio was affected (p<0.05) by month. Conclusion: Korean cattle may not have been significantly affected by alert HS during the growing stage. Growth performance was higher during hotter months, although some changes in blood metabolites were observed. The RPF supplementation affected some blood lipids and carbohydrate metabolites but did not affect growth performance.

• Korean Journal of Heritage: History & Science
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• v.37
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• pp.267-284
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• 2004

As an initial step to understand the transitions in Korean bronze technology the present study has examined metallurgical microstructures of 8 artifacts excavated from the Silla Wang-Gyong site in Kyongju. Important trends have been found in alloy compositions and also in manufacturing processes. In the design of alloys, the Sn content was apparently changing toward the peritectic point, 22 mass %, of the Cu-Sn phase diagram while the Pb addition was intentionally avoided. This trend in composition was found accompanied by the introduction, subsequent to casting, of such special thermo-mechanical treatments as quenching and forging in artifact manufacture. In addition, the Sn content in alloys containing a significant amount of As was relatively low and no evidence of forging was observed in them. The use of quenching and forging and the rejection of Pb and As from alloys are all necessary requirements if the brittle nature of high Sn alloys is to be overcome in bronze working. This paper will show that the Wang-Gyong era corresponds to that of innovations leading to the technical climax in Korean bronze tradition, which has been maintained up to the present.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.7
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• pp.353-362
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• 2019

Thermodynamic analysis of cascade refrigeration systems has attracted considerable research attention. On the other hand, a system evaluation based on thermodynamic analyses of the individual parts, including the evaporator, condenser, intercooler, expansion valve, etc., has received less attention. In this study, performance analysis was conducted on a cascade refrigeration system, which has an individual cooling and refrigeration evaporator, and equips the intercooler and air-cooled condenser in a series in a lower cycle. The thermo-fluid design was then performed on the major components of the system - upper condenser, lower condenser, cooling evaporator, refrigeration evaporator, intercooler, compressor, electronic expansion valve - of 15 kW refrigeration, and 8 kW cooling capacity using R-410A. A series of simulations were conducted on the designed system. The change in outdoor temperature from 26 C to 38 C resulted in the cooling capacity of the lower evaporator remaining approximately the same, whereas it decreased by 9% at the upper evaporator and by 63% at the intercooler. The COP decreased with increasing outdoor temperature. In addition, the COP of the cycle with the intercooler operation was higher that of the cycle without the intercooler operation. Furthermore, the increase in the upper condenser size by two fold increased the upper evaporator by 4%. On the other hand, the lower evaporator capacity remained the same. The COP of the upper cycle increased with increasing upper condenser size, whereas that of the lower cycle remained almost the same. When the size of the lower condenser was increased 2.8 fold, the intercooler capacity increased by 8%, whereas those of upper and the lower evaporator remained approximately the same. Furthermore, the COP of the lower cycle increased with an increase in the lower condenser. On the other hand, the change of the upper condenser was minimal.

• Journal of Digital Convergence
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• v.19 no.3
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• pp.245-251
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• 2021

This study was to investigate the effect of the new surface treatment method of zirconia on the shear bond strength with resin cement. The zirconia specimens were classified according to the surface treatment. CON: non-treatment, HF: 10 minutes exposure to 9% HF, ZS15: Apply 15% ZrO2 slurry, ZS30: Apply 30% ZrO2 slurry, ZS50: Apply 50% ZrO2 slurry. The resin cement was layered on the surface treated zirconia, and the shear bond strength between the zirconia and the resin cement was measured after thermo-cycling. The statistical methods for shear bond strength were Kruskal-Wallis test, Mann-Whitney U test, and Bonferroni correction(α=.05/10=.005). ZS15, ZS30, and ZS50 groups treated with zirconia slurry showed higher shear bond strength than CON and HF groups(p<.05/10=.005). Within the limits of this study, the surface treatment using zirconia slurry increased the shear bond strength with resin cement. The new surface treatment method complements and improves the limitations of the adhesion of zirconia, so that various clinical applications of zirconia can be expected.