• Title/Summary/Keyword: Thermal stability and mechanical analysis

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A Study on Stratified Charge GDI Engine Development - Combustion Analysis according to the Variations of Injection Pressure and Load - (연소실 직접분사식 성층급기 가솔린기관 개발에 관한 연구 - 연료분사압력과 부하변동에 따른 연소특성 해석 -)

  • Lee, Sang Man;Jeong, Young Sik;Chae, Jae Ou
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.9
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    • pp.1317-1324
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    • 1998
  • In general, DI gasoline engine has the advantages of higher power output, higher thermal efficiency, higher EGR tolerance and lower emissions due to the operation characteristics of increased volumetric efficiency, compression ratio and ultra-lean combustion scheme. In order to apply the concept of stratified charge into direct injection gasoline engine, some kinds of methodologies have been adapted in various papers. In this study, a reflector was adapted around the injector nozzle to apply the concept of stratified charge combustion which leads the air-fuel mixture to be rich near spark plug. Therefore, the mixture near the spark plug is locally rich to ignite while the lean mixture is wholly introduced into the combustion chamber. The characteristics of combustion is analyzed with the variations of fuel injection pressure and load in a stratified -charge direct injection single cylinder gasoline engine. The obtained results are summarized as follows ; 1. The MBT spark timing approached to TDC with the increase of load on account of the increase of evaporation energy, but has little relation with fuel injection pressure. 2. The stratification effects are apparent with the increase of injection pressure. It is considered by the development of secondary diffusive combustion and the increase of heat release of same region, but proceed rapidly than diesel engine. Especially, in the case of high pressure injection (l70bar) and high load (3.0kgf m), the diffusive combustion parts are developed excessively and results in the decrease of peak pressure than in the case of middle load. 3. The index of engine stability, COVimep value, is drastically decreased with the increase of load. 4. To get better performance of DI gasoline engine development, staged optimizaion must be needed such as injection pressure, reflector, intake swirl, injection timing, chamber shape, ignition system and so on. In this study, the I50bar injection pressure is appeared as the optimum.

A Study on the Shielding Analysis in Vitrification Facility of Low-and Intermediate Level Radioactive Wastes ($\cdot$저준위 방사성폐기물 유리화 시설의 차폐해석에 관한 연구)

  • 이창민;이건재;지평국;박종길;하종현;송명재
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.524-531
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    • 2003
  • The usefulness of vitrification technology for low- and intermediate- level radioactive wastes was demonstrated because of high volume reduction, mechanical and chemical stability of final waste forms. Thus, a construction of the commercial vitrification plant Is currently promoted. Due to the high radiation level of the waste, shielding analysis has to be carried out for safe design in a vitrification facility. Because there has been no experience in the construction and operation of the vitrification facility in Korea, in this study, in order to get some information for help the detailed design and plan for operation in vitrification facility, shielding analysis for each facility in pilot plant is carried out by using source term from established study. For the selection of the shielding material, concrete was chosen compared to the lead because of economic advantage, weight consideration, and thermal resistance.

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A STUDY ON THE PHYSICAL PROPERTIES AND VOLUMETRIC STABILITY OF SR-IVOCAP RESIN SYSTEM (SR-Ivocap resin system의 물리적 특성과 체적 안정성에 관한 연구)

  • Eun, Sung-Sik;Kweon, Hyeog-Sin;Chung, Chae-Heon
    • The Journal of Korean Academy of Prosthodontics
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    • v.36 no.3
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    • pp.453-467
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    • 1998
  • This study helps to clarify conflicting reports by comparing the physical properties and accuracy of complete denture processed by the pack and press technique, continuous- pressure injection technique(SR-Ivocap system) and Mark press technique. The 6 different specimens have been evaluated using the SEM, Impact test, DSC (Differential Scanning Calorimetry) and DMTA (Dynamic Mechanical Thermal Analysis). Each sample was made of SR-Ivocap resin and QC-20 resin by different processing methods. The results were as follows ; 1. As the result of the observation on the fracture surface of resin by use of SEM, sample SR-Ivocap resin cured by continuous pressure injection method showed the most homogeneous structure. This is why molecules in SR-Ivocap resin have no orientation. 2. As the result of the Impact test in order to measure the deformity, fracture energy and impact resistance of resin, the samples with QC-20 acrylic resin and SR-Ivocap resin cured by continuous pressure injection method were exellent. 3. In consequence of measuring ${\alpha}$-glass transition temperature by use of DSC on the basis of temperature change, the glass transition temperatures of sample QC-20 resin cured by pack and press method and sample SR-Ivocap resin cured by continuous pressure injection method were very similar. Thus volumetric stability could not be evaluated only by glass transition temperature. 4. In comparing volumetric stability data by DMTA, the glass transition temperature(Tg) showed $137.88^{\circ}C$ at sample QC-20 resin cured by pack and press method and $139.78^{\circ}C$ at sample SR-Ivocap resin cured by continuous pressure injection method. Therefore sample SR-Ivocap resin cured by continuous pressure injection method seems to be superior to sample QC-20 resin cured by pack and press method in the dimensional stability at high temperature. 5. In comparing storage modulus data by DMTA, the storage modulus of sample SR-Ivocap resin cured by continuous pressure injection method was higher than that of sample QC-20 resin cured by pack and press method. So. sample SR-Ivocap resin cured by continuous pressure injection method seems to be superior to sample QC-20 resin cured by pack and press method in impact strength.

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Preparation of Organophilic MMT Modified with Various Aromatic Amines and Characterization of Polyimide Nanocomposite Films (다양한 구조의 방향족 아민으로 개질된 친유기성 MMT의 제조와 이를 이용한 폴리이미드 나노복합필름의 특성)

  • Han, Seung San;Choi, Kil-Yeong;Im, Seung Soon;Kim, Yong Seok
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.177-182
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    • 2006
  • In this work, we have prepared organophilic MMT having thermal stability by ion exchange reaction of various aromatic ammonium salts with MMT containing sodium ion. The organic modifiers having alkyl side chains and amine functional group were successfully synthesized by effectively introducing the surfaces of MMT via ion exchange reaction to form organophilic MMTs with a view to improve the reactivity and thermal stability. The WAXD patterns of organophilic MMT showed the more increased gallery spacing by $3.3{\AA}$ than that of the pristine MMT and also the onset of initial decomposition of organophilic MMT was $275^{\circ}C$ as determined by a thermogravimetric analysis. The polyimide (PI) nanocomposite films based on poly(amic acid) and organophilic MMT were prepared by a solution blending followed by cyclodehydration reaction. We have investigated the dispersity of organophilic MMTs in PI matrix by using WAXD and the effect of the organophilic MMT content on the mechanical properties of PI nanocomposite films was studied.

The Effect of Diamine and Solvent on The Synthesis of Polyimides and Their Film Properties (폴리이미드의 합성과 필름의 물성에 미치는 디아민과 용매의 효과)

  • Choi, Hyeong-Ki;Lee, Ho-Sik;Chung, Chang-Nam;Kim, Jum-Sik
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.253-261
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    • 1991
  • Polyamic acids, precursor polymers of polyimides have been obtained by the solution polycondensation of benzophenone tetracarboxylic dianhydride (BTDA) with 4, 4'-diamino diphenyl methane (MDA) and/or 3, 3'-dimethyl benzidine (OTB). The reaction was carried in two solvent systems such as m-cresol and m-cresol/xylene mixture. The results of TGA analysis showed that the polyimide films had good thermal stability with the initial decomposition temperature ranging from $540^{\circ}$ to $590^{\circ}$. According to DSC analysis of polymers, the glass transition temperature was over $340^{\circ}$. Polyimide film samples, showed good mechanical and electrical properties, had over $16Kg/mm^2$ of tensile strength and about 200 KV/mm of dielectric breakdown voltage. The properties of the copolymer from MAD/OTB were better than those of the homopolymer from MDA. And the polymer synthesized in m-cresol had lower properties than that obtained in m-cresol/xylene.

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Accelerated Degradation Test and Failure Analysis of Rapid Curing Epoxy Resin for Restoration of Cultural Heritage (문화재 복원용 속(速)경화형 Epoxy계 수지의 가속열화시험 및 고장분석 연구)

  • Nam, Byeong Jik;Jang, Sung Yoon
    • Journal of Conservation Science
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    • v.33 no.6
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    • pp.467-483
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    • 2017
  • In this study, the degradation properties by temperature stress of $Araldite^{(R)}$ rapid-curing epoxy resin used for inorganic cultural heritages, was identified. The tensile and tensile shear strength of durability decreased for 12,624 hours at temperatures of $40{\sim}60^{\circ}C$. In terms of stability of external stress and temperature, the slow-curing epoxy was superior to the rapid-curing epoxy, and cultural heritage conservation plans should therefore consider the strength and stress properties of restoration materials. Color differences increased for 12,624 hours at temperatures of $40{\sim}60^{\circ}C$, and glossiness decreased. Both color and gloss stability were weak, which necessitates the improvement of optical properties. Thermal properties (weight loss, decomposition temperature, and glass transition temperature) of adhesives are linked to mechanical properties. Interfacial properties of the adherend and water vapor transmission rates of adhesives are linked to performance variation. For porous media (ceramics, brick, and stone), isothermal and isohumid environments are important. For outdoor artifacts on display in museums, changes in physical properties by exposure to varying environmental conditions need to be minimized. These results can be used as baseline data in the study of the degradation velocity and lifetime prediction of rapid-curing epoxy resin for the restoration of cultural heritages.

Studies on the Preparation of Conducting Composite Film by a Vapor Phase in situ Polymerization (전도성 복합필름의 기상중합과 특성에 대한 연구)

  • Park, Jun-Seo;Park, Jang-Woo
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.902-906
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    • 1999
  • Electrically conducting composite films were prepared by a vapor phase in situ polymerization of pyrrole in the methyl cellulose film containing a copper(II) perchlorate. Methylcellulose had high affinity to pyrrole and was used as a matrix polymer. Conducting polypyrrole was embedded in the methylcellulose film forming a conducting network and the conductivity of the composite films ranged $10^{-1}$ to $10^{-7}S/cm$. The conductivities of conducting composite films were dependent on the nature of the matrix polymers, concentration of oxidant and polymerization time. In situ polymerization of pyrrole was observed in the matrix polymer and confirmed by UV-vis spectra. From the results of the thermogravimetric analysis, the chemical oxidative polymerization of pyrrole in the matrix polymers did not give any negative effects on the thermal stability of the composite films. Electron micrograph of composites indicated good penetration of PPy in the matrix polymer. DMA suggested a certain degree of incompatibility of the polypyrrole in the composites.

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Performance Test of Isolator for Reaction Wheel Micro-Vibration (인공위성 반작용휠 미소진동 감쇠기의 성능 측정)

  • Oh, Shi-Hwan;Seo, Hyun-Ho;Yim, Jo-Ryeong;Rhee, Seung-Wu
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.376-379
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    • 2006
  • Reaction Wheel Assembly (RWA) is one of the major disturbance sources that have influence upon the Line of Sight (LOS) of payload. A micro-vibration induced by RWA is propagated through the satellite structure and decrease the LOS stability performance of payload. This effect shall be analyzed through the jitter analysis. If a requirement or specification of payload jitter level is found to be not satisfied according to the jitter analysis campaign, some modification or redesign should be done on the satellite structure or a couple of isolator should be attached on the RWA interface in order to reduce the transmitted vibration level of RWA. The purpose of ???RWA isolator test? is to roughly evaluate the performance of vibration suppression level with a passive RWA isolator made of rubber. For this test, actual RWA is used as a vibration source and a couple of cube-shaped rubber mount designed for satellite is used as a passive isolator. There may be several considerations in order to accommodate RWA isolator to spacecraft such as not only vibration reduction performance but also thermal conduction problem, mechanical size, RWA alignment problem, etc. But in this report the feasibility of RWA isolator is analyzed only in a vibration suppression point of view. As a result, high frequency vibration of RWA above 50Hz is perfectly attenuated with isolators, however, first harmonic components below 50Hz became larger due to the additional low frequency resonance modes of roll, pitch, yaw rigid body motion of RWA+bracket.

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Correlation between Microstructure and Mechanical Properties of the Additive Manufactured H13 Tool Steel (적층 제조된 H13 공구강의 미세조직과 기계적 특성간의 상관관계)

  • An, Woojin;Park, Junhyeok;Lee, Jungsub;Choe, Jungho;Jung, Im Doo;Yu, Ji-Hun;Kim, Sangshik;Sung, Hyokyung
    • Korean Journal of Materials Research
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    • v.28 no.11
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    • pp.663-670
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    • 2018
  • H13 tool steels are widely used as metallic mold materials due to their high hardness and thermal stability. Recently, many studies are undertaken to satisfy the demands for manufacturing the complex shape of the mold using a 3D printing technique. It is reported that the mechanical properties of 3D printed materials are lower than those of commercial forged alloys owing to micropores. In this study, we investigate the effect of microstructures and defects on mechanical properties in the 3D printed H13 tool steels. H13 tool steel is fabricated using a selective laser melting(SLM) process with a scan speed of 200 mm/s and a layer thickness of $25{\mu}m$. Microstructures are observed and porosities are measured by optical and scanning electron microscopy in the X-, Y-, and Z-directions with various the build heights. Tiny keyhole type pores are observed with a porosity of 0.4 %, which shows the lowest porosity in the center region. The measured Vickers hardness is around 550 HV and the yield and tensile strength are 1400 and 1700 MPa, respectively. The tensile properties are predicted using two empirical equations through the measured values of the Vickers hardness. The prediction of tensile strength has high accuracy with the experimental data of the 3D printed H13 tool steel. The effects of porosities and unmelted powders on mechanical properties are also elucidated by the metallic fractography analysis to understand tensile and fracture behavior.

A Study on Flammability and Mechanical Properties of HDPE/EPDM/Boron Carbide/Triphenyl Phosphate Blends with Compatibilizer (HDPE/EPDM/Boron Carbide/Triphenyl Phosphate 블렌드의 상용화제 첨가에 따른 난연성 및 기계적 물성 연구)

  • Shin, Bum-Sik;Jung, Seung-Tae;Jeun, Joon-Pyo;Kim, Hyun-Bin;Oh, Seung-Hwan;Kang, Phil-Hyun
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.549-554
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    • 2012
  • It was known that triphenyl phosphate wasn't homogeneously dispersed in HDPE/EPDM/boron carbide blends, which caused the decrease in mechanical properties. HDPE, EPDM, boron carbide, and triphenyl phosphate were blended with PE-g-MAH(polyethylene-graft-maleic anhydride) as a compatiblizer for improving the miscibility of triphenyl phosphate. Tensile strength of HDPE/EPDM/boron carbide blends decreased with increasing the contents of triphenyl phosphate for flammability. However, the mechanical properties of HDPE/EPDM/boron carbide/triphenyl phosphate blends increased by the addition of compatiblizer because triphenyl phosphate was homogeneously mixed in the blend system. The homogeneous dispersibility of triphenyl phosphate was confirmed by using scanning electron microscopy (SEM). Increased thermal stability and flammability derived from high miscibility of triphenyl phosphate were confirmed by the results of thermogravimetric analysis (TGA) and limiting oxygen index (LOI). A self-extinguishing HDPE/EPDM/boron carbide/triphenyl phosphate blend was successfully fabricated with more than 21% LOI.