• Journal of the Korean Solar Energy Society
• /
• v.23 no.1
• /
• pp.29-38
• /
• 2003

To develope chemical heat pump using available energy sources, solar heat and other kinds of waste thermal energy, we have studied the material and heat transfer rate in the cylindrical bed reactor packed with Calcined Dolomite. Our results from the studies are as follows ; 1 The time needed to complete dehydration reaction at the wall side of the cylindrical reactor(r/rL=0.5) was shorter than that of the center(r/rL=0.0) as much as 12%. 2. Two dimensional (radial and circumferential) partial differential equations, concerning heat and mass transfer rate in the packed bed of calcined Dolomite, are solved numerically to describe the characteristics of the reaction in the cylindrical reactor. The solution reads rate of reaction in the packed bed reactor depends on the temperature and concentration of reactants. These results read the supplied heat transfers from the wall side of the cylinder to the center, dehydration reaction begins at the inner side of the wall of the cylindrical reactor and the dehydration reaction proceeds from the wall side to center of cylinder.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.7 no.4
• /
• pp.104-112
• /
• 2012

This study involves investigating the correlation between variation of internal structure and heating temperature of alkali-activated fire protection materials using fly ash. Dehydration and micro crack thermal expansion occur in cement hydrates of cementitious materials heated by fire. Internal structure difference due to both the dehydration of cement hydrates and pore solution causes and influences changes in the properties of materials. Also, this study is concerned with change in microstructure and dehydration of the alkali-activated fire protection materials at high temperatures. The testing methods of alkali-activated fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. The study results show that the alkali-activated fire resistant finishing material composed of potassium hydroxide, sodium silicate and fly ash has the high temperature thermal stability. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction.

• Journal of Microbiology and Biotechnology
• /
• v.29 no.7
• /
• pp.1053-1060
• /
• 2019

Thermal drying is a common process used in the food industry for the modification of agricultural products. However, while various studies have investigated the alteration in physiochemical properties and chemical composition after drying, research focusing on the relationship between different dehydration conditions and bioactivity is scarce. In the current study, we prepared dried ginger under nine different conditions by varying the processing time and temperature and compared their immunomodulatory effects. Interestingly, depending on the drying condition, there were significant differences in the immunestimulating activity of the dried ginger samples. Gingers processed at $50^{\circ}C$ 1h displayed the strongest activation of macrophages measured by $TNF-{\alpha}$ and IL-6 levels, whereas, freezedried or $70^{\circ}C$- and $90^{\circ}C$-dried ginger showed little effect. Similar results were recapitulated in primary bone marrow-derived macrophages, further confirming that different dehydration conditions can cause significant differences in the immune-stimulating activity of ginger. Induction of ERK, p38, and JNK signaling was found to be the major underlying molecular mechanism responsible for the immunomodulatory effect of ginger. These results highlight the potential to improve the bioactivity of functional foods by selectively controlling processing conditions.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.19 no.8
• /
• pp.785-789
• /
• 2006

BiSrCaCuO(2223) superconductor was fabricated by the thermal pyrolysis method. The superconducting precursor produced by the dehydration of the gel at $120^{\circ}C$ for 12 h is not in the amorphous state as expected but in a crystalline state. In this paper, the establishment of fabrication condition was examined so as to improve the related properties to the practical use of BiSrCaCuO superconductor, and we reported the production of the BiSrCaCuO by the pyrolysis method.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2020.06a
• /
• pp.140-141
• /
• 2020

Concrete has a lower thermal conductivity or thermal diffusion coefficient compared to other building materials, so it is widely used as fireproof compartment material or refractory material for structures. However, in the event of thermal damage such as fire, cement curing agents and aggregates act differently, resulting in heat generation or deterioration of tissue due to dehydration, resulting in deterioration of physical properties and fire resistance. Therefore, in this study, the processing structure of cement paste is measured through nitrogen absorption method. The test specimen is a cement paste of 40% W/C and is set at 1000 ℃ under heating temperature conditions. As the temperature rose, the micro-pore mass below was reduced based on about 0.01 감소m, but the air gap above that was increased.Thus, in the range of pores measured in nitrogen adsorption, the air mass tended to decrease under high temperature conditions.

• Journal of the Korean Ceramic Society
• /
• v.13 no.2
• /
• pp.31-38
• /
• 1976

Korean tremoitic talc, wollastonite and clay have been used to develop a wall tile body to appropriate to the fast firing process. Some of ceramic properties of the raw materials were investigated by X-ray diffraction, thermal analysis and chemical analysis. The body compositions were formulated from the range of 35~75% tremolitic talc, 0~30% wollastonite and 25~35% plastic clay. Thermal gravity analysis and thermal expansion were tested for each of unfired bodies to study the correlation between thermal dehydration and linear shrinkage during the firing procedure. Linear shrinkage and water absorption of the fired bodies at the various temperature were taken as a measures for determining the proper firing range of the bodies. Increasing the content of wollastonite and firing temperature, the thermal expansion of the fired body showed the gradual decrease, and the thermal expansion curves showed a tendency to straighten. These observations may be resulted from the fact that the amounts of diopside and anorthite formed were gradually increased and those of quartz relatively decreased. The optimum compositions of the wall tile bodies for fast firing are 30% clay, 10~20% wollastonite and 50~60% tremolitic talc.

• Journal of the Korean Society of Safety
• /
• v.16 no.2
• /
• pp.75-79
• /
• 2001

For handling and storage of reactive chemicals, the hazard evaluations have been extremely important. In the chemical industry, the most concerns are focused on the thermal harzards such as runaway reactions and thermal decompositions, which are mostly governed by thermodynamics and reaction kinetics or these reactive chemical in the system. This study no investigated the thermal decomposition characteristics of nitrophenylhydrazine isomers by using differential scanning calorimeter(DSC) and accelerating rate calorimeter(ARC). Experimental results showed that exothermic onset-temperatures in nitrophenylhydrazine(NPH) isomers were about 160-$210^{\circ}C$ by DSC and 100-$150^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about 50-$60^{\circ}C$ lower than that by DSC. Reaction heats were about 40-100cal/g by DSC and 330-750ca1/g by ARC. While ortho isomer of NPH show two distinct exothermic peaks, para isomer shows a single peak in DSC curves. The first exothermic peak for 2-NPH is mainly due to intramolecular dehydration forming 1-hydroxybenzotriazole(HOBT) and the second exothermic peak is mainly due to the decomposition of HOBT formed in the first step of decomposition. The exothermin peak in the DSC curve for 4-NPH is mainly due to dissociation of hydrazino and nitro groups.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2003.11a
• /
• pp.509-512
• /
• 2003

Dehydration and micro crack thermal expansion occur in cement hydrates of concrete structure heated by fire for a long time. The characteristic of concrete exposed to high temperature can be analyzed from distribution of porosity and pore size. Porosity showed a tendency to increase irrespective of specimen types. This is due to both the outbreak of collapse of gel comprising the cement and a micro crack by heating. Porosity did not affect the variety of specimen and increased with the same tendency throughout every specimen. In addition, the deteriorate of compressive strength resulted from increase in porosity

• Bulletin of the Korean Chemical Society
• /
• v.11 no.5
• /
• pp.403-406
• /
• 1990

Two types of new silica catalysts modified with benzenesulfonic acid derivatives were prepared by esterification or phenylation followed by sulfonation. Both catalysts thus prepared were tested as acid catalysts for 2-propanol dehydration and cumene dealkylation reactions. B catalyst () were more active than A catalyst (). Highter catalytic activity for B catalyst may be accounted for by higher resistance to water, higher acid strength, more acidity, and better thermal stability as compared with A catalyst.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.29 no.2
• /
• pp.61-70
• /
• 2019

Geopolymer is an eco-friendly construction material that has various advantages such as reduced $CO_2$ emission, fire resistance and low thermal conductivity compared to cement. However, it has not been many studies on the thermal behavior of the surface of the geopolymer panel when flame is applied to the surface. In this study, surface characteristics of hardened geopolymer on flame exposure was investigated to observe its characteristics as heat-resistant architectural materials. External structure changes and crack due to the heat shock were not observed during the exposure on flame. According to the residue of calcite and halo pattern of aluminosilicate gel, decarboxylation and dehydration were extremely limited to the surface and, therefore, it is thought that durability of hardened geopolymer was sustained. Gehlenite and calcium silicate portion was inversely proportional to quartz and calcite and significantly directly proportional to BFS replacement ratio. Microstructure changes due to the thermal shock caused decarboxylation and dehydration of crystallization and it was developed the pore and new crystalline phase like calcium silicate and gehlenite. It is thought that those crystalline phase worked as a densification and strengthening mechanism on geopolymer panel surface.