• Title/Summary/Keyword: Thermal forming

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Characteristics of Chemical Reaction and Ignition Delay of $H_2$/Air/HFP Mixtures (수소/공기/HFP 혼합기의 화학반응 및 점화지연 특성)

  • Lee, Eui-Ju;Oh, Chang-Bo
    • Journal of the Korean Society of Safety
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    • v.25 no.1
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    • pp.17-21
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    • 2010
  • The chemistry and ignition delay of hydrogen/air/HFP premixed mixtures was investigated numerically with unsteady perfectly stirred reactor(PSR). The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The results shows the temporal concentration variations of major or reactants such as hydrogen and oxygen during autoignition were similar to the spatial distribution of premixed flame while water vapor produced at the ignition temperature was decomposed later, which can be clarified with the relate species production rates that the the re-growth (or shoulder) of OH concentration is a result of F radicals attacking $H_20$ forming OH and HF. For the stoichiometric $H_2$/air mixture inhibited by 20% HFP, HFP thermal decomposition reaction prevails over the radical attack such as H at initial stage. Even though relatively large HFP addition contributes to delay the ignition, chemical effect on the ignition delay is not effective because of late thermal decomposition of HFP. The most small ignition delay was observed at a slightly fuel lean condition ($\phi$ = 0.9), and temperature dependency of ignition delay was clearly shown near 900 K.

An Experimental Study on the Effects of Porous Layer Treatment on Evaporative Cooling of an Inclined Surface (다공물질 표면처리가 경사판의 증발냉각에 미치는 영향에 관한 실험적 연구)

  • Lee Dae Young;Lee Jae Wan;Kang Byung Ha
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.1
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    • pp.25-32
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    • 2005
  • Falling film heat transfer has been widely used in many applications in which heat and mass transfer occur simultaneously, such as evaporative coolers, cooling towers, absorption chillers, etc. In such cases, it is desirable that the falling film spreads widely on the surface forming thin liquid film to enlarge contact surface and to reduce the thermal resistance across the film and/or the flow resistance to the vapor stream over the film. In this work, the surface is treated to have thin porous layer on the surface. With this treatment, the liquid can be spread widely on the surface by the capillary force resulting from the porous structure. In addition to this, the liquid can be held within the porous structure to improve surface wettedness regardless of the surface inclination. The experiment on the evaporative cooling of an inclined surface has been conducted to verify the effectiveness of the surface treatment. It is measured that the evaporative heat transfer increases about $50\%$ by the porous layer treatment as compared with that from orignal bare surfaces.

A Study on the Properties and Fabrication of Bulk Forming GeSe Based Chalcogenide Glass for Infrared Optical Lens (적외선 광학렌즈 제작을 위한 GeSe의 벌크 제작 및 특성 연구)

  • Bae, Dong-Sik;Yeo, Jong-Bin;Park, Jung-Hoo;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.9
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    • pp.641-645
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    • 2013
  • Chalcogenide glass has superior property of optical transmittance in the infrared region. Glass made using Ge-Se how many important optical applications. We have determined the composite formular of $Ge_{0.25}Se_{0.75}$ to be the GeSe chalcogenide glass composition appropriate for IR lenses. Also, the optical, thermal and physical characteristics of chalcogenide glass depended on the composition ratio. GeSe bulk sample is produced using the traditional melt-quenching method. The optical, structural, thermal and physical properties of the compound were measured by using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Differential scanning calorimeter (DSC), and Scanning electron microscope (SEM) respectively.

Structure of a DNA Duplex Containing a Site-Specific Dewar Isomer: Structural Influence of the 3'-T.G base pair of the Dewar product.

  • Lee, Joon-Hwa;Choi, Byong-Seok
    • BMB Reports
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    • v.33 no.3
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    • pp.268-275
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    • 2000
  • In contrast to the pyrimidine (6-4)pyrimidone photoproduct [(6-4) adduct], its Dewar valence isomer (Dewar product) is low mutagenic and produces a broad range of mutations with a 42 % replicating error frequency. In order to determine the origin of the mutagenic property of the Dewar product, we used experimental NMR restraints and molecular dynamics to determine the solution structure of a Dewar·lesion DNA decamer duplex, which contains a mismatched base pair between the 3'-T residue and an opposed G residue. The 3'-T of the Dewar lesion forms stable hydrogen bonds with the opposite G residue. The helical bending and unwinding angles of the DW/GA duplex, however, are much higher than those of the DW/AA duplex. The stable hydrogen bonding of the G 15 residue does not increase the thermal stability of the overall helix. It also does not restore the distorted backbone conformation of the DNA helix that is caused by the forming of a Dewar lesion. These structural features implicate that no thermal stability, or conformational benefits of G over A opposite the 3'-T of the Dewar lesion, facilitate the preferential incorporation of an A. This is in accordance with the A rule during translesion replication and leads to the low frequent $3'-T{\rightarrow}C$ mutation at this site.

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An Experimental Study on the Evaluation of Fastening Unit Insulation Developed for the Insulation of Curtain Wall

  • Kim, Bong-Joo;Kim, Kyeong-A
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.2
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    • pp.243-256
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    • 2012
  • This study is the experimental study to improve the insulation of the fastening unit system, which has the most vulnerable insulation in the curtain walls. The Fastening Units were designed and fabricated to minimize the connection part of mullions. In addition, slight movements were taken into account and the performance of the middle layer was evaluated by forming an insulation layer with the vibration-proof rubber and the silicon to satisfy the mechanical and thermal performance criteria. A total of 10 experiments were performed under various conditions, such as indoor-outdoor temperature difference, type of insulation material, thickness of insulation material, and others. using the fabricated Fastening Units. As a result, the vibration-proof rubber insulation showed the temperature difference of $2.2^{\circ}C-5.0^{\circ}C$, and the silicon insulation showed the temperature difference of $2.8^{\circ}C-4.5^{\circ}C$, compared to the non-insulated Fasteniirature difference, typesng Units. When these results were compared with the psychometric chart graph, the insulated Fastening Unit designed in this study can be considered to prevent the dew condensation.

A study on the fabrication method of middle size LGP using continuous micro-lenses made by LIGA reflow

  • Kim, Jong-Sun;Ko, Young-Bae;Hwang, Chul-Jin;Kim, Jong-Deok;Yoon, Kyung-Hwan
    • Korea-Australia Rheology Journal
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    • v.19 no.3
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    • pp.171-176
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    • 2007
  • LCD-BLU (Liquid Crystal Display-Back Light Unit) of medium size is usually manufactured by forming numerous dots with $50{\sim}300\;{\mu}m$ in diameter by etching process and V-grove shape with $50\;{\mu}m$ in height by mechanical cutting process. However, the surface of the etched dots is very rough due to the characteristics of the etching process and V-cutting needs rather high cost. Instead of existing optical pattern made by etching and mechanical cutting, 3-dimensional continuous micro-lens of $200\;{\mu}m$ in diameter was applied in the present study. The continuous micro-lens pattern fabricated by modified LIGA with thermal reflow process was tested to this new optical design of LGP. The manufacturing process using LIGA-reflow is made up of three stages as follows: (i) the stage of lithography, (ii) the stage of thermal reflow process and (iii) the stage of electroplating. The continuous micro-lens patterned LGP was fabricated with injection molding and its test results showed the possibility of commercial use in the future.

Study on an Intermediate Compound Preparation for a HTGR Nuclear Fuel (고온가스로용 핵연료 중간화합물 제조에 대한 연구)

  • Kim, Yeon-Ku;Suhr, Dong-Soo;Jeong, Kyung-Chai;Oh, Seung-Chul;Cho, Moon-Sung
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.725-733
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    • 2008
  • In this study the preparation method of the spherical ADU droplets, intermediate compound of a HTGR nuclear fuel, was detailed-reviewed and then, the characteristics on an ageing and a washing steps among the wet process and the thermal treatment process on the died-ADU${\rightarrow}UO_3$ conversion with the high temperature furnaces were studied. The key parameters for spherical droplets forming are a precise control of feed rate and a suitable viscosity value selection of a broth solution. Also, a harmony of vibrating frequency and amplitude of a vibration dropping system are important factor. In our case, an uranium concentration is $0.5{\sim}0.7mol/l$, viscosity is $50{\sim}80$ centi-Poise, vibration frequency is about 100Hz. In thermal treatment for no crack spherical $UO_3$ particle, the heating rate in the calcination must be operated below $2^{\circ}C$/min, in air atmosphere.

Characteristics of NMOS Transistors with Phosphorus Source/Drain Formed by Rapid Thermal Diffusion (고속 열확산 공정에 의해 형성된 Phosphorus Source/Drain을 갖는 NMOS 트랜지스터의 특성)

  • 조병진;김정규;김충기
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.27 no.9
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    • pp.1409-1418
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    • 1990
  • Characteristics of NMOS transistors with phosphorus source/drain junctions formed by two-step rapid thermal diffusion (RTD) process using a solid diffusion source have been investigated. Phosphorus profiles after RTD were measured by SIMS analysis. In the case of 1100\ulcorner, 10sec RTD of, P, the specific contact resistance of n+ Si-Al was 2.4x10**-7 \ulcorner-cm\ulcorner which is 1/5 of the As junction The comparison fo P junction devices formed by RTD and conventional As junction devices shows that both short channel effect and hot carrier effect of P junction devices are smaller than those of As junction devices when the devices have same junction depths. P junction device had maximum of 0.4 times lower Isub/Id than As junction device. Characteristics of P junction formed by several different RTD conditions have been compared and 1000\ulcorner RTD sample had the smaller hot carrier generation. Also, it has been shown that the hot carrier generation can be futher reduced by forming the P junctions by 3-step RTD which has RTO-driven-in process additionally.

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Effect of Introducing EG on Foamed Cellular Structure and Properties in the Foaming Process of Rigid PU (경질 PU발포공정에 있어서 EG의 첨가가 발포체의 구조와 물성에 미치는 영향)

  • Baek, Woon-Seon;Lee, Kee-Yoon
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.528-535
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    • 2001
  • Polyurethane specimens were mainly composed of polyol, MDI, silicone surfactant, and water. The effects of ethylene glycol on the cell size, forming magnification, cream time, gel time, take free time, final free rising height, and reactive temperature were investigated. The cyclopentane was used for PU foam as a physical blowing agent. The components were hand-mixed at about 5000 rpm within 4 seconds at room temperature. The mixtures with various ethylene glycol contents were foamed in the wood mold. When the index of isocyanate was fixed, as the amount of ethylene glycol increased, cell size and thermal conductivity were decreased by about 5.1% and 14%, respectively.

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Thermal Lamination of Polyethylene Film on Aluminum by Surface Modification (표면개질을 이용한 폴리에틸렌 필름과 알루미늄간의 열융착)

  • Cho, Dong-Lyun;Yun, Ta-Song
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.594-601
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    • 2001
  • Direct thermal lamination of polyethylene film on aluminum plate without using adhesive was tried by modifying their surfaces to have polar groups. Polyethylene film was modified by treating with oxygen or acrylic acid plasma. Aluminum plate was modified by treating with boiling water or diaminocyclohexane plasma. Fairly high adhesion strength was obtained even in the case when only the polyethylene film was modified, and adhesion strength was so high that film was broken during the adhesion test if both the film and the aluminum plate were modified. Even chemical bonding seemed to be possible when the film treated with acrylic acid was laminated on the plate treated with diaminocyclohexane plasma by forming amide linkage through the reaction between COOH groups on the film surface and NH$_2$ groups on the plate surface.

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