• 제목/요약/키워드: Thermal evolution

검색결과 356건 처리시간 0.024초

산화철의 환원-산화 반응을 이용한 수소저장에 미치는 Rh/Ce/Zr의 효과 (The effect of Rh/Ce/Zr additives on the redox cycling of iron oxide for hydrogen storage)

  • 이동희;차광서;박주식;강경수;김영호
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2007년도 춘계학술대회
    • /
    • pp.49-52
    • /
    • 2007
  • We investigated hydrogen storage and production properties using redox system of iron oxide($Fe_{3}O_{4}$ + $4H_{2}$ ${\leftrightarrows}$ 3Fe + $4H_{2}O$) modified with rhodium, ceria and zirconia under atmospheric pressure. Reduction of iron oxide with hydrogen(hydrogen storage) and re-oxidation of reduced iron oxide with steam(hydrogen evolution) was carried out using a temperature programmed reaction(TPR) technique. On the temperature programmed studies, the effects of amounts of cerium and zirconium on the re-oxidation rate of partial reduced iron oxides were increased with increasing metal additives amount, but the rhodium amount showed little effect on the re-oxidation rate. On the thermal studies, the re-oxidation rates were enhanced with increasing temperature(300 $^{\circ}C$ < 350 $^{\circ}C$).

  • PDF

가열로 내부에서 발생하는 고탄소강 주편의 판파단 원인 분석 (Fracture Analysis of High Carbon Steel Slabs in a Furnace)

  • 김용주;장민지;;정영진;김형섭
    • 소성∙가공
    • /
    • 제29권3호
    • /
    • pp.151-156
    • /
    • 2020
  • In general, the cause of slab cracking during heat treatment has been analyzed with focus on processing conditions. However, in the present work, the cause of cracking is analyzed based on the microstructural evolution during heat treatment. The microstructural analysis indicates that the structure of the slab consists of three main regions as the top, quarter, and center parts. The tensile properties are investigated in each region of the slab in the temperature range from 25 to 350 ℃. Results demonstrate that the cracking is mainly attributed to the thermal stress and specific morphology of the microstructure. It is proposed that the cracking during the heat treatment is related to the presence of inclusion at the ferrite phase which is located at the boundary of pearlite grains.

Construction sequence modelling of continuous steel-concrete composite bridge decks

  • Dezi, Luigino;Gara, Fabrizio;Leoni, Graziano
    • Steel and Composite Structures
    • /
    • 제6권2호
    • /
    • pp.123-138
    • /
    • 2006
  • This paper proposes a model for the analysis of the construction sequences of steel-concrete composite decks in which the slab is cast-in-situ for segments. The model accounts for early age shrinkage, such as thermal and endogenous shrinkage, drying shrinkage, tensile creep effects and the complex sequences of loading due to pouring of the different slab segments. The evolution of the structure is caught by suitably defining the constitutive relationships of the concrete and the steel reinforcements. The numerical solution is obtained by means of a step-by-step procedure and the finite element method. The proposed model is then applied to a composite deck in order to show its potential.

Tensile Characterization of Ceramic Matrix Composites (CMCs) with Nondestructive Evaluation (NDE) Techniques

  • Kim, Jeongguk;Lee, Joon-Hyun
    • 한국복합재료학회:학술대회논문집
    • /
    • 한국복합재료학회 2003년도 추계학술발표대회 논문집
    • /
    • pp.190-194
    • /
    • 2003
  • Two different types of nondestructive evaluation (NDE) techniques were employed to investigate the tensile behavior of ceramic matrix composites (CMCs). Two NDE methods, ultrasonic testing (UT) and infrared (IR) thermography, were used to assess defects and/or damage evolution before and during mechanical testing. Prior to tensile testing, a UTC-scan and a xenon flash method were performed to obtain initial defect information in light of UT C-scans and thermal diffusivity maps, respectively. An IR camera was used for in-situ monitoring of progressive damages. The IR camera measured temperature changes during tensile testing. This paper has presented the feasibility of using NDE techniques to interpret structural performance of CMCs.

  • PDF

탄소강의 펄라이트 변태에 대한 유한요소 해석 (Finite Element Analysis for Pearlite Transformation of Carbon Steel)

  • 탄소강
    • 한국생산제조학회지
    • /
    • 제9권3호
    • /
    • pp.69-75
    • /
    • 2000
  • The object of the research is to estimate for pearlite structure of quenched carbon steels. The effects of temperature on physical properties metallic structures and the latent heat by phase transformation were considered. In this study a set of constitutive equations relevant to the analysis of thermo-elasto plastic materials with pearlite phase transformation during quenching process way presented on the basis of continuum thermo-dynamics. The iso-thermal transformation curve of the SM50C was formlated by cubic spline curve. The formulated equations of evolution in pearlite transformation was used for structure analysis. The volume fraction of pearlite was obtained from the results of calculated metallic structure by Finite element equation.

  • PDF

Nucleic Acid Aptamers: New Methods for Selection, Stabilization, and Application in Biomedical Science

  • Kong, Hoon Young;Byun, Jonghoe
    • Biomolecules & Therapeutics
    • /
    • 제21권6호
    • /
    • pp.423-434
    • /
    • 2013
  • The adoption of oligonucleotide aptamer is well on the rise, serving an ever increasing demand for versatility in biomedical field. Through the SELEX (Systematic Evolution of Ligands by EXponential enrichment), aptamer that can bind to specific target with high affinity and specificity can be obtained. Aptamers are single-stranded nucleic acid molecules that can fold into complex three-dimensional structures, forming binding pockets and clefts for the specific recognition and tight binding of any given molecular target. Recently, aptamers have attracted much attention because they not only have all of the advantages of antibodies, but also have unique merits such as thermal stability, ease of synthesis, reversibility, and little immunogenicity. The advent of novel technologies is revolutionizing aptamer applications. Aptamers can be easily modified by various chemical reactions to introduce functional groups and/or nucleotide extensions. They can also be conjugated to therapeutic molecules such as drugs, drug containing carriers, toxins, or photosensitizers. Here, we discuss new SELEX strategies and stabilization methods as well as applications in drug delivery and molecular imaging.

Impact of Massive Neutrinos and Dark Radiation on the High-Redshift Cosmic Web

  • Rossi, Graziano
    • 천문학회보
    • /
    • 제43권1호
    • /
    • pp.38.1-38.1
    • /
    • 2018
  • With upcoming high-quality data from surveys such as eBOSS or DESI, improving the theoretical modeling and gaining a deeper understanding of the effects of neutrinos and dark radiation on structure formation at small scales are necessary, to obtain robust constraints free from systematic biases. Using a novel suite of hydrodynamical simulations that incorporate dark matter, baryons, massive neutrinos, and dark radiation, we present a detailed study of their impact on Lyman-Alpha forest observables. In particular, we accurately measure the tomographic evolution of the shape and amplitude of the small-scale matter and flux power spectra and search for unique signatures along with preferred scales where a neutrino mass detection may be feasible. We then investigate the thermal state of the intergalactic medium (IGM) through the temperature-density relation. Our results indicate that the IGM at z ~ 3 provides the best sensitivity to active and sterile neutrinos.

  • PDF

Synthesis and electromagnetic properties of FeNi alloy nanofibers using an electrospinning method

  • Lee, Young-In;Choa, Yong-Ho
    • 한국결정성장학회지
    • /
    • 제22권5호
    • /
    • pp.218-222
    • /
    • 2012
  • FeNi alloy nanofibers have been prepared by an electrospinning process followed by air-calcination and H2 reduction to develop electromagnetic (EM) wave absorbers in the giga-hertz (GHz) frequency range. The thermal behavior and phase and morphology evolution in the synthetic processes were systematically investigated. Through the heat treatments of calcination and H2 reduction, as-spun PVP/FeNi precursor nanofiber has been stepwise transformed into nickel iron oxide and FeNi phases but the fibrous shape was maintained perfectly. The FeNi alloy nanofiber had the high aspect ratio and the average diameter of approximately 190 nm and primarily composed of FeNi nanocrystals with an average diameter of ~60 nm. The FeNi alloy nanofibers could be used for excellent EM wave absorbing materials in the GHz frequency range because the power loss of the FeNi nanofibers increased up to 20 GHz without a degradation and exhibited the superior EM wave absorption properties compared to commercial FeNi nanoparticles.

플라이 애쉬를 이용한 다공성 코디어라이트의 합성 및 특성 (Properties and Synthesis of Porous Cordierite from Fly Ash)

  • 김성진;방희곤;박상엽
    • 한국세라믹학회지
    • /
    • 제43권6호
    • /
    • pp.344-350
    • /
    • 2006
  • Porous cordierite was synthesized by the mechano-chemical processing using fly ash. The phase evolution of cordierite was investigated as a function of processing variables such as milling time and sintering temperature. In this study, the phase transition path of cordierite from fly ash was followed by sapprine/spinel ${\to}$ mullite/spinel ${\to}{\alpha}$-cordierite. Porous cordierite fabricated after 32 h of milling time and sintering at $1150^{\circ}C$ showed relatively low thermal expansion coefficient ($2.5{\times}10^{-6}/^{\circ}C\;(25{\sim}1000^{\circ}C$)) and high porosity (75%).