• Title/Summary/Keyword: Thermal reduction

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Stoichiometry, Thermal Stability and Reducibility of Perovskite-Type Mixed Oxide LaBO$_3$ (B = Fe, Co, Ni)

  • Park, Il-Hyun;Lee, Hyung-Pyo
    • Bulletin of the Korean Chemical Society
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    • v.9 no.5
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    • pp.283-288
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    • 1988
  • The titled properties on reduction of the perovskite $LaBO_3$ (B = Fe, Co, Ni) have been investigated by means of temperature-programmed reduction, isothermal reduction and X-ray diffraction methods. Nominal composition of $LaFeO_{3.18},\;LaCoO_{3.00}\;and\;LaNiO_{2.92}$ are determined. Reduction reaction of these mixed oxides differed according to B-site transition metal and thermal stability on reduction decreased as following order: $LaFeO_{3.18}$ > $LaCoO_{3.00}$ > $LaNiO_{2.92}$. From the results of isothermal reaction, kinetics on reduction of the perovskite has been discussed in detail.

A Study on the Thermal Analysis of the Valve in the Selective Catalytic Reduction(SCR) System (선택적 환원촉매장치(SCR)에서 밸브의 열해석에 관한 연구)

  • Choi, Jae-Wook;Kwag, Dong-Gi
    • Journal of the Korea Convergence Society
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    • v.10 no.8
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    • pp.153-158
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    • 2019
  • The overall environmental regulations of the industry have been strengthened due to environmental pollution that occurred in modern society. Therefore, R&D of selective reduction catalyst (SCR) is needed to meet these environmental regulations. This paper carried out thermal analysis to develop the pneumatic damper valve (PDV), which is a key component of SCR system. For thermal analysis, verification of material properties was performed first. Verification was performed through the thermal properties test and the thermal tensile test of the specimen, and the results were reinforced with the material properties to enhance the reliability of the thermal analysis.The heat analysis was intended to identify thermal characteristics with PDV in total of three materials (SM400B, SS275, SB410) applied under the conditions of use of PDV, and to confirm the structural stability of the PDV.

Thermal Stability of $MnOx-WO_3-TiO_2$ Catalysts Prepared by the Sol-gel Method for Low-temperature Selective Catalytic Reduction

  • Sin, Byeong-Gil;Lee, Hui-Su
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.28.2-28.2
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    • 2011
  • The selective catalytic reduction (SCR) of NOx by $NH_3$ is well known as one of the most convenient, efficient, and economical method to prevent NOx emission in flue gas from stationary sources. The degradation of the reactivity is the obstacle for its real application, since high concentrations of sulfur dioxide and thermal factor would deactivate the catalyst. It is necessary to develop high stability of catalysts for low-temperature SCR. Among the transition metal oxides, $WO_3$ is known to exhibit high SCR activity and good thermal stability. The $MnOx-WO_3-TiO_2$ catalysts prepared by sol-gel method with various $WO_3$ contents were investigated for low-temperature SCR. These catalysts were observed in terms of micro-structure and spectroscopy analyses. The $WO_3$ catalyst as a promoter is used to enhance the thermal stability of catalyst since it increases the phase transition temperature of $TiO_2$ support. It was found that the addition of tungsten oxides not only maintained the temperature window of NO conversion but also increased the acid sites of catalyst.

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ICA based Thermal Source Extraction and Thermal Distortion Compensation for Machine Tools

  • Lee, Dong-Soo;Park, Jin-Young;Park, Doo-Hyun
    • 제어로봇시스템학회:학술대회논문집
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    • 2002.10a
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    • pp.91.2-91
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    • 2002
  • $\textbullet$ Machine tools $\textbullet$ Thermal distortion compensation $\textbullet$ Independent component analysis $\textbullet$ Temperature variable reduction $\textbullet$ Thermal distortion modeling $\textbullet$ Hardware Implementation $\textbullet$ Experiments

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Optimal maintenance scheduling of pumps in thermal power stations through reliability analysis based on few data

  • Nakamura, Masatoshi;Kumarawadu, Priyantha;Yoshida, Akinori;Hatazaki, Hironori
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10a
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    • pp.271-274
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    • 1996
  • In this paper we made a reliability analysis of power system pumps by using the dimensional reduction method which over comes the problem due to unavailability of enpugh data in the actual systems under many different operational environments. Hence a resonable method was proposed to determine the optimum maintenance interval of given pump in thermal power stations. This analysis was based on an actual data set of pumps for over ten years in thermal power stations belonged to Kyushu Electric Power Company, Japan.

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Studies on the Thermal Insulation Effect of Bedding(III) - Thermal Insulation Effect of Underquilt - (이부자리 보온력에 관한 연구(III) - 요의 보온력 -)

  • Lee, Song-Ja;Sung, Su-Kwang
    • Journal of the Korean Society of Clothing and Textiles
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    • v.17 no.2
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    • pp.301-306
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    • 1993
  • Since the underquilt has an important role of supporting the human body in sleeping, it needs to sustain ample degrees of hardness, elasticity, humidity absorption, and warmth retention property and also to have the two ergonimical requirements : It should not be too soft to allow human bodies to sink in, and that it should be comfortable for humans to tum over in sleeping. This study aims to investigate the effect of the thermal insulation of the variation in weight applied to the underquilt. For this purpose, six items were selected as filling materials for the underquilt : cotton, wool, silk, down, polyester, cotton/ployester. Various weights were applied to each of the underquilts to survey the reduction tendency of its thermal insulation effect. The results are as follow : 1. The Thermal insulation effect of each underquilt decreased in an exponetial function as the weight on the underquilt was increased. 2. The thermal reduction curves according to the load weight insrease were shown to be constant in shape regardless of the weight increase. 3. At the weight of more than $25kg/m^2$ the degree of the thermal insulation effect of each underquilt was found to be in order of down>cotton>silk>polyester>wool>cotton/ployester. 4. The variation in load weight applied to each underquilt was shown to be in reverse correlation with the thermal insulation effect. An estimated regression formula can be made on the data.

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Convective Heat Transfer of a Paraffin Slurry in a Drag Reducing Carrier Fluid (유동저항 감소유체를 운반유체로 한 파라핀 슬러리의 대류 열전달에 관한 연구)

  • 정동주;최은수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.12
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    • pp.1275-1281
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    • 2001
  • Aqueous polymer solutions are known to have small pressure reduction. Paraffin slurries are known to have high thermal capacity. Paraffin particles are mixed into an aqueous polymer solution to make a new heat transfer fluid having high thermal capacity but low pressure reduction. The heat transfer characteristics of the new slurry was tested in a circular tube having a constant heat transfer boundary condition. The new slurry was found to have high Nusselt numbers as well as high thermal capacity and low pressure reduction in the laminar flow. The trends of the Nusselt numbers along the heating test section were studied for various heating conditions.

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Fabrication of Nitride Fuel Pellets by Using Simulated Spent Nuclear Fuel (모의 사용후 핵연료를 이용한 질화물 핵연료 소결체 제조)

  • Ryu, Ho-Jin;Lee, Jae-Won;Lee, Young-Woo;Lee, Jung-Won;Park, Geun-Il
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.87-94
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    • 2008
  • In order to investigate a nitriding process of spent oxide fuel and the subsequent change in thermal properties after nitriding, simulated spent fuel powder was converted into a nitride pellet with simulated fission product elements through a carbothermic reduction process. Nitriding rate of simulated spent fuel was decreased with increasing of the amount of fission products. Contents of Ba and Sr in simulated spent fuel were decreased after the carbothermic reduction process. The thermal conductivity of the nitride pellet was decreased by an addition of fission product element but was higher than that of the oxide fuel containing fission product elements.

Optical and Dielectric Properties of Reduced SrTiO3 Single Crystals

  • Kang, Bong-Hoon
    • Journal of the Korean Ceramic Society
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    • v.48 no.4
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    • pp.278-281
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    • 2011
  • The optical band gap energy for $SrTiO_3$ by reduction at high temperature was 3.15 eV. The reflectivity of reduced $SrTiO_3$ single crystals showed little variation, however, the reflectivity by the reduction condition had no effect. For the phonon mode at about 790 $cm^{-1}$, a blue-shift took place upon $N_2$ reduction and the decreased. However, a red-shift took place upon a $H_2-N_2$ reduction and the increased at the same phonon mode. With decreasing temperature the dielectric constant decreased rapidly. The thermal activation energies were 0.92-1.02 eV.

A Study of Thermal Imaging Noise Reduction based on 3D Noise Reduction Method (3D Noise Reduction 방법에 기반한 열 영상 잡음 감쇠에 관한 연구)

  • Kim, Myung-kwang;Kim, Young-kil
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.05a
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    • pp.160-163
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    • 2009
  • 최근 적외선 열 영상의 유용함이 발표되어감에 따라 이 기술에 대한 이해와 도입폭이 점진적으로 넓혀져 가고 있다. 국내는 물론 세계적으로 많은 제조, 개발 관련 업체들이 생겨나고 있으며, 업체들의 기술이 발전함에 따라 높은 온도 분해능과 해상도는 물론, 시스템 전체의 크기가 휴대가 가능할 정도로 소형화 되어가고 있는 추세이다. 이러한 열 영상 카메라에서 중요한 역할을 하는 적외선 열 감지 센서에서는 주변 온도, 대상 온도, 표면 온도 등의 측정 오차 및 열상 측정 소자의 온도, Bias 불안정 등의 매우 다양한 원인으로 인한 잡음이 발생하기 쉽다. 이러한 다양한 잡음의 감소는 해상도 및 온도 분해능의 향상과 직결되므로, 잡음을 줄이기 위한 많은 연구가 도처에서 행해지고 있다. 본 논문은 이러한 노력의 일환으로써 각각의 잡음 원인을 규명하지 않고 최종 열 영상 출력물에서 인접 프레임들의 비교, 혼합 하여 제거하는 3D Noise Reduction 기술을 이용해 노이즈를 감쇠하는 방법에 대해 연구하였다.

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