• 한국화재소방학회논문지
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• 제13권2호
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• pp.26-32
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• 1999

쌀겨분진의 연소 및 전기적 점화에너지에 의한 폭발 위험성을 조사하기 위하여 시차주사열량계(DSC, Differential Scanning Calorimeter) 및 열중량 분석기(TGA, Thermogravimetric Analysis)와 순간승압조정기를 이용하여 온도 및 전기 스파크에 따른 발열개시온도, 발열량 등을 조사하였으며, 또한 Hartman 식 측정장치를 이용하여 쌀겨분진의 폭발 위험성을 측정하고자 하였다. DSC 분석 결과 대기 분위기에서 발열량이 증가하였으며 또한 승온속도가 증가하고 입도가 미세해질수록 발열량이 증가하였고, TGA 분석 결과 입도가 미세해질수록 분해량이 증가하였다. 한편 쌀겨분진의 폭발 위험성은 입도가 감소하고 농도가 증가할수록 또한 전기적 점화에너지가 클수록 폭발압력이 증가하였으며, 전기 점화원에 인가된 전압변화에 따른 폭발압력의 변화를 조사하였고, 50/60 mesh, 1.5mg/㎤에서 약 13.5kgf/$\textrm{cm}^2$의 최대 폭발압력을 나타내었다.

• 공업화학
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• 제10권8호
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• pp.1141-1146
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• 1999

PA6/PP-g-MA 블렌드계에 상용성 충격개선제로서 SEBS-g-MA를 첨가하여 용융혼합하였고 기계적 물성과 모폴로지 변화를 조사하였다. SEBS-g-MA의 첨가에 의해 인장강도는 약간 감소하지만 파단신율은 증가하였다. 충격강도는 PP-g-MA와 SEBS-g-MA 함량이 증가할수록 증가하였다. 이는 무수말레산의 카르복시기와 아마이드의 반응에 의해 계면접착력과 상용성의 개선이 이루어졌기 때문이다. Dynamic mechanical thermal analyzer(DMTA)를 이용한 tan ${\delta}$의 변화에서도 전형적인 고분자 블렌드의 상용화거동을 보였다. 최종적으로 이 블렌드물의 상구조를 관찰한 결과에서도 SEBS-g-MA의 첨가에 따라 분산상의 크기가 감소하는 것으로 보아 상용성과 계면접착력이 개선됨을 확인하였다.

• 한국수소및신에너지학회논문집
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• 제19권5호
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• pp.367-376
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• 2008

To obtain the data of the pressure loss and differential pressure at the inside of the stack that was composed of 126 cells with 7,500 cm2 electrode area, 75kW molten carbonate fuel cell system has been operated. Computational fluid dynamics was applied to estimate reactions and thermal fluid behavior inside of the stack that was adopted with internal manifold type separator. The pressure loss coefficient K showed 72.29 to 84.01 in anode and 6.34 to 8.75 in cathode at low part of cells at the inside of 75 kW MCFC stack respectively. Meanwhile, the pressure loss coefficient of the higher part of cells at the interior of the stack showed 15.36 and 56.44 in anode and cathode respectively. These results mean that there is no big total pressure difference between anode and cathode at the inner part of 75 kW MCFC stack. This result will be reflected in 250kW MCFC system design.

• 천문학회보
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• 제36권2호
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• pp.155.1-155.1
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• 2011

The Korea Astronomy and Space Science Institute (KASI) and the Department of Astronomy at the University of Texas at Austin (UT) are developing a near infrared wide-band high resolution spectrograph, IGRINS (Immersion Grating Infrared Spectrograph). The white-pupil design of the instrument optics uses 7 cryogenic mirrors including 3 aspherical off-axis collimators and 4 flat fold mirrors. Two of the 3 collimators are H- and K-band pupil transfer mirrors and they are designed as compensators for the system alignment in each channel. Therefore, their mount design will be one of the most sensitive parts in the IGRINS optomechanical system. The other flat fold mirrors are designed within the limited area. Each of those includes the features of 3 axial hard points and 2 radial hard points with one spring plunger in order for the proper deflection of the mirror. The design work will include the computer-aided 3D modeling and finite element analysis (FEA) to optimize the structural stability and the thermal behavior of the mount models. The mount body will also include a tip-tilt and translation adjustment mechanism to be used as the alignment compensators.

• Computers and Concrete
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• 제26권1호
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• pp.75-94
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• 2020

The aim of this research is to investigate free vibration of a novel five layer Timoshenko microbeam which consists of a transversely flexible porous core made of Al-foam, two graphen platelets (GPL) nanocomposite reinforced layers to enhance the mechanical behavior of the structure as well as two piezo-magneto-electric face sheets layers. This microbeam is subjected to a thermal load and resting on Pasternak's foundation. To accomplish the analysis, constitutive equations of each layer are derived by means of nonlocal strain gradient theory (NSGT) to capture size dependent effects. Then, the Hamilton's principle is employed to obtain the equations of motion for five layer Timoshenko microbeam. They are subsequently solved analytically by applying Navier's method so that discretized governing equations are determined in form of dynamic matrix giving the possibility to gain the natural frequencies of the Timoshenko microbeam. Eventually, after a validation study, the numerical results are presented to study and discuss the influences of various parameters such as nonlocal parameter, strain gradient parameter, aspect ratio, porosity, various volume fraction and distributions of graphene platelets, temperature change and elastic foundation coefficients on natural frequencies of the sandwich microbeam.

• 동력기계공학회지
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• 제22권1호
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• pp.79-86
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• 2018

Many countries have conducted extensive studies for biomass co-firing to enhance the durability of reactor on high-temperature corrosion. However, due to the complicated mechanisms of biomass co-firing, there have been limitations in accurately determining the current state of corrosion and predicting the potential risk of corrosion of power plant. In order to solve this issue, this study introduced Lab-scale corrosion system to analyze the corrosion characteristics of the A213 T91 material under the biomass co-firing conditions. The corrosion status of the samples was characterized using SEM/EDS analysis and mass loss measurement according to various biomass co-firing conditions such as corrosion temperature, $SO_2$ concentration, and corrosion time. As a result, the corrosion severity of A213 T91 material was gradually increased with the increase of $SO_2$ concentration in the reactor. When $SO_2$ concentration was changed from 0 ppm to 500 ppm, both corrosion severity and oxide layer thickness were proportionally increased by 15% and 130%, respectively. The minimum corrosion was observed when the corrosion temperature was $450^{\circ}C$. As the temperature was increased up to $650^{\circ}C$, the faster corrosion behavior of A213 T91 was observed. A213 T91 was observed to be more severely corroded by the effect of chlorine, resulting in faster corrosion rate and thicker oxide layer. Interestingly, corrosion resistance of A213 T91 tended to gradually decrease rather than increases as the oxide layer was formed. The results of this study is expected to provide necessary research data on boiler corrosion in biomass co-firing power plants.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2005년도 춘계학술발표대회 개요집
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• pp.387-392
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• 2005

For the production of further functional bio-degradable plastic(polybutylene succinate:PBS) with $TiO_{2}$ as photocatalyst, which shows the decomposition of detrimental organic compound and pollutant under ultraviolet irradiation, we attempted to prepare $TiO_{2}$ coatings on PBS substrate by HVOF and plasma spraying techniques under various conditions. The microstructures of coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of coatings was evaluated through the photo degradation of gaseous acetaldehyde. The effects of primary particle size and spraying parameters on the formation behavior, photo catalytic performance and mechanical characteristics of the coatings have been investigated. The results indicated that with respect to both the HVOF sprayed $P_{200}$ and $P_{30}$ coatings, the high anatase ratio off 100% can be achieved regardless of fuel gas pressure. On the other hand, the HVOF sprayed $P_{7}$ coating exhibited largely decreased anatase ratio (from 100% to 49.1%) with increasing the fuel gas pressure, which may be attributed to the much higher susceptibility to heat of 7nm agglomerated powder. In terms of photocatalytic efficiency, HVOF sprayed $P_{200}$ and $P_{30}$ coatings seem to predominate as compared to that of plasma sprayed $P_{200}$ coatings owing to the higher anatase ratio. However, the HVOF sprayed $P_{7}$ coatings didn't show the photo catalytic activity, which may result from the extremely small reaction surface area to the photo-catalytic activity and low anatase ratio. Such functional PBS with new roles is expected to cosiderably contribute to the reduction of aggravated environmel problem.

• 한국결정성장학회지
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• 제10권6호
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• pp.407-411
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• 2000

전자 package용 저온봉착 유리를 실험적으로 합성하고 이 유리의 결정화 거동을 비등온 조건하에서 열분석기(DTA)를 이용하여 조사하였다. 이 유리의 조성을 미량의 CaO, $SiO_2$$A1_2$$O_3$ 및 $P_2$$O_5$ 등이 함유된 PbO-ZnO-$B_2$$O_3$-$TiO_2$유리로부터 결정하였다. 연 티탄산염($PbTiO_3$)생성에 해당되는 결정화 발열이 관찰되었다. 이 $PbTiO_3$의 결정화는 삼차원과정으로 진행되었고 유리기지(glass matrix)로부터 생성되는 이 결정의 평균 활성화에너지는 223$\pm$3 kJ/mo1 이었다.

• 대한화학회지
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• 제33권1호
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• pp.65-69
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• 1989

방사성 바륨 또는 방사성 란탄 추적자를 함유하고 있는 Ba(NO$_3)_2$ 와 TiO(NO$-3)_2$의 무기혼합용액을 옥살산의 에탄올 용액으로 적정하므로써 바륨티탄닐의 옥살산 염을 합성하였고, 이를 1000$^{\circ}$C에서 하소시켜 BaTiO$_3$를 만들었다. 옥살산염의 분석결과는 BaTiO(C$_2O_4)_2{\cdot}4H_2O$이며, 무기혼합용액중 Ba/Ti의 몰비가 0.950∼1.05 범위 내에서 화학양론적 결합으로 합성됨을 방사성 바륨 추적자의 도움으로 쉽게 확인하였고, Perovskite형의 구조임을 XRD로 확인하였다. 그리고 란탄 첨가제가 침전에 화학적으로 균일하게 혼입됨은 방사성 란탄의 추적자 실험으로 발견하였다. 이와 같은 실험적 사실로부터 침전물의 구성 성분의 결합이 분자준위에서 일어나고 또 티탄산바륨이 단일상의 결정임을 설명하였다.

• 한국전기전자재료학회논문지
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• 제21권11호
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• pp.968-972
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• 2008

Ni/Ti/Al multilayer system ('/'denotes the deposition sequence) was tested for low-resistance ohmic contact formation to Al-implanted p-type 4H-SiC. Ni 30 nm / Ti 50 nm / Al 300 nm layers were sequentially deposited by e-beam evaporation on the 4H-SiC samples which were implanted with Al (norminal doping concentration = $4\times10^{19}cm^{-3}$) and then annealed at $1700^{\circ}C$ for dopant activation. Rapid thermal anneal (RTA) temperature for ohmic contact formation was varied in the range of $840\sim930^{\circ}C$. Specific contact resistances were extracted from the measured current vs. voltage (I-V) data of linear- and circular transfer length method (TLM) patterns. In constrast to Ni contact, Ni/Ti/Al contact shows perfectly linear I-V characteristics, and possesses much lower contact resistance of about $2\sim3\times10^{-4}\Omega{\cdot}cm^2$ even after low-temperature RTA at $840^{\circ}C$, which is about 2 orders of magnitude smaller than that of Ni contact. Therefore, it was shown that RTA temperature for ohmic contact formation can be lowered to at least $840^{\circ}C$ without significant compromise of contact resistance. X-ray diffraction (XRD) analysis indicated the existence of intermetallic compounds of Ni and Al as well as $NiSi_{1-x}$, but characteristic peaks of $Ti_{3}SiC_2$, a probable narrow-gap interfacial alloy responsible for low-resistance Ti/Al ohmic contact formation, were not detected. Therefore, Al in-diffusion into SiC surface region is considered to be the dominant mechanism of improvement in conduction behavior of Ni/Ti/Al contact.