• 제목/요약/키워드: Thermal reduction

검색결과 1,644건 처리시간 0.028초

Stoichiometry, Thermal Stability and Reducibility of Perovskite-Type Mixed Oxide LaBO$_3$ (B = Fe, Co, Ni)

  • Park, Il-Hyun;Lee, Hyung-Pyo
    • Bulletin of the Korean Chemical Society
    • /
    • 제9권5호
    • /
    • pp.283-288
    • /
    • 1988
  • The titled properties on reduction of the perovskite $LaBO_3$ (B = Fe, Co, Ni) have been investigated by means of temperature-programmed reduction, isothermal reduction and X-ray diffraction methods. Nominal composition of $LaFeO_{3.18},\;LaCoO_{3.00}\;and\;LaNiO_{2.92}$ are determined. Reduction reaction of these mixed oxides differed according to B-site transition metal and thermal stability on reduction decreased as following order: $LaFeO_{3.18}$ > $LaCoO_{3.00}$ > $LaNiO_{2.92}$. From the results of isothermal reaction, kinetics on reduction of the perovskite has been discussed in detail.

선택적 환원촉매장치(SCR)에서 밸브의 열해석에 관한 연구 (A Study on the Thermal Analysis of the Valve in the Selective Catalytic Reduction(SCR) System)

  • 최재욱;곽동기
    • 한국융합학회논문지
    • /
    • 제10권8호
    • /
    • pp.153-158
    • /
    • 2019
  • 현대사회에 이르며 발생한 환경오염으로 인해 산업 전반적인 환경규제가 강화되었다. 따라서 이러한 환경규제를 충족하기 위해 선택적 환원촉매장치(SCR)의 연구개발이 필요하다. 본 논문은 SCR 시스템의 핵심부품인 공압식 댐퍼 밸브(PDV)를 개발하기 위하여 열해석을 수행하였다. 열해석을 위해 우선적으로 재질의 물성치 검증을 실시하였다. 검증은 시편의 열물성시험과 열인장시험을 통해 하였으며 결과를 재질의 물성치에 보강하여 열해석의 신뢰성을 높이도록 하였다. 열해석은 유한 요소 프로그램(Ansys)를 사용하여 PDV가 갖는 사용 조건에 따라 적용된 총 3개 재질(SM400B, SS275, SB410)에서의 PDV가 보이는 열 특성을 확인하고자 하였으며, 이를 통해 PDV가 갖는 구조적 안정성을 확인하고자 하였다.

Thermal Stability of $MnOx-WO_3-TiO_2$ Catalysts Prepared by the Sol-gel Method for Low-temperature Selective Catalytic Reduction

  • 신병길;이희수
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2011년도 추계학술발표대회
    • /
    • pp.28.2-28.2
    • /
    • 2011
  • The selective catalytic reduction (SCR) of NOx by $NH_3$ is well known as one of the most convenient, efficient, and economical method to prevent NOx emission in flue gas from stationary sources. The degradation of the reactivity is the obstacle for its real application, since high concentrations of sulfur dioxide and thermal factor would deactivate the catalyst. It is necessary to develop high stability of catalysts for low-temperature SCR. Among the transition metal oxides, $WO_3$ is known to exhibit high SCR activity and good thermal stability. The $MnOx-WO_3-TiO_2$ catalysts prepared by sol-gel method with various $WO_3$ contents were investigated for low-temperature SCR. These catalysts were observed in terms of micro-structure and spectroscopy analyses. The $WO_3$ catalyst as a promoter is used to enhance the thermal stability of catalyst since it increases the phase transition temperature of $TiO_2$ support. It was found that the addition of tungsten oxides not only maintained the temperature window of NO conversion but also increased the acid sites of catalyst.

  • PDF

ICA based Thermal Source Extraction and Thermal Distortion Compensation for Machine Tools

  • Lee, Dong-Soo;Park, Jin-Young;Park, Doo-Hyun
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 제어로봇시스템학회 2002년도 ICCAS
    • /
    • pp.91.2-91
    • /
    • 2002
  • $\textbullet$ Machine tools $\textbullet$ Thermal distortion compensation $\textbullet$ Independent component analysis $\textbullet$ Temperature variable reduction $\textbullet$ Thermal distortion modeling $\textbullet$ Hardware Implementation $\textbullet$ Experiments

  • PDF

Optimal maintenance scheduling of pumps in thermal power stations through reliability analysis based on few data

  • Nakamura, Masatoshi;Kumarawadu, Priyantha;Yoshida, Akinori;Hatazaki, Hironori
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 제어로봇시스템학회 1996년도 Proceedings of the Korea Automatic Control Conference, 11th (KACC); Pohang, Korea; 24-26 Oct. 1996
    • /
    • pp.271-274
    • /
    • 1996
  • In this paper we made a reliability analysis of power system pumps by using the dimensional reduction method which over comes the problem due to unavailability of enpugh data in the actual systems under many different operational environments. Hence a resonable method was proposed to determine the optimum maintenance interval of given pump in thermal power stations. This analysis was based on an actual data set of pumps for over ten years in thermal power stations belonged to Kyushu Electric Power Company, Japan.

  • PDF

이부자리 보온력에 관한 연구(III) - 요의 보온력 - (Studies on the Thermal Insulation Effect of Bedding(III) - Thermal Insulation Effect of Underquilt -)

  • 이송자;성수광
    • 한국의류학회지
    • /
    • 제17권2호
    • /
    • pp.301-306
    • /
    • 1993
  • Since the underquilt has an important role of supporting the human body in sleeping, it needs to sustain ample degrees of hardness, elasticity, humidity absorption, and warmth retention property and also to have the two ergonimical requirements : It should not be too soft to allow human bodies to sink in, and that it should be comfortable for humans to tum over in sleeping. This study aims to investigate the effect of the thermal insulation of the variation in weight applied to the underquilt. For this purpose, six items were selected as filling materials for the underquilt : cotton, wool, silk, down, polyester, cotton/ployester. Various weights were applied to each of the underquilts to survey the reduction tendency of its thermal insulation effect. The results are as follow : 1. The Thermal insulation effect of each underquilt decreased in an exponetial function as the weight on the underquilt was increased. 2. The thermal reduction curves according to the load weight insrease were shown to be constant in shape regardless of the weight increase. 3. At the weight of more than $25kg/m^2$ the degree of the thermal insulation effect of each underquilt was found to be in order of down>cotton>silk>polyester>wool>cotton/ployester. 4. The variation in load weight applied to each underquilt was shown to be in reverse correlation with the thermal insulation effect. An estimated regression formula can be made on the data.

  • PDF

유동저항 감소유체를 운반유체로 한 파라핀 슬러리의 대류 열전달에 관한 연구 (Convective Heat Transfer of a Paraffin Slurry in a Drag Reducing Carrier Fluid)

  • 정동주;최은수
    • 설비공학논문집
    • /
    • 제13권12호
    • /
    • pp.1275-1281
    • /
    • 2001
  • Aqueous polymer solutions are known to have small pressure reduction. Paraffin slurries are known to have high thermal capacity. Paraffin particles are mixed into an aqueous polymer solution to make a new heat transfer fluid having high thermal capacity but low pressure reduction. The heat transfer characteristics of the new slurry was tested in a circular tube having a constant heat transfer boundary condition. The new slurry was found to have high Nusselt numbers as well as high thermal capacity and low pressure reduction in the laminar flow. The trends of the Nusselt numbers along the heating test section were studied for various heating conditions.

  • PDF

모의 사용후 핵연료를 이용한 질화물 핵연료 소결체 제조 (Fabrication of Nitride Fuel Pellets by Using Simulated Spent Nuclear Fuel)

  • 류호진;이재원;이영우;이정원;박근일
    • 한국분말재료학회지
    • /
    • 제15권2호
    • /
    • pp.87-94
    • /
    • 2008
  • In order to investigate a nitriding process of spent oxide fuel and the subsequent change in thermal properties after nitriding, simulated spent fuel powder was converted into a nitride pellet with simulated fission product elements through a carbothermic reduction process. Nitriding rate of simulated spent fuel was decreased with increasing of the amount of fission products. Contents of Ba and Sr in simulated spent fuel were decreased after the carbothermic reduction process. The thermal conductivity of the nitride pellet was decreased by an addition of fission product element but was higher than that of the oxide fuel containing fission product elements.

Optical and Dielectric Properties of Reduced SrTiO3 Single Crystals

  • Kang, Bong-Hoon
    • 한국세라믹학회지
    • /
    • 제48권4호
    • /
    • pp.278-281
    • /
    • 2011
  • The optical band gap energy for $SrTiO_3$ by reduction at high temperature was 3.15 eV. The reflectivity of reduced $SrTiO_3$ single crystals showed little variation, however, the reflectivity by the reduction condition had no effect. For the phonon mode at about 790 $cm^{-1}$, a blue-shift took place upon $N_2$ reduction and the decreased. However, a red-shift took place upon a $H_2-N_2$ reduction and the increased at the same phonon mode. With decreasing temperature the dielectric constant decreased rapidly. The thermal activation energies were 0.92-1.02 eV.

3D Noise Reduction 방법에 기반한 열 영상 잡음 감쇠에 관한 연구 (A Study of Thermal Imaging Noise Reduction based on 3D Noise Reduction Method)

  • 김명광;김영길
    • 한국정보통신학회:학술대회논문집
    • /
    • 한국해양정보통신학회 2009년도 춘계학술대회
    • /
    • pp.160-163
    • /
    • 2009
  • 최근 적외선 열 영상의 유용함이 발표되어감에 따라 이 기술에 대한 이해와 도입폭이 점진적으로 넓혀져 가고 있다. 국내는 물론 세계적으로 많은 제조, 개발 관련 업체들이 생겨나고 있으며, 업체들의 기술이 발전함에 따라 높은 온도 분해능과 해상도는 물론, 시스템 전체의 크기가 휴대가 가능할 정도로 소형화 되어가고 있는 추세이다. 이러한 열 영상 카메라에서 중요한 역할을 하는 적외선 열 감지 센서에서는 주변 온도, 대상 온도, 표면 온도 등의 측정 오차 및 열상 측정 소자의 온도, Bias 불안정 등의 매우 다양한 원인으로 인한 잡음이 발생하기 쉽다. 이러한 다양한 잡음의 감소는 해상도 및 온도 분해능의 향상과 직결되므로, 잡음을 줄이기 위한 많은 연구가 도처에서 행해지고 있다. 본 논문은 이러한 노력의 일환으로써 각각의 잡음 원인을 규명하지 않고 최종 열 영상 출력물에서 인접 프레임들의 비교, 혼합 하여 제거하는 3D Noise Reduction 기술을 이용해 노이즈를 감쇠하는 방법에 대해 연구하였다.

  • PDF