• 제목/요약/키워드: Thermal mixing

검색결과 794건 처리시간 0.028초

수화물 소성에 의한 고순도 다공성 CaO·Al2O3 클링커의 합성 (Synthesis of Pure and Porous CaO·Al2O3 Clinker by Burning of Hydrates)

  • 김두혁;송태웅
    • 한국세라믹학회지
    • /
    • 제47권5호
    • /
    • pp.401-406
    • /
    • 2010
  • For the lower-temperature preparation of calcium monoaluminate(CA, C:CaO, A:$Al_2O_3$) clinker which is hard to synthesize purely within its melting point, an equimolar hydrate was obtained and then used as a starting raw material of clinker burning. The hydrate was prepared from a mixture of waste oyster shell and industrial aluminium hydroxide by heating to $1200^{\circ}C$, grinding and mixing with water. The hydrate was composed of amorphous aluminium hydroxide and $C_3AH_6$(H:$H_2O$) formed by resolution-precipitation mechanism of the system C-A-H. By heating the hydrate, nearly pure and porous calcium monoaluminate clinker was formed at $1400^{\circ}C$ which is fairly lower temperature than that of its melting point. The formation of calcium monoaluminate was performed mainly by the reaction between amorphous alumina and $C_{12}A_7$ caused by the decomposition of $C_3AH_6$. The immediate and earlier formation of $C_{12}A_7$ seemed to be accelerated by not only high surface area and instability of the thermally decomposed hydrate but also the catalytic effect of water decomposed from the hydrate. The final calcium monoaluminate clinker was very porous because of the influence of highly porous shape of the thermally decomposed hydrate.

10 nm 두께의 니켈 코발트 합금 박막으로부터 제조된 니켈코발트 복합실리사이드의 미세구조 분석 (Microstructure Characterization for Nano-thick Nickel Cobalt Composite Silicides from 10 nm-Ni0.5Co0.5 Alloy films)

  • 송오성;김상엽;김종률
    • 한국전기전자재료학회논문지
    • /
    • 제20권4호
    • /
    • pp.308-317
    • /
    • 2007
  • We fabricated thermally-evaporated 10 nm-Ni/(poly)Si and 10 nm-$Ni_{0.5}Co_{0.5}$/(Poly)Si structures to investigate the microstructure of nickel silicides at the elevated temperatures required lot annealing. Silicides underwent rapid annealing at the temperatures of $600{\sim}1100^{\circ}C$ for 40 seconds. Silicides suitable for the salicide process formed on top of both the single crystal silicon actives and the polycrystalline silicon gates. A four-point tester was used to investigate the sheet resistances. A transmission electron microscope and an Auger depth profilescope were employed for the determination of vortical microstructure and thickness. Nickel silicides with cobalt on single crystal silicon actives and polycrystalline silicon gates showed low resistance up to $1100^{\circ}C$ and $900^{\circ}C$, respectively, while the conventional nickle monosilicide showed low resistance below $700^{\circ}C$. Through TEM analysis, we confirmed that a uniform, $10{\sim}15 nm$-thick silicide layer formed on the single-crystal silicon substrate for the Co-alloyed case while a non-uniform, agglomerated layer was observed for the conventional nickel silicide. On the polycrystalline silicon substrate, we confirmed that the conventional nickel silicide showed a unique silicon-silicide mixing at the high silicidation temperature of $1000^{\circ}C$. Auger depth profile analysis also supports the presence of this mixed microstructure. Our result implies that our newly proposed NiCo-alloy composite silicide process may widen the thermal process window for the salicide process and be suitable for nano-thick silicides.

정밀주조용 쉘 몰드에 알루미노실리케이트계 졸의 응용에 관한 연구 ( I ) (A Study on the Application of Aluminosilicate Sols in Shell Mold for Investment Casting ( I ))

  • 김재원;김두현;서성문;조창용;최승주;김재철;박영규
    • 한국재료학회지
    • /
    • 제9권12호
    • /
    • pp.1188-1195
    • /
    • 1999
  • 알루미노실리케이트 계 졸이 지르콘 쉘 몰드의 뮬라이트 층 생성에 미치는 영향을 고찰하였다. 알루미노실리케이트 졸은 콜로이달 실리카와 수용성 질산알루미늄을 혼합하여 제조하였으며 50$^{\circ}C$에서 48시간 조건에서 겔화 하였다. 이러한 겔은 깁사이트 및 알루미노실리케이트 복합 겔로 구성되어 있었으며, Si 이온과 결합하는 모든 Al 이온의 배위수가 4임을 확인하였다. 뮬라이트 상은 1300$^{\circ}C$ 이상에서 소결하였을 때 관찰되었으며 뮬라이트의 XRD 피크는 소결 온도와 질산알루미늄의 농도가 증가할수록 노실리케이트 졸 슬러리를 2차 층에 코팅하였다. 그 결과 1차 및 3차 층의 분리가 일어났으며, 이는 소결시 졸의 1차 및 3차 층으로 침윤 발생과 잔류 실리카와 뮬라이트 간의 열팽창계수 차이에 기인한 것으로 판단된다.

  • PDF

F급 플라이애쉬의 혼입방법을 달리한 콘크리트 특성에 관한 실험적 연구 (A Study on the Properties of the Concrete Containing Fly-ash of Class F According to the 3 Different Mixture Design)

  • 문종욱;유택동;서치호
    • 한국구조물진단유지관리공학회 논문집
    • /
    • 제3권2호
    • /
    • pp.191-198
    • /
    • 1999
  • The purpose of this study is investigating characteristics of the concrete containing Fly-ash according to different 4 mix design, that is, the first mix design is partial replace Fly-ash of cement, second is partial replace Fly-ash of cement and fine aggregate, third is partial replace Fly-ash of fine aggregate, fourth partial replacement of fine and coarse aggregate. For this purpose, selected test variables were water-binder ratio with two levels of 45%, 50%, and Fly-ash contents with four levels 0%, 10%, 20%, 30%, As the result of this study are as follow. 1) The result of mix design of a partial replacement of cement, the slump-flow value was appeared a promotive effect of viscosity. But in case of the over with Fly-ash 10% and the other mix design was not changed slump value. 2) The unit weight of the mixing rate with Fly-ash 0% was $1.875{\sim}1.884t/m^3$, the other mix design 10% over with Fly-ash was $1.846{\sim}1.615t/m^3$, the difference was appeared less about 15% than that. 3) In design, partial replace Fly-ash of fine aggregate, this compressive strength was appeared that the concrete age after 7 days was higher than in partial replacement of cement, therefore, the default of a concrete with Fly-ash, that is the earlier compressive strength was to lessen, was improved. 4) The thermal conductivity of the all mix design was $0.447{\sim}1.144kcal/mh^{\circ}C$, this value was as good as a lightweight aggregate concrete.

  • PDF

폐석 및 석분 슬러지를 활용한 인조석판재의 제조 (Manufacture of Artificial stone using Wasts Stone and Powder Sludge)

  • 손정수;김병규;김치권
    • 자원리싸이클링
    • /
    • 제4권1호
    • /
    • pp.4-11
    • /
    • 1995
  • 국내 각 채석장 및 석재 가공공정에서 발생되는 폐석과 석분 슬러지를 활용하여 장식재, 바닥재 및 내외장재 등에 쓰이는 인조 석판재 제조기술을 개발하고자 하였다. 인조석재는 폐석과 결합제 및 경화제 등을 혼합하여 제조하였으며 성형압력, 폐석 및 석분 슬러지의 결합비 그리고 결합제의 양 등의 변화에 따른 인조석재 각각의 특성을 비교하였다. 천연석재와 인조석재와의 물성을 비교하기 위하여 $\circled1$ 비중,$\circled2$ 흡수율, $\circled3$ 탄성파속도, $\circled4$ 압축강도, $\circled5$ 인장강도, $\circled6$ 반발경도, $\circled7$ 탄성계수 $\circled8$ 포아송비를 측정하였으며 $\circled9$ 내열성도 함께 조사하였는데 석재의 물성은 원료의 혼합정도, 성형압력 및 결합제의 양에 의해 좌우됨을 알 수 있었다. 본 인조석재의 제조에도 석분에 비해 고가인 결합제의 사용을 가능한한 최소로 하여 폐기물로 배출되는 폐석 및 석분슬러지를 최대한 활용할 수 있도록 하였으며 성형압력 $200kg/\textrm{cm}^2$, 결합제의 양 12~15wt.%의 제조조건에서 원하는 물성을 갖는 인조석재를 제조할 수 있었다.

  • PDF

저선회 모델 연소기의 연소특성 및 선회각도 영향 (Effect of Swirl Angles and Combustion Characteristics of Low Swirl Model Combustor)

  • 정황희;이기만
    • 한국추진공학회지
    • /
    • 제20권4호
    • /
    • pp.40-49
    • /
    • 2016
  • 본 연구의 목적은 저선회 모델 연소기에서 저선회 연소의 특성을 확인하는 것이다. 이를 위해 선회각도에 따른 화염의 형상 및 안정화 영역, 배기성능에 대한 평가가 실험적으로 수행되었다. 저선회 연소의 큰 특징은 화염이 부상되어 존재하게 되는데, 이러한 부상화염은 확대유동과 예혼합 화염의 전파특성이 절묘하게 결합되어 발생하게 된다. 본 연소기에서 이러한 부상화염의 특징을 속도 유동장을 통하여 확인하였으며 화염을 가시화하여 나타내었다. 가시화된 화염은 열용량과 당량비에 따라 분류하였다. 선회각도의 변화에 따른 연구를 통해 선회각도만으로도 희박 가연한계를 확장시킬 수 있음을 보였다. 또한 선회각도가 증가할수록 혼합이 향상되고 체류시간이 짧아져 NOx와 CO의 배출이 감소되는 것으로 확인되었다.

사인 웨이브 핀과 타원관으로 구성된 핀-관 열교환기의 공기측 성능 (Air-Side Performance of Fin-and-Tube Heat Exchangers Having Sine Wave Fins and Oval Tubes)

  • 최병남;풍익;심현민;김내현
    • 설비공학논문집
    • /
    • 제25권5호
    • /
    • pp.279-288
    • /
    • 2013
  • Heat transfer and pressure drop characteristics of fin-and-tube heat exchangers having sine wave fins and oval tubes were investigated. Oval tubes having an aspect ratio of 0.6 were made, by deforming 12.7 mm round tubes. Twelve samples, having different fin pitch and tube row, were tested. The effect of fin pitch on the j and f factors was negligible. The effect of the tube row on the j factor, however, was different from that of common fin-and-tube heat exchangers having plain fins and round tubes. The highest j factor was obtained for a two-row configuration, while the lowest one was obtained for a one-row configuration. A possible reason was attributed to the flow mixing characteristics of the sine wave channel of the present geometry. Comparison with a plain fin-and-tube heat exchanger having 15.88 mm O. D. round tube reveals that the present oval fin-and-tube heat exchanger shows generally superior thermal performance, except for the one-row configuration.

ASSESSMENT OF CFD CODES USED IN NUCLEAR REACTOR SAFETY SIMULATIONS

  • Smith, Brian L.
    • Nuclear Engineering and Technology
    • /
    • 제42권4호
    • /
    • pp.339-364
    • /
    • 2010
  • Following a joint OECD/NEA-IAEA-sponsored meeting to define the current role and future perspectives of the application of Computational Fluid Dynamics (CFD) to nuclear reactor safety problems, three Writing Groups were created, under the auspices of the NEA working group WGAMA, to produce state-of-the-art reports on different aspects of the subject. The work of the second group, WG2, was to document the existing assessment databases for CFD simulation in the context of Nuclear Reactor Safety (NRS) analysis, to gain a measure of the degree of quality and trust in CFD as a numerical analysis tool, and to take initiatives to extend the existing databases. The group worked over the period of 2003-2007 and produced a final state-of-the-art report. The present paper summarises the material gathered during the study, illustrating the points with a few highlights. A total of 22 safety issues were identified for which the application of CFD was considered to potentially bring real benefits in terms of better understanding and increased safety. A list of the existing databases was drawn up and synthesised, both from the nuclear area and from other parallel, non-nuclear, industrial activities. The gaps in the technology base were also identified and discussed. In order to initiate new ways of bringing experimentalists and numerical analysts together, an international workshop -- CFD4NRS (the first in a series) -- was organised, a new blind benchmark activity was set up based on turbulent mixing in T-junctions, and a Wiki-type web portal was created to offer online access to the material put together by the group giving the reader the opportunity to update and extend the contents to keep the information source topical and dynamic.

Micrometeorological Characteristics in the Atmospheric Boundary Layer in the Seoul Metropolitan Area during High-Event and Non-event Days

  • Park, Il-Soo;Park, Moon-Soo;Lee, Joonsuk;Jang, Yu Woon
    • 한국환경과학회지
    • /
    • 제29권12호
    • /
    • pp.1223-1237
    • /
    • 2020
  • This study focused on comparing the meteorological conditions in the Atmospheric Boundary Layer (ABL) on high-event days and non-event days in the Seoul Metropolitan Area (SMA). We utilized observed PM10 and meteorological variables at the surface as well as at the upper heights. The results showed that high-event days were consistently associated with lower wind speed, whereas wind direction showed no particular difference between high-event and non-event days with frequent westerlies and northwesterlies for both cases. During high-event days, the temperature was much warmer than the monthly normal values with a sharp increasing trend, and Relative Humidity (RH) was higher than the monthly normal, especially on high-event days in February. During high-event days in spring, a double inversion layer was present at surface and upper heights. This indicates that stability in the multi-layer is an important indicator of higher PM10 concentrations. Net radiation in spring and winter is also closely associated with higher PM10 concentrations. Strong net radiation resulted in large sensible heat, which in turn facilitated a deeper mixing height with diluted PM10 concentrations; in contrast, PM10 concentrations were higher when sensible heat in spring and winter was very low. We also confirmed that convective and friction velocity was higher on non-event days than on high-event days, and this was especially obvious in spring and winter. This indicated that thermal turbulence was dominant in spring, whereas in winter, mechanical turbulence was dominant over the SMA.

2018년 8월 1일 홍천에서의 기록적인 고온 사례(41.0℃)에 영향을 준 푄 바람 (Effect of Foehn Wind on Record-Breaking High Temperature Event (41.0℃) at Hongcheon on 1 August 2018)

  • 김석환;이재규;김유진
    • 대기
    • /
    • 제31권2호
    • /
    • pp.199-214
    • /
    • 2021
  • A record-breaking high surface air temperature of 41.0℃ was observed on 1 August 2018 at Hongcheon, South Korea. In this study, to quantitatively determine the formation mechanism of this extremely high surface air temperature, particularly considering the contributions of the foehn and the foehnlike wind, observational data from Korea Meteorological Administration (KMA) and the Weather Research and Forecasting (WRF) model were utilized. In the backward trajectory analysis, trajectories of 100 air parcels were released from the surface over Hongcheon at 1600 LST on 1 August 2018. Among them, the 47 trajectories (38 trajectories) are tracked back above (below) heights of 1.4 km above mean sea level at 0900 LST 31 July 2018 and are defined as upper (lower) routes. Lagrangian energy budget analysis shows that for the upper routes, adiabatic heating (11.886 × 103 J kg-1) accounts for about 77% of the increase in the thermal energy transfer to the air parcels, while the rest (23%) is diabatic heating (3.650 × 103 J kg-1). On the other hand, for the lower routes, adiabatic heating (6.111 × 103 J kg-1) accounts for about 49% of the increase, the rest (51%) being diabatic heating (6.295 × 103 J kg-1). Even though the contribution of the diabatic heating to the increase in the air temperature rather varies according to the routes, the contribution of the diabatic heating should be considered. The diabatic heating is caused by direct heating associated with surface sensible heat flux and heating associated with the turbulent mixing. This mechanism is the Type 4 foehn described in Takane and Kusaka (2011). It is concluded that Type 4 foehn wind occurs and plays an important role in the extreme event on 1 August 2018.