• Title/Summary/Keyword: Thermal properties

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Effect of Thermal Aging on Electrical Properties of Low Density Polyethylene

  • Wang, Can;Xie, Yaoheng;Pan, Hua;Wang, Youyuan
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2412-2420
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    • 2018
  • The thermal degradation of low density polyethylene (LDPE) will accelerate the production of carbonyl groups (C=O), which can act as the induced dipoles under high voltage. In this paper, we researched the dielectric properties and space charge behavior of LDPE after thermal aging, which can help us to understand the correlation between carbonyl groups (C=O) and electrical properties of LDPE. The spectra results show that LDPE exhibit obvious thermooxidative reactions when the aging time is 35 days and the productions mainly contain carboxylic acid, carboxylic eater and carboxylic anhydride, whose amount increase with the increasing of aging time. The dielectric properties show that the real permittivity of LDPE is inversely proportional to temperature before aging and subsequently become proportional to temperature after thermal aging. Furthermore, both the real and imaginary permittivity increase sharply with the increasing of aging time. The fitting results of imaginary permittivity show that DC conductivity become more sensitive about temperature after thermal aging. On this basis, the active energies of materials calculated from DC conductivity increase first and then decrease with the increasing of aging time. In addition, the space charge results show that the heterocharges accumulated near electrodes in LDPE change to the homocharges after thermal aging and the mean volume charge density increase with the increasing of aging time. It is considered that the overlaps caused by electrical potential area is the main reason for the increase of DC conductivity.

Fiber Loading Effect on the Interlaminar, Mechanical, and Thermal Properties of Novel Lyocell/Poly(butylene succinate) Biocomposites (새로운 라이오셀/poly(butylene succinate) 바이오복합재료의 층간전단, 기계적, 열적 특성에 미치는 섬유함량의 영향)

  • Lee, Jae Young;Kim, Jin Myung;Cho, Donghwan;Park, Jong Kyoo
    • Journal of Adhesion and Interface
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    • v.10 no.2
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    • pp.106-112
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    • 2009
  • In the present work, novel biocomposites made with biodegradable Lyocell woven fabrics and poly (butylene succinate) were successfully fabricated for the first time. Lyocell/poly(butylene succinate) biocomposites with different fiber loadings of 0, 30, 40, 50 and 60 wt% were prepared by compression molding with a sheet interleaving manner. The effect of Lyocell fabric loading on the interlaminar shear strength, tensile and flexural properties, heat deflection temperature, thermal expansion behavior, and thermal stability of the biocomposites was investigated. The properties strongly depended on the fabric loading and the results were consistent with each other. It was demonstrated that the Lyocell fabrics played a remarkable role in improving the properties of poly(butylene succinate) resin by incorporating the fabrics into the resin. The greatest inter-laminar, tensile, flexural and thermal properties of the biocomposites were obtained with Lyocell fabrics of 50% by weight.

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A Study of Relations of Chain Lengths and Properties for Bifunctional linear DGEBF/Linear Amino (EDA, HMDA) Cure Systems (선형 이관능성 DGEBF/선형아민(EDA, HMDA) 경화계의 경화제 사슬길이와 물성과의 관계에 대한 연구)

  • Myung In-Ho;Lee Jae-Rock
    • Composites Research
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    • v.17 no.6
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    • pp.37-43
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    • 2004
  • To determine the effect of chain length and chemical structure of linear amine curing agents on thermal and mechanical properties, a standard bifunctional linear DGEBF epoxy resin was cured with EDA and HMDA having amine group at the both ends of main chain in a stoichiometrically equivalent ratio in condition of preliminary and post cure. From this work, the effect of linear amine curing agents on the thermal and mechanical properties is significantly influenced by numbers of carbon atoms of main chain. In contrast, the results show that the DCEBF/EDA system having two carbons had higher values in the thermal stability, density, shrinkage (%), grass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBF/HMDA system having six carbons, whereas the DGEBF/EDA cure system had relatively low values in maximum ekothermic temperature, maximum conversion of epoxide, thermal expansion coefficient than the DGEBF/HDMA cure system. These findings indicate that the packing capability (rigid property) in the EDA structure affects the thermal and mechanical properties predominantly. It shows that flexural fracture properties have a close relation to flexural modulus and strength.

Effect of Low Temperature Plasma Treatment on Wool Fabric Properties

  • Kan C. W.;Yuen C. W. M.
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.169-173
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    • 2005
  • Low temperature plasma (LTP) treatment was applied to wool fabric with the use of a non-polymerizing gas, namely oxygen. After the LTP treatment, the fabric properties including low-stress mechanical properties, air permeability and thermal properties, were evaluated. The low-stress mechanical properties were evaluated by means of Kawabata Evaluation System Fabric (KES-F) revealing that the tensile, shearing, bending, compression and surface properties were altered after the LTP treatment. The changes in these properties are believed to be related closely to the inter-fiber and inter-yam frictional force induced by the LTP. The decrease in the air permeability of the LTP-treated wool fabric was found to be probably due to the plasma action effect on increasing in the fabric thickness and a change in fabric surface morphology. The change in the thermal properties of the LTP-treated wool fabric was in good agreement with the above findings and can be attributed to the amount of air trapped between the yams and fibers. This study suggested that the LTP treatment can influence the final properties of the wool fabric.

Thermoelastic dynamic analysis of wavy carbon nanotube reinforced cylinders under thermal loads

  • Moradi-Dastjerdi, Rasool;Payganeh, Gholamhassan
    • Steel and Composite Structures
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    • v.25 no.3
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    • pp.315-326
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    • 2017
  • In this work, thermoelastic dynamic behavior of functionally graded carbon nanotube reinforced composite (FG-CNTRC) cylinders subjected to mechanical pressure loads, uniform temperature environment or thermal gradient loads is investigated by a mesh-free method. The material properties and thermal stress wave propagation of the nanocomposite cylinders are derived after solving of the transient thermal equation and obtaining of the time history of temperature field of the cylinders. The nanocomposite cylinders are made of a polymer matrix and wavy single-walled carbon nanotubes (SWCNTs). The volume fraction of carbon nanotubes (CNTs) are assumed variable along the radial direction of the axisymmetric cylinder. Also, material properties of the polymer and CNT are assumed temperature-dependent and mechanical properties of the nanocomposite are estimated by a micro mechanical model in volume fraction form. In the mesh-free analysis, moving least squares shape functions are used to approximate temperature and displacement fields in the weak form of motion equation and transient thermal equation, respectively. Also, transformation method is used to impose their essential boundary conditions. Effects of waviness, volume fraction and distribution pattern of CNT, temperature of environment and direction of thermal gradient loads are investigated on the thermoelastic dynamic behavior of FG-CNTRC cylinders.

Thermal, Mechanical Properties of LAS with the Addition of Mullite ($Li_2O-Al_2O_3-SiO_2$계 소지의 Mullite 첨가에 의한 열적, 기계적 특성에 관한 연구)

  • 최도문;유재근;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.5
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    • pp.381-388
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    • 1993
  • Due to the anisotropy of thermal expansion, LAS system which has low thermal expansion property is hard to obtain a dense sintered body. Therefore, the thermal expansion coefficient and the mechanical strength were decreased. In this study, mullite, which has good mechanical properties in high temperature and comparatively low thmeral expansion coefficient, was taken as a additive in LAS system. And then, sintering, thermal, and mechanical properties were investigated. The results are follows; When mullite is added in eucryptite composition (Li2O.Al2O3.2SiO2) of LAS system, the creation of liquid phase results in the densification of sintered body and the specimen sintered at 136$0^{\circ}C$ for 2 hours shows optimum sintering condition. With the addition of mullite in eucryptite composition, mechanical strength is increased by the control of grain growth. Especially, flexual strength of EM0 specimen was about double value than the basic composition. Thermal expansion coefficients of EM0 and EM15 specimens sintered at 136$0^{\circ}C$ were -8.23$\times$10-6/$^{\circ}C$ and -4.90$\times$10-6/$^{\circ}C$ in the temperature range of RT.~80$0^{\circ}C$. As the mullite content are increased, negative thermal expansion ratios are decreased.

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Thermal Properties of 0.9CaMgSi2O6-0.1MgSiO3 Glass-Ceramics

  • Jeon, Chang-Jun;Sun, Gui-Nam;Lee, Jong-Kyu;Ju, Han-Sae;Kim, Eung-Soo
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.111-117
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    • 2012
  • Dependencies of thermal properties on the crystallization behavior of $0.9CaMgSi_2O_6-0.1MgSiO_3$ glass-ceramics were investigated as a function of heat-treatment temperature from $750^{\circ}C$ to $950^{\circ}C$. The crystallization behavior of the specimens depended on the heat-treatment temperature, which could be evaluated by differential thermal analysis (DTA), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) analysis by the Rietveld-reference intensity ratio (RIR) combined procedure. With an increase of the heat-treatment temperature, the thermal conductivity and thermal diffusivity of the heat-treated specimens increased. These results could be attributed to the increase of crystallization with heat-treatment temperature. However, the specific heat capacity of the heat-treated specimens was not affected by the heat-treatment temperature. The thermal conductivities measured from $25^{\circ}C$ to $100^{\circ}C$ were also discussed for application to lighting-emitting diode (LED) packages and substrate materials.

A Study on the Mechanical, Thermal, Morphological, and Water Absorption Properties of Wood Plastic Composites (WPCs) Filled with Talc and Environmentally-Friendly Flame Retardants (친환경 난연제와 탈크를 첨가한 목재·플라스틱 복합재의 기계적, 열적, 형태학적 및 수분흡수 특성에 관한 연구)

  • Lee, Danbee;Kim, Birm-June
    • Journal of the Korea Furniture Society
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    • v.27 no.2
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    • pp.137-144
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    • 2016
  • Wood plastic composite (WPC) is a green composite made of wood flour and thermoplastics to provide better performance by removing the defects of both wood and plastics. However, relatively low thermal stability and poor fire resistance of wood and plastics included in WPC have been still issues in using WPC as a building material for interior applications. This study investigated the effect of environmentally-friendly flame retardants (EFFRs) on the mechanical, thermal, morphological, and water absorption properties of wood flour (WF)/talc/polypropylene (PP) composites in comparison with neat PP. The whole EFFRs-filled WF/talc/PP composites showed higher values in flexural strength, flexural modulus, and impact strength compared to neat PP. In thermal properties, aluminum hydroxide (AH)-filled composite showed a $36^{\circ}C$ reduction in maximum thermal decomposition temperature ($T_{max}$) compared to neat PP, but magnesium hydroxide (MH) played an important role in improving thermal stability of filled composite by showing the highest $T_{max}$. From this research, it can be said that MH has potentials in reinforcing PP-based WPCs with improvement of thermal stability.

Relationship Between Coefficient of Thermal Expansion and Glass Transition Temperature in Phosphate Glasses (인산염유리의 선팽창계수와 유리전이온도의 관계)

  • 전재삼;차명룡;정병해;김형순
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1127-1131
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    • 2003
  • Phosphate glasses known for low melting temperature glasses in electrical parts has been recently used in wide area with modification of thermal properties using alkali oxides. It is our purpose to find a correlation between thermal expansion coefficient, glass transition temperature and melting temperature through investigating thermal properties in P$_2$O$\sub$5/-SnO-ZnO-SiO$_2$/B$_2$O$_3$. As a result, the product of thermal expansion coefficient and the glass transition temperature in the glasses is found to be a constant value would be a unique value for knowing one of thermal properties.

Study on the Physical and Thermal Properties of Rice Kernels - Thermal Properties - (벼의 물리적(物理的) 및 열적(熱的) 특성(特性)에 관(関)한 연구(硏究) -열적(熱的) 특성(特性)에 관(関)하여-)

  • Koh, Hak Kyun;Noh, Sang Ha;Chung, Jong Hoon
    • Journal of Biosystems Engineering
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    • v.9 no.2
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    • pp.89-96
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    • 1984
  • This study was intended to search the thermal properties of rice which are necessary in preventing qualitative and quantitative losses in the drying and milling processes. First, the coefficient of cubical thermal expansion of brown rice was measured, which is required for analyzing the internal stress of rice, and then theoretical thermal and moisture stresses were calculated. The results are summarized as follows: 1. The coefficient of cubical thermal expansion of brown rice was about $2.81{\times}10^{-4}/^{\circ}C$ in the temperature range of $10^{\circ}C-60^{\circ}C$. 2. When the shape of brown rice was assumed to be a sphere or a cylinder, maximum thermal stress due to temperature change of $20^{\circ}C-60^{\circ}C$ was in the range of $25-100kg/cm^2$. And maximum moisture stress was in the range of $450-650kg/cm^2$ when the drying temperature was $35^{\circ}C$, initial and final moisture contents of brown rice were 20% and 14% (w.b.), and the moisture diffusion coefficient was assumed to be $6.79{\times}10^{-4}cm^2/hr$. 3. Consequently, it was concluded that crack formation in a rice kernel is mainly caused by moisture stress.

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