• 제목/요약/키워드: Thermal-structure Stability

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등온가열 수평원관내 융해과정동안의 열적 불안정성 (Thermal instability during the melting process in an isothermally heated horizontal cylinder)

  • 정재동;유호선;이준식
    • 대한기계학회논문집B
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    • 제20권6호
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    • pp.2046-2056
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    • 1996
  • The constrained melting inside an isothermally heated horizontal cylinder has been repeatedly investigated in many studies only for the moderate Rayleigh numbers. This study extends the range of Rayleigh numbers to systematically investigate the transition during melting processes, especially focusing on the complex multi-cellular flow pattern and thermal instability. The enthalpy-porosity formulation, with appropriate source terms to account for the phase change, is employed. For low Rayleigh numbers, initially developed single-cell base flow keeps the flow stable. For moderate Rayleigh numbers, even small disturbances in balance between thermal buoyance force and viscous force result in branched flow structure. For high Rayleight numbers, Benard type convection is found to develop within a narrow gap between thee wall and the unmelted solid. The marginal Rayleigh number and the corresponding wave number are in excellent agreement with those from linear stability theory.

One-step Physical Method for Synthesis of Cu Nanofluid in Ethylene Glycol

  • Bac, L.H.;Yun, K.S.;Kim, J.S.;Kim, J.C.;Rhee, C.K.
    • 한국분말재료학회지
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    • 제17권6호
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    • pp.464-469
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    • 2010
  • The Cu nanofluid in ethylene glycol was prepared by electrical explosion of wire, a novel one-step method. The X-ray diffraction, field emission scanning electron microscope and transmission electron microscope were used to study the properties of Cu nanoparticles. The results showed that the nanoparticles were consisted of pure face-centered cubic structure and near spherical shape with average grain size of 65 nm. Ultraviolet-visible spectroscopy (UV-Vis) confirmed Cu nanoparticles with a single absorbance peak of Cu surface plasmon resonance band at 600 nm. The nanofluid was found to be stable due to high positive zeta potential value, +51 mV. The backscattering level of nanofluid in static stationary was decreased about 2% for 5 days. The thermal conductivity measurement showed that Cu-ethylene glycol nanofluid with low concentration of nanoparticles had higher thermal conductivity than based fluid. The enhancement of thermal conductivity of nanofluid at a volume fraction of 0.1% was approximately 5.2%.

Why Are Cool Structures in the Universe Usually Filamentary?

  • 송인혁;최광선;이시백;전홍달
    • 천문학회보
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    • 제44권1호
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    • pp.48.4-48.4
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    • 2019
  • Small-scale shear flows are ubiquitous in the universe, and astrophysical plasmas are often magnetized. We study the thermal condensation instability in magnetized plasmas with shear flows in relation to filamentary structure formation in cool structures in the universe, representatively solar prominences and supernova remnants. A linear stability analysis is extensively performed in the framework of magnetohydrodynamics (MHD) with radiative cooling, plasma heating and anisotropic thermal conduction to find the eigenfrequencies and eigenfunctions for the unstable modes. For a shear velocity less than the Alfven velocity of the background plasma, the eigenvalue with the maximum growth rate is found to correspond to a thermal condensation mode, for which the density and temperature variations are anti-phased (of opposite signs). Only when the shear velocity in the k-direction is near zero, the eigenfunctions for the condensation mode are of smooth sinusoidal forms. Otherwise each eigenfunction for density and temperature is singular and of a discrete form like delta functions. Our results indicate that any non-uniform velocity field with a magnitude larger than a millionth of the Alfven velocity can generate discrete eigenfunctions of the condensation mode. We therefore suggest that condensation at discrete layers or threads should be quite a natural and universal process whenever a thermal instability arises in magnetized plasmas.

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Crystal Structure and Thermal Stability Study on Tetrabutylammonium Hexamolybdate [n-Bu4N]2[Mo6O19](TBAM)

  • Zhao, Pu Su;Zhao, Zhan Ru;Jian, Fang Fang;Lu, Lu De
    • 대한화학회지
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    • 제47권6호
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    • pp.553-558
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    • 2003
  • $[n-Bu_4N]_2[Mo_6O_{19}]$(TBAM)의 결정구조는 X-ray 분석기로 결정되었다. 그 결정은 monoclinic 계이며 ${\alpha}$=16.314(5), b=17.288(5), c=17.776(4) ${\AA}$, ${\beta}$=101.47(3) 그리고 z=4의 결정파라미터를 갖는 sapce group 이 C2/c인 결정이다 $[Mo_6O{19}]^{2-}$ 음이온에서, Mo 원자는 팔면체의 여섯 개 모서리를 차지하며 각 Mo 원자는 여석개의 산소원자에 배위되어 찌그러진 팔면체 배위 기하학을 지닌다. Mo-Ot(말단기), Mo-Ob(연결된), 그리고Mo-Oc(중앙)의 평균거리는 각각 1.680 ${\AA}$, 1.931 ${\AA}$ 및 2.325 ${\AA}$ 이다. $[n-Bu_4N]^+$ 양이온에서 N원자는 약간 찌그러진 사면체 모형을 갖는다. 격자안에서 폭 넓은 C-H ${\cdots}$ O 수소결합이 있으며, 그것에 의하여 분자들을 연결하고 결정구조를 안정화 한다. 열분석에 의하여 제목의 열적분핸ㄴ 두개의 전이가 일어나며 356.0와 803.5 $^{\circ}$에서 각각 무게를 잃는다. 그리고 분해된 생성물은 $Mo_2O_2$로 추정된다. 따라서, 제목의 화합물은 높은 열적 안정성을 갖는다.

각종 편성소재에 따른 스포츠양말의 위생성과 형태안정성에 관한 연구 (A Study of Sports Socks Varying Knitted Fabrics on Hygienic and stability Properties)

  • 이명자;김칠순
    • 복식문화연구
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    • 제7권5호
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    • pp.165-176
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    • 1999
  • The purpose of this study was to evaluate the effect of various knitted fabrics of sports socks on their properties of hygiene and stability. Seventeen men\`s sports socks to represent five groups with different fiber content, knit structure, yarn fineness, and finishing were used. Properties of hygiene and stability of socks were determined. The results were as follows ; 1. Evaluation of Water, vapor and heat transport properties in socks with varing fiber content showed that cotton 100% socks had the highest drop absorbency, wickability, water absorbency and water retention. Polypropylene 100% socks had an excellent wickability and moisture permeability. Acrylic blend socks had the highest thermal resistance. 2. The greatest knit stretch and knit growth of socks having lower power were found to be with cotton 100% socks had the lowest stretch. Acrylic blend socks had a excellent stretch but low fabric growth, which could give a good fir sensation during wear. 3. The commerical antimicrobial finished socks showed excellent durability after repeated cycles of laundering. 4. Length and width shrinkages were found in all laundered samples during initial cycles due to rearrangement by mechanical relaxation. Shrinkages showed no further changes and reached equilibriums after 5 cycles. Cotton 100% or cotton blend socks showed lower dimensional stability than other socks during fabric care.

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알루미나 나노 Particle의 분산 평가 및 최적화

  • 박국효;신효순;여동훈;홍연우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.251-251
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    • 2009
  • The generation of energy and the cooling of system using thermoelectric semiconductor material have been in spotlight. Thermoelectric effect increases with the decrease of the thermal conductivity. In the thermoelectric devices, thermal conductivity is related to phonon scattering. Therefore, few studies have been conducted in the thermoelectric materials dispersed nano oxide particle for increasing the phonon scattering. However, core-shell structure which nano particle disperses in solvents and then which thermoelectric materials coated on the nano oxide particles has not been reported. In this study, we selected commercial nano powder such as $Al_2O_3$. This nano particle was about 20nm and was crushed aggregate by mechanical treatment. We have developed the effect of the dispersant and the solvent. The properties of particles were evaluated by SEM, TEM, particle size analysis, and BET. Dispersion and dispersion stability were evaluated by electronic microscope and turbidity.

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Correlation defects of macrostructure with morphology of BGO crystals grown by low thermal gradient Czochralski technique

  • Shlegel, V.N.;Shubin, Yu.V.;Ivannikova, N.V.
    • 한국결정성장학회지
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    • 제13권1호
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    • pp.1-4
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    • 2003
  • In the present work we consider morphological structure of the faces of BGO crystals grown by Czochralski technique under the conditions of low temperature gradient (0.1~1 deg/cm) and interconnection between the morphological features of faces at the crystallization front and the formation of defects within the crystal volume. It is demonstrated that the {112} faces retain stability while the growing surface deviates from the crystallographic (112) plane up to 1 degree. At larger deviation, the region of the stable facet growth passes either to the region of macrosteps or to the region of normal growth. depending on conditions.

열교환법 공정에서 고/액 계면의 형태에 미치는 자연대류의 영향 (Effects of natural convection on the melt/solid interface shape in the HEM process)

  • 왕종회;김도현
    • 한국결정성장학회지
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    • 제7권1호
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    • pp.41-46
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    • 1997
  • 열교환법에 의한 결정 성장에서 용융액 내에서의 유동장의 변화와 대류 열전달이 고/액 계면의 형태와 위치에 미치는 영향에 대해 고찰하였다. 비록 도가니 내의 온도분포가 안정한 구조라도 고/액 계면이 반구형태를 가지기 때문에 안정화가 깨어지게 되고, 반경방향 온도 기울기에 의한 용응액 내에서의 자연대류 흐름이 무시할 수 없을 정도로 발생한다. 대류 열전달이 존재하는 경우에 최대 휨도는 대류 열전달이 존재하지 않은 경우에 비해 감소하며, 열교환법에서의 정확한 열전달 공정모사를 위해 대류 열전달이 고려되어야 한다.

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Preparation of New Polyenaminonitriles Containing Cyclic and Methylene Units and Their Thermal Properties

  • Cho, Jeong-Hyun;Gong, Myoung-Seon
    • Macromolecular Research
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    • 제8권5호
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    • pp.209-214
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    • 2000
  • Polyenaminonitriles containing cycloaliphatic and aliphatic units were prepared by interfacial or solution polymerization reaction of p-bis(1-chloro-2,2-dicyanovinyl) benzene (1) with 4-aminobenzyl-amine, 1-(2-aminoethyl)piperazine, 2-(aminomethyl)pyrrolidine and 4-(aminomethyl)piperidine. The chemical structure of the polymers was confirmed through a syntheses of the model compound. The resulting polymers possessed inherent viscosities of 0.29∼0.62 dL/g and they were easily soluble in polar aprotic solvents and common organic solvents. Thermal properties of the polymers such as curability and stability were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and infrared spectroscopy. The polymers exhibited a large exotherm in DSC analyses and underwent a curing reaction around 340-370$\^{C}$ to form insoluble materials. The polymers showed 70-80% residual weight at 600 $\^{C}$ under nitrogen.

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Synthesis and electroluminescent properties of highly twisted anthracene derivatives

  • Park, Sung-Jin;Park, Jong-Won;Jung, Sung-Ouk;Kim, Yun-Hi;Kwon, Soon-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.533-536
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    • 2008
  • The anthracene derivatives were synthesized by Suzuki coupling reaction. The thermal, optical and electronic properties of MNAn and BIPAn were investigated by thermogravimetric analysis (TGA), differential scanning calorimetry(DSC), UV-vis absorption, photoluminescen ce spectroscopies, and cyclic voltammetry. The materials exhibit high thermal stability and high per formance in EL devices.

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