DOI QR코드

DOI QR Code

Thermal Properties of 0.9CaMgSi2O6-0.1MgSiO3 Glass-Ceramics

  • Jeon, Chang-Jun (Department of Materials Engineering, Kyonggi University) ;
  • Sun, Gui-Nam (Department of Materials Engineering, Kyonggi University) ;
  • Lee, Jong-Kyu (Department of Materials Engineering, Kyonggi University) ;
  • Ju, Han-Sae (Department of Materials Engineering, Kyonggi University) ;
  • Kim, Eung-Soo (Department of Materials Engineering, Kyonggi University)
  • Received : 2011.10.25
  • Accepted : 2012.01.19
  • Published : 2012.01.31

Abstract

Dependencies of thermal properties on the crystallization behavior of $0.9CaMgSi_2O_6-0.1MgSiO_3$ glass-ceramics were investigated as a function of heat-treatment temperature from $750^{\circ}C$ to $950^{\circ}C$. The crystallization behavior of the specimens depended on the heat-treatment temperature, which could be evaluated by differential thermal analysis (DTA), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) analysis by the Rietveld-reference intensity ratio (RIR) combined procedure. With an increase of the heat-treatment temperature, the thermal conductivity and thermal diffusivity of the heat-treated specimens increased. These results could be attributed to the increase of crystallization with heat-treatment temperature. However, the specific heat capacity of the heat-treated specimens was not affected by the heat-treatment temperature. The thermal conductivities measured from $25^{\circ}C$ to $100^{\circ}C$ were also discussed for application to lighting-emitting diode (LED) packages and substrate materials.

Keywords

References

  1. H. S. Kim, R. D. Rawlings, and P. S. Rogers, "Quantitative Determination of Crystalline and Amorphous Phases in Glass-Ceramics by X-ray Diffraction Analysis," Br. Ceram. Trans. J., 88 21-5 (1989).
  2. K. Yasukawa, Y. Terashi, and A. Nakayama, "Crystallinity Analysis of Glass-Ceramics by the Rietveld Method," J. Am. Ceram. Soc., 81 2978-82 (1998). https://doi.org/10.1111/j.1151-2916.1998.tb02723.x
  3. L. Barbieri, F. Bondioli, I. Lancellotti, C. Leonelli, M. Montorsi, A. M. Ferrari, and P. Miselli, "The Anorthite-Diopside System: Structural and Devitrification Study. Part II: Crystallinity Analysis by the Rietveld-RIR Method," J. Am. Ceram. Soc., 88 3131-6 (2005). https://doi.org/10.1111/j.1551-2916.2005.00578.x
  4. T. Roisnel and J. R. Carvajal, "WinPLOTR: A Windows Tool for Powder Diffraction Patterns Analysis," Mat. Sci. Forum, 378-81 118-23 (2001). https://doi.org/10.4028/www.scientific.net/MSF.378-381.118
  5. J. R. Clark, D. E. Appleman, and J. J. Papike, "Crystal-Chemical Characterization of Clinopyroxenes Based on Eight New Structure Refinements," Mineral. Soc. Amer. Spec. Pap., 2 31-50 (1969).
  6. N. Ishizawa, T. Miyata, I. Minato, F. Marumo, and S. Iwai, "A Structural Investigation of ${\alpha}-Al_2O_3$ at 2170 K," Acta Cryst., B36 228-30 (1980).
  7. K. Matusita and S. Sakka, "Kinetic Study of Crystallization of Glass by Differential Thermal Analysis-Criterion on Application of Kissinger Plot," J. Non-Cryst. Solids, 38-9 741-6 (1980). https://doi.org/10.1016/0022-3093(80)90525-6
  8. A. Goel, D. U. Tulyaganov, V. V. Kharton, A. A. Yaremchenko, and J. M. F. Ferreira, "The Effect of $Cr_2O_3$ Addition on Crystallization and Properties of $La_2O_3$-Containing Diopside Glass-Ceramics," Acta Mater., 56 3065-76 (2008). https://doi.org/10.1016/j.actamat.2008.02.036
  9. A. Goel, D. U. Tulyaganov, E. R. Shaaban, C. S. Knee, S. Eriksson, and J. M. F. Ferreira, "Structure and Crystallization Behaviour of Some $MgSiO_3$-Based Glasses," Ceram. Int., 35 1529-38 (2009). https://doi.org/10.1016/j.ceramint.2008.08.012
  10. P. J. Hayward, E. R. Vance, and D. C. Doern, "DTA/SEM Study of Crystallization in Sphene Glass-Ceramics," Am. Ceram. Soc. Bull., 66 1620-6 (1987).
  11. A. Goel, R. Shaaban, D. U. Tulyaganov, and J. M. F. Ferreira, "Study of Crystallization Kinetics in Glasses along the Diopside-Ca-Tschermak Join," J. Am. Ceram. Soc., 91 2690-7 (2008). https://doi.org/10.1111/j.1551-2916.2008.02495.x
  12. K. Omori, "Analysis of the Infrared Absorption Spectrum of Diopside," Am. Mineral., 56 1607-16 (1971).
  13. R. Chen, Y. Wang, Y. Hu, Z. Hu, and C. Liu, "Modification on Luminescent Properties of $SrAl_2O_4:Eu^{2+}, Dy^{3+}$ phosphor by $Yb^{3+}$ ions doping," J. Lumin., 128 1180-4 (2008). https://doi.org/10.1016/j.jlumin.2007.11.094
  14. C. J. Jeon, W. J. Yeo, and E. S. Kim, "Effect of Crystallization on Thermal Conductivity of Diopside," J. Ceram. Soc. Jpn., 118 1079-82 (2010). https://doi.org/10.2109/jcersj2.118.1079
  15. A. Karamanov and M. Pelino, "Evaluation of the Degree of Crystallisation in Glass-Ceramics by Density Measurements," J. Eur. Ceram. Soc., 19 649-54 (1999). https://doi.org/10.1016/S0955-2219(98)00226-X
  16. S. Y. Choi, D. H. Lee, D. W. Shin, S. Y. Choi, J. W. Cho, and J. M. Park, "Properties of F-Free Glass System as a Mold Flux: Viscosity, Thermal Conductivity and Crystallization Behavior," J. Non-Cryst. Solids, 345-6 157-60 (2004). https://doi.org/10.1016/j.jnoncrysol.2004.08.015
  17. C. Clauser and E. Huenges, "Thermal Conductivity of Rocks and Minerals," pp. 105-26 in Rocks Physics and Phase Relationsa Handbook of Physical Constants, AGU Reference Shelf, Vol. 3, Ed. by T. J. Ahrens, American Geophysical Union, Washington, DC, USA, 1995.