• Bulletin of the Korean Chemical Society
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• v.29 no.9
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• pp.1737-1741
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• 2008

The electrochemical and thermal stability of $LiNi_{0.8}Co_{0.16}Al_{0.04}O_2$ were studied before and after $Co_3(PO_4)_2$ coating. Different to conventional coating material such as $ZrO_2$ or AlPO4, the coating layer was not detected clearly by TEM analysis, indicating that the $Co_3(PO_4)_2$ nanoparticles effectively reacted with surface impurities such as $Li_2CO_3$. The coated sample showed similar capacity at a low C rate condition. However, the rate capability was significantly improved by the coating effect. It is associated with a decrease of impedance after coating because impedance can act as a major barrier for overall cell performances in high C rate cycling. In the DSC profile of the charged sample, exothermic peaks were shifted to high temperatures and heat generation was reduced after coating, indicating the thermal reaction between electrode and electrolyte was sucessfully suppressed by $Co_3(PO_4)_2$ nanoparticle coating.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.7
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• pp.841-855
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• 1999

In the present work, the effect of a flow maldistribution on the thermal and conversion response of 8 monolith catalytic converter is Investigated. To achieve this goal, a combined chemical reaction and multi-dimensional fluid dynamic mathematical model has been developed. The present results show that flow uniformity within the monolith brick has 8 great impact on light-off performance of the catalytic converter. In the case of lower flow uniformity, large portions of the monolith remain cold due to locally concentrated high velocities and CO, HC are unconverted during warm-up period, which loads to retardation of light-off. It has been also found that the heat-up pattern of the monolith ill similar to the flow distribution profile, In the early stage of the reaction. It may be concluded that flow maldistribution can cause a significant retardation of the light-off and hence can eventually worsen tho conversion efficiency of automotive catalytic converter.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• v.9 no.1
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• pp.363-366
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• 2005

A micro flow sensor on silicon substrate allows the fabrication of small components where many different functions can be integrated so that the functionality of the sensors can be increased. Further more, due to the small size of the elements the sensors can be quite fast. A thermal mass flow sensor measures the asymmetry of temperature profile around the heater which is modulated by the fluid flow. In normal, a mass flow sensor is composed of a central heater and a pair of temperature sensing elements around the heater. A new 2-D wide range micro flow sensor structure with three pairs of temperature sensors and a central heater was proposed and numerically simulated by the Finite difference formulation to confirm the feasibility of the flow sensor structure.

• Nuclear Engineering and Technology
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• v.30 no.6
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• pp.541-554
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• 1998

A computer code COSMOS has been developed based on the CARO-D5 for the thermal analysis of LWR UO$_2$ and MOX fuel rod under steady-state and transient operating conditions. The main purpose of the COSMOS, which considers high turnup characteristics such as thermal conductivity degradation with turnup and rim formation at the outer part of fuel pellet, is to calculate temperature profile across fuel pellet and fission gas release up to high burnup. A new mechanistic fission gas release model developed based on physical processes has been incorporated into the code. In addition, the features of MOX fuel such as change in themo-mechanical properties and the effect of microscopic heterogeneity on fission gas release have been also taken into account so that it can be applied to MOX fuel. Another important feature of the COSMOS is that it can analyze fuel segment refabricated from base irradiated fuel rods in commercial reactors. This feature makes it possible to analyze database obtained from international projects such as the MALDEN and RISO, many of which were collected from refabricated fuel segments. The capacity of the COSMOS has been tested with some number of experimental results obtained from the HALDEN, RISO and FIGARO programs. Comparison with the measured data indicates that, although the COSMOS gives reasonable agreement, the current models need to be improved. This work is being performed using database available from the OECD/NEA.

• Journal of the Korean Institute of Gas
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• v.2 no.1
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• pp.83-89
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• 1998

Experiments had been conducted Qualitatively regarding flow measurement errors of orifice flowmeter due to temperature difference between the inside and outside the natural gas meter-run in case of no pipe insulations. The primary factors considered in this study are fluid velocity and surrounding temperature. In addition, a portion of thermal radiation due to the sun was involved as a factor. The results showed that the considerable errors were not detected even in conditions of low flow rates and large temperature difference between the inside and outside the meter-run.

• Advances in aircraft and spacecraft science
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• v.5 no.3
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• pp.295-318
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• 2018

This research studies thermo-elastic behavior of rotating micro discs that are employed in various micro devices such as micro gas turbines. It is assumed that material is functionally graded with a variable profile thickness, density, shear modulus and thermal expansion in terms of radius of micro disc and as a power law function. Boundary condition is considered fixed-free with uniform thermal loading and elastic field is symmetric. Using incompressible material's constitutive equation, we extract governing differential equation of four orders; to solution this equation, we utilize general differential quadrature (GDQ) method and the results are schematically pictured. The obtained result in a particular case is compared with another work and coincidence of results is shown. We will find out that surface effect tends to split micro disc's area to compressive and tensile while nonlocal parameter tries to converge different behaviors with each other; this convergence feature make FGIMs capable to resist in high temperature and so in terms of thermo-elastic behavior we can suggest, using FGIMs in micro devices such as micro turbines (under glass transition temperature).

• Steel and Composite Structures
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• v.33 no.3
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• pp.463-472
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• 2019

Initial thermo-elastic and steady state creep deformation of a rotating functionally graded simple blade is studied using first-order shear deformation theory. A variable thickness model for cantilever beam has been considered. The blade geometry and loading are defined as functions of length so that one can define his own blade profile and loading using any arbitrary function. The blade is subjected to a transverse distributed load, an inertia body force due to rotation and a distributed temperature field due to a thermal gradient between the tip and the root. All mechanical and thermal properties except Poisson's ratio are assumed to be longitudinally variable based on the volume fraction of reinforcement. The creep behaviour is modelled by Norton's law. Considering creep strains in stress strain relation, Prandtl-Reuss relations, Norton' law and effective stress relation differential equation in term of effective creep strain is established. This differential equation is solved numerically. By effective creep strain, steady state stresses and deflections are obtained. It is concluded that reinforcement particle size and form of distribution of reinforcement has significant effect on the steady state creep behavior of the blade.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.213-217
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• 2008

This paper describes an application of centrifugal compressor optimization system, in which the blade profile of impeller is represented with NURBS(Non-Uniform Rational B-Spline) curve. A commercial CFD(Computational Fluid Dynamics) program named NUMECA fine/turbo was used to evaluate the performance of the whole centrifugal compressor flow passage including impeller and diffuser. The whole optimization design system was integrated based on iSIGHT, a commercial integration and optimization software, which provides a direct application of some optimization algorithms. To insure the practicability of optimization, the performance of centrifugal compressor under all condition was concerned during the optimizing process. That means a compositive object function considering the aerodynamic efficiency, pressure ratio and mass flow rate under different work condition was applied by using different weight number for different conditions. Using the optimization method described in this paper, an optimized design of the impeller blade of centrifugal compressor was obtained. Comparing to the original design, optimized design has a better performance not only under the design work condition, but also the off-design work condition including near stall and near choke condition.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.10
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• pp.689-695
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• 2008

Experimental study has been performed to investigate the influence of non-condensible gas(NCG) charged mass on the thermal performance of a variable conductance heat pipe(VCHP) with screen mesh wick. The VCHP is furnished by screen mesh number 200 for the pipe outer diameter of 12.7mm and the pipe length of 500 mm. The VCHP is filled with water as working fluid of 4.8g and nitrogen as NCG and has evaporator, condenser and adiabatic section, respectively. For the results from experiment, it is found that, for the same charged mass of working fluid, the overall wall temperatures of heat pipe grows up with increasing NCG charged mass. The variation of operating temperature of VCHP reduces with increasing NCG mass. In addition, the profile of axial wall temperature distribution is presented for heat transport capacity of heat pipe, the temperature of cooling water of condenser, inclination angle, and operating temperature.

• Macromolecular Research
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• v.16 no.3
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• pp.189-193
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• 2008

Thermal cross-linking method of poly(vinyl alcohol) (PVA) using poly(acrylic acid) (PAA) was carried out on PVA/PAA hydrogels. The level of gelation was measured in the PVA/PAA hydrogels with various PAA contents. The swelling behavior at various pHs showed that the swelling kinetics and water contents of the PVA/PAA hydrogels reached equilibrium after 30 h, and the time to reach the equilibrium state decreased with increasing PAA content in the hydrogel. The water content increased with increasing pH of the buffer solution. The permeation and release of the drug were tested using indomethacin as a model drug. The permeated and released amounts of the drug increased with decreasing the PAA content because of the low free volume in the hydrogel due to the higher cross-linking density. The kinetic profile of drug release at various pHs showed that all samples reached the equilibrium state within the 5 h.