• Title/Summary/Keyword: Thermal diffusing

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Thermal diffusion properties of Zn, Cd, S, and B at the interface of CuInGaSe2 solar cells

  • Yoon, Young-Gui;Choi, In-Hwan
    • Current Photovoltaic Research
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    • v.1 no.1
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    • pp.52-58
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    • 2013
  • Two different window-structured $CuInGaSe_2$(CIGS) solar cells, i.e., CIGS/thin-CdS/ZnO:B(sample A) and CIGS/very thin-CdS/Zn(S/O)/ZnO:B(sample B), were prepared, and the diffusivity of Zn, Cd, S, and B atoms, respectively, in the CIGS, ZnO or Zn(S/O) layer was estimated by a theoretical fit to experimental secondary ion mass spectrometer data. Diffusivities of Zn, Cd, S, and B atoms in CIGS were $2.0{\times}10^{-13}(1.5{\times}10^{-13})$, $4.6{\times}10^{-13}(4.4{\times}10^{-13})$, $1.6{\times}10^{-13}(1.8{\times}10^{-13})$, and $1.2{\times}10^{-12}cm^2/s$ at 423K, respectively, where the values in parentheses were obtained from sample B and the others from sample A. The diffusivity of the B atom in a Zn(S/O) of sample B was $2.1{\times}10^{-14}cm^2/sec$. Moreover, the diffusivities of Cd and S atoms diffusing back into ZnO(sample A) or Zn(S/O)(sample A) layers were extremely low at 423K, and the estimated diffusion coefficients were $2.2{\times}10^{-15}cm^2/s$ for Cd and $3.0{\times}10^{-15}cm^2/s$ for S.

Microstructure and Dielectric Properties of (Sr.Ca)$TiO_3$-based Ceramics Exhibiting nonlinear Characteristics (비선형 특성을 갖는 (Sr.Ca)$TiO_3$계 세라믹의 미세구조 및 유전특성)

  • 최운식;강재훈;김진사;김충혁;조춘남
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.406-409
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    • 2001
  • In this paper, the microstructure and the dielectric properties of the Sr$_{1-x}$ Ca$_{x}$TiO$_3$(0$\leq$$\chi$$\leq$0.2) -based grain boundary layer ceramics were investigated. The specimens were sintered from 142$0^{\circ}C$ to 152$0^{\circ}C$ for 4hr. in $N_2$ gas. The 2nd phase formed by thermal diffusing from the surface lead to a very high apparent dielectric constant, $\varepsilon$$_{r}$>50000. The structural properties of the specimens were studied by X-ray diffraction and SEM, EDX. All specimens exhibited cubic structure. Increasing content of Ca, the peak intensity were decreased.ed.d.

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Voltage-Current Characteristics of (Sr.Ca)$TiO_3$-based Ceramics with contents of Calcite (Ca 변화량에 따른 (Sr.Ca)$TiO_3$계 세라믹의 전압-전류 특성)

  • Choi, Woon-Shik;Kang, Jae-Hun;Seo, Yong-Jin;Lee, Won-Jae
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1384-1386
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    • 2001
  • In this paper, the structural and electrical properties of the $Sr_{1-x}Ca_xTiO_3$($0{\leq}x{\leq}0.2$)-based grain boundary layer ceramics were investigated by X-ray, SEM and V-I system. Increasing content of Ca, the average gram size and the lattice constant were decreased. The relative density of all specimens was > 96%. The 2nd phase formed by thermal diffusing from the surface lead to a very excellent electrical properties, that is, ${\varepsilon}_r$ > 50000, tan${\delta}$ < 0.05, $\Delta$C < ${\pm}$ 10%.

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Endoscopic Laser Irradiation Condition of Urethra in Tubular Structure (관형 요도 조직 대상 내시경적 레이저 조사 조건 연구)

  • Hwarang, Shin;Seonghee, Lim;Yeachan, Lee;Hyun Wook, Kang
    • Journal of Biomedical Engineering Research
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    • v.44 no.1
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    • pp.85-91
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    • 2023
  • Stress urinary incontinence (SUI) occurs when abdominal pressure increases, such as sneezing, exercising, and laughing. Surgical and non-surgical treatments are the common methods of SUI treatment; however, the conventional treatments still require continuous and invasive treatment. Laser have been used to treat SUI, but excessive temperature increase often causes thermal burn on urethra tissue. Therefore, the optimal conditions must be considered to minimize the thermal damage for the laser treatment. The current study investigated the feasibility of the laser irradiation condition for SUI treatment using non-ablative 980 nm laser from a safety perspective through numerical simulations. COMSOL Multiphysics was used to analyze the numerical simulation model. The Pennes bioheat equation with the Beer's law was used to confirm spatio-temporal temperature distributions, and Arrhenius equation defined the thermal damage caused by the laser-induced heat. Ex vivo porcine urethral tissue was tested to validate the extent of both temperature distribution and thermal damage. The temperature distribution was symmetrical and uniformly observed in the urethra tissue. A muscle layer had a higher temperature (28.3 ℃) than mucosal (23.4 ℃) and submucosal layers (25.5 ℃). MT staining revealed no heat-induced collagen and muscle damage. Both control and treated groups showed the equivalent thickness and area of the urethral mucosal layer. Therefore, the proposed numerical simulation can predict the appropriate irradiation condition (20 W for 15 s) for the SUI treatment with minimal temperature-induced tissue.

Growth mechanism of three dimensionally structured TiO2 thin film for gas sensors (가스 감응용 3차원 구조체 TiO2 박막 성장기구)

  • Moon, Hi-Gyu;Yoon, Seok-Jin;Park, Hyung-Ho;Kim, Jin-Sang
    • Journal of Sensor Science and Technology
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    • v.18 no.2
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    • pp.110-115
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    • 2009
  • Polystyrene (PS) microspheres were used to good advantage as a template material to prepare macroporous $TiO_2$ thin films. This is enabled to run the thermal decomposition of the PS without the collapsing of the 3-D macroporous framework during the calcination step. $TiO_2$ thin films were deposited onto the colloidal templated substrates at room temperature by RF sputtering, and then samples were thermally treated at $450^{\circ}C$ for 40.min in air to remove the organic colloidal template and induce crystallization of the $TiO_2$ film. The macroporous $TiO_2$ thin film exhibited a quasi-ordered partially hexagonal close-packed structure. Burst holes, estimated to be formed during PS thermal decomposition, are seen as the hemisphere walls. the inner as well as the outer surfaces of the hollow hemispheres formed by the method of thermal decomposition can be easily accessed by the diffusing gas species. As a consequence, the active surface area interacting with the gas species is expected to be enlarged about by a factor of fourth as large as compared to that of a planar films. Also the thickness at neighboring hemisphere could be controlled a few nm thickness. If the acceptor density becomes as large that depletion width reaches those thickness, the device is in the pinch off-situation and a strong resistance change should be observed.

Diffusion of buried contact grooves with spin-on source (스핀 온 소스를 이용한 함몰형 전극 형성을 위한 확산)

  • A.U. Ebong;S.H. Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.3
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    • pp.424-430
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    • 1996
  • The present processing sequence for solar cells is very elaborate and ads to the cost of the fabricated cells. This processing cost, which accounts for about 30% of the total cost, can be reduced if the many high temperature sequences can be reduced without significantly reducing the cells energy conversion efficiency. By using the spin-on glasses (SOG) in conjunction with the conventional tube furnace (CTF) or rapid thermal annealer (RTA), the many high temperature process can be reduced to only one. In order to achieve efficiencies similar to the standard high temperature sequences using the solid or liquid sources, some basic characterization of the groove diffusion is necessary to ascertain the its suitability. This paper describes the work done in diffusing the buried contact grooves using the phosphorus SOG.

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Analysis of the Carburizing Heat Treatment Process for SNCM Alloy Steel Using the Finite Element Method (유한요소법을 이용한 SNCM 합금강의 침탄열처리 공정 해석)

  • Choi S.C.;Lee D.J.;Kim H.Y.;Kim H.J.
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.10 s.253
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    • pp.1284-1292
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    • 2006
  • Heat treatment is a controlled heating and cooling process to improve the physical and/or mechanical properties of metal products without changing their shapes. Today finite element method is widely used to simulate lots of manufacturing processes including heat treatment and surface hardening processes, which aims to reduce the number of time- and cost-consuming experimental tryouts. In this study we tried, using this method, to simulate the full carburizing process that consists of carburizing, diffusing and quenching, and to predict the distribution of carbon contents, phase fraction and hardness, thermal deformation and other mechanical characteristics as the results. In the finite element analysis deformation, heat transfer, phase transformation and diffusion effects are taken into consideration. The carburizing process of a lock gear, a part of the car seat recliner, that is manufactured by the fine blanking process is adopted as the analysis model. The numerical results are discussed and partly compared with experimental data. And a combination of process parameters that is expected to give the highest surface hardness is proposed on the basis of this discussion.

Study on the electrical properties in the ceramic of (Sr¡¤Ca)Ti${O}_{2}$ system ((Sr.Ca)Ti${O}_{3}$계 세라믹의 전기적 특성에 관한 연구)

  • 최운식;김용주;이준웅
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.44 no.12
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    • pp.1610-1616
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    • 1995
  • The (Sr$_{1-x}$ .Ca$_{x}$)TiO$_{3}$(0.05.leq.x.leq.0.2) ceramics were fabricated to form semiconducting ceramics by sintering at about 1350[.deg. C] in a reducing atmosphere (N$_{2}$ gas). After being fired in a reducing atmosphere, metal oxides, CuO, was painted on the both surface of the specimens to diffuse to the grain boundary. They were annealed at 1100[.deg. C] for 2 hours. The 2nd phase formed by thermal diffusing from the surface lead to a very high apparent dielectric constant. The results of the capacitance-valtage measurements indicated that the grain boundary was composed of the continuous insulating layers. The capacitance is almost unchanged below about 20[V], but decreased slowly over 20[V]. The conduction mechanism of the specimens observed in the temperature range of 25~125[.deg. C], and is divided into three regions having different mechanism as the current increased: the region I below 200[V/cm] shows the ohmic conduction. The region II between 200[V/cm] and 2000[V/cm] can be explained by the Poole-Frenkel emission theory, and the region III above 2000[V/cm] is dominated by the tunneling effect.ct.

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In Situ PCR on the Glass Slide Using the Conventional DNA Thermal Cycler (기존의 핵산증폭기를 사용한 유리슬라이드상에서의 원위치 중합효소 연쇄반응)

  • 오정균;장진수;이재영
    • Korean Journal of Microbiology
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    • v.39 no.3
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    • pp.197-200
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    • 2003
  • In order to establish effective in situ PCR on the glass slide using the conventional DNA thermal cycler, several parameters should be considered. These include full accessibility of PCR reagents into the cells, prevention of diffusing PCR products out of the cells, loss of PCR reagents by nonspecific adherence onto the glass slide, dryness of PCR reagents by heat, and heat conductivity from the heat block to the glass slide. Especially, to guarantee the full accessibility of PCR reagents to sample, relatively higher concentration of PCR reagents (particularly 4.5 mM of $Mg^{++}$) was required while 5 to 10 units/50 ${\mu}l$ reaction of Taq enzyme was enough as long as the step of pre-PCR incubation was included. Dryness of sample was prevented by addition of distilled water into the empty slots in the heat block, thereby providing the reproducible temperature-time profile of PCR. Observed temperature was lower than the programmed temperature by 3 to $4^{\circ}C$.

Phosphorus Cycle in a Deep Reservoir in Asian Monsoon Are3 (Lake Soyang, Korea) and the Modeling with a 2-D Hydrodynamic Water Quality Model [CE-QUAL-W2] (아시아 몬순지역의 대형댐(소양호)에서의 인순환과 2차원모델의 적용)

  • Kim, Yoon-Hee;Kim, Bom-Chul
    • Korean Journal of Ecology and Environment
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    • v.37 no.2 s.107
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    • pp.205-212
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    • 2004
  • Phosphorus cycle was studied in a deep stratified reservoir in summer monsoon area (Lake Soyang, Korea) by surveying phosphorus input from the watershed and the movement of phosphorus within the reservoir. And the spatial and temporal distribution of phosphorus was modeled with a 2-dimensional water quality model (CE-QUAL-W2), Phosphorus loading was calculated by measuring TP in the main inflowing river (the Soyang River) accounting for 90% of watershed discharge. TP of the Soyang River showed a large daily variation with the flow rate. High phosphorus loading occurred during a few episodic storm runoff laden with suspended sediments and phosphorus. Because storm runoff water on rainy days have lower temperature, it plunges into a depth of same temperature (usually below 20m depth), forming an intermediate turbidity layer with a thickness of 20 ${\sim}$ 30 m. Because of stable thermal stratification in summer the intermediate layer water of high phosphorus content was discharged from the dam through a mid-depth outlet without diffusing into epilimnion. The movement of runoff water within the reservoir, and the subsequent distribution of phosphorus were well simulated by the water quality model showing a good accuracy. The major parameter for the calibration of phosphorus cycle was a settling velocity of detritus, which was calibrated to be 0.75 m ${\cdot}$ $day^{-1}$. It is concluded that the model can be a good simulator of limnological phenomena in reservoirs of summer monsoon area.