• Title/Summary/Keyword: Thermal interference

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Quantitative Approaches for the Determination of Volatile Organic Compounds (VOC) and Its Performance Assessment in Terms of Solvent Types and the Related Matrix Effects

  • Ullah, Md. Ahsan;Kim, Ki-Hyun;Szulejko, Jan E.;Choi, Dal Woong
    • Asian Journal of Atmospheric Environment
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    • v.11 no.1
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    • pp.1-14
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    • 2017
  • For the quantitative analysis of volatile organic compounds (VOC), the use of a proper solvent is crucial to reduce the chance of biased results or effect of interference either in direct analysis by a gas chromatograph (GC) or with thermal desorption analysis due to matrix effects, e.g., the existence of a broad solvent peak tailing that overlaps early eluters. In this work, the relative performance of different solvents has been evaluated using standards containing 19 VOCs in three different solvents (methanol, pentane, and hexane). Comparison of the response factor of the detected VOCs confirms their means for methanol and hexane higher than that of pentane by 84% and 27%, respectively. In light of the solvent vapor pressure at the initial GC column temperature ($35^{\circ}C$), the enhanced sensitivity in methanol suggests the potential role of solvent vapor expansion in the hot injector (split ON) which leads to solvent trapping on the column. In contrast, if the recurrent relationships between homologues were evaluated using an effective carbon number (ECN) additivity approach, the comparability assessed in terms of percent difference improved on the order of methanol (26.5%), hexane (6.73%), and pentane (5.24%). As such, the relative performance of GC can be affected considerably in the direct injection-based analysis of VOC due to the selection of solvent.

Development of the Korean 2.75 inch Rocket Propulsion System (한국형 2.75 인치 로켓 추진기관 개발)

  • Kang, Kiha;Lee, Yongbum;Yeom, Yongyeol;Bang, Gibok;Yang, Youngjun
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.3
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    • pp.70-77
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    • 2014
  • In this paper, the development of unique model of the 2.75 inch rocket propulsion system is described. Recently developed korean 2.75 inch rocket propulsion system shows the improvement of a flame stability resulted from a change in the configuration of propellant grain, and of an incidental ignition protection function using the EMI(electromagnetic interference) filter on ignition system. Moreover it is shown that a directional flight stability is improved by increasing the number of fins and changing the nozzle configuration. Static firing test and thermal shock test were conducted for the validation before flight, and flight test of 210 rounds of rockets was conducted to verify the trajectory uniformity. In addition, intellectual property issues can be overcome with the unique korean 2.75 inch rocket motor as well as the performance improvement.

Magnetostriction Measurement of an $Fe_49Co_49V_2$ Alloy using the Michelson Laser Interferometer Compensated by Feedback Signal (궤환신호로 보상되는 Michelson 레이저 간섭계를 이용한 $Fe_49Co_49V_2$ 합금의 자기변형 측정)

  • 안승준;김철기;김호섭;김호철;남궁정
    • Journal of the Korean Magnetics Society
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    • v.10 no.5
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    • pp.246-249
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    • 2000
  • An Fe$_{49}$ Co$_{49}$ V$_2$alloy is annealed in thermal annealing furnace at 50$0^{\circ}C$, 75$0^{\circ}C$, 80$0^{\circ}C$, and 90$0^{\circ}C$. Annealed samples were cooled in air. The magnetostriction is measured by using a Michelson laser interferometer. Receiving the feedback signal of interference, a mirror attached to piezoelectric transducer (PZT) maintains the optical path length (OPL) between two arms of laser interferometer relatively constant. The feedback voltage is calibrated to the OPL variation. A magnetostriction of 2$\times$10$^{-6}$ at H = 60 Oe increases up to 33.68$\times$10$^{-6}$ at an annealing temperature of 90$0^{\circ}C$, suggesting that the magnetostrictive characteristics are improved by the microstructural modification.

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A Study on the Effects of Hydrogen Addition and Swirl Intensity in CH4-Air Premixed Swriling Flames (메탄-공기 예혼합 선회화염에서 수소첨가와 선회강도 영향에 관한 연구)

  • KIM, HAN SEOK;CHO, JU HYEONG;KIM, MIN KUK;HWANG, JEONGJAE;LEE, WON JUNE
    • Journal of Hydrogen and New Energy
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    • v.30 no.6
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    • pp.593-600
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    • 2019
  • The combustion characteristics of methane/hydrogen pre-mixed flame have been investigated with swirl stabilized flame in a laboratory-scale pre-mixed combustor with constant heat load of 5.81 kW. Hydrogen/methane fuel and air were mixed in a pre-mixer and introduced to the combustor through a burner nozzle with different degrees of swirl angle. The effects of hydrogen addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using particle image velocimetry (PIV), micro-thermocouples, various optical interference filters and gas analyzers to provide information about flow velocity, temperature distributions, and species concentrations of the reaction field. The results show that higher swirl intensity creates more recirculation flow, which reduces the temperature of the reaction zone and, consequently, reduces the thermal NO production. The distributions of flame radicals (OH, CH, C2) are dependent more on the swirl intensity than the percentage of hydrogen added to methane fuel. The NO concentration at the upper part of the reaction zone is increased with an increase in hydrogen content in the fuel mixture because higher combustibility of hydrogen assists to promote faster chemical reaction, enabling more expansion of the gases at the upper part of the reaction zone, which reduces the recirculation flow. The CO concentration in the reaction zone is reduced with an increase in hydrogen content because the amount of C content is relatively decreased.

A Study on the Analysis for Development of a Deflector Type Miniature Ball Screw (초소형 디플렉터 타입 볼스크류 개발을 위한 해석에 관한 연구)

  • Lee, Choon-Man;Moon, Sung-Ho;Lee, Young-Hun;Kim, Jun-Hwan
    • Journal of the Korean Society for Precision Engineering
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    • v.33 no.12
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    • pp.979-984
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    • 2016
  • Recently, ball screws have been used in machine tools, robot parts, and medical instruments. The demand for ball screws of high precision and reduced size is increasing because of the growth of high value-added industries. Three types of ball screws are typically used: deflector type, end-cap type, and tube type. They are also classified from C0 to C9 according to the precision level. A deflector type ball screw can reduce the variation of rotational torque and the size of the nut of the ball screw is minimized. To ensure the reliable design of ball screws, it is important to perform a structural analysis. The purpose of this study is to perform a stability evaluation through analysis of a deflector type miniature ball screw for weapon systems. The analysis is performed through Finite Elements Method (FEM) simulation to predict characteristics such as deformation, stress, and thermal effects. The interference between the shaft and the deflector for smooth rotation are also studied. Based on the results of the analysis, the development of the deflector type miniature ball screw for weapon systems is performed.

A Study on the Correlation of Cold Hypersensitivity and Digestive Function (여성의 냉한 정도와 소화기능의 상관성에 관한 연구)

  • Nam, Eun-Young;Lee, Jeong-Im;Kim, Gyeong-Mi;Kim, Hyung-Jun
    • The Journal of Korean Obstetrics and Gynecology
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    • v.27 no.1
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    • pp.140-151
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    • 2014
  • Objectives: Cold hypersensitivity has been regarded to be associated with digestive function. This study is aims to evaluate the correlation between digestive function and coldness of hands. Methods: We made a research of 80 women who is in ${\bigcirc}{\bigcirc}$ University. The patients were subjected to thermometer, and those with thermal difference between upper arm and palm were diagnosed with cold hypersensitivity. The patients were divided into two group by cold hypersensitivity group (n=20), and non-cold hypersensitivity group (n=19), and 39 women are mesured by Nepean dyspepsia index-Korean version (NDI-K) to evaluate the severity of functional dyspepsia. Results: There was no difference between two groups on age, height, weight. In functional dyspepsia symptom score, 6 symptoms (Pain in upper abdomen, Burning in upper abdomen, Cramps in upper abdomen, Pressure in upper abdomen, Vomiting, Bad breath) out of 15 were significantly increased in cold hypersensitivity group compared with non-cold hypersensitivity group. And in quality of life score, 3 domains (Tension/sleep, Interference with daily activities, Knowledge/control) out of 5, and total quality of life score were significantly decreased in cold hypersensitivity group compared with non-cold hypersensitivity group. Conclusions: This study shows the correlation between cold hypersensitivity and digestive function.

An Integrated System for Radioluminescence, Thermoluminescence and Optically Stimulated Luminescence Measurements

  • Park, Chang-Young;Park, Young-Kook;Chung, Ki-Soo;Lee, Jong-Duk;Lee, Jungil;Kim, Jang-Lyul
    • Journal of Radiation Protection and Research
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    • v.43 no.4
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    • pp.160-169
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    • 2018
  • Background: This study aims to develop an integrated optical system that can simultaneously or selectively measure the signals obtained from radioluminescence (RL), thermoluminescence (TL), and optically stimulated luminescence (OSL), which are luminescence phenomena of materials stimulated by radioactivity, heat, and light, respectively. The luminescence mechanism of various materials could be investigated using the glow curves of the luminescence materials. Materials and Methods: RL/TL/OSL integrated measuring system was equipped with a X-ray tube (50 kV, $200{\mu}A$) as an ionizing radiation source to irradiate the sample. The sample substrate was used as a heating source and was also designed to optically stimulate the sample material using various light sources, such as high luminous blue light emitting diode (LED) or laser. The system measured the luminescence intensity versus the amount of irradiation/stimulation on the sample for the purpose of measuring RL, TL and OSL sequentially or by selectively combining them. Optical filters were combined to minimize the interference of the stimulation light in the OSL signal. A long-pass filter (420 nm) was used for 470 nm LED, an ultraviolet-pass filter (260-390 nm) was used for detecting the luminescence of the sample by PM tube. Results and Discussion: The reliability of the system was evaluated using the RL/OSL characteristics of $Al_2O_3:C$ and the RL/TL characteristics of LiF:Mg,Cu,Si, which were used as dosimetry materials. The RL/OSL characteristics of $Al_2O_3:C$ showed relatively linear dose-response characteristics. The glow curve of LiF:Mg,Cu,Si also showed typical RL/OSL characteristics. Conclusion: The reliability of the proposed system was verified by sequentially measuring the RL characteristics of radiation as well as the TL and OSL characteristics by concurrent thermal and optical stimulations. In this study, we developed an integrated measurement system that measures the glow curves of RL/TL/OSL using universal USB-DAQs and the control program.

A Conductive-grid based EMI Shielding Composite Film with a High Heat Dissipation Characteristic (전도성 그리드를 활용한 전자파 흡수차폐/방열 복합소재 필름)

  • Park, Byeongjin;Ryu, Seung Han;Kwon, Suk Jin;Kim, Suryeon;Lee, Sang Bok
    • Composites Research
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    • v.35 no.3
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    • pp.175-181
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    • 2022
  • Due to the increasing number of wireless communication devices in mmWave frequency bands, there is a high demand for electromagnetic interference (EMI) shielding and heat dissipating materials to avoid device malfunctions. This paper proposes an EMI shielding composite film with a high heat dissipation characteristic. To achieve this, a conductive grid is integrated with a polymer-based composite layer including magnetic and heat dissipating filler materials. A high shielding effectiveness (>40 dB), low reflection shielding effectiveness (<3 dB), high thermal conductivity (>10 W/m·K), thin thickness (<500 ㎛) are simultaneously achieved with a tailored design of composite layer compositions and grid geometries in 5G communication band of 26.5 GHz.

Advantages and disadvantages of renewable energy-oil-environmental pollution-from the point of view of nanoscience

  • Shunzheng Jia;Xiuhong Niu;Fangting Jia;Tayebeh Mahmoudi
    • Advances in concrete construction
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    • v.16 no.1
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    • pp.69-78
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    • 2023
  • This investigation delves into the adverse repercussions stemming from the impact of arsenic on steel pipes concealed within soil designated for rice cultivation. Simultaneously, the study aims to ascertain effective techniques for detecting arsenic in the soil and to provide strategies for mitigating the corrosion of steel pipes. The realm of nanotechnology presents promising avenues for addressing the intricate intersection of renewable energy, oil, and environmental pollution from a novel perspective. Nanostructured materials, characterized by distinct chemical and physical attributes, unveil novel pathways for pioneering materials that exert a substantial impact across diverse realms of food production, storage, packaging, and quality control. Within the scope of the food industry, the scope of nanotechnology encompasses processes, storage methodologies, packaging paradigms, and safeguards to ensure the safety of consumables. Of particular note, silver nanoparticles, in addition to their commendable antibacterial efficacy, boast anti-fungal and anti-inflammatory prowess, environmental compatibility, minimal irritability and allergenicity, resilience to microbial antagonism, thermal stability, and robustness. Confronting the pressing issue of arsenic contamination within both environmental settings and the food supply is of paramount importance to preserve public health and ecological equilibrium. In response, this study introduces detection kits predicated upon silver nanoparticles, providing an expeditious and economically feasible avenue for identifying arsenic concentrations ranging from 0.5 to 3 ppm within rice. Subsequent quantification employs Hydride Atomic Absorption Spectroscopy (HG-AAS), which features a detection threshold of 0.05 ㎍/l. A salient advantage inherent in the HG-AAS methodology lies in its capacity to segregate analytes from the sample matrix, thereby significantly reducing instances of spectral interference. Importantly, the presence of arsenic in the soil beneath rice cultivation establishes a causative link to steel pipe corrosion, with potential consequences extending to food contamination-an intricate facet embedded within the broader tapestry of renewable energy, oil, and environmental pollution.

Reliability Estimation of High Voltage Ceramic Capacitor by Failure Analysis (고압 커패시터의 고장 분석을 통한 신뢰도 예측)

  • Yang, Seok-Jun;Kim, Jin-Woo;Shin, Seung-Woo;Lee, Hee-Jin;Shin, Seung-Hun;Ryu, Dong-Su;Chang, Seog-Weon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.21 no.6
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    • pp.618-629
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    • 2001
  • This paper presents a result of failure analysis and reliability evaluation for high voltage ceramic capacitors. The failure modes and failure mechanisms were studied in two ways in order to estimate component life and failure rate. The causes of failure mechanisms for zero resistance phenomena under withstanding voltage test in high voltage ceramic capacitors molded by epoxy resin were studied by establishing an effective root cause failure analysis. Particular emphasis was placed on breakdown phenomena at the ceramic-epoxy interface. The validity of the results in this study was confirmed by the results of accelerated testing. Thermal cycling test for high voltage ceramic capacitor mounted on a magnetron were implemented. Delamination between ceramic and epoxy, which might cause electrical short in underlying circuitry, can occur during curing or thermal cycle. The results can be conveniently used to quickly identify defective lots, determine $B_{10}$ life estimation each lot at the level of inspection, and detect major changes in the vendors processes. Also, the condition for dielectric breakdown was investigated for the estimation of failure rate with load-strength interference model.

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